CN104877402A - Compound water-based inorganic anticorrosive paint and preparation method - Google Patents
Compound water-based inorganic anticorrosive paint and preparation method Download PDFInfo
- Publication number
- CN104877402A CN104877402A CN201510274269.3A CN201510274269A CN104877402A CN 104877402 A CN104877402 A CN 104877402A CN 201510274269 A CN201510274269 A CN 201510274269A CN 104877402 A CN104877402 A CN 104877402A
- Authority
- CN
- China
- Prior art keywords
- preparation
- inorganic anti
- corrosion paint
- anticorrosive paint
- zinc powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to an anticorrosive paint, particularly to a compound water-based inorganic anticorrosive paint with the functions of cathode protection and anti-static electricity and a preparation method. The compound water-based inorganic anticorrosive paint comprises the following components in mass percent: 0.1-4% of oxidized graphene, 22-34% of zinc powder, 1-3% of attapulgite AT, 15-18% of potassium silicate, 11% of iron oxide red, 30-45% of distilled water and 0.2-0.8% of sodium polyacrylate. The anticorrosive paint has the characteristics that oxidized graphene and zinc powder are used as the main raw materials of the anticorrosive paint, the use amount of zinc powder is greatly reduced, the electrical conductivity and hardness of the paint are improved, the technology is simple, the anticorrosive paint is green, environment-friendly and good in corrosion resistance, and can be applicable to anticorrosive painting of various metal pipelines and metal members.
Description
Technical field
The present invention relates to a kind of protective system, be specifically related to a kind of to there is cloudy guarantor and antistatic property
Compound waterborne inorganic anti-corrosion paint and preparation method.
Technical background
Zinc-rich paint is a kind of protective system with galvanic protection effect; in zinc-rich paint, the content of zinc powder is very high; can up to 90% (weight ratio); like this in its dry film between zinc particle; contact with each other between zinc powder and steel substrate; under this kind of state; when moisture invades in paint film; namely microbattery is formed between zinc powder and steel substrate; because zinc is the metal (current potential is low) sprinkled than ironwork in electrochemistry; so just flow through anticorrosive current from zinc powder to iron and steel, thus cathode protection effect is played to iron and steel.
Also there is a lot of problem in current zinc-rich paint, the general weathering resistance of organic coating, thermotolerance are not fine, and physical strength is not high, and easily aging, electric conductivity is low, is unfavorable for galvanic protection; Solvent based coating VOC content is high, during dried coating film, volatilizes organic gas inflammable, explosive, poisonous in a large number, and large to human injury, potential safety hazard is high, and environmental pollution is large; Water-borne coatings is the direction of future development on the whole, but in actual applications, still there is a lot of problem, as the time of doing solid work is longer, to envrionment temperature and humidity requirement high, bad to iron and steel sticking power, easily cause ablation etc.; The current Problems existing of inorganic zinc coating mainly concentrates in the research to its auxiliary aid, particularly high-module silicate zinc-rich paint has very outstanding antiseptic property, the occasion of multiple circumstance complication can be applied to, but deposit free settling, the large easily gel of viscosity, these are all problem demanding prompt solutions.
Theoretically, zinc content is higher, and galvanic protection effect is better; But; difference due to corrosive environment in Practical Project often falls flat; as; in the place that water-wet is serious; in film, the stripping of zinc powder is more severe, and what at this moment zinc content was large easily causes paint blister, and therefore during application, zinc content can not be too high; general not higher than 70%, this just have impact on galvanic protection effect greatly.
For solving the problem, product of the present invention adopts graphene oxide and the composite making protective system of zinc powder, namely ensure that anticathode protects the contact of the most basic condition-metal/metal, has again good mechanical property and antiseptic property.
Summary of the invention
The object of the invention is to produce that a kind of antiseptic property is good, physical strength is high, sticking power is large, eco-friendly zinc-rich paint.
Compound waterborne inorganic anti-corrosion paint of the present invention, its component calculates according to mass percent and is:
Graphene oxide 0.1 ~ 4%, zinc powder 22 ~ 34%(is less than 700 orders), attapulgite (AT) 1 ~ 3%, potassium silicate 15 ~ 18% (ratio of Si:K SiO
2: K
2o is 2 ~ 4), red iron oxide 11%, distilled water 30 ~ 45%, sodium polyacrylate 0.2 ~ 0.8%.
Graphene oxide involved in the present invention has excellent electroconductibility, preservative property and surface hydrophobicity; Zinc powder is comparatively active a kind of metal, plays the galvanic protection effect of sacrificial anode; Attapulgite be a kind of have chain Rotating fields containing the U.S. silicate clay mineral in Shuifu County, dissemination is risen to Graphene and zinc powder, can effectively prevent coating precipitated and separated, be easy to brushing, and there is stronger resistance to acids and bases and erosion resistance.
Material mentioned by the present invention all can be commercially.
Efficient compound aqueous inorganic anti-corrosion paint preparation method of the present invention is simple, is completed by following steps:
(1) by graphene oxide and zinc powder mixing, stir at 60 ~ 70 DEG C and make powder.
(2) potassium silicate, red iron oxide, distilled water, sodium polyacrylate are uniformly mixed at 35 ~ 45 DEG C make base-material.
(3) the above-mentioned powder for preparing and base-material are mixed with attapulgite (AT), stir at 50 ~ 55 DEG C and make coating.
The stirring of described step 1 refers to stirs 90 minutes with 2000 ~ 2500r/min.
The stirring of described step 2 refers to stirs 45 minutes with 1200 ~ 1500r/min.
The stirring of described step 3 refers to stirs 45 minutes with 1500 ~ 1700r/min.
Described graphene oxide is less than 500 object Graphene powder for raw material with particle, adopts wet chemical oxidation method (Hummers) to prepare.
the present invention has following beneficial effect:
It is as follows that Compound waterborne inorganic anti-corrosion paint of the present invention detects analytical results:
(1) sticking power/level: 1 ~ 2; Opacifying power (g/m2): 630; Hardness: > 6H.
(2) water tolerance (50d): unchanged; Wet-heat resisting (80 DEG C, 100%RH30d) is unchanged; Resistance to gasoline (30d): unchanged; Salt water resistance: (3% salt solution room temperature 50d) is unchanged; Salt spray resistance (1000h) is non-foaming, wrinkle resistant.
(3) electroconductibility (resistivity) < 10
4Ω/cm.
In addition, the beneficial effects such as the anticorrosion coating that simple, with low cost, the environmental protection of present invention process, antiseptic property be good, be applicable to all kinds of metallic conduit and hardware.
(1) adopt graphene oxide can greatly reduce zinc powder consumption, improve coating adhesion, electroconductibility and hardness.
(2) attapulgite is adopted obviously to improve zinc powder and the phenomenon such as Graphene is easily reunited, precipitation.
(3) after solidification, coating has good sticking power, shock-resistance, snappiness, electroconductibility; There is long-acting the moon and protect preservative effect, be applicable to the anticorrosion coating of all kinds of metallic conduit and hardware.
(4) this product environmental protection, construction safety.
Embodiment
embodiment 1:
0.2Kg graphene oxide is mixed with 30Kg zinc powder and drops into agitator, stir with 2000r/min speed at 70 DEG C and obtain powder in 90 minutes; Drop into 17Kg potassium silicate, then the mixing of 35Kg distilled water adds 11Kg red iron oxide as solvent, finally drops into 0.8Kg sodium polyacrylate, stirs obtain base-material in 45 minutes at 35 DEG C with 1200r/min speed; Powder and base-material mixed and adds 1Kg attapulgite, at 50 DEG C, stirring 45 minutes with 1500r/min speed, obtaining finished product Compound waterborne inorganic anti-corrosion paint.
Coating property detected result:
(1) sticking power/level: 1; Opacifying power (g/m2): 646; Hardness: 6.3H.
(2) water tolerance (50d): unchanged; Wet-heat resisting (80 DEG C, 100%RH35d) is unchanged; Resistance to gasoline (35d): unchanged; Salt water resistance: (3% salt solution room temperature 60d) is unchanged; Salt spray resistance (1700h) is non-foaming, wrinkle resistant.
(3) electroconductibility (resistivity): 0.6 × 10
4Ω/cm.
embodiment 2:
1.3Kg graphene oxide is mixed with 28Kg zinc powder, stirs with 2500r/min speed at 60 DEG C and obtain powder in 90 minutes.
Using 16Kg potassium silicate, the mixing of 35Kg distilled water as solvent, then add 11Kg red iron oxide, 0.7Kg sodium polyacrylate to stir with 1500r/min speed at being blended in 45 DEG C and obtain base-material in 45 minutes; By powder and base-material mix and blend, add 2Kg attapulgite, at 55 DEG C, stir 45 minutes with 1700r/min speed, obtain finished product Compound waterborne inorganic anti-corrosion paint.
Coating property detected result:
(1) sticking power/level: 1; Opacifying power (g/m2): 644; Hardness: 6.7H.
(2) water tolerance (50d): unchanged; Wet-heat resisting (80 DEG C, 100%RH38d) is unchanged; Resistance to gasoline (40d): unchanged; Salt water resistance: (3% salt solution room temperature 62d) is unchanged; Salt spray resistance (1700h) is non-foaming, wrinkle resistant.
(3) electroconductibility (resistivity): 0.3 × 10
4Ω/cm.
embodiment 3:
Stir with 2200r/min speed at 2.1Kg graphene oxide and 28.5Kg zinc powder are blended in 65 DEG C and obtain powder in 90 minutes.
Using 18Kg potassium silicate, the mixing of 34Kg distilled water as solvent, then add 11Kg red iron oxide, 0.4Kg sodium polyacrylate to stir with 1500r/min speed at being blended in 40 DEG C and obtain base-material in 45 minutes; By powder and base-material mix and blend, add 2Kg attapulgite, at 52 DEG C, stir 45 minutes with 1500r/min speed, obtain finished product Compound waterborne inorganic anti-corrosion paint.
Coating property detected result:
(1) sticking power/level: 1; Opacifying power (g/m2): 652; Hardness: 6.6H.
(2) water tolerance (50d): unchanged; Wet-heat resisting (80 DEG C, 100%RH37d) is unchanged; Resistance to gasoline (39d): unchanged; Salt water resistance: (3% salt solution room temperature 63d) is unchanged; Salt spray resistance (1800h) is non-foaming, wrinkle resistant.
(3) electroconductibility (resistivity): 0.1 × 10
4Ω/cm.
Claims (8)
1. a Compound waterborne inorganic anti-corrosion paint, is characterized in that: component calculates according to mass percent and is:
Graphene oxide 0.1 ~ 4%, zinc powder 22 ~ 34%, attapulgite AT 1 ~ 3%, potassium silicate 15 ~ 18%, red iron oxide 11%, distilled water 30 ~ 45%, sodium polyacrylate 0.2 ~ 0.8%.
2. a kind of Compound waterborne inorganic anti-corrosion paint as claimed in claim 1, is characterized in that: described zinc powder is less than 700 orders.
3. a kind of Compound waterborne inorganic anti-corrosion paint as claimed in claim 1, is characterized in that: the ratio of Si:K SiO of described potassium silicate
2: K
2o is 2 ~ 4.
4. the preparation method of a kind of Compound waterborne inorganic anti-corrosion paint as claimed in claim 1, is characterized in that step is as follows:
(1) by graphene oxide and zinc powder mixing, stir at 60 ~ 70 DEG C and make powder;
(2) potassium silicate, red iron oxide, distilled water, sodium polyacrylate are uniformly mixed at 35 ~ 45 DEG C make base-material;
(3) the above-mentioned powder for preparing and base-material are mixed with attapulgite AT, stir at 50 ~ 55 DEG C and make coating.
5. the preparation method of a kind of Compound waterborne inorganic anti-corrosion paint as claimed in claim 4, is characterized in that: the stirring of described step (1) refers to stirs 90 minutes with 2000 ~ 2500r/min.
6. the preparation method of a kind of Compound waterborne inorganic anti-corrosion paint as claimed in claim 4, is characterized in that: the stirring of described step (2) refers to stirs 45 minutes with 1200 ~ 1500r/min.
7. the preparation method of a kind of Compound waterborne inorganic anti-corrosion paint as claimed in claim 4, is characterized in that: the stirring of described step (3) refers to stirs 45 minutes with 1500 ~ 1700r/min.
8. the preparation method of a kind of Compound waterborne inorganic anti-corrosion paint as claimed in claim 4, is characterized in that: described graphene oxide is less than 500 object Graphene powder for raw material with particle, adopts wet chemical oxidation method to prepare.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510274269.3A CN104877402A (en) | 2015-05-27 | 2015-05-27 | Compound water-based inorganic anticorrosive paint and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510274269.3A CN104877402A (en) | 2015-05-27 | 2015-05-27 | Compound water-based inorganic anticorrosive paint and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104877402A true CN104877402A (en) | 2015-09-02 |
Family
ID=53945095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510274269.3A Pending CN104877402A (en) | 2015-05-27 | 2015-05-27 | Compound water-based inorganic anticorrosive paint and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104877402A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105566973A (en) * | 2015-10-29 | 2016-05-11 | 中国航空工业集团公司北京航空材料研究院 | Cold-spraying-zinc anticorrosive paint with graphene and method for preparing cold-spraying-zinc anticorrosive paint |
| CN106118364A (en) * | 2016-07-08 | 2016-11-16 | 上海晶顿科技有限公司 | A kind of graphene oxide anticorrosive paint |
| CN106366712A (en) * | 2016-09-09 | 2017-02-01 | 常州大学 | Graphene conductive anticorrosive coating |
| CN106634320A (en) * | 2016-09-09 | 2017-05-10 | 常州大学 | Silicone acrylate emulsion and graphene oxide-modified inorganic paint and preparation method thereof |
| CN107141850A (en) * | 2017-06-30 | 2017-09-08 | 广东美的厨房电器制造有限公司 | A kind of coating of hydrophilic high-antistatic performance and preparation method thereof |
| CN107384045A (en) * | 2017-08-08 | 2017-11-24 | 肥西县通力机械有限公司 | A kind of excavating machinery surface weather-resistant coating |
| CN108285719A (en) * | 2017-03-06 | 2018-07-17 | 苏州鼎烯聚材纳米科技有限公司 | A kind of low zinc content anticorrosive paint and its application |
| CN108610676A (en) * | 2016-12-08 | 2018-10-02 | 辽宁法库陶瓷工程技术研究中心 | A kind of high temperature resistant graphene corrosion-inhibiting coating and preparation method thereof |
| CN108753112A (en) * | 2018-06-29 | 2018-11-06 | 佛山腾鲤新能源科技有限公司 | A kind of preparation method of conductive coating |
| CN109021621A (en) * | 2018-07-25 | 2018-12-18 | 广东好邦石墨烯新材料科技有限公司 | A kind of zinc powder of graphene modified, preparation method and its application in water-based anticorrosive paint |
| CN110218469A (en) * | 2019-06-25 | 2019-09-10 | 东方电气集团东方汽轮机有限公司 | A kind of high temperature resistant graphene conductive water-based anticorrosive paint |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1288028A (en) * | 2000-10-11 | 2001-03-21 | 武汉锐普科技有限责任公司 | Water soluble inorganic ceramic zinc silicate anti-corrosive paint |
| CN1676550A (en) * | 2004-04-01 | 2005-10-05 | 北京中科远迪高新技术有限公司 | Water-soluble zinc-rich anticorrosive coating |
| CN101418150A (en) * | 2007-10-24 | 2009-04-29 | 廊坊中科远迪化工防腐技术有限公司 | Novel waterborne zinc-rich anti-corrosive paint |
| CN103173095A (en) * | 2013-03-06 | 2013-06-26 | 常州第六元素材料科技股份有限公司 | Zinc-rich epoxy anticorrosion paint and preparation method thereof |
| CN103497636A (en) * | 2013-09-07 | 2014-01-08 | 中国科学院合肥物质科学研究院 | Waterborne epoxy zinc-rich paint modified by nanometer conductive carbon material and preparation method thereof |
| CN103740152A (en) * | 2013-11-12 | 2014-04-23 | 宁波墨西科技有限公司 | Graphene-modified chromium-free Dacromet coating material |
-
2015
- 2015-05-27 CN CN201510274269.3A patent/CN104877402A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1288028A (en) * | 2000-10-11 | 2001-03-21 | 武汉锐普科技有限责任公司 | Water soluble inorganic ceramic zinc silicate anti-corrosive paint |
| CN1676550A (en) * | 2004-04-01 | 2005-10-05 | 北京中科远迪高新技术有限公司 | Water-soluble zinc-rich anticorrosive coating |
| CN101418150A (en) * | 2007-10-24 | 2009-04-29 | 廊坊中科远迪化工防腐技术有限公司 | Novel waterborne zinc-rich anti-corrosive paint |
| CN103173095A (en) * | 2013-03-06 | 2013-06-26 | 常州第六元素材料科技股份有限公司 | Zinc-rich epoxy anticorrosion paint and preparation method thereof |
| CN103497636A (en) * | 2013-09-07 | 2014-01-08 | 中国科学院合肥物质科学研究院 | Waterborne epoxy zinc-rich paint modified by nanometer conductive carbon material and preparation method thereof |
| CN103740152A (en) * | 2013-11-12 | 2014-04-23 | 宁波墨西科技有限公司 | Graphene-modified chromium-free Dacromet coating material |
Non-Patent Citations (4)
| Title |
|---|
| 屈凌波: "《新型功能材料设计及应用》", 31 May 2014, 郑州大学出版社 * |
| 耿耀宗: "《现代水性涂料 工艺·配方·应用（第二版）》", 30 April 2013, 中国石化出版社 * |
| 贾瑛等: "《轻质碳材料的应用》", 30 November 2013, 国防工业出版社 * |
| 颜红侠: "《现代精细化工实验》", 31 January 2015, 西北工业大学出版社 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105566973A (en) * | 2015-10-29 | 2016-05-11 | 中国航空工业集团公司北京航空材料研究院 | Cold-spraying-zinc anticorrosive paint with graphene and method for preparing cold-spraying-zinc anticorrosive paint |
| CN106118364A (en) * | 2016-07-08 | 2016-11-16 | 上海晶顿科技有限公司 | A kind of graphene oxide anticorrosive paint |
| CN106366712A (en) * | 2016-09-09 | 2017-02-01 | 常州大学 | Graphene conductive anticorrosive coating |
| CN106634320A (en) * | 2016-09-09 | 2017-05-10 | 常州大学 | Silicone acrylate emulsion and graphene oxide-modified inorganic paint and preparation method thereof |
| CN108610676A (en) * | 2016-12-08 | 2018-10-02 | 辽宁法库陶瓷工程技术研究中心 | A kind of high temperature resistant graphene corrosion-inhibiting coating and preparation method thereof |
| CN108285719A (en) * | 2017-03-06 | 2018-07-17 | 苏州鼎烯聚材纳米科技有限公司 | A kind of low zinc content anticorrosive paint and its application |
| CN107141850A (en) * | 2017-06-30 | 2017-09-08 | 广东美的厨房电器制造有限公司 | A kind of coating of hydrophilic high-antistatic performance and preparation method thereof |
| CN107141850B (en) * | 2017-06-30 | 2020-09-01 | 广东美的厨房电器制造有限公司 | Hydrophilic coating with high antistatic performance and preparation method thereof |
| CN107384045A (en) * | 2017-08-08 | 2017-11-24 | 肥西县通力机械有限公司 | A kind of excavating machinery surface weather-resistant coating |
| CN108753112A (en) * | 2018-06-29 | 2018-11-06 | 佛山腾鲤新能源科技有限公司 | A kind of preparation method of conductive coating |
| CN109021621A (en) * | 2018-07-25 | 2018-12-18 | 广东好邦石墨烯新材料科技有限公司 | A kind of zinc powder of graphene modified, preparation method and its application in water-based anticorrosive paint |
| CN110218469A (en) * | 2019-06-25 | 2019-09-10 | 东方电气集团东方汽轮机有限公司 | A kind of high temperature resistant graphene conductive water-based anticorrosive paint |
| CN110218469B (en) * | 2019-06-25 | 2021-04-20 | 东方电气集团东方汽轮机有限公司 | High-temperature-resistant graphene conductive water-based anticorrosive paint |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104877402A (en) | Compound water-based inorganic anticorrosive paint and preparation method | |
| CN105838195B (en) | A kind of water corrosion-resistant epoxy paint and preparation method thereof containing graphene oxide | |
| CN103409033B (en) | Conductive anticorrosive coating and preparation method thereof | |
| CN102911586B (en) | Epoxy anticorrosion decoration paint | |
| CN101407690A (en) | Bi-component epoxy zinc rich primer | |
| CN107400441A (en) | Graphene modified waterborne epoxy anticorrosive paint preparation technology | |
| CN104877499A (en) | High-temperature-resistant zinc-rich paint and preparation method thereof | |
| CN104403463A (en) | Aqueous low-surface treatment coating for iron power transmission tower surface protection and preparation method for aqueous low-surface treatment coating | |
| CN104877500A (en) | Lithium silicate-sodium silicate mixed zinc-rich paint and technology thereof | |
| CN106366712A (en) | Graphene conductive anticorrosive coating | |
| CN103709903A (en) | High solid conduction type epoxy zinc rich primer | |
| CN1850926A (en) | Corrision-resistant zinc-base aliuminium-magnesium rare-earth alloy coating, and its preparing method | |
| CN105001688A (en) | Water-borne inorganic anti-corrosive paint added with lithium stearate | |
| CN105038469A (en) | Water-based inorganic anti-corrosive paint added with aluminum stearate | |
| CN105062162A (en) | Preparation technology of composite metal organic soap-containing inorganic anticorrosive paint | |
| CN108531043B (en) | Rare earth modified graphene water-based zinc-rich primer | |
| CN105062277A (en) | Sodium stearate-containing inorganic anticorrosive paint and preparation technology thereof | |
| CN104356868A (en) | Coating composition directly painted on rust layer | |
| CN104927533A (en) | Water-based zinc rich paint with good film-forming property and preparation method thereof | |
| CN105017922A (en) | Aqueous zinc-rich flake cathode protection prime coat, preparation method and uses thereof | |
| CN108948898B (en) | Low-surface-treatment cold-spray zinc coating and preparation method thereof | |
| WO2019146163A1 (en) | Anticorrosion-treated metallic member and coating paint | |
| CN102153930A (en) | Chelate type flashing erosion-resistant water-based metal anticorrosion coating and preparation method thereof | |
| CN109575754B (en) | Low-surface-treatment coating and preparation method thereof | |
| CN106221320A (en) | A kind of inorganic anti-corrosion paint adding composite modifier |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150902 |
|
| RJ01 | Rejection of invention patent application after publication |