CN105566973A - Cold-spraying-zinc anticorrosive paint with graphene and method for preparing cold-spraying-zinc anticorrosive paint - Google Patents
Cold-spraying-zinc anticorrosive paint with graphene and method for preparing cold-spraying-zinc anticorrosive paint Download PDFInfo
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- CN105566973A CN105566973A CN201510717444.1A CN201510717444A CN105566973A CN 105566973 A CN105566973 A CN 105566973A CN 201510717444 A CN201510717444 A CN 201510717444A CN 105566973 A CN105566973 A CN 105566973A
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Abstract
The invention relates to cold-spraying-zinc anticorrosive paint with graphene and a method for preparing the cold-spraying-zinc anticorrosive paint. The cold-spraying-zinc anticorrosive paint comprises, by weight, 75-85 parts of zinc powder, 2-3 parts of organic resin, 15-25 parts of solvents, 0.1-2 parts of the graphene, 0.1-1 part of dispersing agents and 0.1-1 part of anti-settling agents. The method for preparing the cold-spraying-zinc anticorrosive paint includes weighing raw materials according to the weight, mixing the graphene, the dispersing agents and a part of the solvents with one another and ultrasonically uniformly dispersing the graphene, the dispersing agents and the solvents; mixing the organic resin with the residual solvents for dissolving; adding dispersed graphene liquid into dissolved resin liquid, and uniformly dispersing at a high speed to obtain mixed liquid; adding the zinc powder and the anti-settling agents into the mixed liquid, and uniformly dispersing at a high speed to obtain the cold-spraying-zinc anticorrosive paint with the graphene. The cold-spraying-zinc anticorrosive paint and the method have the advantages that coatings are good in adhesion and impact resistance and excellent in anticorrosive performance; the cold-spraying-zinc anticorrosive paint comprises single components and is convenient to construct; the cold-spraying-zinc anticorrosive paint is excellent in antistatic property and applicable to the antistatic coatings.
Description
Technical field
The present invention relates to a kind of coating and preparation method, specifically relate to a kind of Graphene cold-applied anticorrosion paint for zinc and preparation method thereof.
Background technology
Cold-applied anticorrosion paint for zinc is zinc-plated also known as film, Zinc-base plating etc., is a kind of special single component zinc-rich paint.In cold-applied zinc dry film, zinc content is up to 96%; under the corrosive environment of heavy antisepsis; be not only the galvanic protection effect that iron and steel provides good, and resin special in cold-applied zinc and oxidation zinc salt can be coating and provide barrier protection effect, thus have excellent antiseptic property.But, because in cold-applied zinc coating dry film, zinc content is high, resin content is low, existing cold-applied zinc product has the following disadvantages: 1. the sticking power of cold-applied zinc coating and steel is low: in existing cold-applied zinc product, the reached 5.0MPa that sticking power is high, low only has 1.0 ~ 1.5MPa, is inorganic type >=3.0MPa to the requirement of zinc rich primer in HG/T3668-2009Z; Organic type >=6.0MPa.2. film flexibility is poor, and shock-resistance index can not meet the demands.
Graphene is a kind of two-dimensional material of the novel individual layer sheet structure be made up of carbon atom.Graphene has high-specific surface area, Quick conductive, outstanding mechanical property, in coating with mixed with resin after, the mechanical property of coating can be significantly improved.
Summary of the invention
The object of the invention is: for the deficiencies in the prior art, Graphene cold-applied anticorrosion paint for zinc that a kind of coating shock-resistance is good, high with steel sticking power and preparation method thereof is provided.
Realize the object of the invention technical scheme as follows:
A kind of Graphene cold-applied anticorrosion paint for zinc, coating comprises the following component by mass parts: zinc powder, 75 ~ 85 parts; Organic resin, 2 ~ 3 parts; Solvent, 15 ~ 25 parts; Graphene, 0.1 ~ 2 part; Dispersion agent, 0.1 ~ 1 part; Antisettling agent, 0.1 ~ 1 part.
Further, zinc powder is the zinc powder of Zn content >=99.5% of median size≤5 μm; Organic resin is epoxy ester, vinylformic acid, highly-chlorinated polyethylene, polystyrene or polysiloxane; Solvent is vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol or high boiling aromatic hydrocarbon.
Further, Graphene is graphite through oxidation, then carries out peeling off obtaining; Mode of oxidizing is preferably from Hummers method, Staudenmaier method or Brodie method; Stripping mode is preferably peeled off from microwave, pyrolysis expansion is peeled off or ultrasonic disperse.
Further, dispersion agent is organo silane coupling agent, titanate coupling agent or KH550.
Further, antisettling agent is at least the one in organobentonite, polyamide wax or aerosil.
Further, a kind of preparation method of Graphene cold-applied anticorrosion paint for zinc, the method is by Graphene, dispersion agent and a part of solvent, and ultrasonic disperse is even; Organic resin and remaining solvent are dissolved; Then add in the resin liquid of dissolving by scattered Graphene liquid, high speed dispersion is even; Finally add zinc powder, antisettling agent, high speed dispersion is even again, obtains Graphene cold-applied anticorrosion paint for zinc.
With immediate prior art ratio, technical scheme provided by the invention has following excellent effect:
1. coating adhesion, shock-resistance are good, and antiseptic property is excellent;
2. single component, easy construction;
3. there is good static resistance, can be used for anti-static coating.
Embodiment
Below by specific embodiment; the present invention will be further described, but protection scope of the present invention is not limited thereto, and is anyly familiar with those skilled in the art in scope disclosed by the invention; the change that can expect easily or replacement, all should be encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the scope of claim protection.
Embodiment 1:
Graphene, 1 part; Titanate coupling agent, 0.5 part; Acrylic resin, 2.5 parts; Vinyl acetic monomer, 20 parts; Zinc powder, 75.5 parts; Organobentonite, 0.5 part.
(1) by 1 part of Graphene, 0.5 part of titanate coupling agent and 10 parts of vinyl acetic monomer mixing, ultrasonic disperse is even, obtains Graphene liquid;
(2) by 2.5 parts of acrylic resins and 10 parts of vinyl acetic monomer mixed dissolutions, resin liquid is obtained;
(3) the Graphene liquid in step (1) 11.5 parts is added in the resin liquid 12.5 parts of step (2), 800 ~ 1000rpm is uniformly dispersed, then 75.5 parts of zinc powders, 0.5 part of organobentonite is added, 1200 ~ 1500rpm is uniformly dispersed, after filtering, Graphene cold-applied anticorrosion paint for zinc is obtained.
Embodiment 2:
Graphene, 1 part; KH550,0.5 part; Polystyrene, 2.5 parts; High boiling aromatic hydrocarbon solvent, 20 parts; Zinc powder, 75.5 parts; Aerosil, 0.5 part.
(1) by 1 part of Graphene, 0.5 part of KH550 and 10 part of high boiling aromatic hydrocarbon solvent, ultrasonic disperse is even, obtains Graphene liquid;
(2) 2.5 parts of polystyrene resins and 10K high boiling aromatic hydrocarbon solvent are dissolved, obtain resin liquid;
(3) the Graphene liquid in step (1) 11.5 parts is added in the resin liquid 12.5 parts of step (2), 800 ~ 1000rpm is uniformly dispersed, then 75.5 parts of zinc powders, 0.5 part of aerosil is added, 1200 ~ 1500rpm is uniformly dispersed, after filtering, Graphene cold-applied anticorrosion paint for zinc is obtained.
Embodiment 3:
Graphene, 0.5 part; Titanate coupling agent, 0.8 part; Acrylic resin, 2.5 parts; Vinyl acetic monomer, 18 parts; Zinc powder, 77.8 parts; Organobentonite, 0.4 part.
(1) by 0.5 part of Graphene, 0.8 part of titanate coupling agent and 8 parts of vinyl acetic monomer mixing, ultrasonic disperse is even, obtains Graphene liquid;
(2) by 2.5 parts of acrylic resins and 10 parts of vinyl acetic monomer mixed dissolutions, resin liquid is obtained;
(3) the Graphene liquid in step (1) 9.3 parts is added in the resin liquid 12.5 parts of step (2), 800 ~ 1000rpm is uniformly dispersed, then 77.8 parts of zinc powders, 0.4 part of organobentonite is added, 1200 ~ 1500rpm is uniformly dispersed, after filtering, Graphene cold-applied anticorrosion paint for zinc is obtained.
Embodiment 4:
Graphene, 0.5 part; KH550,0.8 part; Polystyrene, 2.5 parts; High boiling aromatic hydrocarbon solvent, 18 parts; Zinc powder, 77.8 parts; Aerosil, 0.5 part.
(1) by 0.5 part of Graphene, 0.8 part of KH550 and 8 part of high boiling aromatic hydrocarbon solvent, ultrasonic disperse is even, obtains Graphene liquid;
(2) 2.5 parts of polystyrene resins and 10K high boiling aromatic hydrocarbon solvent are dissolved, obtain resin liquid;
(3) the Graphene liquid in step (1) 9.3 parts is added in the resin liquid 12.5 parts of step (2), 800 ~ 1000rpm is uniformly dispersed, then 77.8 parts of zinc powders, 0.5 part of aerosil is added, 1200 ~ 1500rpm is uniformly dispersed, after filtering, Graphene cold-applied anticorrosion paint for zinc is obtained.
After the coating difference film-forming prepared by above-described embodiment 1 ~ 4, the film performance formed is as table 1.
Table 1: the performance test results
The data declaration of table 1 prepare through the inventive method Graphene cold-applied anticorrosion paint for zinc possesses very strong coating adhesion, shock-resistance is good, the effect of the excellent and good corrosion resistance of antiseptic property, and also have good static resistance, can be used for anti-static coating.
Above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit; those of ordinary skill in the field are to be understood that; can modify to the specific embodiment of the present invention with reference to above-described embodiment or equivalent to replace, these do not depart from any amendment of spirit and scope of the invention or equivalently to replace within the claims that all awaits the reply in application.
Claims (10)
1. a Graphene cold-applied anticorrosion paint for zinc, is characterized in that, described coating comprises the following component by mass parts:
Zinc powder, 75 ~ 85 parts; Organic resin, 2 ~ 3 parts; Solvent, 15 ~ 25 parts; Graphene, 0.1 ~ 2 part;
Dispersion agent, 0.1 ~ 1 part; Antisettling agent, 0.1 ~ 1 part.
2. a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 1, is characterized in that, described zinc powder is the zinc powder of Zn content >=99.5% of median size≤5 μm.
3. a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 1, is characterized in that, described organic resin is epoxy ester, vinylformic acid, highly-chlorinated polyethylene, polystyrene or polysiloxane.
4. a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 1, is characterized in that, described solvent is vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol or high boiling aromatic hydrocarbon.
5. a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 1, is characterized in that, described Graphene is graphite through oxidation, then carries out peeling off obtaining.
6. a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 5, is characterized in that, described mode of oxidizing is preferably from Hummers method, Staudenmaier method or Brodie method.
7. a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 5, is characterized in that, described stripping mode is preferably peeled off from microwave, pyrolysis expansion is peeled off or ultrasonic disperse.
8. a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 1, is characterized in that, described dispersion agent is organo silane coupling agent, titanate coupling agent or KH550.
9. a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 1, it is characterized in that, described antisettling agent is at least the one in organobentonite, polyamide wax or aerosil.
10. prepare a method for a kind of Graphene cold-applied anticorrosion paint for zinc as claimed in claim 1, it is characterized in that, the method is by Graphene, dispersion agent and a part of solvent, and ultrasonic disperse is even; Organic resin and remaining solvent are dissolved; Then add in the resin liquid of dissolving by scattered Graphene liquid, high speed dispersion is even; Finally add zinc powder, antisettling agent, high speed dispersion is even again, obtains Graphene cold-applied anticorrosion paint for zinc.
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| CN201510717444.1A CN105566973A (en) | 2015-10-29 | 2015-10-29 | Cold-spraying-zinc anticorrosive paint with graphene and method for preparing cold-spraying-zinc anticorrosive paint |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118297A (en) * | 2016-07-04 | 2016-11-16 | 苏州云舒新材料科技有限公司 | A kind of acrylic resin modified anti-static coatings of Graphene |
| CN106634438A (en) * | 2016-12-27 | 2017-05-10 | 苏州高通新材料科技有限公司 | Graphene modified solvent type epoxy zinc-rich coating as well as preparation method and application thereof |
| CN106704720A (en) * | 2017-01-11 | 2017-05-24 | 江苏星源电站冶金设备制造有限公司 | Bi-metal composite abrasion-resistant pipe and preparation method thereof |
| CN106947983A (en) * | 2017-03-31 | 2017-07-14 | 湖南金磐新材料科技有限公司 | Intercalation Zn-Al alloy powder and its zinc-aluminium of preparation collaboration anticorrosive paint and method |
| CN107022254A (en) * | 2017-02-15 | 2017-08-08 | 滁州金桥德克新材料有限公司 | High-iron carriage shell anti-corrosion composite coating and preparation method thereof |
| CN107043597A (en) * | 2017-01-22 | 2017-08-15 | 燕园众欣纳米科技（北京）有限公司 | A kind of cold spray zinc/aluminium resin solution of graphite ene-type and preparation method thereof |
| CN107043596A (en) * | 2017-01-22 | 2017-08-15 | 燕园众欣纳米科技（北京）有限公司 | A kind of graphite ene-type single-component cold aluminising anticorrosive paint and preparation method thereof |
| CN107286814A (en) * | 2017-06-26 | 2017-10-24 | 江苏兰陵高分子材料有限公司 | The cold-applied zinc coating of organic inorganic hybridization a kind of is resin dedicated and its production and use |
| CN107652879A (en) * | 2017-10-22 | 2018-02-02 | 惠州市阿斯顿涂料有限公司 | A kind of long-acting cold galvanizing fire-resistant anticorrosion paint |
| CN111286238A (en) * | 2020-02-27 | 2020-06-16 | 无锡华东锌盾科技有限公司 | Cold spray zinc alkene coating and preparation method thereof |
| CN111876049A (en) * | 2020-07-28 | 2020-11-03 | 天津中航百慕新材料技术有限公司 | Graphene cold-coating zinc coating and preparation method thereof |
| CN112592610A (en) * | 2020-12-14 | 2021-04-02 | 山西省安瑞风机电气股份有限公司 | High-temperature-resistant cold-coated zinc and preparation method thereof |
| CN112694804A (en) * | 2021-01-08 | 2021-04-23 | 湖南翰坤实业有限公司 | Anti-stain zinc-plating coating and preparation method thereof |
| CN113105800A (en) * | 2021-04-01 | 2021-07-13 | 浙江天女集团制漆有限公司 | Graphene and carbon nanotube cold-coating zinc anticorrosive paint and preparation method thereof |
| CN114213911A (en) * | 2022-02-08 | 2022-03-22 | 深圳市中科纳米科技有限公司 | Formula and preparation method of efficient anticorrosive coating for carbon nano tube |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS573870A (en) * | 1980-06-10 | 1982-01-09 | Dainippon Toryo Co Ltd | Zinc-rich paint |
| CN102618132A (en) * | 2012-03-19 | 2012-08-01 | 天长市巨龙车船涂料有限公司 | Primer-topcoat cold-spray zinc coating and preparation method for same |
| CN103497636A (en) * | 2013-09-07 | 2014-01-08 | 中国科学院合肥物质科学研究院 | Waterborne epoxy zinc-rich paint modified by nanometer conductive carbon material and preparation method thereof |
| CN103740152A (en) * | 2013-11-12 | 2014-04-23 | 宁波墨西科技有限公司 | Graphene-modified chromium-free Dacromet coating material |
| CN104877402A (en) * | 2015-05-27 | 2015-09-02 | 常州大学 | Compound water-based inorganic anticorrosive paint and preparation method |
-
2015
- 2015-10-29 CN CN201510717444.1A patent/CN105566973A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS573870A (en) * | 1980-06-10 | 1982-01-09 | Dainippon Toryo Co Ltd | Zinc-rich paint |
| CN102618132A (en) * | 2012-03-19 | 2012-08-01 | 天长市巨龙车船涂料有限公司 | Primer-topcoat cold-spray zinc coating and preparation method for same |
| CN103497636A (en) * | 2013-09-07 | 2014-01-08 | 中国科学院合肥物质科学研究院 | Waterborne epoxy zinc-rich paint modified by nanometer conductive carbon material and preparation method thereof |
| CN103740152A (en) * | 2013-11-12 | 2014-04-23 | 宁波墨西科技有限公司 | Graphene-modified chromium-free Dacromet coating material |
| CN104877402A (en) * | 2015-05-27 | 2015-09-02 | 常州大学 | Compound water-based inorganic anticorrosive paint and preparation method |
Non-Patent Citations (1)
| Title |
|---|
| 林璟: "《耐热性聚氨酯复合树脂及其IMD油墨应用技术》", 31 October 2014, 西北工业大学出版社 * |
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| CN106118297A (en) * | 2016-07-04 | 2016-11-16 | 苏州云舒新材料科技有限公司 | A kind of acrylic resin modified anti-static coatings of Graphene |
| CN106634438A (en) * | 2016-12-27 | 2017-05-10 | 苏州高通新材料科技有限公司 | Graphene modified solvent type epoxy zinc-rich coating as well as preparation method and application thereof |
| CN106704720B (en) * | 2017-01-11 | 2019-09-13 | 江苏星源电站冶金设备制造有限公司 | Bimetal composite wear resistant tube and preparation method thereof |
| CN106704720A (en) * | 2017-01-11 | 2017-05-24 | 江苏星源电站冶金设备制造有限公司 | Bi-metal composite abrasion-resistant pipe and preparation method thereof |
| CN107043597A (en) * | 2017-01-22 | 2017-08-15 | 燕园众欣纳米科技（北京）有限公司 | A kind of cold spray zinc/aluminium resin solution of graphite ene-type and preparation method thereof |
| CN107043596A (en) * | 2017-01-22 | 2017-08-15 | 燕园众欣纳米科技（北京）有限公司 | A kind of graphite ene-type single-component cold aluminising anticorrosive paint and preparation method thereof |
| CN107022254A (en) * | 2017-02-15 | 2017-08-08 | 滁州金桥德克新材料有限公司 | High-iron carriage shell anti-corrosion composite coating and preparation method thereof |
| CN106947983A (en) * | 2017-03-31 | 2017-07-14 | 湖南金磐新材料科技有限公司 | Intercalation Zn-Al alloy powder and its zinc-aluminium of preparation collaboration anticorrosive paint and method |
| CN106947983B (en) * | 2017-03-31 | 2019-06-18 | 湖南金磐新材料科技有限公司 | Intercalation Zn-Al alloy powder and its zinc-aluminium of preparation collaboration anticorrosive paint and method |
| CN107286814A (en) * | 2017-06-26 | 2017-10-24 | 江苏兰陵高分子材料有限公司 | The cold-applied zinc coating of organic inorganic hybridization a kind of is resin dedicated and its production and use |
| CN107286814B (en) * | 2017-06-26 | 2019-04-23 | 江苏兰陵高分子材料有限公司 | A kind of cold-applied zinc coating of hybrid inorganic-organic is resin dedicated and its preparation method and application |
| CN107652879A (en) * | 2017-10-22 | 2018-02-02 | 惠州市阿斯顿涂料有限公司 | A kind of long-acting cold galvanizing fire-resistant anticorrosion paint |
| CN111286238A (en) * | 2020-02-27 | 2020-06-16 | 无锡华东锌盾科技有限公司 | Cold spray zinc alkene coating and preparation method thereof |
| CN111876049A (en) * | 2020-07-28 | 2020-11-03 | 天津中航百慕新材料技术有限公司 | Graphene cold-coating zinc coating and preparation method thereof |
| CN112592610A (en) * | 2020-12-14 | 2021-04-02 | 山西省安瑞风机电气股份有限公司 | High-temperature-resistant cold-coated zinc and preparation method thereof |
| CN112694804A (en) * | 2021-01-08 | 2021-04-23 | 湖南翰坤实业有限公司 | Anti-stain zinc-plating coating and preparation method thereof |
| CN113105800A (en) * | 2021-04-01 | 2021-07-13 | 浙江天女集团制漆有限公司 | Graphene and carbon nanotube cold-coating zinc anticorrosive paint and preparation method thereof |
| CN114213911A (en) * | 2022-02-08 | 2022-03-22 | 深圳市中科纳米科技有限公司 | Formula and preparation method of efficient anticorrosive coating for carbon nano tube |
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Application publication date: 20160511 |