CN106118276A - A kind of black temperature becomes paint - Google Patents
A kind of black temperature becomes paint Download PDFInfo
- Publication number
- CN106118276A CN106118276A CN201610660137.9A CN201610660137A CN106118276A CN 106118276 A CN106118276 A CN 106118276A CN 201610660137 A CN201610660137 A CN 201610660137A CN 106118276 A CN106118276 A CN 106118276A
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- China
- Prior art keywords
- temperature
- paint
- resin
- solvent
- mibk
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/26—Thermosensitive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of black temperature and become paint, including resin, pigment, solvent and auxiliary agent, according to percentage by weight, each one-tenth is grouped into as follows: resin: (1) polyurethane resin 24 ± 1%；(2) thermoplastic acrylic resin 10 ± 2%；(3) full etherified amino resins 5 ± 2%；Pigment: (1) temperature camouflage paint 25 ± 5%；Solvent: (1) Ketohexamethylene 5 ± 0.5%；(2) dimethylbenzene 8 ± 0.5%；(3) butyl ester 12 ± 0.5%；(4) methyl iso-butyl ketone (MIBK) (MIBK) 9 ± 0.5%；Auxiliary agent: (1) fluorine richness levelling agent 1 ± 0.2%；(2) silicon class defoamer 2 ± 0.3%；(3) high-molecular copolymer alkylammonium salt dispersion 1 ± 0.3%.
Description
Technical field
The present invention relates to a kind of black temperature and become paint, be specifically related to one and be widely used in rustless steel, aluminium alloy, cast iron, electricity
The black temperature of the incrustation of the industrial products such as wood becomes paint.
Background technology
Thermochromatic material is in certain temperature range, and its color occurs the function material of significant change with the change of temperature
Material.Before more than 100 years, people have found that the phenomenon of thermo-color.The research comprehensively of thermochromatic material and application, the most
Through there being the developing history of 1 year, also there is the history of more than 30 year in China.Through the research and development of decades, people
Have been developed for all kinds of materials with thermochromic properties such as inorganic, organic, liquid crystal, polymer and biomacromolecule.
At present, the protection of the metal substrate equipment pipe such as boiler, chemical reaction tower, exhaustor, chimney, baking oven uses all
Common paint, in the environment can not the change of temperature etc. on display device surface, higher temperature may make equipment surface
Paint come off, make equipment expose in the environment, cause serious corrosion, make shortened equipment life.Another aspect, is producing
In, owing to device temperature is high, workman is difficult to grasp operation, therefore, market is badly in need of the incrustation having a kind of simplicity, low cost
Coating with paint film meeting automatic color-changing.
Summary of the invention
In order to overcome the shortcoming of prior art with not enough, it is an object of the invention to use special modified resin, organic facies with
Warm variable pigments that inorganic phase combines, environmentally friendly solvent, environment-friend auxiliaries etc. are primary raw material, prepare a kind of black temperature and become paint.
It is as follows that the present invention solves the technical scheme that above-mentioned technical problem taked:
A kind of black temperature becomes paint, it is characterised in that include resin, pigment, solvent and auxiliary agent, according to percentage by weight, and each composition
Form as follows:
Resin:
(1) polyurethane resin 24 ± 1%；
(2) thermoplastic acrylic resin 10 ± 2%；
(3) full etherified amino resins 5 ± 2%；
Pigment:
(1) temperature camouflage paint 25 ± 5%；
Solvent:
(1) Ketohexamethylene 5 ± 0.5%；
(2) dimethylbenzene 8 ± 0.5%；
(3) butyl ester 12 ± 0.5%；
(4) methyl iso-butyl ketone (MIBK) (MIBK) 9 ± 0.5%；
Auxiliary agent:
(1) fluorine richness levelling agent 1 ± 0.2%；
(2) silicon class defoamer 2 ± 0.3%；
(3) high-molecular copolymer alkylammonium salt dispersant 1 ± 0.3%.
Preferably, described temperature camouflage paint is electron transfer type organic compound.
Preferably, according to percentage by weight, each one-tenth is grouped into as follows:
Resin:
(1) polyurethane resin 24%；
(2) thermoplastic acrylic resin 10%；
(3) full etherified amino resins 5%；
Pigment:
(1) temperature camouflage paint 25%；
Solvent:
(1) Ketohexamethylene 5%；
(2) dimethylbenzene 8%；
(3) butyl ester 12%；
(4) MIBK 9%；
Auxiliary agent:
(1) fluorine richness levelling agent 1%；
(2) silicon class defoamer 2%；
(3) high-molecular copolymer alkylammonium salt dispersant 1%.
Preferably, according to percentage by weight, each one-tenth is grouped into as follows:
Resin:
(1) polyurethane resin 24.5%；
(2) thermoplastic acrylic resin 9.5%；
(3) full etherified amino resins 5%；
Pigment:
(1) temperature camouflage paint 26%；
Solvent:
(1) Ketohexamethylene 4.5%；
(2) dimethylbenzene 8.5%；
(3) butyl ester 11.5%；
(4) MIBK 9.5%；
Auxiliary agent:
(1) fluorine richness levelling agent 1.1%；
(2) silicon class defoamer 2.3%；
(3) high-molecular copolymer alkylammonium salt dispersant 0.7%.
Preferably, the preparation method of described temperature camouflage paint includes: temperature-sensitive powder is mixed into polyethylene (PE), polypropylene
(PP), the transparent or semitransparent plastics such as polystyrene (PS), flexible PVC (S-PVC), AS and ABS injection, be extruded into
Type.
Preferably, the preparation method of described temperature camouflage paint includes: temperature-sensitive powder is mixed into unsaturated polyester, asphalt mixtures modified by epoxy resin
Casting in fat, lucite or nylon monomer, mold pressing, curing molding.
Temperature of the present invention becomes paint, and film is bright-colored, temperature tolerance good, contained content of beary metal low (feature of environmental protection is good), can adopt
Construct (such as spraying, brushing etc.) are carried out by multiple coating aspect.The present invention is simultaneously achieved from sense temperature to visualization temperature
Transformation, measure temperature by color first.
Other features and advantages of the present invention will illustrate in the following description, and, partly become from description
Obtain it is clear that or understand by implementing the present invention.The purpose of the present invention and other advantages can be by the explanations write
Method, step specifically noted in book, claims realize and obtain.
Detailed description of the invention
Embodiments of the present invention are described in detail, whereby to the present invention how application technology hands below with reference to embodiment
Section solves technical problem, and the process that realizes reaching technique effect can fully understand and implement according to this.It should be noted that only
Otherwise constituting conflict, each embodiment in the present invention and each feature in each embodiment can be combined with each other, and formed
Technical scheme all within protection scope of the present invention.
In order to overcome the shortcoming of prior art with not enough, it is an object of the invention to use special modified resin, organic facies with
Warm variable pigments that inorganic phase combines, environmentally friendly solvent, environment-friend auxiliaries etc. are primary raw material, prepare a kind of black temperature and become paint.
Temperature of the present invention becomes paint, and film is bright-colored, temperature tolerance good, contained content of beary metal low (feature of environmental protection is good), can use multiple painting
Cover aspect and carry out construct (such as spraying, brushing etc.).The present invention is simultaneously achieved from sense temperature to the transformation of visualization temperature, first
Secondary color measures temperature.
It is an object of the invention to be reached by following measures:
A kind of black temperature becomes paint, and including resin, pigment, solvent and auxiliary agent, according to percentage by weight, each one-tenth is grouped into as follows:
Resin:
(1) polyurethane resin 24 ± 1%；
(2) thermoplastic acrylic resin 10 ± 2%；
(3) full etherified amino resins 5 ± 2%；
Pigment:
(1) temperature camouflage paint 25 ± 5%；
Solvent:
(1) Ketohexamethylene 5 ± 0.5%；
(2) dimethylbenzene 8 ± 0.5%；
(3) butyl ester 12 ± 0.5%；
(4) methyl iso-butyl ketone (MIBK) (MIBK) 9 ± 0.5%；
Auxiliary agent:
(1) fluorine richness levelling agent 1 ± 0.2%；
(2) silicon class defoamer 2 ± 0.3%；
(3) high-molecular copolymer alkylammonium salt dispersant 1 ± 0.3%.
Wherein, the coating parameter prepared by the present invention is as follows:
Outward appearance: dark thick liquid
Film color changes: black (room temperature or temperature≤65 DEG C)；Priming paint (two are coated with) or material (is coated with) become color (temperature >=65
DEG C)
Viscosity: 55-60 KU/25 DEG C
Hardness: H-2H
Adhesive force: 100%
Diluent: TN609B(is not necessarily a kind of diluent, can be several or several classes)
Open dilute ratio: AK7115162A:TN609B=1:0.5；
Baking condition: 150 DEG C of * 25-30min
Thickness: 15-20um
Storage stability: under normal temperature condition at least 6 months
Embodiment 1
Resinae percentage ratio:
(1) polyurethane resin 24%
(2) thermoplastic acrylic resin 10%
(3) full etherified amino resins 5%
Pigment class percentage ratio:
(1) electron transfer type organic compound 25%
Solvent percentage ratio:
(1) Ketohexamethylene 5%
(2) dimethylbenzene 8%
(3) butyl ester 12%
(4) MIBK 9%
Auxiliary agent class percentage ratio:
(1) fluorine richness levelling agent 1%
(2) silicon class defoamer 2%
(3) high-molecular copolymer alkylammonium salt dispersant 1%
Processing step is as follows:
A. being initially charged matrix resin and the dispersant of band reactive group, part mixed solvent, low speed (400-600r/min) stirs
Uniformly；
B. adding temperature change powder under stirring condition, low speed (400-600r/min) carries out disperseing and moistening, and this is the pre-slurrying of leading portion；
C. pre-slurrying three-roller or sand mill are ground to fineness≤15um, with mixed solvent cleaning robot equipment；
After good feed liquid the most to be ground is cooled to room temperature (≤35 DEG C), add amino resins, levelling agent, adhesive agent, catalyst etc., low
Speed (400-600r/min) mix homogeneously, mends damage with residue mixed solvent and adjusts viscous.
Through above-mentioned technique prepare temperature become paint parameter as follows:
Outward appearance: dark thick liquid
Film color changes: when >=65 DEG C, redness become white
Viscosity: 55-60KU/25 DEG C；
Hardness: 1H-2H；
Adhesive force: 100%
Diluent: TN609B
Open dilute ratio: AK7115162A:TN609B=1:0.5；
Baking condition: 150 DEG C of * 25-30min；
Thickness: 15-20um；
Embodiment 2
Resinae percentage ratio:
(1) polyurethane resin 24.5%
(2) thermoplastic acrylic resin 9.5%
(3) full etherified amino resins 5%
Pigment class percentage ratio:
(1) electron transfer type organic compound 26%
Solvent percentage ratio:
(1) Ketohexamethylene 4.5%
(2) dimethylbenzene 8.5%
(3) butyl ester 11.5%
(4) MIBK 9.5%
Auxiliary agent class percentage ratio:
(1) fluorine richness levelling agent 1.1%
(2) silicon class defoamer 2.3%
(3) high-molecular copolymer alkylammonium salt dispersant 0.7%
Processing step is as follows:
A. being initially charged matrix resin and the dispersant of band reactive group, part mixed solvent, low speed (400-600r/min) stirs
Uniformly；
B. adding temperature change powder under stirring condition, low speed (400-600r/min) carries out disperseing and moistening, and this is the pre-slurrying of leading portion；
C. pre-slurrying three-roller or sand mill are ground to fineness≤15um, with mixed solvent cleaning robot equipment；
After good feed liquid the most to be ground is cooled to room temperature (≤35 DEG C), add amino resins, levelling agent, adhesive agent, catalyst etc., low
Speed (400-600r/min) mix homogeneously, mends damage with residue mixed solvent and adjusts viscous.
Through above-mentioned technique prepare temperature become paint parameter as follows:
Outward appearance: dark thick liquid
Film color changes: when >=65 DEG C, redness become white
Viscosity: 55-60KU/25 DEG C；
Hardness: 1H-2H；
Adhesive force: 100%
Diluent: TN609B
Open dilute ratio: AK7115162A:TN609B=1:0.5；
Baking condition: 150 DEG C of * 25-30min；
Thickness: 15-20um；
The warm allochroic paint being prepared by the method for the present invention out, has the property that
1, film color changes in response to temperature, and has reversibility and repeatability；
2, excellent to the adhesive force of various priming paint and metal base；
3, film has the water boiling resistance of excellence；
4, excellent ply adhesion, can recoat；
5, excellent endurance and anti-corrosive properties.
These, it is preferred to, the preparation method of described temperature camouflage paint includes: temperature-sensitive powder is mixed into polyethylene (PE), gathers
The injection of transparent or semitransparent plastics, the extrusion moldings such as propylene (PP), polystyrene (PS), flexible PVC (S-PVC), AS and ABS
Molding.
Or, the preparation method of described temperature camouflage paint includes: temperature-sensitive powder is mixed into unsaturated polyester, epoxy resin, has
Casting in machine glass or nylon monomer, mold pressing, curing molding.
Finally it is noted that the foregoing is only the preferred embodiments of the present invention, it is not limited to the present invention,
Although being described in detail the present invention with reference to previous embodiment, for a person skilled in the art, it still may be used
So that the technical scheme described in foregoing embodiments to be modified, or wherein portion of techniques feature is carried out equivalent.
All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included in the present invention's
Within protection domain.
Claims (6)
1. a black temperature becomes paint, it is characterised in that includes resin, pigment, solvent and auxiliary agent, according to percentage by weight, respectively becomes
It is grouped into as follows:
Resin:
(1) polyurethane resin 24 ± 1%；
(2) thermoplastic acrylic resin 10 ± 2%；
Full etherified amino resins 5 ± 2%；
Pigment:
Temperature camouflage paint 25 ± 5%；
Solvent:
(1) Ketohexamethylene 5 ± 0.5%；
(2) dimethylbenzene 8 ± 0.5%；
(3) butyl ester 12 ± 0.5%；
(4) methyl iso-butyl ketone (MIBK) (MIBK) 9 ± 0.5%；
Auxiliary agent:
(1) fluorine richness levelling agent 1 ± 0.2%；
(2) silicon class defoamer 2 ± 0.3%；
(3) high-molecular copolymer alkylammonium salt dispersant 1 ± 0.3%.
Black temperature the most according to claim 1 becomes paint, it is characterised in that described temperature camouflage paint is that electron transfer type is organic
Compound.
Black temperature the most according to claim 1 becomes paint, it is characterised in that according to percentage by weight, and each one-tenth is grouped into as follows:
Resin:
(1) polyurethane resin 24%；
(2) thermoplastic acrylic resin 10%；
(3) full etherified amino resins 5%；
Pigment:
(1) temperature camouflage paint 25%；
Solvent:
(1) Ketohexamethylene 5%；
(2) dimethylbenzene 8%；
(3) butyl ester 12%；
(4) MIBK 9%；
Auxiliary agent:
(1) fluorine richness levelling agent 1%；
(2) silicon class defoamer 2%；
(3) high-molecular copolymer alkylammonium salt dispersant 1%.
Black temperature the most according to claim 1 becomes paint, it is characterised in that according to percentage by weight, and each one-tenth is grouped into as follows:
Resin:
(1) polyurethane resin 24.5%；
(2) thermoplastic acrylic resin 9.5%；
(3) full etherified amino resins 5%；
Pigment:
(1) temperature camouflage paint 26%；
Solvent:
(1) Ketohexamethylene 4.5%；
(2) dimethylbenzene 8.5%；
(3) butyl ester 11.5%；
(4) MIBK 9.5%；
Auxiliary agent:
(1) fluorine richness levelling agent 1.1%；
(2) silicon class defoamer 2.3%；
(3) high-molecular copolymer alkylammonium salt dispersant 0.7%.
Black temperature the most according to claim 1 becomes paint, it is characterised in that the preparation method of described temperature camouflage paint includes:
Temperature-sensitive powder is mixed into polyethylene (PE), polypropylene (PP), polystyrene (PS), flexible PVC (S-PVC), AS and ABS etc. saturating
Bright or the injection of translucent plastic, extrusion moulding.
Black temperature the most according to claim 1 becomes paint, it is characterised in that the preparation method of described temperature camouflage paint includes:
Cast in temperature-sensitive powder is mixed into unsaturated polyester, epoxy resin, lucite or nylon monomer, mold, curing molding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610660137.9A CN106118276A (en) | 2016-08-12 | 2016-08-12 | A kind of black temperature becomes paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610660137.9A CN106118276A (en) | 2016-08-12 | 2016-08-12 | A kind of black temperature becomes paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106118276A true CN106118276A (en) | 2016-11-16 |
Family
ID=57257813
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610660137.9A Pending CN106118276A (en) | 2016-08-12 | 2016-08-12 | A kind of black temperature becomes paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN106118276A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833297A (en) * | 2016-12-15 | 2017-06-13 | 滁州市自然空间建材有限公司 | A kind of temperature-sensing color-changing material of applied metal door and window accessory and preparation method thereof |
| CN107418412A (en) * | 2017-09-04 | 2017-12-01 | 深圳市鑫太庆科技有限公司 | A kind of light becomes coating |
| CN107459919A (en) * | 2017-09-04 | 2017-12-12 | 深圳市鑫太庆科技有限公司 | A kind of release coating |
| CN107502080A (en) * | 2017-09-04 | 2017-12-22 | 深圳市鑫太庆科技有限公司 | A kind of self-cleaning coating |
| CN108680976A (en) * | 2018-07-25 | 2018-10-19 | 浙江夜光明光电科技股份有限公司 | A kind of production method of double-colored heat reflective pad pasting |
| CN108973290A (en) * | 2018-07-25 | 2018-12-11 | 浙江夜光明光电科技股份有限公司 | A kind of induction discoloration reflective fabric |
| CN115353772A (en) * | 2022-08-26 | 2022-11-18 | 无锡市春阳印刷包装有限公司 | Thermochromic water-based ink for paper material and preparation method thereof |
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| CN103396730A (en) * | 2013-08-15 | 2013-11-20 | 东莞市通源达喷涂科技咨询有限公司 | Thermochromic coating for metal, glass and ceramic and preparation method thereof |
| CN105086692A (en) * | 2015-09-11 | 2015-11-25 | 句容市兴武包装有限公司 | Carton thermosensitive paint |
| CN105331267A (en) * | 2015-11-13 | 2016-02-17 | 湖北大学 | Weather-resisting reversible thermoindicator sun-blocking coating for transformer accessory and preparing method thereof |
| CN105331199A (en) * | 2015-11-27 | 2016-02-17 | 国家电网公司 | Visual temperature-measuring and insulating method for power product |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396730A (en) * | 2013-08-15 | 2013-11-20 | 东莞市通源达喷涂科技咨询有限公司 | Thermochromic coating for metal, glass and ceramic and preparation method thereof |
| CN105086692A (en) * | 2015-09-11 | 2015-11-25 | 句容市兴武包装有限公司 | Carton thermosensitive paint |
| CN105331267A (en) * | 2015-11-13 | 2016-02-17 | 湖北大学 | Weather-resisting reversible thermoindicator sun-blocking coating for transformer accessory and preparing method thereof |
| CN105331199A (en) * | 2015-11-27 | 2016-02-17 | 国家电网公司 | Visual temperature-measuring and insulating method for power product |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833297A (en) * | 2016-12-15 | 2017-06-13 | 滁州市自然空间建材有限公司 | A kind of temperature-sensing color-changing material of applied metal door and window accessory and preparation method thereof |
| CN107418412A (en) * | 2017-09-04 | 2017-12-01 | 深圳市鑫太庆科技有限公司 | A kind of light becomes coating |
| CN107459919A (en) * | 2017-09-04 | 2017-12-12 | 深圳市鑫太庆科技有限公司 | A kind of release coating |
| CN107502080A (en) * | 2017-09-04 | 2017-12-22 | 深圳市鑫太庆科技有限公司 | A kind of self-cleaning coating |
| CN108680976A (en) * | 2018-07-25 | 2018-10-19 | 浙江夜光明光电科技股份有限公司 | A kind of production method of double-colored heat reflective pad pasting |
| CN108973290A (en) * | 2018-07-25 | 2018-12-11 | 浙江夜光明光电科技股份有限公司 | A kind of induction discoloration reflective fabric |
| CN115353772A (en) * | 2022-08-26 | 2022-11-18 | 无锡市春阳印刷包装有限公司 | Thermochromic water-based ink for paper material and preparation method thereof |
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Application publication date: 20161116 |