CN106118297A - A kind of acrylic resin modified anti-static coatings of Graphene - Google Patents
A kind of acrylic resin modified anti-static coatings of Graphene Download PDFInfo
- Publication number
- CN106118297A CN106118297A CN201610518036.8A CN201610518036A CN106118297A CN 106118297 A CN106118297 A CN 106118297A CN 201610518036 A CN201610518036 A CN 201610518036A CN 106118297 A CN106118297 A CN 106118297A
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- China
- Prior art keywords
- parts
- graphene
- acrylic resin
- modified anti
- static coatings
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of acrylic resin modified anti-static coatings of Graphene, this coating comprises following parts by weight of component: water-borne acrylic resin 65 70 parts, isopropyl benzene hydroperoxide 68 parts, 58 parts of glacial acetic acid, polysulfone resin 13 15 parts, isocyanuric acid melamine 5 12 parts, Graphene 13 15 parts, NPE 8 13 parts, 35 parts of sulfomethylated humic acid sodium, Lauryl Alcohol ester 46 parts, dimethylformamide 10 12 parts.The acrylic resin modified anti-static coatings of Graphene of the present invention can effectively prevent electrostatic, and environmental protection, green, weatherability are strong, and coating surface is smooth, hard wear resistant, pressure impact resistance; good corrosion resistance; can play effect protection, service life is long, and easy construction.
Description
Technical field
The present invention relates to a kind of coating, particularly relate to a kind of acrylic resin modified anti-static coatings of Graphene.
Background technology
Anti-static coatings, also known as static conductive coating, the series of standards worked out with country, uses static conductive coating, from work
Industry building and equipment are designed with static conductive coating, and from the functional analysis of coating, coating can be led within the short time of 10-2 second
Let out electrostatic pressure savings, it is to avoid produce electric discharge and cause fire alarm or destroy the accident of electronic devices and components, and the generation of electrostatic with savings is
Nature objective reality, not opposing technical ability, led, for not measuring of fabric, the theoretical antistatic agent product let out,
Clothing accumulation of electrostatic in wearing process can be prevented.It is widely used in semi-conductor industry, LCD industry, electronics industrial, electric
Son electrically, communication manufacture, precision instrument, optics manufacture, the industry such as medical industry and biological engineering.
Acrylic resin, English name: poly (1-carboxyethylene) or Poly (acrylic acid).It is by third
The resin that olefin(e) acid esters and methyl acrylic ester and other olefinic type monomers copolymerization are made, by select different resin structure,
Different formula, production technology and solvent compositions, can synthesize the acrylic acid tree of dissimilar, different performance and different application occasion
Fat, acrylic resin can be divided into again thermoplastic acrylic resin and thermoset acrylics tree according to the difference of structure and membrane formation mechanism
Fat.With the acrylic resin of acrylate and methacrylate monomer copolymerization, the main absworption peak of light is in solar spectrum
Outside scope, so the acrylic resin paint prepared has the light resistance of excellence and anti-outdoor aging performance.And the most on the market
The shortcomings such as acrylic resin anti-static coatings compact in paint film is low, electrostatic conductive performance general, application property difference, the market share is relatively
Little.Along with developing rapidly of modern science and technology and production, along with coating is proposed the highest requirement, that is accomplished by painting
The performance of material proposes higher requirement.The most how overcoming the deficiencies in the prior art is that current those skilled in the art need solution badly
Problem.
Summary of the invention
It is an object of the invention to provide a kind of acrylic resin modified anti-static coatings of Graphene.
To achieve these goals, the invention provides a kind of acrylic resin modified anti-static coatings of Graphene, comprise
Following parts by weight of component: water-borne acrylic resin 65-70 part, isopropyl benzene hydroperoxide 6-8 part, glacial acetic acid 5-8 part, polysulfone resin
13-15 part, isocyanuric acid melamine 5-12 part, Graphene 13-15 part, NPE 8-13 part, the corruption of sulphur methyl
Grow acid sodium 3-5 part, Lauryl Alcohol ester 4-6 part, dimethylformamide 10-12 part.
It also comprises alkyl polyglucoside 10-15 part.
It also comprises VTES 5-7 part.
It also comprises mica powder 10-15 part.
Beneficial effect: the acrylic resin modified anti-static coatings of Graphene of the present invention can effectively prevent electrostatic, environmental protection,
Green, weatherability strong, and coating surface is smooth, hard wear resistant, pressure impact resistance, good corrosion resistance, effect can be played and protect
Protecting, service life is long, and easy construction.
Detailed description of the invention
Embodiment 1
The acrylic resin modified anti-static coatings of Graphene of the present embodiment, comprises following parts by weight of component: water soluble acrylic acid tree
65 parts of fat, isopropyl benzene hydroperoxide 6 parts, 5 parts of glacial acetic acid, polysulfone resin 13 parts, isocyanuric acid melamine 5 parts, Graphene 13
Part, NPE 8 parts, 3 parts of sulfomethylated humic acid sodium, Lauryl Alcohol ester 4 parts, dimethylformamide 10 parts.
Embodiment 2
The acrylic resin modified anti-static coatings of Graphene of the present embodiment, comprises following parts by weight of component: water soluble acrylic acid tree
70 parts of fat, isopropyl benzene hydroperoxide 8 parts, 8 parts of glacial acetic acid, polysulfone resin 15 parts, isocyanuric acid melamine 12 parts, Graphene 15
Part, NPE 13 parts, 5 parts of sulfomethylated humic acid sodium, Lauryl Alcohol ester 6 parts, dimethylformamide 12 parts, alkyl
15 parts of glucosides.
Embodiment 3
The acrylic resin modified anti-static coatings of Graphene of the present embodiment, comprises following parts by weight of component: water soluble acrylic acid tree
65 parts of fat, isopropyl benzene hydroperoxide 6 parts, 5 parts of glacial acetic acid, polysulfone resin 13 parts, isocyanuric acid melamine 5 parts, Graphene 13
Part, NPE 8 parts, 3 parts of sulfomethylated humic acid sodium, Lauryl Alcohol ester 4 parts, dimethylformamide 10 parts, alkyl
10 parts of glucosides, VTES 5 parts.
Embodiment 4
The acrylic resin modified anti-static coatings of Graphene of the present embodiment, comprises following parts by weight of component: water soluble acrylic acid tree
70 parts of fat, isopropyl benzene hydroperoxide 8 parts, 8 parts of glacial acetic acid, polysulfone resin 15 parts, isocyanuric acid melamine 12 parts, Graphene 15
Part, NPE 13 parts, 5 parts of sulfomethylated humic acid sodium, Lauryl Alcohol ester 6 parts, dimethylformamide 12 parts, alkyl
15 parts of glucosides, VTES 7 parts, mica powder 15 parts.
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, though
So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any technology people being familiar with this specialty
Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or modification
For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention
Any simple modification, equivalent variations and the modification being made above example, all still falls within the scope of technical solution of the present invention
In.
Claims (4)
1. the acrylic resin modified anti-static coatings of Graphene, it is characterised in that comprise following parts by weight of component: aqueous third
Olefin(e) acid resin 65-70 part, isopropyl benzene hydroperoxide 6-8 part, glacial acetic acid 5-8 part, polysulfone resin 13-15 part, isocyanuric acid trimerization
Cyanogen ammonium 5-12 part, Graphene 13-15 part, NPE 8-13 part, sulfomethylated humic acid sodium 3-5 part, Lauryl Alcohol
Ester 4-6 part, dimethylformamide 10-12 part.
2. according to the acrylic resin modified anti-static coatings of the Graphene described in claim 1, it is characterised in that: it also comprises
Alkyl polyglucoside 10-15 part.
3. according to the acrylic resin modified anti-static coatings of the Graphene described in claim 2, it is characterised in that: it also comprises
VTES 5-7 part.
The acrylic resin modified anti-static coatings of Graphene the most according to claim 3, it is characterised in that: it also comprises
Mica powder 10-15 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610518036.8A CN106118297A (en) | 2016-07-04 | 2016-07-04 | A kind of acrylic resin modified anti-static coatings of Graphene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610518036.8A CN106118297A (en) | 2016-07-04 | 2016-07-04 | A kind of acrylic resin modified anti-static coatings of Graphene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106118297A true CN106118297A (en) | 2016-11-16 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610518036.8A Pending CN106118297A (en) | 2016-07-04 | 2016-07-04 | A kind of acrylic resin modified anti-static coatings of Graphene |
Country Status (1)
| Country | Link |
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| CN (1) | CN106118297A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103097470A (en) * | 2010-08-05 | 2013-05-08 | 韩华石油化学株式会社 | High-efficiency heat-dissipating paint composition using a carbon material |
| CN103937350A (en) * | 2014-04-16 | 2014-07-23 | 常州大学 | Graphene-rod-like aluminum-doped zinc oxide antistatic coating and preparation method thereof |
| CN104449010A (en) * | 2014-12-26 | 2015-03-25 | 苏州格瑞丰纳米科技有限公司 | Polymer/graphene anti-static coating, preparation method and application thereof |
| JP2015078289A (en) * | 2013-10-16 | 2015-04-23 | 日本合成化学工業株式会社 | Coating composition, coating film obtained therefrom, multilayer structure, and method of manufacturing multilayer structure |
| CN105566973A (en) * | 2015-10-29 | 2016-05-11 | 中国航空工业集团公司北京航空材料研究院 | Cold-spraying-zinc anticorrosive paint with graphene and method for preparing cold-spraying-zinc anticorrosive paint |
| CN105670442A (en) * | 2016-04-18 | 2016-06-15 | 金华知产婺源信息技术有限公司 | Preparation method of dustproof anti-static automobile paint |
-
2016
- 2016-07-04 CN CN201610518036.8A patent/CN106118297A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103097470A (en) * | 2010-08-05 | 2013-05-08 | 韩华石油化学株式会社 | High-efficiency heat-dissipating paint composition using a carbon material |
| JP2015078289A (en) * | 2013-10-16 | 2015-04-23 | 日本合成化学工業株式会社 | Coating composition, coating film obtained therefrom, multilayer structure, and method of manufacturing multilayer structure |
| CN103937350A (en) * | 2014-04-16 | 2014-07-23 | 常州大学 | Graphene-rod-like aluminum-doped zinc oxide antistatic coating and preparation method thereof |
| CN104449010A (en) * | 2014-12-26 | 2015-03-25 | 苏州格瑞丰纳米科技有限公司 | Polymer/graphene anti-static coating, preparation method and application thereof |
| CN105566973A (en) * | 2015-10-29 | 2016-05-11 | 中国航空工业集团公司北京航空材料研究院 | Cold-spraying-zinc anticorrosive paint with graphene and method for preparing cold-spraying-zinc anticorrosive paint |
| CN105670442A (en) * | 2016-04-18 | 2016-06-15 | 金华知产婺源信息技术有限公司 | Preparation method of dustproof anti-static automobile paint |
Non-Patent Citations (1)
| Title |
|---|
| 胡楠等: "水性丙烯酸树脂", 《塑料工业》 * |
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Application publication date: 20161116 |
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