CN103589301B - A kind of ultraviolet light polymerization edge sealing transparent priming coating - Google Patents
A kind of ultraviolet light polymerization edge sealing transparent priming coating Download PDFInfo
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- CN103589301B CN103589301B CN201310559524.XA CN201310559524A CN103589301B CN 103589301 B CN103589301 B CN 103589301B CN 201310559524 A CN201310559524 A CN 201310559524A CN 103589301 B CN103589301 B CN 103589301B
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- edge sealing
- ultraviolet light
- light polymerization
- transparent priming
- sealing transparent
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Abstract
The present invention relates to paint field, particularly to a kind of ultraviolet light polymerization edge sealing transparent priming coating.A kind of ultraviolet light polymerization edge sealing transparent priming coating, it is characterised in that be made up of the component of following mass percent: resin 23 ~ 53%；Monomer 20 ~ 40%；Filler 10 ~ 25%；Light trigger 4 ~ 7%；Defoamer 0.2 ~ 0.5%；Levelling agent 0.1 ~ 0.3%；Anti-settling agent 5 ~ 8%；Described resin is epoxy acrylate, modified epoxy acrylate, the mixture of modified polyurethane acrylate.The painting material process of the present invention is simple, and viscosity is low, and levelling line is good, carries out edge sealing in the case of without PU or PE priming paint.
Description
Technical field
The present invention relates to paint field, particularly to a kind of ultraviolet light polymerization edge sealing transparent priming coating.
Background technology
UV paint is photocureable coating, and it is current Application comparison one of furniture lacquer widely, and main feature has: process through intensive ultraviolet photocuring, color stability, for a long time Chang Xin.So being widely used at aspects such as cabinet family properties, resist collapse, hardness, reduction cost etc. can be improved, but on the edge sealing of cabinet family property, govern the efficiency of production.On edge sealing, general UV paint reaches to spray requirement, and levelling line to be increased owing to needs interpolation solvent reduces viscosity, and paint film penetrating odor is big, and environmental pollution is serious, causes UV to paint Difficulty.Traditional way is to carry out edge sealing with PU or PE priming paint.So causing operation to increase, man-hour lengthens, and reduces the whole efficiency of application.
Summary of the invention
It is simple that the technical problem to be solved is to provide a kind of operation, good leveling property, the ultraviolet light polymerization edge sealing transparent priming coating that viscosity is low.
The technical problem to be solved is achieved by the following technical programs:
A kind of ultraviolet light polymerization edge sealing transparent priming coating, it is made up of the component of following mass percent:
Resin 23 ~ 53%；
Monomer 20 ~ 40%；
Filler 10 ~ 25%；
Light trigger 4 ~ 7%；
Defoamer 0.2 ~ 0.5%；
Levelling agent 0.1 ~ 0.3%；
Anti-settling agent 5 ~ 8%.
Described resin is epoxy acrylate, modified epoxy acrylate, the mixture of modified polyurethane acrylate.
Further, described resin accounts for the mass percent of total formula weight and is: epoxy acrylate 5 ~ 15%, modified epoxy acrylate 15 ~ 30%, modified polyurethane acrylate 3 ~ 8%.Epoxy acrylate used is standard epoxy acrylate.Modified epoxy acrylate is the modified epoxy acrylate that the art is conventional, being coated with beautiful YTM2085 as refined, it has extraordinary pliability as matrix resin, and contractility ratio is relatively low, can effectively reduce the shrinkage stress of system, the raising to adhesive force has well effect.Modified urethane acrylate selects the modified urethane acrylate that the art is conventional, it is coated with beautiful YTM5200 as refined, it is as assisted resin, there are extraordinary wettability and low-down contractility, relatively low viscosity plays reduction paint viscosity, and selected resin defoaming is good, it is possible to quickly froth breaking, workability is made to reach requirement.
Further, described monomer be tri (propylene glycol) diacrylate (TPGDA), trimethylolpropane trimethacrylate (TMPTA), 1, at least one in 6-hexanediyl ester (HDDA), hydroxyethyl methylacrylate (HEMA)；They can play reduction viscosity, improves adhesive force, and can give the good levelability of product and dilution property, improves the effect of paint film.
Further, described filler is at least one in Pulvis Talci, transparent powder, zinc stearate.
Further, described light trigger be 1-hydroxyl-cyclohexyl-phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, (2,4; 6-trimethylbenzoyl) at least one in diphenyl phosphine oxide; they play reduction viscosity, increase hardness and resistance to scraping, improve the effect of adhesive force.
Further, described defoamer is acrylic acid defoamer, and such as the BYK141 that the art is conventional, levelling agent is BYK-333 or DEGO450 that acrylic acid levelling agent, preferably the art are conventional.
The most described anti-settling agent is at least one in organobentonite, Tissuemat E, aerosil.
There is advantages that
In the middle of the present invention, can be painted on ground by this priming paint, by ultraviolet light polymerization, reduce operation, man-hour, efficiency is greatly improved.And on the premise of need not add any solvent, the dope viscosity of the present invention is low, and levelling line is good, in the case of without PU or PE priming paint, carry out edge sealing.
Detailed description of the invention
Above-mentioned material is fabricated to photocureable priming coat by the painting method commonly used according to those skilled in the art.
Following example are the ultraviolet light polymerization preferred formula of edge sealing transparent priming; these formula are non-limiting implementation; it is for illustrating the present invention, and those skilled in the art can be protection scope of the present invention according to the formula that the thinking of the present invention and proportioning of selecting materials filter out completely.
Embodiment 1
A kind of ultraviolet light polymerization edge sealing transparent priming, by weight percentage: epoxy acrylate 5%, YTM2085 15%, YTM5200 3%, TPGDA 15.4%, TMPTA 12%, HDDA 11%, HEMA 6%, Pulvis Talci 3%, calcium carbonate 7%, zinc stearate 10%, 184 2%, TPO 3%, BKY141 0.4%, BYK-333 0.2%, Tissuemat E 6%, aerosil 1%.Above-mentioned material is fabricated to photocureable priming coat by the painting method commonly used according to those skilled in the art, with in spraying process application to ground, and the fast setting of UV paint, can greatly improve production efficiency.Test abnormal smells from the patient after solidification, can reach the effect of low abnormal smells from the patient.Being painted on ground by this priming paint, by ultraviolet light polymerization, reduce operation, man-hour, efficiency is greatly improved.
Embodiment 2
A kind of ultraviolet light polymerization edge sealing transparent priming, by weight percentage: epoxy acrylate 5%, YTM2085 18%, YTM5200 5%, TPGDA 17.3%, TMPTA 12%, HDDA 8%, calcium carbonate 10%, transparent powder 12%, TPO 4%, BKY141 0.5%, BYK-333 0.2%, organobentonite 4%, Tissuemat E 4%.Above-mentioned material is fabricated to photocureable priming coat by the painting method commonly used according to those skilled in the art, with in spraying process application to ground, and the fast setting of UV paint, can greatly improve production efficiency.Test abnormal smells from the patient after solidification, can reach the effect of low abnormal smells from the patient.Being painted on ground by this priming paint, by ultraviolet light polymerization, reduce operation, man-hour, efficiency is greatly improved.
Embodiment 3
A kind of ultraviolet light polymerization edge sealing transparent priming, by weight percentage: epoxy acrylate 8%, YTM2085 18%, YTM5200 5%, TPGDA 15%, HEMA 18%, transparent powder 12%, zinc stearate 10%, 184 3%, 1173 2.5%, BKY141 0.2%, DEGO450 0.3%, Tissuemat E 8%, above-mentioned material is fabricated to photocureable priming coat by the painting method commonly used according to those skilled in the art, with in spraying process application to ground, the fast setting of UV paint, can greatly improve production efficiency.Test abnormal smells from the patient after solidification, can reach the effect of low abnormal smells from the patient.Being painted on ground by this priming paint, by ultraviolet light polymerization, reduce operation, man-hour, efficiency is greatly improved.
Embodiment 4
A kind of ultraviolet light polymerization edge sealing transparent priming, by weight percentage: epoxy acrylate 10%, YTM2085 20%, YTM5200 5%, TMPTA 16%, HDDA 12%, HEMA 6%, calcium carbonate 15%, 1,173 5.2%, BKY141 0.5%, BYK-333 0.3%, machine bentonite 2%, Tissuemat E 5%, aerosil 3%.Above-mentioned material is fabricated to photocureable priming coat by the painting method commonly used according to those skilled in the art, with in spraying process application to ground, and the fast setting of UV paint, can greatly improve production efficiency.Test abnormal smells from the patient after solidification, can reach the effect of low abnormal smells from the patient.Being painted on ground by this priming paint, by ultraviolet light polymerization, reduce operation, man-hour, efficiency is greatly improved.
Embodiment 5
A kind of ultraviolet light polymerization edge sealing transparent priming, by weight percentage: epoxy acrylate 10%, YTM2085 22%, YTM5200 6%, TMPTA 7%, HDDA 9%, HEMA 14%, calcium carbonate 13%, transparent powder 7%, 1173 2%, 184 4%, BKY141 0.4%, DEGO450 0.1%, organobentonite 3%, Tissuemat E 2.5%.Above-mentioned material is fabricated to photocureable priming coat by the painting method commonly used according to those skilled in the art, with in vacuum deposition application to ground, and the fast setting of UV paint, can greatly improve production efficiency.Test performance after solidification, can reach the edge sealing performance of routine.By direct for this priming paint airless spraying on ground, by ultraviolet light polymerization, reducing operation, man-hour, efficiency is greatly improved.
Embodiment 6
A kind of ultraviolet light polymerization edge sealing transparent priming, by weight percentage: epoxy acrylate 15%, YTM2085 25%, YTM5200 8%, HDDA 21%, zinc stearate 9%, Pulvis Talci 10%, 184 1%, TPO 4%, BKY141 0.4%, DEGO450 0.3%, organobentonite 2%, Tissuemat E 3%, aerosil 1.3%.Above-mentioned material is fabricated to photocureable priming coat by the painting method commonly used according to those skilled in the art, with in spraying process application to ground, and the fast setting of UV paint, can greatly improve production efficiency.Test abnormal smells from the patient after solidification, can reach the effect of low abnormal smells from the patient.Being painted on ground by this priming paint, by ultraviolet light polymerization, reduce operation, man-hour, efficiency is greatly improved.
Embodiment described above only have expressed embodiments of the present invention; it describes more concrete and detailed; but therefore can not be interpreted as the restriction to the scope of the claims of the present invention; in every case the technical scheme using the form of equivalent or equivalent transformation to be obtained, all should fall within the scope and spirit of the invention.
Claims (4)
1. a ultraviolet light polymerization edge sealing transparent priming coating, it is characterised in that be made up of the component of following mass percent:
Resin 23～53%；
Monomer 20～40%；
Filler 10～25%；
Light trigger 4～7%；
Defoamer 0.2～0.5%；
Levelling agent 0.1～0.3%；
Anti-settling agent 5～8%；
Described resin is the mixture of epoxy acrylate, modified epoxy acrylic ester, modified urethane acrylate,
Described resin accounts for the mass percent of total formula weight: epoxy acrylate 5～15%, modified epoxy acrylic ester 15～30%, modified urethane acrylate 3～8%,
Described monomer be tri (propylene glycol) diacrylate, trimethylolpropane trimethacrylate, 1, at least one in 6-hexanediyl ester, hydroxyethyl methylacrylate,
Described filler is at least one in Pulvis Talci, transparent powder, zinc stearate.
A kind of ultraviolet light polymerization edge sealing transparent priming coating the most according to claim 1; it is characterized in that: described light trigger be 1-hydroxy-cyclohexyl-phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, (2; 4,6-trimethylbenzoyls) at least one in diphenyl phosphine oxide.
A kind of ultraviolet light polymerization edge sealing transparent priming coating the most according to claim 1, it is characterised in that: described defoamer is acrylic acid defoamer, and levelling agent is acrylic acid levelling agent.
A kind of ultraviolet light polymerization edge sealing transparent priming coating the most according to claim 1, it is characterised in that: described anti-settling agent is at least one in organobentonite, Tissuemat E, aerosil.
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| CN201310559524.XA CN103589301B (en) | 2013-11-12 | 2013-11-12 | A kind of ultraviolet light polymerization edge sealing transparent priming coating |
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| CN201310559524.XA CN103589301B (en) | 2013-11-12 | 2013-11-12 | A kind of ultraviolet light polymerization edge sealing transparent priming coating |
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| CN103589301A CN103589301A (en) | 2014-02-19 |
| CN103589301B true CN103589301B (en) | 2016-08-17 |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130670A (en) * | 2014-08-20 | 2014-11-05 | 崇州市美涂士涂料科技有限公司 | Solvent-free UV vacuum spraying under-coating paint and preparation method thereof |
| CN104152007A (en) * | 2014-08-20 | 2014-11-19 | 崇州市美涂士涂料科技有限公司 | Solvent-free UV vacuum spraying priming paint and preparation method thereof |
| CN104530903A (en) * | 2014-12-11 | 2015-04-22 | 惠州市长润发涂料有限公司 | Leveling-free UV primer for vacuum spraying |
| CN104830209A (en) * | 2015-05-04 | 2015-08-12 | 君子兰化工（上海）有限公司 | Organic volatile solvent-free environmentally friendly anti-cracking transparent UV spray priming paint |
| CN106010066A (en) * | 2016-05-31 | 2016-10-12 | 无锡伊佩克科技有限公司 | Ultraviolet-cured aqueous polyurethane antibacterial coating and preparation method thereof |
| CN108299886A (en) * | 2016-08-10 | 2018-07-20 | 上海长悦涂料有限公司 | A kind of solvent-free UV spray paints coating and preparation method thereof |
| CN109929396A (en) * | 2017-12-15 | 2019-06-25 | 惠州市长润发涂料有限公司 | A kind of UV Kun painting transparent priming applied to building material surface |
| CN112280440A (en) * | 2019-07-25 | 2021-01-29 | 上海飞凯光电材料股份有限公司 | UV adhesive coating, preparation method thereof and preparation method of coated workpiece |
| CN110564270A (en) * | 2019-08-23 | 2019-12-13 | 广州凌玮科技股份有限公司 | Antirust UV (ultraviolet) curing coating |
| CN110804372A (en) * | 2019-12-06 | 2020-02-18 | 上海展辰涂料有限公司 | UV vacuum spraying transparent primer suitable for water-based finish paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544869A (en) * | 2008-03-27 | 2009-09-30 | 上海富臣化工有限公司 | Packless ultraviolet curing transparent priming lacquer for woodenware |
| CN102134437A (en) * | 2011-02-28 | 2011-07-27 | 上虞市佑谦特种材料有限公司 | UV (ultraviolet)-curing glass coating paint |
| CN103305100A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | Ultraviolet (UV)-spray sanding primer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR970004598B1 (en) * | 1993-12-30 | 1997-03-29 | 고려화학 주식회사 | Photo-hardening coating composition |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101544869A (en) * | 2008-03-27 | 2009-09-30 | 上海富臣化工有限公司 | Packless ultraviolet curing transparent priming lacquer for woodenware |
| CN102134437A (en) * | 2011-02-28 | 2011-07-27 | 上虞市佑谦特种材料有限公司 | UV (ultraviolet)-curing glass coating paint |
| CN103305100A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | Ultraviolet (UV)-spray sanding primer |
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Address after: 516221 No. 30 Xiayong Petrochemical Avenue, Daya Bay, Huizhou City, Guangdong Province Co-patentee after: TIANJIN CHANGRUNFA CHEMICAL Co.,Ltd. Patentee after: Guangdong Libang Changrunfa Science and Technology Material Co.,Ltd. Address before: 516221 Xintang Industrial Zone, Qiuchang Town, Huiyang District, Huizhou City, Guangdong Province Co-patentee before: TIANJIN CHANGRUNFA CHEMICAL Co.,Ltd. Patentee before: HUIZHOU CHANGRUNFA COATING Co.,Ltd. |
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Effective date of registration: 20221219 Address after: 516221 No. 30 Xiayong Petrochemical Avenue, Daya Bay, Huizhou City, Guangdong Province Patentee after: Guangdong Libang Changrunfa Science and Technology Material Co.,Ltd. Address before: 516221 No. 30 Xiayong Petrochemical Avenue, Daya Bay, Huizhou City, Guangdong Province Patentee before: Guangdong Libang Changrunfa Science and Technology Material Co.,Ltd. Patentee before: TIANJIN CHANGRUNFA CHEMICAL Co.,Ltd. |
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