CN103756518A - Laser roller painting UV (ultraviolet) matte white paint - Google Patents

Laser roller painting UV (ultraviolet) matte white paint Download PDF

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Publication number
CN103756518A
CN103756518A CN201310743427.6A CN201310743427A CN103756518A CN 103756518 A CN103756518 A CN 103756518A CN 201310743427 A CN201310743427 A CN 201310743427A CN 103756518 A CN103756518 A CN 103756518A
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CN
China
Prior art keywords
radium
finish paint
roller coat
dumb light
white finish
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310743427.6A
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Chinese (zh)
Inventor
叶谦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI CHANGRUNFA PAINT CO Ltd
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SHANGHAI CHANGRUNFA PAINT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by SHANGHAI CHANGRUNFA PAINT CO Ltd filed Critical SHANGHAI CHANGRUNFA PAINT CO Ltd
Priority to CN201310743427.6A priority Critical patent/CN103756518A/en
Publication of CN103756518A publication Critical patent/CN103756518A/en
Pending legal-status Critical Current

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Abstract

The invention provides a laser roller painting UV (ultraviolet) matte white paint. The white paint comprises UV white pulp, polyester acrylic resin, a reactive diluent, a flatting agent and filler, wherein the UV white pulp is prepared by mixing raw materials comprising standard bisphenol A epoxy acrylic resin, dispersing agent and titanium dioxide, and the white paint also can comprise an additive and a photoinitiator. The laser roller painting UV matte white paint has good covering power, aridity, adhesive force and yellowing resistance, and excellent hand feeling; the white paint is painted by laser, and the paint film has excellent flatness and can be widely used in flow line production.

Description

The radium-shine roller coat dumb light of a kind of UV white finish paint
Technical field
The present invention relates to a kind of UV white finish paint, relate in particular to the radium-shine roller coat dumb light of a kind of UV white finish paint.
Background technology
Coating, is also referred to as paint, refers to coat that body surface can form film under certain conditions and play protection, decorate or a class I liquid I or the solid material of other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.).By filmogen, can be divided into pyroxylin(e)finish, ethenoid resin paint, Polyester Paint etc.
Coating is generally comprised of filmogen, auxiliary agent, solvent and pigment.Filmogen comprises emulsion, resin etc., is the main component of filming, and determines the fundamental property of coating; Auxiliary agent comprises defoamer, flow agent etc., can not film forming and addition little, base-material is formed to process and the weather resistance of filming and plays considerable effect; Solvent comprises varsol, lipid solvent, ether solvent etc., contributes to construction and improves some performance of filming; Dyestuff comprises tinting pigment such as titanium dioxide, chrome yellow etc. and pigment extender such as calcium carbonate, talcum powder etc., for paint film provides color and opacifying power.
Traditional coating exists VOC to discharge too high problem, and also due to the rising of cost of material and the demand of environment, in order to limit the discharge of VOC, green coating becomes one of research centre.
UV paint is the english abbreviation of Ultraviolet Curing Paint, and ultraviolet light cured paint, also claims light-initiated coating or photo-cured coating.Generally, UV paint be by the automatic roller coat of machinery equipment or showering to furniture plate surface, under the irradiation of UV-light (wavelength is 320～390nm), impel decomposition of initiator, produce free radical, cause resin reaction, instantaneous solidification film forming.UV paint, due to features such as solid content are high, VOC discharge is low, rate of drying is fast, has obtained a large amount of research and fast development.
As Chinese patent CN103031034A discloses a kind of white finish paint optical curing of UV coating and preparation method thereof, it consists of weight percent and counts: 20～60% epoxy acrylate, 20～60% urethane acrylate, 2～5% phenyl-acetone light trigger, 0.2～1% phenyl phosphine oxide light trigger, 0.2～1% dispersion agent, 0.2～1% flow agent, 1～40% titanium dioxide, 2 functional group's reactive thinners of 5～15%, 3 functional group's reactive thinners of 5～30%.This coating has the feature of gloss sticking power good leveling property.
But UV white finish paint because opacifying power is poor, solidifies rear surface weak effect in roller coat, suffered restriction is larger in actual applications, cannot substitute traditional solvent-borne type spraying paint.
Summary of the invention
For above-mentioned technical problem, the radium-shine roller coat dumb light of a kind of UV white finish paint provided by the present invention.
The invention provides the radium-shine roller coat dumb light of a kind of UV white finish paint, count by weight, comprise:
Wherein, the white slurry of described UV is become by the mixed raw material that comprises standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide, and the weight ratio of described standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide is (38～58): (0.2～2): (40～60).
Wherein, the radium-shine roller coat dumb light of described UV white finish paint can also comprise light trigger; weighing scale with the radium-shine roller coat dumb light of described UV white finish paint; described light trigger is 2～6 parts of weight parts; described light trigger can be selected from 2-hydroxy-2-methyl-1-phenyl-acetone, 1-hydroxy-cyclohexyl phenyl ketone, 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide, phenyl two (2; 4,6-trimethylbenzoyl phosphine oxide) one or more in.
Preferably; described light trigger comprises 2-hydroxy-2-methyl-1-phenyl-acetone, 2; 4; 6-trimethylbenzoyl-diphenyl phosphine oxide; weighing scale with the radium-shine roller coat dumb light of described UV white finish paint; described 2-hydroxy-2-methyl-1-phenyl-acetone is 1～4 weight part, described 2,4, and 6-trimethylbenzoyl-diphenyl phosphine oxide is 1～2 weight part.
Preferably, described light trigger comprises 2-hydroxy-2-methyl-1-phenyl-acetone, and with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described 2-hydroxy-2-methyl-1-phenyl-acetone is 4 weight parts.
Wherein, the radium-shine roller coat dumb light of described UV white finish paint also can also comprise auxiliary agent, weighing scale with the radium-shine roller coat dumb light of described UV white finish paint, described auxiliary agent is 0.5～2 weight part, and described auxiliary agent can be any one or a few in defoamer, wetting dispersing agent, flow agent, anti-settling agent, ultraviolet absorbers.
Preferably, described auxiliary agent comprises defoamer, anti-settling agent, wetting dispersing agent, in the parts by weight of the radium-shine roller coat dumb light of described UV white finish paint, described defoamer is that 0.01～0.2 weight part, described anti-settling agent are that 0.1～1.2 weight part, described wetting dispersing agent are 0.1～0.6 weight part.
More preferably, described auxiliary agent comprises defoamer, anti-settling agent, wetting dispersing agent, in the parts by weight of the radium-shine roller coat dumb light of described UV white finish paint, described defoamer is that 0.1 weight part, described anti-settling agent are that 0.6 weight part, described wetting dispersing agent are 0.3 weight part.
Preferably, described defoamer is acrylate defoamer.
Preferably, described anti-settling agent is polyamide wax anti-settling agent.
Preferably, described wetting dispersing agent is BYK2150 or BYK2009.
Preferably, the white slurry of described UV is mixed by standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide.
Preferably, to starch in vain the weight ratio of Plays bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide be 54:1:45 to described UV.
Preferably, described titanium dioxide is Rutile type Titanium Dioxide or anatase thpe white powder, and Rutile type Titanium Dioxide more preferably.
Preferably, the solid content of the radium-shine roller coat dumb light of described UV white finish paint is 100%.
Wherein, described reactive thinner is selected from any one or a few in tri (propylene glycol) diacrylate, Viscoat 295, hydroxyethyl methylacrylate, 1,6 hexanediol diacrylate.
Preferably, described reactive thinner comprises tri (propylene glycol) diacrylate, Viscoat 295, with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described tri (propylene glycol) diacrylate work is that 12～18 weight parts, described Viscoat 295 are 15～20 weight parts.
Preferably, described reactive thinner comprises tri (propylene glycol) diacrylate, Viscoat 295, hydroxyethyl methylacrylate, with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described tri (propylene glycol) diacrylate is that 10～15 weight parts, described Viscoat 295 are that 15～20 weight parts, described hydroxyethyl methylacrylate are 2～5 weight parts.
Wherein, described matting agent can be selected from one or more in aerosil, diatomite, delustring wax powder.
Preferably, described matting agent comprises aerosil, and with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described aerosil is 6～8 weight parts.
More preferably, described aerosil is Grace 2105.
Wherein, described filler can be selected from one or more in talcum powder, transparent powder, coarse whiting.
Preferably, described filler comprises talcum powder, and with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described talcum powder is 3.5～6 weight parts.
Preferably, described talcous particle diameter is 1200～2000 orders.
It is good that UV dumb light white finish paint provided by the invention has opacifying power, and drying property is good, and sticking power is good, and feel is splendid, photocuring film forming have surface smoothing, hardness high, without special odor, process velocity is fast and have certain yellowing resistance.Adopt radium-shine roller application, there is excellent planeness.
Embodiment
The invention provides the radium-shine roller coat dumb light of a kind of UV white finish paint, count by weight, comprise:
Wherein, the white slurry of described UV is mixed by standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide, and the weight ratio of described standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide is (38～58): (0.2～2): (40～60).
The radium-shine roller coat dumb light of described UV white finish paint can also comprise auxiliary agent, and in the radium-shine roller coat dumb light of described UV white finish paint parts by weight, described auxiliary agent is 0.5～2 weight part.
The radium-shine roller coat dumb light of described UV white finish paint can also comprise light trigger, and in the radium-shine roller coat dumb light of described UV white finish paint parts by weight, described light trigger is 2～6 weight parts.
Below by specific embodiment, the present invention is carried out to detailed and concrete introduction, to better understand the present invention, but following examples do not limit the scope of the invention.
Embodiment 1
The radium-shine roller coat dumb light of UV white finish paint described in the present embodiment, counts by weight, comprises:
Wherein, UV starches preparation process in vain: standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide are distributed to fineness and are less than 20 microns below 50oC, make UV and starch in vain, wherein, the weight ratio of standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide is 54:1:45.
Above-mentioned each component is mixed, and 600rpm～900rpm stirs 40～50 minutes, has both obtained the radium-shine roller coat dumb light of UV white finish paint.
Embodiment 2
The radium-shine roller coat dumb light of UV white finish paint described in the present embodiment, counts by weight, comprises:
Wherein, UV starches preparation process in vain: standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide are distributed to fineness and are less than 20 microns below 50oC, make UV and starch in vain, wherein, the weight ratio of standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide is 54:1:45.
Above-mentioned each component is mixed, and 600rpm～900rpm stirs 40～50 minutes, has both obtained the radium-shine roller coat dumb light of UV white finish paint.
Embodiment 3
The radium-shine roller coat dumb light of UV white finish paint described in the present embodiment, counts by weight, comprises:
Wherein, UV starches preparation process in vain: standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide are distributed to fineness and are less than 20 microns below 50oC, make UV and starch in vain, wherein, the weight ratio of standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide is 54:1:45.
Above-mentioned each component is mixed, and 600rpm～900rpm stirs 40～50 minutes, has both obtained the radium-shine roller coat dumb light of UV white finish paint.
Embodiment 4
The radium-shine roller coat dumb light of UV white finish paint described in the present embodiment, counts by weight, comprises:
Wherein, UV starches preparation process in vain: standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide are distributed to fineness and are less than 20 microns below 50oC, make UV and starch in vain, wherein, the weight ratio of standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide is 54:1:45.
Above-mentioned each component is mixed, and 600rpm～900rpm stirs 40～50 minutes, has both obtained the radium-shine roller coat dumb light of UV white finish paint.
Embodiment 5
The radium-shine roller coat dumb light of UV white finish paint described in the present embodiment, counts by weight, comprises:
Wherein, UV starches preparation process in vain: standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide are distributed to fineness and are less than 20 microns below 50oC, make UV and starch in vain, wherein, the weight ratio of standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide is 54:1:45.
Above-mentioned each component is mixed, and 600rpm～900rpm stirs 40～50 minutes, has both obtained the radium-shine roller coat dumb light of UV white finish paint.
The radium-shine roller coat dumb light of UV provided by the invention white finish paint opacifying power is good, and drying property is good, and sticking power is good, feel is splendid, and hardness is greater than 1H, and has certain yellowing resistance, reach as high as 0.5, glossiness can change on a large scale at 15～80 degree by adjusting the content of matting agent.Adopt radium-shine roller application, film forming paint film planeness is fabulous, and efficiency is high, can significantly simplify production process, enhances productivity, and reduces input artificial, paint, reduce production costs, and environmental friendliness, VOC free discharge.
Above specific embodiments of the invention be have been described in detail, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and alternative also all among category of the present invention.Therefore, equalization conversion and the modification done without departing from the spirit and scope of the invention, all should contain within the scope of the invention.

Claims (10)

1. the radium-shine roller coat dumb light of a UV white finish paint, is characterized in that, counts by weight, comprises:
Wherein, the white slurry of described UV is become by the mixed raw material that comprises bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide, and the weight ratio of described standard bisphenol-A epoxy acrylic resin, dispersion agent and titanium dioxide is (38～58): (0.2～2): (40～60).
2. the radium-shine roller coat dumb light of UV white finish paint as claimed in claim 1, it is characterized in that, described reactive thinner comprises tri (propylene glycol) diacrylate, Viscoat 295, with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described tri (propylene glycol) diacrylate is that 12～18 weight parts, described Viscoat 295 are 15～20 weight parts.
3. the radium-shine roller coat dumb light of UV white finish paint as claimed in claim 1, it is characterized in that, described reactive thinner comprises tri (propylene glycol) diacrylate, Viscoat 295, hydroxyethyl methylacrylate, with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described tri (propylene glycol) diacrylate is that 10～15 weight parts, described Viscoat 295 are that 15～20 weight parts, described hydroxyethyl methylacrylate are 2～5 weight parts.
4. the radium-shine roller coat dumb light of UV white finish paint as claimed in claim 1, is characterized in that, described matting agent comprises aerosil, and with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described aerosil is 6～8 weight parts.
5. the radium-shine roller coat dumb light of UV white finish paint as claimed in claim 1, is characterized in that, described filler comprises talcum powder, and with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described talcum powder is 3.5～6 weight parts.
6. the radium-shine roller coat dumb light of UV white finish paint as claimed in claim 1, is characterized in that, the radium-shine roller coat dumb light of described UV white finish paint also comprises light trigger, and with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described light trigger is 2～6 weight parts.
7. the radium-shine roller coat dumb light of UV white finish paint as claimed in claim 6; it is characterized in that; described light trigger comprises 2-hydroxy-2-methyl-1-phenyl-acetone and 2; 4; 6-trimethylbenzoyl-diphenyl phosphine oxide, with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described 2-hydroxy-2-methyl-1-phenyl-acetone is 1～4 weight part, described 2; 4,6-trimethylbenzoyl-diphenyl phosphine oxide is 1～2 weight part.
8. the radium-shine roller coat dumb light of UV white finish paint as claimed in claim 6, it is characterized in that, the radium-shine roller coat dumb light of described UV white finish paint also comprises auxiliary agent, weighing scale with the radium-shine roller coat dumb light of described UV white finish paint, described auxiliary agent is 0.5～2 weight part, and described auxiliary agent is selected from any one or a few in defoamer, wetting dispersing agent, flow agent, anti-settling agent, ultraviolet absorbers.
9. the radium-shine roller coat dumb light of UV white finish paint as claimed in claim 8, it is characterized in that, described auxiliary agent comprises defoamer, anti-settling agent, dispersion agent, with the weighing scale of the radium-shine roller coat dumb light of described UV white finish paint, described defoamer is that 0.01～0.2 weight part, described anti-settling agent are that 0.1～1.2 weight part, described dispersion agent are 0.1～0.6 weight part.
10. as the radium-shine roller coat dumb light of UV as described in claim 1～9 any one white finish paint, it is characterized in that, it is 100% that the radium-shine roller coat dumb light of described UV white finish paint solidifies amount.
CN201310743427.6A 2013-12-27 2013-12-27 Laser roller painting UV (ultraviolet) matte white paint Pending CN103756518A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103980803A (en) * 2014-06-04 2014-08-13 广东美涂士建材股份有限公司 UV woodware laser roller-coating white finish coat and preparation method thereof
CN104073165A (en) * 2014-06-26 2014-10-01 林创举 UV (ultraviolet) paint capable of being quickly dried from inside to outside
CN105111857A (en) * 2015-07-20 2015-12-02 百仪家具有限公司 High-grade furniture transparent primer
CN106700841A (en) * 2015-11-15 2017-05-24 惠州市长润发涂料有限公司 Laser roller painting type UV matted white finish
CN111471375A (en) * 2020-04-30 2020-07-31 上海展辰涂料有限公司 Anti-scratch photocuring odorless matte white finish

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103980803A (en) * 2014-06-04 2014-08-13 广东美涂士建材股份有限公司 UV woodware laser roller-coating white finish coat and preparation method thereof
CN104073165A (en) * 2014-06-26 2014-10-01 林创举 UV (ultraviolet) paint capable of being quickly dried from inside to outside
CN104073165B (en) * 2014-06-26 2016-05-04 广东葫芦堡文化科技股份有限公司 One is rapid-curing cutback UV paint from inside to outside
CN105111857A (en) * 2015-07-20 2015-12-02 百仪家具有限公司 High-grade furniture transparent primer
CN106700841A (en) * 2015-11-15 2017-05-24 惠州市长润发涂料有限公司 Laser roller painting type UV matted white finish
CN111471375A (en) * 2020-04-30 2020-07-31 上海展辰涂料有限公司 Anti-scratch photocuring odorless matte white finish

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