CN103589301A - Transparent ultraviolet-curing edge-sealing primer coating - Google Patents

Transparent ultraviolet-curing edge-sealing primer coating Download PDF

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Publication number
CN103589301A
CN103589301A CN201310559524.XA CN201310559524A CN103589301A CN 103589301 A CN103589301 A CN 103589301A CN 201310559524 A CN201310559524 A CN 201310559524A CN 103589301 A CN103589301 A CN 103589301A
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China
Prior art keywords
edge sealing
ultraviolet light
light polymerization
agent
transparent priming
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CN201310559524.XA
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Chinese (zh)
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CN103589301B (en
Inventor
阳辉
练世斌
戴超
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Guangdong Libang Changrunfa Science and Technology Material Co., Ltd.
TIANJIN CHANGRUNFA CHEMICAL CO., LTD.
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TIANJIN CHANGRUNFA CHEMICAL Co Ltd
Huizhou Changrunfa Coating Co Ltd
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Publication of CN103589301A publication Critical patent/CN103589301A/en
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Publication of CN103589301B publication Critical patent/CN103589301B/en
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Abstract

The invention relates to the field of coatings, particularly to a transparent ultraviolet-curing edge-sealing primer coating. The transparent ultraviolet-curing edge-sealing primer coating is characterized by comprising components in percentage by mass as follows; 23-53% of resin, 20-40% of monomers, 10-25% of a filler, 4-7% of a photoinitiator, 0.2-0.5% of an antifoaming agent, 0.1-0.3% of a leveling agent and 5-8% of an anti-setting agent; and the resin is a mixture of epoxy acrylate, modified epoxy acrylate and modified polyurethane acrylate. The coating is simple in process, low in viscosity and good in leveling property, and edges can be sealed with no PU (poly urethane) or PE (poly ethylene) primer required.

Description

A kind of ultraviolet light polymerization edge sealing transparent priming coating
Technical field
The present invention relates to paint field, particularly a kind of ultraviolet light polymerization edge sealing transparent priming coating.
Background technology
UV paint is photo-cured coating, and it is one of the furniture lacquer more widely of application at present, and principal feature has: through intensive ultraviolet photocuring, process, color and luster is stable, for a long time Chang Xin.So be widely used at aspects such as cabinet family properties, can improve and anti-subside, hardness, reduce costs etc., but restricting the efficiency of producing on the edge sealing of cabinet family property.On edge sealing, general UV paint reduces viscosity and reaches spraying requirement because needs add solvent, and will increase levelling line, and paint film irritating smell is large, and environmental pollution is serious, causes UV paint Difficulty.Traditional way is to carry out edge sealing with PU or PE priming paint.Cause like this operation to increase, lengthen man-hour, reduced the whole efficiency of application.
 
Summary of the invention
It is simple that technical problem to be solved by this invention is to provide a kind of operation, good leveling property, the ultraviolet light polymerization edge sealing transparent priming coating that viscosity is low.
Technical problem to be solved by this invention is achieved by the following technical programs:
An edge sealing transparent priming coating, its component by following mass percent forms:
Resin 23 ~ 53%;
Monomer 20 ~ 40%;
Weighting agent 10 ~ 25%;
Light trigger 4 ~ 7%;
Defoamer 0.2 ~ 0.5%;
Flow agent 0.1 ~ 0.3%;
Anti-settling agent 5 ~ 8%.
Described resin is the mixture of epoxy acrylate, modified epoxy CALCIUM ACRYLATE, modified polyurethane CALCIUM ACRYLATE.
Further, described resin account for formula gross weight mass percent be: epoxy acrylate 5 ~ 15%, modified epoxy CALCIUM ACRYLATE 15 ~ 30%, modified polyurethane CALCIUM ACRYLATE 3 ~ 8%.Epoxy acrylate used is standard epoxy acrylate.Modified epoxy CALCIUM ACRYLATE is the conventional modified epoxy CALCIUM ACRYLATE of the art, YTM2085 as beautiful in refined painting, it has extraordinary snappiness as matrix resin, and shrinkability is lower, the string stress that can effectively reduce system, has good effect to the raising of sticking power.Modified urethane acrylate is selected the conventional modified urethane acrylate of the art, YTM5200 as beautiful in refined painting, it is as assisted resin, there are extraordinary wettability and low-down shrinkability, lower viscosity plays and reduces paint viscosity, and selected resin defoaming is good, froth breaking, makes workability reach requirement fast.
Further, described monomer is at least one in tri (propylene glycol) diacrylate (TPGDA), Viscoat 295 (TMPTA), 1,6 hexanediol diacrylate (HDDA), hydroxyethyl methylacrylate (HEMA); They can play reduction viscosity, improve sticking power, and can give the good levelling property of product and dilution property, improve the effect of paint film.
Further, described weighting agent is at least one in talcum powder, transparent powder, Zinic stearas.
Further, described light trigger is 1-hydroxyl-cyclohexyl-phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, (2,4; 6-trimethylbenzoyl) at least one in diphenyl phosphine oxide; they play reduction viscosity, increase hardness and scrath resistance, improve the effect of sticking power.
Further, described defoamer is vinylformic acid defoamer, BYK141 as conventional in the art, and flow agent is the agent of vinylformic acid levelling, preferably conventional BYK-333 or the DEGO450 of the art.
Further described anti-settling agent is at least one in organobentonite, polyethylene wax, aerosil.
 
The present invention has following beneficial effect:
In the middle of the present invention, this priming paint can be painted on ground, by ultraviolet light polymerization, reduce operation, man-hour, efficiency improves greatly.And do not needing to add under the prerequisite of any solvent, dope viscosity of the present invention is low, and levelling line is good, without PU or PE priming paint in the situation that, carry out edge sealing.
Embodiment
The painting method conventional according to those skilled in the art is made into photocureable priming coat by above-mentioned materials.
Following examples are that ultraviolet light polymerization edge sealing transparent priming is preferably filled a prescription; these formulas are indefiniteness embodiment; it is for illustrating the present invention, and those skilled in the art can be protection scope of the present invention according to thinking of the present invention and the formula that the proportioning of selecting materials filters out completely.
Embodiment 1
An edge sealing transparent priming, by weight percentage: epoxy acrylate 5%, YTM2085 15%, YTM5200 3%, and TPGDA 15.4%, and TMPTA 12%, HDDA 11%, and HEMA 6%, talcum powder 3%, calcium carbonate 7%, Zinic stearas 10%, 184 2%, TPO 3%, and BKY141 0.4%, and BYK-333 0.2%, polyethylene wax 6%, aerosil 1%.The painting method conventional according to those skilled in the art is made into photocureable priming coat by above-mentioned materials, and with spraying method application, to ground, the fast setting of UV paint, can greatly improve production efficiency.After solidifying, test smell, can reach the effect of low smell.This priming paint is painted on ground, by ultraviolet light polymerization, reduces operation, man-hour, efficiency improves greatly.
Embodiment 2
A kind of ultraviolet light polymerization edge sealing transparent priming, by weight percentage: epoxy acrylate 5%, YTM2085 18%, and YTM5200 5%, TPGDA 17.3%, TMPTA 12%, HDDA 8%, calcium carbonate 10%, transparent powder 12%, TPO 4%, BKY141 0.5%, BYK-333 0.2%, organobentonite 4%, polyethylene wax 4%.The painting method conventional according to those skilled in the art is made into photocureable priming coat by above-mentioned materials, and with spraying method application, to ground, the fast setting of UV paint, can greatly improve production efficiency.After solidifying, test smell, can reach the effect of low smell.This priming paint is painted on ground, by ultraviolet light polymerization, reduces operation, man-hour, efficiency improves greatly.
Embodiment 3
An edge sealing transparent priming, by weight percentage: epoxy acrylate 8%, YTM2085 18%, YTM5200 5%, and TPGDA 15%, and HEMA 18%, transparent powder 12%, Zinic stearas 10%, 184 3%, 1173 2.5%, BKY141 0.2%, DEGO450 0.3%, polyethylene wax 8%, the painting method conventional according to those skilled in the art is made into photocureable priming coat by above-mentioned materials, uses spraying method application to ground, the fast setting of UV paint, can greatly improve production efficiency.After solidifying, test smell, can reach the effect of low smell.This priming paint is painted on ground, by ultraviolet light polymerization, reduces operation, man-hour, efficiency improves greatly.
Embodiment 4
An edge sealing transparent priming, by weight percentage: epoxy acrylate 10%, YTM2085 20%, YTM5200 5%, and TMPTA 16%, and HDDA 12%, HEMA 6%, calcium carbonate 15%, 1,173 5.2%, BKY141 0.5%, BYK-333 0.3%, machine wilkinite 2%, polyethylene wax 5%, aerosil 3%.The painting method conventional according to those skilled in the art is made into photocureable priming coat by above-mentioned materials, and with spraying method application, to ground, the fast setting of UV paint, can greatly improve production efficiency.After solidifying, test smell, can reach the effect of low smell.This priming paint is painted on ground, by ultraviolet light polymerization, reduces operation, man-hour, efficiency improves greatly.
Embodiment 5
An edge sealing transparent priming, by weight percentage: epoxy acrylate 10%, YTM2085 22%, YTM5200 6%, TMPTA 7%, HDDA 9%, HEMA 14%, calcium carbonate 13%, transparent powder 7%, 1173 2%, 184 4%, BKY141 0.4%, DEGO450 0.1%, organobentonite 3%, polyethylene wax 2.5%.The painting method conventional according to those skilled in the art is made into photocureable priming coat by above-mentioned materials, and with vacuum deposition application, to ground, the fast setting of UV paint, can greatly improve production efficiency.Test performance after solidifying, can reach conventional edge sealing performance.The direct vacuum spraying of this priming paint, on ground, by ultraviolet light polymerization, is reduced to operation, man-hour, and efficiency improves greatly.
Embodiment 6
An edge sealing transparent priming, by weight percentage: epoxy acrylate 15%, YTM2085 25%, YTM5200 8%, and HDDA 21%, Zinic stearas 9%, talcum powder 10%, 184 1%, TPO 4%, BKY141 0.4%, DEGO450 0.3%, organobentonite 2%, polyethylene wax 3%, aerosil 1.3%.The painting method conventional according to those skilled in the art is made into photocureable priming coat by above-mentioned materials, and with spraying method application, to ground, the fast setting of UV paint, can greatly improve production efficiency.After solidifying, test smell, can reach the effect of low smell.This priming paint is painted on ground, by ultraviolet light polymerization, reduces operation, man-hour, efficiency improves greatly.
The above embodiment has only expressed embodiments of the present invention; it describes comparatively concrete and detailed; but can not therefore be interpreted as the restriction to the scope of the claims of the present invention; as long as employing is equal to the technical scheme that the form of replacement or equivalent transformation obtains, within all should dropping on protection scope of the present invention.

Claims (7)

1. a ultraviolet light polymerization edge sealing transparent priming coating, is characterized in that being comprised of the component of following mass percent:
Resin 23 ~ 53%;
Monomer 20 ~ 40%;
Weighting agent 10 ~ 25%;
Light trigger 4 ~ 7%;
Defoamer 0.2 ~ 0.5%;
Flow agent 0.1 ~ 0.3%;
Anti-settling agent 5 ~ 8%;
Described resin is the mixture of epoxy acrylate, modified epoxy CALCIUM ACRYLATE, modified polyurethane CALCIUM ACRYLATE.
2. a kind of ultraviolet light polymerization edge sealing transparent priming coating according to claim 1, it is characterized in that: the mass percent that described resin accounts for formula gross weight is: epoxy acrylate 5 ~ 15%, modified epoxy CALCIUM ACRYLATE 15 ~ 30%, modified polyurethane CALCIUM ACRYLATE 3 ~ 8%.
3. a kind of ultraviolet light polymerization edge sealing transparent priming coating according to claim 1, it is characterized in that: described monomer is at least one in tri (propylene glycol) diacrylate, Viscoat 295,1,6 hexanediol diacrylate, hydroxyethyl methylacrylate.
4. a kind of ultraviolet light polymerization edge sealing transparent priming coating according to claim 1, is characterized in that: described weighting agent is at least one in talcum powder, transparent powder, Zinic stearas.
5. a kind of ultraviolet light polymerization edge sealing transparent priming coating according to claim 1; it is characterized in that: described light trigger is 1-hydroxyl-cyclohexyl-phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, (2; 4,6-trimethylbenzoyl) at least one in diphenyl phosphine oxide.
6. a kind of ultraviolet light polymerization edge sealing transparent priming coating according to claim 1, is characterized in that: described defoamer is vinylformic acid defoamer, and flow agent is the agent of vinylformic acid levelling.
7. a kind of ultraviolet light polymerization edge sealing transparent priming coating according to claim 1, is characterized in that: described anti-settling agent is at least one in organobentonite, polyethylene wax, aerosil.
CN201310559524.XA 2013-11-12 2013-11-12 A kind of ultraviolet light polymerization edge sealing transparent priming coating Active CN103589301B (en)

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CN103589301B CN103589301B (en) 2016-08-17

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104130670A (en) * 2014-08-20 2014-11-05 崇州市美涂士涂料科技有限公司 Solvent-free UV vacuum spraying under-coating paint and preparation method thereof
CN104152007A (en) * 2014-08-20 2014-11-19 崇州市美涂士涂料科技有限公司 Solvent-free UV vacuum spraying priming paint and preparation method thereof
CN104530903A (en) * 2014-12-11 2015-04-22 惠州市长润发涂料有限公司 Leveling-free UV primer for vacuum spraying
CN104830209A (en) * 2015-05-04 2015-08-12 君子兰化工(上海)有限公司 Organic volatile solvent-free environmentally friendly anti-cracking transparent UV spray priming paint
CN106010066A (en) * 2016-05-31 2016-10-12 无锡伊佩克科技有限公司 Ultraviolet-cured aqueous polyurethane antibacterial coating and preparation method thereof
CN108299886A (en) * 2016-08-10 2018-07-20 上海长悦涂料有限公司 A kind of solvent-free UV spray paints coating and preparation method thereof
CN109929396A (en) * 2017-12-15 2019-06-25 惠州市长润发涂料有限公司 A kind of UV Kun painting transparent priming applied to building material surface
CN110564270A (en) * 2019-08-23 2019-12-13 广州凌玮科技股份有限公司 Antirust UV (ultraviolet) curing coating
CN110804372A (en) * 2019-12-06 2020-02-18 上海展辰涂料有限公司 UV vacuum spraying transparent primer suitable for water-based finish paint
CN112280440A (en) * 2019-07-25 2021-01-29 上海飞凯光电材料股份有限公司 UV adhesive coating, preparation method thereof and preparation method of coated workpiece

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970004598B1 (en) * 1993-12-30 1997-03-29 고려화학 주식회사 Photo-hardening coating composition
CN101544869A (en) * 2008-03-27 2009-09-30 上海富臣化工有限公司 Packless ultraviolet curing transparent priming lacquer for woodenware
CN102134437A (en) * 2011-02-28 2011-07-27 上虞市佑谦特种材料有限公司 UV (ultraviolet)-curing glass coating paint
CN103305100A (en) * 2013-06-28 2013-09-18 江苏海田技术有限公司 Ultraviolet (UV)-spray sanding primer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970004598B1 (en) * 1993-12-30 1997-03-29 고려화학 주식회사 Photo-hardening coating composition
CN101544869A (en) * 2008-03-27 2009-09-30 上海富臣化工有限公司 Packless ultraviolet curing transparent priming lacquer for woodenware
CN102134437A (en) * 2011-02-28 2011-07-27 上虞市佑谦特种材料有限公司 UV (ultraviolet)-curing glass coating paint
CN103305100A (en) * 2013-06-28 2013-09-18 江苏海田技术有限公司 Ultraviolet (UV)-spray sanding primer

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104130670A (en) * 2014-08-20 2014-11-05 崇州市美涂士涂料科技有限公司 Solvent-free UV vacuum spraying under-coating paint and preparation method thereof
CN104152007A (en) * 2014-08-20 2014-11-19 崇州市美涂士涂料科技有限公司 Solvent-free UV vacuum spraying priming paint and preparation method thereof
CN104530903A (en) * 2014-12-11 2015-04-22 惠州市长润发涂料有限公司 Leveling-free UV primer for vacuum spraying
CN104830209A (en) * 2015-05-04 2015-08-12 君子兰化工(上海)有限公司 Organic volatile solvent-free environmentally friendly anti-cracking transparent UV spray priming paint
CN106010066A (en) * 2016-05-31 2016-10-12 无锡伊佩克科技有限公司 Ultraviolet-cured aqueous polyurethane antibacterial coating and preparation method thereof
CN108299886A (en) * 2016-08-10 2018-07-20 上海长悦涂料有限公司 A kind of solvent-free UV spray paints coating and preparation method thereof
CN109929396A (en) * 2017-12-15 2019-06-25 惠州市长润发涂料有限公司 A kind of UV Kun painting transparent priming applied to building material surface
CN112280440A (en) * 2019-07-25 2021-01-29 上海飞凯光电材料股份有限公司 UV adhesive coating, preparation method thereof and preparation method of coated workpiece
CN110564270A (en) * 2019-08-23 2019-12-13 广州凌玮科技股份有限公司 Antirust UV (ultraviolet) curing coating
CN110804372A (en) * 2019-12-06 2020-02-18 上海展辰涂料有限公司 UV vacuum spraying transparent primer suitable for water-based finish paint

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Address after: 516221 No. 30 Xiayong Petrochemical Avenue, Daya Bay, Huizhou City, Guangdong Province

Co-patentee after: TIANJIN CHANGRUNFA CHEMICAL CO., LTD.

Patentee after: Guangdong Libang Changrunfa Science and Technology Material Co., Ltd.

Address before: 516221 Xintang Industrial Zone, Qiuchang Town, Huiyang District, Huizhou City, Guangdong Province

Co-patentee before: TIANJIN CHANGRUNFA CHEMICAL CO., LTD.

Patentee before: Huizhou Changrunfa Coating Co., Ltd.