CN106010066A - Ultraviolet-cured aqueous polyurethane antibacterial coating and preparation method thereof - Google Patents

Ultraviolet-cured aqueous polyurethane antibacterial coating and preparation method thereof Download PDF

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Publication number
CN106010066A
CN106010066A CN201610374715.2A CN201610374715A CN106010066A CN 106010066 A CN106010066 A CN 106010066A CN 201610374715 A CN201610374715 A CN 201610374715A CN 106010066 A CN106010066 A CN 106010066A
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parts
ultraviolet light
antibiotic paint
coating
nano
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尤为
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Wuxi Epic Technology Co Ltd
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Wuxi Epic Technology Co Ltd
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Priority to CN201610374715.2A priority Critical patent/CN106010066A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an ultraviolet-cured aqueous polyurethane antibacterial coating and a preparation method thereof. The antibacterial coating comprises aqueous polyurethane, tripropylene glycol diacrylate, epoxy acrylate, hydroxylethyl methacrylate, diacetone alcohol, nanometer alumina, graphene oxide, nanometer titanium dioxide, a light initiator, a leveling agent, an anti-settling agent and an antifoaming agent. The preparation method comprises the following steps: uniformly mixing the light initiator with diacetone alcohol, sequentially adding other components, and fully stirring and uniformly mixing all the components to obtain the ultraviolet-cured aqueous polyurethane antibacterial coating. The aqueous ultraviolet-cured coating prepared in the invention has the advantages of no pollution to environment, fast curing speed, realization of room temperature curing, high production efficiency, energy saving, good performances of a cured product, and suitableness for high-speed automatic production; a coating layer formed by the coating has the advantages of high hardness, good wear resistance, hard scratch resistance and high glossiness; and the coating also has the advantages of good antibacterial and antistatic performances, stable effect and long action time.

Description

A kind of ultraviolet light solidfication water polyurethane antibiotic paint and preparation method thereof
Technical field
The present invention relates to antibiotic paint technical field, be specifically related to a kind of ultraviolet light solidfication water polyurethane antibiotic paint and Its preparation method.
Background technology
Solvent based coating, through long-run development, has high-decoration, durable protectiveness, multifunctionality；But organic solvent Volatilization, causes environmental pollution, majority to have and solvent is to people, animal, biology, even to plant poisonous and harmful.Along with people's environmental protection The enhancing of consciousness, water paint quickly grows in China.But compared with solvent based coating, existing water paint there is also hardness The problem such as low, richness is poor, high temperature after-tacks, and drying time of constructing is long, is not suitable for the large-scale production of large-scale furniture enterprise Demand.
Along with the enhancing of global environmental protection consciousness, coatings industry also begins to develop along sustainability direction.Therefore, may be used To see increasing solventless coatings or to use the coating system of a small amount of VOC to occur.UV is coating material solidified As a kind of environmental protection coating material, just becoming increasingly popular and experienced by growth at a high speed in recent years.
Specifically, UV Curing Coatings for Plastics has the advantage that compared with tradition volatilization organic coating: (1) is quickly solid Change, production efficiency height；(2) excellent curing membrane performance (wearability, chemical-resistant resistance etc.)；(3) low-temperature setting, is suitable to thermal sensitivity Base material (such as plastics)；(4) solvent is low or does not contains solvent, little to environmental hazard；(5) saving space, energy expenditure is low.
Water paint and photocureable coating technology are combined, can effectively utilize photocuring technology curing rate fast, The advantages such as environmental protection, obtain easy construction, properties preferably UV-curable waterborne coatings.Present UV-curable waterborne Coating because of under solar exposure out of doors, paint film quickly xanthochromia, powder.
The most often adding antibacterial in coating, antibacterial is broadly divided into two kinds, inorganic antiseptic (TiO 2 series light Catalytic antimicrobial agent, metal ion antibacterial agent etc.) and some organic antibacterial agents.Organic antibacterial agent easily decomposes, effect duration is short, thermostability Difference, is easily generated drug resistance, is irritating to the skin, and difficult degradation, environment is had pollution, is the most gradually eliminated.Wherein due to inorganic Antibiotic paint broad-spectrum antimicrobial effect is good, effect duration is long, heat-resist, does not produce drug resistance, and the advantages such as safety is high, nontoxic are by extensively General utilization.But at present antibiotic paint exists that antibacterial effect is the best, antibacterial ageing long and wood product surface antimicrobial coating resistance to The factors such as scrubbing property difference, seriously constrain its range of application.
Summary of the invention
For the deficiencies in the prior art, the present invention provides a kind of ultraviolet light solidfication water polyurethane antibiotic paint and preparation thereof Method, the paint machine of preparation is functional, and has the excellent antibacterial ability of longer aging.
The technical solution used in the present invention is as follows:
A kind of ultraviolet light solidfication water polyurethane antibiotic paint, the following components including in parts by weight: aqueous polyurethane 100 Part, tri (propylene glycol) diacrylate 20～30 parts, epoxy acrylate 5～10 parts, hydroxyethyl methylacrylate 2～10 Part, DAA 40～80 parts, nano-aluminium oxide 3～12 parts, graphene oxide 3～8 parts, nano titanium oxide 5～10 Part, light trigger 1～3 parts, levelling agent 0.3～0.6 part, anti-settling agent 0.3～0.6 part, defoamer 0.6～1 part.
Preferably, described ultraviolet light solidfication water polyurethane antibiotic paint, the following components including in parts by weight: water Property polyurethane 100 parts, tri (propylene glycol) diacrylate 25 parts, epoxy acrylate 6 parts, hydroxyethyl methylacrylate 8 parts, DAA 60 parts, nano-aluminium oxide 7.5 parts, graphene oxide 5 parts, nano titanium oxide 4 parts, light trigger 2.5 parts, Levelling agent 0.5 part, anti-settling agent 0.4 part, defoamer 0.8 part.
Preferably, described light trigger is bis(benzoylphenyl) phosphine oxide.
Preferably, described levelling agent is polydimethylsiloxane or PSI.
Preferably, described anti-settling agent is polyamide wax.
Preferably, described defoamer is dimethicone or polysiloxanes.
The preparation method of described ultraviolet light solidfication water polyurethane antibiotic paint, comprises the following steps:
(1) each component is weighed by weight, standby；
(2) light trigger and DAA are joined in reactor, stir；Then the poly-ammonia of aqueous it is sequentially added into Ester, tri (propylene glycol) diacrylate, epoxy acrylate, hydroxyethyl methylacrylate and defoamer, stir；
(3) by nano-aluminium oxide, graphene oxide, nano titanium oxide, levelling agent and anti-settling agent, at 50 DEG C～80 DEG C Stirring 4h～8h, can prepare ultraviolet light solidfication water polyurethane antibiotic paint.
Beneficial effect: the aquosity ultraviolet light photocureable coating of the present invention is free from environmental pollution, curing rate is fast, can be solid at room temperature Changing, production efficiency is high, saves the energy, cured product performance is good, be suitable for high-speed automated production；The hardness of coating is high, wear-resisting Property good, resistance to hard thing scratches, and glossiness is high；The present invention also has good antibiotic antistatic performance, and effect stability, action effective Long.
Detailed description of the invention
Below by specific embodiment, the present invention is further described in detail, but is not limited to this.
Embodiment 1
A kind of ultraviolet light solidfication water polyurethane antibiotic paint, the following components including in parts by weight: aqueous polyurethane 100 Part, tri (propylene glycol) diacrylate 20 parts, epoxy acrylate 5 parts, hydroxyethyl methylacrylate 2 parts, DAA 40 Part, nano-aluminium oxide 3 parts, graphene oxide 3 parts, nano titanium oxide 5 parts, bis(benzoylphenyl) phosphine oxide 1 part, poly- Dimethyl siloxane 0.3 part, polyamide wax 0.3 part, dimethicone 0.6 part.
The preparation method of described ultraviolet light solidfication water polyurethane antibiotic paint, comprises the following steps:
(1) each component is weighed by weight, standby；
(2) bis(benzoylphenyl) phosphine oxide and DAA are joined in reactor, stir；Add the most successively Enter aqueous polyurethane, tri (propylene glycol) diacrylate, epoxy acrylate, hydroxyethyl methylacrylate and dimethyl-silicon Oil, stirs；
(3) by nano-aluminium oxide, graphene oxide, nano titanium oxide, polydimethylsiloxane and polyamide wax, 50 Stir 4h at DEG C, ultraviolet light solidfication water polyurethane antibiotic paint can be prepared.
Embodiment 2
A kind of ultraviolet light solidfication water polyurethane antibiotic paint, the following components including in parts by weight: aqueous polyurethane 100 Part, tri (propylene glycol) diacrylate 30 parts, epoxy acrylate 10 parts, hydroxyethyl methylacrylate 10 parts, DAA 80 parts, nano-aluminium oxide 12 parts, graphene oxide 8 parts, nano titanium oxide 10 parts, bis(benzoylphenyl) phosphine oxide 3 Part, polydimethylsiloxane 0.6 part, polyamide wax 0.6 part, polysiloxanes 1 part.
The preparation method of described ultraviolet light solidfication water polyurethane antibiotic paint, comprises the following steps:
(1) each component is weighed by weight, standby；
(2) bis(benzoylphenyl) phosphine oxide and DAA are joined in reactor, stir；Add the most successively Enter aqueous polyurethane, tri (propylene glycol) diacrylate, epoxy acrylate, hydroxyethyl methylacrylate and polysiloxanes, Stir；
(3) by nano-aluminium oxide, graphene oxide, nano titanium oxide, polydimethylsiloxane and polyamide wax, 80 Stir 8h at DEG C, ultraviolet light solidfication water polyurethane antibiotic paint can be prepared.
Embodiment 3
A kind of ultraviolet light solidfication water polyurethane antibiotic paint, the following components including in parts by weight: aqueous polyurethane 100 Part, tri (propylene glycol) diacrylate 28 parts, epoxy acrylate 6 parts, hydroxyethyl methylacrylate 4 parts, DAA 70 Part, nano-aluminium oxide 10 parts, graphene oxide 7 parts, nano titanium oxide 7 parts, bis(benzoylphenyl) phosphine oxide 2.5 Part, PSI 0.4 part, polyamide wax 0.5 part, dimethicone 0.9 part.
The preparation method of described ultraviolet light solidfication water polyurethane antibiotic paint, comprises the following steps:
(1) each component is weighed by weight, standby；
(2) bis(benzoylphenyl) phosphine oxide and DAA are joined in reactor, stir；Add the most successively Enter aqueous polyurethane, tri (propylene glycol) diacrylate, epoxy acrylate, hydroxyethyl methylacrylate and dimethyl-silicon Oil, stirs；
(3) by nano-aluminium oxide, graphene oxide, nano titanium oxide, PSI and polyamide wax, Stir 6h at 75 DEG C, ultraviolet light solidfication water polyurethane antibiotic paint can be prepared.
Embodiment 4
A kind of ultraviolet light solidfication water polyurethane antibiotic paint, the following components including in parts by weight: aqueous polyurethane 100 Part, tri (propylene glycol) diacrylate 25 parts, epoxy acrylate 6 parts, hydroxyethyl methylacrylate 8 parts, DAA 60 Part, nano-aluminium oxide 7.5 parts, graphene oxide 5 parts, nano titanium oxide 4 parts, bis(benzoylphenyl) phosphine oxide 2.5 Part, PSI 0.5 part, polyamide wax 0.4 part, polysiloxanes 0.8 part.
The preparation method of described ultraviolet light solidfication water polyurethane antibiotic paint, comprises the following steps:
(1) each component is weighed by weight, standby；
(2) bis(benzoylphenyl) phosphine oxide and DAA are joined in reactor, stir；Add the most successively Enter aqueous polyurethane, tri (propylene glycol) diacrylate, epoxy acrylate, hydroxyethyl methylacrylate and polysiloxanes, Stir；
(3) by nano-aluminium oxide, graphene oxide, nano titanium oxide, PSI and polyamide wax, Stir 5h at 60 DEG C, ultraviolet light solidfication water polyurethane antibiotic paint can be prepared.
Comparative example
A kind of ultraviolet light solidfication water polyurethane antibiotic paint, the following components including in parts by weight: aqueous polyurethane 100 Part, tri (propylene glycol) diacrylate 25 parts, epoxy acrylate 6 parts, hydroxyethyl methylacrylate 8 parts, DAA 60 Part, nano-aluminium oxide 7.5 parts, nano titanium oxide 4 parts, bis(benzoylphenyl) phosphine oxide 2.5 parts, polymethyl-benzene base silicon 0.5 part of oxygen alkane, polyamide wax 0.4 part, polysiloxanes 0.8 part.
The preparation method of described ultraviolet light solidfication water polyurethane antibiotic paint, comprises the following steps:
(1) each component is weighed by weight, standby；
(2) bis(benzoylphenyl) phosphine oxide and DAA are joined in reactor, stir；Add the most successively Enter aqueous polyurethane, tri (propylene glycol) diacrylate, epoxy acrylate, hydroxyethyl methylacrylate and polysiloxanes, Stir；
(3) by nano-aluminium oxide, nano titanium oxide, PSI and polyamide wax, stir at 60 DEG C 5h, can prepare ultraviolet light solidfication water polyurethane antibiotic paint.
The ultraviolet light solidfication water polyurethane antibiotic paint preparing above-described embodiment 1 to 4 and comparative example carries out performance survey Examination, test result is as shown in the table:
As can be seen from the above table, the ultraviolet light solidfication water polyurethane antibiotic paint of above-described embodiment 1 to 4 preparation is respectively provided with well Performance, and antibacterial effect is superior to comparative example, is primarily due to, and nano titanium oxide is as the one of photocatalysis nano material Kind, there is antibacterial sterilization functions, but it is relatively low for visible-light absorptivity, nanoparticle trends towards assembling, and greatly reduces it and goes out Bacterium effect.Containing in nanometer titanium dioxide antibiotic coating, introduce graphene oxide, coating can be significantly improved to visible absorption Rate, and strengthen the photocatalytic activity of nano titanium oxide and antibacterial, sterilization capability, make modified aqueous polyurethane go out antibacterial Bacterium combination property aspect improves a lot, and has good surface property, resistance to water and mechanical property.

Claims (7)

1. a ultraviolet light solidfication water polyurethane antibiotic paint, it is characterised in that include following components in parts by weight: water Property polyurethane 100 parts, tri (propylene glycol) diacrylate 20～30 parts, epoxy acrylate 5～10 parts, hydroxyethyl methacrylate Ethyl ester 2～10 parts, DAA 40～80 parts, nano-aluminium oxide 3～12 parts, graphene oxide 3～8 parts, nano-silica Change titanium 5～10 parts, light trigger 1～3 parts, levelling agent 0.3～0.6 part, anti-settling agent 0.3～0.6 part, defoamer 0.6～1 part.
Ultraviolet light solidfication water polyurethane antibiotic paint the most according to claim 1, it is characterised in that include with weight portion The following components of meter: aqueous polyurethane 100 parts, tri (propylene glycol) diacrylate 25 parts, epoxy acrylate 6 parts, methyl 2-(Acryloyloxy)ethanol 8 parts, DAA 60 parts, nano-aluminium oxide 7.5 parts, graphene oxide 5 parts, nano titanium oxide 4 Part, light trigger 2.5 parts, levelling agent 0.5 part, anti-settling agent 0.4 part, defoamer 0.8 part.
Ultraviolet light solidfication water polyurethane antibiotic paint the most according to claim 1, it is characterised in that described is light-initiated Agent is bis(benzoylphenyl) phosphine oxide.
Ultraviolet light solidfication water polyurethane antibiotic paint the most according to claim 1, it is characterised in that described levelling agent For polydimethylsiloxane or PSI.
Ultraviolet light solidfication water polyurethane antibiotic paint the most according to claim 1, it is characterised in that described anti-settling agent For polyamide wax.
Ultraviolet light solidfication water polyurethane antibiotic paint the most according to claim 1, it is characterised in that described defoamer For dimethicone or polysiloxanes.
7. the preparation method of the ultraviolet light solidfication water polyurethane antibiotic paint described in claim 1 to 6 any one, its feature It is to comprise the following steps:
(1) each component is weighed by weight, standby；
(2) light trigger and DAA are joined in reactor, stir；Then the poly-ammonia of aqueous it is sequentially added into Ester, tri (propylene glycol) diacrylate, epoxy acrylate, hydroxyethyl methylacrylate and defoamer, stir；
(3) by nano-aluminium oxide, graphene oxide, nano titanium oxide, levelling agent and anti-settling agent, at 50 DEG C～80 DEG C Stirring 4h～8h, can prepare ultraviolet light solidfication water polyurethane antibiotic paint.
CN201610374715.2A 2016-05-31 2016-05-31 Ultraviolet-cured aqueous polyurethane antibacterial coating and preparation method thereof Pending CN106010066A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109664576A (en) * 2018-12-25 2019-04-23 镇江安之盾高温纤维制品有限公司 A kind of energy saving and environment friendly heat insulating mattress
CN109999698A (en) * 2019-05-18 2019-07-12 山东银光科技有限公司 A kind of agitating device for detonation tool internal mix medicament

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016431A (en) * 2007-02-06 2007-08-15 深圳清华大学研究院 Nano antibacterial water woodenware paint and preparing method thereof
CN102872889A (en) * 2012-10-10 2013-01-16 江苏大学 Graphene, silver phosphate and titanium dioxide dual-functional composite and method for preparing same
CN103589301A (en) * 2013-11-12 2014-02-19 惠州市长润发涂料有限公司 Transparent ultraviolet-curing edge-sealing primer coating
WO2015109466A1 (en) * 2014-01-22 2015-07-30 中国科学院化学研究所 Methods for preparing aqueous ice-covering resistant mono-component hybrid coating and coating layer thereof, and use thereof
CN104927627A (en) * 2015-06-09 2015-09-23 成都纳硕科技有限公司 Bacterium-resistant UV curing furniture coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016431A (en) * 2007-02-06 2007-08-15 深圳清华大学研究院 Nano antibacterial water woodenware paint and preparing method thereof
CN102872889A (en) * 2012-10-10 2013-01-16 江苏大学 Graphene, silver phosphate and titanium dioxide dual-functional composite and method for preparing same
CN103589301A (en) * 2013-11-12 2014-02-19 惠州市长润发涂料有限公司 Transparent ultraviolet-curing edge-sealing primer coating
WO2015109466A1 (en) * 2014-01-22 2015-07-30 中国科学院化学研究所 Methods for preparing aqueous ice-covering resistant mono-component hybrid coating and coating layer thereof, and use thereof
CN104927627A (en) * 2015-06-09 2015-09-23 成都纳硕科技有限公司 Bacterium-resistant UV curing furniture coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109664576A (en) * 2018-12-25 2019-04-23 镇江安之盾高温纤维制品有限公司 A kind of energy saving and environment friendly heat insulating mattress
CN109999698A (en) * 2019-05-18 2019-07-12 山东银光科技有限公司 A kind of agitating device for detonation tool internal mix medicament

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Application publication date: 20161012