CN104877548A - Ultraviolet curable water-based environmental protection odor purifying paint used for wooden products - Google Patents
Ultraviolet curable water-based environmental protection odor purifying paint used for wooden products Download PDFInfo
- Publication number
- CN104877548A CN104877548A CN201510247822.4A CN201510247822A CN104877548A CN 104877548 A CN104877548 A CN 104877548A CN 201510247822 A CN201510247822 A CN 201510247822A CN 104877548 A CN104877548 A CN 104877548A
- Authority
- CN
- China
- Prior art keywords
- parts
- environmental protection
- woodwork
- curable water
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to the field of paint and in particular relates to ultraviolet curable water-based environmental protection odor purifying paint used for wooden products. The paint comprises the following raw materials in parts by weight: 40-65 parts of water-based polyurethane acrylate, 5-10 parts of 1,6-hexanediol diacrylate, 5-10 parts of acrylic resin, 5-10 parts of nano aluminium oxide dispersion, 2-4 parts of photoinitiators, 0.2-0.5 part of levelling agent, 10-20 parts of water-based organic assistants, 0.2-0.5 part of anti-settling agent, 0.5-1 part of defoaming agent, 10-15 parts of graphene, 5-10 parts of nano titanium dioxide sol and 2-5 parts of silver ion solution. The paint can meet the requirements of high performance and environmental protection, has composite antibacterial ability and longer valid time, and has good compatibility with ultraviolet curable resin.
Description
Technical field
The invention belongs to paint field, particularly the clean taste coating of a kind of woodwork UV-curable water-borne environmental protection.
Background technology
Solvent based coating, through long-run development, has high-decoration, durable protectiveness, multifunctionality; But organic solvent volatilize, cause environmental pollution, majority have and solvent to people, animal, biology, even to plant poisonous and harmful.Along with the enhancing of people's environmental consciousness, water-borne coatings in China's development rapidly.But compared with solvent based coating, existing water-borne coatings also exists the problems such as hardness is low, fullness ratio is poor, high temperature after-tacks, and construction is long for time of drying, is not suitable for the scale production demand of large-scale furniture enterprise.
Along with the enhancing of global environmental protection consciousness, coatings industry also starts along sustainability future development.Therefore, increasing solventless coatings can be seen or use the coating system of a small amount of volatile organic compounds to occur.UV is coating material solidified as a kind of environmental protection coating material, just day by day popularizes and experienced by growth at a high speed in recent years.
Specifically, UV Curing Coatings for Plastics is compared with tradition volatilization organic coating and is had following benefit:
One, fast setting, production efficiency are high;
Two, excellent curing membrane performance (wear resistance, chemical-resistant resistance etc.);
Three, low-temperature curing, is suitable for heatsensitive substrates (as plastics);
Four, solvent is low or not containing solvent, little to environmental hazard;
Five, save space, energy expenditure is low.
But, UV coating adopts ultraviolet curing, containing a large amount of low molecule photosensitizerss in formula, even if completion of cure, also also have a large amount of photosensitizers fragment to remain, cause UV durability of coating poor, easily turn to be yellow under solar exposure, simultaneously residual photosensitizers can migrate to product surface, has certain toxicity to human body.In addition, the problem of the UV coating surface ubiquity of Gao Guang not damage resistant.
Water-borne coatings and photo-cured coating combine with technique are got up, effectively can utilize the advantages such as photocuring technology curing speed is fast, environmental protection, obtain easy construction, properties preferably UV-curable waterborne coatings.Present UV-curable waterborne coatings because of under solar exposure out of doors, the very fast xanthochromia of paint film, efflorescence; If use UV-curable waterborne coatings on woodenware, also can cause the exposed corrosion of timber, thus reduce the weather resistance of timber.
Major part woodwork usually can and human body between have certain contact, therefore wood product surface coating play protection woodwork while, more and more high standard demand is possessed to germ resistance.Often in coating, add antiseptic-germicide now, antiseptic-germicide is mainly divided into two kinds, inorganic antiseptic (agent of TiO 2 series photocatalysis antibacterial, metal ion antibacterial agent etc.) and some organic antibacterial agents.Organic antibacterial agent easily decomposes, validity period is short, poor heat resistance, easily produces resistance, has stimulation to skin, difficult degradation, has pollution to environment, is eliminated gradually.Wherein because inorganic antibacterial coating broad-spectrum antimicrobial effect is good, validity period is long, good heat resistance, does not produce resistance, and the advantages such as security is high, nontoxic are widely used.But there is the factors such as the abrasion resistance difference of antibacterial effect not good, antibacterial ageing length and wood product surface antimicrobial coating in antibiotic paint at present, seriously constrains its range of application.
In addition, current a lot of wood furniture topcoatings on the market often have larger irritating smell, and dissipation speed is slow, affects HUMAN HEALTH, if therefore there is the woodwork coating that little, the clean taste of a kind of smell is fast, the health of indoor decorating staff will be very beneficial for.
Summary of the invention
The object of the present invention is to provide the clean taste coating of a kind of woodwork UV-curable water-borne environmental protection, the present invention adopts aqueous polyurethane acrylate to coordinate with nano titanic oxide sol, silver ion solution, the requirement that little, the clean taste of smell is fast can not only be met, and there is composite antibacterial ability and possess longer action effective, with UV-cured resin, there is good consistency.
The technical solution used in the present invention is:
The clean taste coating of a kind of woodwork UV-curable water-borne environmental protection, is made up of by mass parts following raw material: aqueous polyurethane acrylate 40-65 part, 1,6-hexanediyl ester 5-10 part, acrylic resin 5-10 part, nano-aluminium oxide dispersion 5-10 part, light trigger 2-4 part, flow agent 0.2-0.5 part, water-based organic additive 10-20 part, anti-settling agent 0.2-0.5 part, defoamer 0.5-1 part, Graphene 10-15 part, nano titanic oxide sol 5-10 part, silver ion solution 2-5 part.
As preferably, described flow agent is organosilicon flow agent or acrylate flow agent.
Preferably, described flow agent adopts polyether-modified polydimethylsiloxane.
As preferably, described light trigger is one or more in 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, phenylbenzene-(2,4,6-trimethylbenzoyl) oxygen phosphorus, benzophenone.
Further, described water-based organic additive adopts hydroxyethyl methylacrylate or Hydroxyethyl acrylate.
Further, described anti-settling agent adopts aerosil anti-settling agent.
Further, described defoamer adopts polysiloxane-polyether copolymer defoamer.
Further, in described nano titanic oxide sol, the content of titanium dioxide is 12 ~ 15%.
Further, in described silver ion solution, the content of silver ions is 1 × 10
-3-5 × 10
-3mol/L.
Graphene is a kind of novel material of the individual layer sheet structure be made up of carbon atom.Be a kind ofly form with sp2 hybridized orbital the flat film that hexangle type is honeycomb lattice by carbon atom, only have the two-dimensional material of a carbon atom thickness.Graphene is the thinnest in the world is at present the hardest nano material also, and it is almost completely transparent, only absorbs the light of 2.3%; Thermal conductivity is up to 5300W/mK, and higher than carbon nanotube and diamond, under normal temperature, its electronic mobility is more than 15000cm2/Vs, again than CNT (carbon nano-tube) or silicon wafer height, and resistivity only about 10-6 Ω cm, than copper or silver lower, be the material that resistivity is minimum in the world at present.At present, also report that no matter Graphene is directly prepare on copper or nickel, or transfer on other metals, all can provide anti-corrosion protection.Copper coating cultivates single-layer graphene, adopts chemical Vapor deposition process, and slower than naked copper seven times of corrosion meeting, nickel coating cultivates multi-layer graphene, corrodes slower than naked nickel more than 20 times.Single-layer graphene has identical anti-corrosion protection effect, and just as conventional organic coating, but the latter wants thick more than five times.
And the present invention prepares nano combined titanium dioxide antibacterial paint by silver ions is titania-doped, overcome the deficiency of traditional optically catalytic TiO 2 coating, improve activity and the range of application of photocatalysis antibacterial, the effective wavelength of photocatalysis antibacterial performance is extended to visible region; There is silver ions simultaneously there is good sterilization effect, directly can contact with bacterium and be killed, no matter under photoirradiation or no light condition, all there is excellent anti-microbial property.Machine in coating-inorganic hybridization high molecular polymer, it forms the binary synergic nano interface structure of wetting ability and lipophilicity two-phase coexistent in nano-area, thus surface can be formed marvellous super amphiphilic.Lipophilicity can form more firm chemical bond with the oxide compound of metallic surface or oxyhydroxide and have excellent sticking power, and generate high strength, fine and close reticulated structure by cross-linking and curing reaction, simultaneously its super amphiphilic can rapidly solidified composite nano titanium dioxide particle, greatly strengthen wash-resistant property and the anti-microbial property of wood product surface antimicrobial coating.
The invention has the beneficial effects as follows as follows:
One, water-based ultraviolet (UV) curable coating of the present invention is free from environmental pollution, and curing speed is fast, in ambient cure, can be suitable for the covering with paint of wood product surface, can not cause negative impact to woodwork, and after covering with paint, lacquer, colour wash, etc., little, the clean taste of smell is fast; The hardness of coating is high, and wear resistance is good, and resistance to hard object scratches, and glossiness is high;
Two, the present invention adopts raw material volatile matter after photocuring is covered with paint, lacquer, colour wash, etc. few, and volatilizes is short, significantly improves the health of interior decoration ornamental work personnel;
Three, the present invention prepares nano combined titanium dioxide antibacterial paint by silver ions is titania-doped, overcome the deficiency of traditional optically catalytic TiO 2 coating, improve activity and the range of application of photocatalysis antibacterial, there is stronger antibacterial effect, and the time length is long, with photocuring system, there is good consistency;
Four, water white transparency of the present invention, can fast setting dry, environment-protecting asepsis, the excellent and lasting stability of antistatic property; Surface drying is good, be not clamminess, return sticky, and scratch resistance is wear-resisting; The application of various wood product surface can be widely used in.
Embodiment
The present invention is set forth further below in conjunction with embodiment:
Embodiment 1
The clean taste coating of a kind of woodwork UV-curable water-borne environmental protection, be made up of by mass parts following raw material: aqueous polyurethane acrylate 40 parts, 1,6-hexanediyl ester 5 parts, acrylic resin 5 parts, nano-aluminium oxide dispersion 5 parts, 1-hydroxycyclohexyl phenyl ketone 2 parts, polyether-modified polydimethylsiloxane 0.2 part, hydroxyethyl methylacrylate 10 parts, aerosil anti-settling agent 0.2 part, polysiloxane-polyether copolymer defoamer 0.5 part, Graphene 10 parts, nano titanic oxide sol 5 parts, silver ion solution 2 parts.
Embodiment 2
The clean taste coating of a kind of woodwork UV-curable water-borne environmental protection, be made up of by mass parts following raw material: aqueous polyurethane acrylate 65 parts, 1,6-hexanediyl ester 10 parts, acrylic resin 10 parts, nano-aluminium oxide dispersion 10 parts, 4 parts, 2-hydroxy-2-methyl-1-phenyl-1-acetone, polyether-modified polydimethylsiloxane 0.5 part, Hydroxyethyl acrylate 20 parts, aerosil anti-settling agent 0.5 part, polysiloxane-polyether copolymer defoamer 1 part, Graphene 15 parts, nano titanic oxide sol 10 parts, silver ion solution 5 parts.
Embodiment 3
The clean taste coating of a kind of woodwork UV-curable water-borne environmental protection, be made up of by mass parts following raw material: aqueous polyurethane acrylate 50 parts, 1,6-hexanediyl ester 8 parts, acrylic resin 8 parts, nano-aluminium oxide dispersion 8 parts, phenylbenzene-(2,4,6-trimethylbenzoyl) 3 parts, oxygen phosphorus, polyether-modified polydimethylsiloxane 0.4 part, hydroxyethyl methylacrylate 18 parts, aerosil anti-settling agent 0.4 part, polysiloxane-polyether copolymer defoamer 0.8 part, Graphene 12 parts, nano titanic oxide sol 8 parts, silver ion solution 3 parts.
With above-mentioned according to desirable embodiment of the present invention for enlightenment, by above-mentioned description, relevant staff in the scope not departing from this invention technological thought, can carry out various change and amendment completely.The technical scope of this invention is not limited to the content on specification sheets, must determine its technical scope according to right.
Claims (9)
1. the clean taste coating of woodwork UV-curable water-borne environmental protection, it is characterized in that being made up of by mass parts following raw material: aqueous polyurethane acrylate 40-65 part, 1,6-hexanediyl ester 5-10 part, acrylic resin 5-10 part, nano-aluminium oxide dispersion 5-10 part, light trigger 2-4 part, flow agent 0.2-0.5 part, water-based organic additive 10-20 part, anti-settling agent 0.2-0.5 part, defoamer 0.5-1 part, Graphene 10-15 part, nano titanic oxide sol 5-10 part, silver ion solution 2-5 part.
2. the clean taste coating of a kind of woodwork UV-curable water-borne according to claim 1 environmental protection, is characterized in that: described flow agent is organosilicon flow agent or acrylate flow agent.
3. the clean taste coating of a kind of woodwork UV-curable water-borne according to claim 1 environmental protection, is characterized in that: described flow agent adopts polyether-modified polydimethylsiloxane.
4. the clean taste coating of a kind of woodwork UV-curable water-borne according to claim 1 environmental protection, it is characterized in that: described light trigger is 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, phenylbenzene-(2,4,6-trimethylbenzoyl) oxygen phosphorus, one or more in benzophenone.
5. the clean taste coating of a kind of woodwork UV-curable water-borne according to claim 1 environmental protection, is characterized in that: described water-based organic additive adopts hydroxyethyl methylacrylate or Hydroxyethyl acrylate.
6. the clean taste coating of a kind of woodwork UV-curable water-borne according to claim 1 environmental protection, is characterized in that: described anti-settling agent adopts aerosil anti-settling agent.
7. the clean taste coating of a kind of woodwork UV-curable water-borne according to claim 1 environmental protection, is characterized in that: described defoamer adopts polysiloxane-polyether copolymer defoamer.
8. the clean taste coating of a kind of woodwork UV-curable water-borne according to claim 1 environmental protection, is characterized in that: in described nano titanic oxide sol, the content of titanium dioxide is 12 ~ 15%.
9. the clean taste coating of a kind of woodwork UV-curable water-borne according to claim 1 environmental protection, is characterized in that: in described silver ion solution, the content of silver ions is 1 × 10
-3-5 × 10
-3mol/L.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510247822.4A CN104877548A (en) | 2015-05-15 | 2015-05-15 | Ultraviolet curable water-based environmental protection odor purifying paint used for wooden products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510247822.4A CN104877548A (en) | 2015-05-15 | 2015-05-15 | Ultraviolet curable water-based environmental protection odor purifying paint used for wooden products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104877548A true CN104877548A (en) | 2015-09-02 |
Family
ID=53945238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510247822.4A Pending CN104877548A (en) | 2015-05-15 | 2015-05-15 | Ultraviolet curable water-based environmental protection odor purifying paint used for wooden products |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104877548A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359369A (en) * | 2018-03-28 | 2018-08-03 | 三河亮克威泽工业涂料有限公司 | Motor-car interior trim antibiotic paint and its preparation method and application |
| CN109207046A (en) * | 2018-10-18 | 2019-01-15 | 合肥永泰新型建材有限公司 | A kind of preparation method of timber environmental protection coating material |
| CN110666915A (en) * | 2019-09-25 | 2020-01-10 | 浙江云峰莫干山地板有限公司 | Solid wood composite floor surface plate and manufacturing method thereof |
| CN112358806A (en) * | 2021-01-12 | 2021-02-12 | 广东大自然家居科技研究有限公司 | Modified coating for ceramic tile-like wood floor and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63225670A (en) * | 1987-03-13 | 1988-09-20 | Yuuhoo Chem Kk | Covering agent composition |
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN102702889A (en) * | 2012-06-01 | 2012-10-03 | 安徽省金盾涂料有限责任公司 | Anti-bacterial water-based paint and preparation method thereof |
-
2015
- 2015-05-15 CN CN201510247822.4A patent/CN104877548A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63225670A (en) * | 1987-03-13 | 1988-09-20 | Yuuhoo Chem Kk | Covering agent composition |
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN102702889A (en) * | 2012-06-01 | 2012-10-03 | 安徽省金盾涂料有限责任公司 | Anti-bacterial water-based paint and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张学敏等: "《涂料与涂装技术 第1版》", 31 January 2006, 化学工业出版社 * |
| 沈海斌等: "石墨烯在涂料领域中的应用", 《涂料技术与文摘》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359369A (en) * | 2018-03-28 | 2018-08-03 | 三河亮克威泽工业涂料有限公司 | Motor-car interior trim antibiotic paint and its preparation method and application |
| CN109207046A (en) * | 2018-10-18 | 2019-01-15 | 合肥永泰新型建材有限公司 | A kind of preparation method of timber environmental protection coating material |
| CN110666915A (en) * | 2019-09-25 | 2020-01-10 | 浙江云峰莫干山地板有限公司 | Solid wood composite floor surface plate and manufacturing method thereof |
| CN112358806A (en) * | 2021-01-12 | 2021-02-12 | 广东大自然家居科技研究有限公司 | Modified coating for ceramic tile-like wood floor and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104877549A (en) | Ultraviolet curable water-based antibacterial paint used for wooden products | |
| CN104877551A (en) | Ultraviolet curable water-based composite antibacterial paint used for wooden products | |
| CN104877552A (en) | Ultraviolet curable water-based paint used for wooden products | |
| CN104877548A (en) | Ultraviolet curable water-based environmental protection odor purifying paint used for wooden products | |
| CN1118525C (en) | Antibacterial antimildew surface decorative material and its application method | |
| CN104629576A (en) | High-performance water-based wood coating | |
| CN1554717A (en) | Nano technology modified ultraviolet solidified woodware paint | |
| CN108034295A (en) | A kind of inorganic environment-friendly interior wall mould proof antibacterial paint | |
| CN104762014A (en) | Polyurethane waterproof mildew-resistant paint and preparation method thereof | |
| CN104530963A (en) | Ultraviolet-curing antifouling anti-doodling bactericidal finishing paint and preparation method thereof | |
| CN109971290A (en) | A kind of high multi-functional water-based coating and preparation method thereof firmly of anti-formaldehyde antibacterial resistant | |
| Wei et al. | Superior mechanical properties of hybrid organic-inorganic superhydrophilic thin film on plastic substrate | |
| CN111513081A (en) | Antibacterial agent and application thereof | |
| CN110252125A (en) | A kind of ordor removing is except aldehyde wall paper care agent and preparation method thereof | |
| CN113729012A (en) | Durable high-activity antibacterial antiviral agent and application thereof | |
| Yuan et al. | SiO2/TiO2 and PDMS modified self-cleaning coating and its application in decorative UHPC surface | |
| CN105694714A (en) | Medical sterilization siloxane coating and preparing method thereof | |
| CN104877528A (en) | Ultraviolet-curing antimicrobial antistatic paint for PCB (printed circuit board) plastic boards | |
| CN107722829A (en) | A kind of wood furniture is painted with flame-proof antibiotic | |
| CN102585683B (en) | Aldehyde-removing, mildew-proof and anti-yellowing ultra-brightness white finish | |
| CN115433497B (en) | Antifouling and antibacterial water-based wood paint and preparation method thereof | |
| CN110183894A (en) | A kind of neutrality mildew-proof putty | |
| CN111423783A (en) | Antibacterial odor-removing water-based environment-friendly building coating and preparation method thereof | |
| DE19606011A1 (en) | Article or material with effective antifouling coating free from biocide | |
| CN106010066A (en) | Ultraviolet-cured aqueous polyurethane antibacterial coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150902 |