CN104530963A - Ultraviolet-curing antifouling anti-doodling bactericidal finishing paint and preparation method thereof - Google Patents
Ultraviolet-curing antifouling anti-doodling bactericidal finishing paint and preparation method thereof Download PDFInfo
- Publication number
- CN104530963A CN104530963A CN201410837428.1A CN201410837428A CN104530963A CN 104530963 A CN104530963 A CN 104530963A CN 201410837428 A CN201410837428 A CN 201410837428A CN 104530963 A CN104530963 A CN 104530963A
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- Prior art keywords
- scribble
- ultraviolet light
- finishing paint
- finish paint
- light polymerization
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to an ultraviolet-curing antifouling anti-doodling bactericidal finishing paint and preparation method thereof. The finishing paint comprises the following components in percentage by weight: 10%-40% of low-surface-tension antifouling resin, 10-40% of polyurethane acrylate, 2%-7% of diphenyl ketone, 2%-7% of 2-hydroxy-2-methyl-1-phenyl-1-propanone, 5%-15% of trihydroxymethylpropane triacrylate, 10-30% of tripropylene glycol diacrylate, 5%-10% of 1,6-hexanediol diacrylate, 3%-15% of matte powder and 0.1%-0.5% of a fungicide. The finishing paint is environment-friendly and non-toxic and is easy to clean, can effectively kill bacteria or control the growth of bacteria and has the characteristics of scratching resistance, impact resistance and the like; and since the finishing paint is free of solvent, harmful heavy metals and pesticide-like organic fungicides, the finishing paint is environment-friendly and harmless and is suitable for interior decorations of kitchens, bathrooms, kitchens, children rooms and the like.
Description
Technical field
The present invention relates to one and can be used in ultraviolet light polymerization resistant anti-scribble sterilization finish paint on floor, desktop, platen, wallboard (ceramic tile) and method.
Background technology
Along with people standard of living improve constantly and science and technology continuous progress, domestic and international human consumer requires that the finish paint be used on floor, desktop, platen, wallboard etc. to possess after environmental protection, the sterilization of resistant anti-scribble, surface lacquer the features such as wear-resisting not easily scuffing lastingly, but traditional wear-resistant paint solvent based coating often, it is more difficult to process, and not easily produces fast.And have part fungus and mildew resistance coating often containing class farm chemical ingredients, or heavy metal etc., be unsuitable for kitchen countertop, the application of the family products such as desktop.
Summary of the invention
Technical problem to be solved by this invention is to overcome the deficiencies in the prior art, provides a kind of ultraviolet light polymerization resistant anti-scribble sterilization finish paint and method.
For solving above technical problem, the present invention takes following technical scheme: a kind of ultraviolet light polymerization resistant anti-scribble sterilization finish paint, it comprises following compositions in weight percentage: low surface tension anti-pollution resin 10% ~ 40%, urethane acrylate 10 ~ 40%, benzophenone 2% ~ 7%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2% ~ 7%, Viscoat 295 5% ~ 15%, tripropylene glycol diacrylate 10% ~ 30%, 1,6 hexanediol diacrylate 5% ~ 10%, dumb light powder 3% ~ 15%, sterilant 0.1% ~ 0.5%.
Preferably, described low surface tension anti-pollution resin is Si modification, fluorine richness urethane acrylate.
Preferably, described sterilant is bactericidal nano-silver agent.
A kind of preparation method as above-mentioned ultraviolet light polymerization resistant anti-scribble sterilization finish paint, it drops into silicone-contained acrylic resin solution successively in steel basin, fluoroacrylic resin, polyurethane acrylic resin, benzophenone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, Viscoat 295, tripropylene glycol diacrylate, 1, 6-hexanediyl ester, the rotating speed of stirrer 1000 revs/min, stir 30 minutes, after above-mentioned material is fully mixed, dumb light powder is added in stirring, nano-disinfection agent, 1500 revs/min are stirred and within 60 minutes, namely obtain ultraviolet light polymerization resistant anti-scribble sterilization finish paint.
Owing to taking above technical scheme, the present invention compared with prior art tool has the following advantages:
The present invention adopts siliceous, fluorine resistance to soiling oligopolymer as matrix resin, and in formula, add nanometer silver auxiliary agent, existing floor production line can be utilized to produce fast, the unsuitable pickup of environment-protecting asepsis, easy cleaning, can effectively kill bacteria or control bacterial reproduction, there is scratch resistance, damage resistant, the feature such as shock-resistant simultaneously, and not containing solvent, not containing harmful heavy metal, not containing the organic bactericide of class agricultural chemicals, environmentally friendly, be applicable to the interior decorations such as kitchen, bathroom, kitchen, child room.
Embodiment
Embodiment: the invention provides a kind of ultraviolet light polymerization resistant anti-scribble sterilization finish paint, its component is the corresponding proportioning of content by weight according to following different embodiment, refers to table 1:
Table 1
| Embodiment one | Embodiment two | Embodiment three | Embodiment four | |
| Silicone-contained acrylic resin solution | 15.0 | 20.0 | 33.0 | 20.0 |
| Fluoroacrylic resin | 20.0 | 10.0 | 10.0 | 10.0 |
| Polyurethane acrylic resin | 20.9 | 21.9 | 18.9 | 19.7 |
| Benzophenone | 2.0 | 2.0 | 2.0 | 2.0 |
| 2-hydroxy-2-methyl-1-phenyl-1-acetone | 4.0 | 4.0 | 4.0 | 4.0 |
| Viscoat 295 | 12.0 | 5.0 | 5.0 | 4.0 |
| Tripropylene glycol diacrylate | 15.0 | 27.0 | 15.0 | 13.0 |
| 1,6 hexanediol diacrylate | 10.0 | 5.0 | 2.0 | 15.0 |
| Dumb light powder | 1.0 | 5.0 | 10.0 | 12.0 |
| Bactericidal nano-silver agent | 0.1 | 0.1 | 0.1 | 0.3 |
According to the formula in above-described embodiment, its concrete preparation method is: in steel basin, drop into silicone-contained acrylic resin solution successively, fluoroacrylic resin, polyurethane acrylic resin, benzophenone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, Viscoat 295, tripropylene glycol diacrylate, 1, 6-hexanediyl ester, the rotating speed of stirrer 1000 revs/min, stir 30 minutes, after above-mentioned material is fully mixed, dumb light powder is added in stirring, nano-disinfection agent, 1500 revs/min are stirred and within 60 minutes, namely obtain ultraviolet light polymerization resistant anti-scribble sterilization finish paint.
The ultraviolet light polymerization resistant anti-scribble sterilization finish paint obtained according to above-described embodiment and in conjunction with above-mentioned preparation method, be sprayed on floor, desktop, platen, wallboard (ceramic tile), through UV-irradiation after 10 ~ 20 seconds, the performance perameter that the film after solidification obtains is in table 2:
Table 2
| Index | Embodiment one | Embodiment two | Embodiment three | Embodiment four |
| Sticking power (hundred lattice) | One-level | One-level | One-level | One-level |
| Shock-resistance kg.cm | ＞60 | ＞60 | ＞60 | ＞60 |
| Antibiotic rate | 82％ | 85％ | 83％ | 93％ |
| Stain resistance | OK | OK | OK | OK |
Above to invention has been detailed description; its object is to allow the personage being familiar with this art can understand content of the present invention and be implemented; can not limit the scope of the invention with this; the equivalence change that all spirit according to the present invention are done or modification, all should be encompassed in protection scope of the present invention.
Claims (4)
1. a ultraviolet light polymerization resistant anti-scribble sterilization finish paint, it comprises following compositions in weight percentage: low surface tension anti-pollution resin 10% ~ 40%, urethane acrylate 10 ~ 40%, benzophenone 2% ~ 7%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2% ~ 7%, Viscoat 295 5% ~ 15%, tripropylene glycol diacrylate 10% ~ 30%, 1,6 hexanediol diacrylate 5% ~ 10%, dumb light powder 3% ~ 15%, sterilant 0.1% ~ 0.5%.
2. ultraviolet light polymerization resistant according to claim 1 anti-scribble sterilization finish paint, is characterized in that: described low surface tension anti-pollution resin is Si modification, fluorine richness urethane acrylate.
3. ultraviolet light polymerization resistant according to claim 1 anti-scribble sterilization finish paint, is characterized in that: described sterilant is bactericidal nano-silver agent.
4. the preparation method of a ultraviolet light polymerization resistant anti-scribble sterilization finish paint as described in claim 1 or 2 or 3, it is characterized in that: in steel basin, drop into silicone-contained acrylic resin solution successively, fluoroacrylic resin, polyurethane acrylic resin, benzophenone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, Viscoat 295, tripropylene glycol diacrylate, 1, 6-hexanediyl ester, the rotating speed of stirrer 1000 revs/min, stir 30 minutes, after above-mentioned material is fully mixed, dumb light powder is added in stirring, nano-disinfection agent, 1500 revs/min are stirred and within 60 minutes, namely obtain ultraviolet light polymerization resistant anti-scribble sterilization finish paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410837428.1A CN104530963A (en) | 2014-12-30 | 2014-12-30 | Ultraviolet-curing antifouling anti-doodling bactericidal finishing paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410837428.1A CN104530963A (en) | 2014-12-30 | 2014-12-30 | Ultraviolet-curing antifouling anti-doodling bactericidal finishing paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN104530963A true CN104530963A (en) | 2015-04-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410837428.1A Pending CN104530963A (en) | 2014-12-30 | 2014-12-30 | Ultraviolet-curing antifouling anti-doodling bactericidal finishing paint and preparation method thereof |
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| CN (1) | CN104530963A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106675297A (en) * | 2016-12-23 | 2017-05-17 | 成都优品化工有限公司 | Ultraviolet light photocuring granite decorative coating and preparation method thereof |
| CN107641458A (en) * | 2017-11-13 | 2018-01-30 | 鹤山市创享科技有限公司 | Floor paint |
| CN111378358A (en) * | 2018-12-27 | 2020-07-07 | 上海海隆赛能新材料有限公司 | Ultraviolet-curing high-stain-resistance wear-resistant matt floor coating |
| CN111777783A (en) * | 2020-07-16 | 2020-10-16 | 吾优新材料科技(江苏)有限公司 | Preparation process and formula of stain-resistant and doodling-resistant decorative film |
| CN114891435A (en) * | 2022-06-30 | 2022-08-12 | 湖南松井新材料股份有限公司 | Preparation method of water-based UV-cured wear-resistant anti-fouling matte coating and coating film |
| CN116463017A (en) * | 2023-04-18 | 2023-07-21 | 千年舟新材科技集团股份有限公司 | Skin-feel stain-resistant wear-resistant UV (ultraviolet) finishing paint and preparation method thereof |
| CN116716033A (en) * | 2023-05-08 | 2023-09-08 | 东周化学工业（昆山）有限公司 | Ultraviolet light curing tannic acid-proof paint and preparation method thereof |
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| CN101638482A (en) * | 2008-07-30 | 2010-02-03 | 比亚迪股份有限公司 | Polymer and preparation method thereof, antifouling coating composition and antifouling coating layer material |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106675297A (en) * | 2016-12-23 | 2017-05-17 | 成都优品化工有限公司 | Ultraviolet light photocuring granite decorative coating and preparation method thereof |
| CN107641458A (en) * | 2017-11-13 | 2018-01-30 | 鹤山市创享科技有限公司 | Floor paint |
| CN111378358A (en) * | 2018-12-27 | 2020-07-07 | 上海海隆赛能新材料有限公司 | Ultraviolet-curing high-stain-resistance wear-resistant matt floor coating |
| CN111378358B (en) * | 2018-12-27 | 2021-09-28 | 上海海隆赛能新材料有限公司 | Ultraviolet-curing high-stain-resistance wear-resistant matt floor coating |
| CN111777783A (en) * | 2020-07-16 | 2020-10-16 | 吾优新材料科技(江苏)有限公司 | Preparation process and formula of stain-resistant and doodling-resistant decorative film |
| CN114891435A (en) * | 2022-06-30 | 2022-08-12 | 湖南松井新材料股份有限公司 | Preparation method of water-based UV-cured wear-resistant anti-fouling matte coating and coating film |
| CN116463017A (en) * | 2023-04-18 | 2023-07-21 | 千年舟新材科技集团股份有限公司 | Skin-feel stain-resistant wear-resistant UV (ultraviolet) finishing paint and preparation method thereof |
| CN116716033A (en) * | 2023-05-08 | 2023-09-08 | 东周化学工业（昆山）有限公司 | Ultraviolet light curing tannic acid-proof paint and preparation method thereof |
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Application publication date: 20150422 |
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