CN101333347A - Antisoil and anti-graffiti coatings and method for preparing same - Google Patents
Antisoil and anti-graffiti coatings and method for preparing same Download PDFInfo
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Abstract
The invention discloses an anti-fouling and anti-doodling dope and a preparation method. The dope contains the following ingredients(based on weight portions): 15-20 portions of biradical fluoro-acrylate oligomer, 3-10 portions of biradical silicone acrylate oligomer, 10-40 portions of 6-radical polyurethane acrylate oligomer, 1-30 portions of biradical epoxy acrylate oligomer, 1-10 portions of photoinitiator, 10-25 portions of reactive diluted monomer, 0.5-5 portions of addition agent and 10-25 portions of organic solvent. Paint film made from the anti-fouling and anti-doodling dope is structurally compact, with surface tension reaching 27-33dyne/centimeter and effectively prevents various doodling materials, such as oil pen, waterborne pen, ink jet and pollutant from infiltrating to the dope or the substrate, thus reducing cleaning difficulties; meanwhile, the dope is good in dirt resistance and doodling resistance and long in service life. The dope can be prepared by mixing the ingredients of the dope to be even, so the preparation method is economic and simple.
Description
Technical field
The present invention relates to a kind of functional coating and preparation method thereof, particularly relate to a kind of coating and preparation method thereof with anti-soil and anti-graffiti function.
Background technology
Scribble and pollution exist constantly in the modern life, such as the scribble of facilities such as call box, electric pole, wall curtain plate, external wall such as free ink pen mark, oil pen's mark, spraying small advertisement, psoriasis advertisement, the pollution of (gas furnace, smoke extractor etc.) etc. all becomes worry in people's daily life day by day on the Metal wall used of interior decoration, kitchen cabinet plate, the kitchen tools in addition, because the porousness of its base material, scribble and pollution are very easily infiltrated in the base material not easy to clean, become people's urgent problem.
In the prior art, the paint film that forms behind traditional paint solidification, it is not enough to exist hardness, and temperature tolerance is poor, and easy problems of crack, when being scribbled or pollution when polluting, can't reach antifouling and anti-graffiti effect.
In traditional anti-graffiti and anti-pollution paint, its effective ingredient is only added organosilicon or organic fluorine composition on the coating surface that paint solidification forms, but its addition is few, and it is seldom crosslinked in the paint film that paint solidification forms as the reaction composition, therefore the internal structure of the paint film of paint solidification formation is fine and close inadequately, scribble material and pollution are very easily infiltrated among the paint film and are caused not easy to clean, and this coating surface this kind active substance after repeatedly cleaning is easy to wearing and tearing, thereby can cause its anti-graffiti and stain resistance to weaken, shorten work-ing life, again application problem such as difficulty again.
So-called crosslinking reaction is meant the new key of formation between the macromolecular chain, makes it to become the reaction of reticular polymer.After the polymer generation was crosslinked, it is more flexible that amorphous polymers just becomes, and intensity also can increase.Crosslinking reaction helps improving use temperature and overcomes phenomenons such as stress cracking.
Therefore, traditional anti-graffiti and anti-pollution paint awaits upgrading.
Summary of the invention
The object of the invention is to provide a kind of anti-soil and anti-doodling paint and preparation method thereof, and the formed paint film of this coating has dense structure, and can effectively prevent to scribble material composition and pollution be infiltrated among the coating paint film.
The sense number is a benchmark with the quantity of the carbon containing carbon unsaturated double-bond C=C of unit formula institute among the present invention, as to contain six carbon carbon unsaturated double-bonds be six functional groups, two carbon-carbon double bonds be two functional groups.
Technical scheme of the present invention is as follows
A kind of have anti-soil and anti-graffiti merit coating, and this coating is made up of following component by weight:
The two perfluoroalkyl acrylate ester oligomer 15-20 of functional group parts;
The two organic silicon acrylic ester oligopolymer 3-10 of functional group parts;
Hexafunctional aliphatic urethane acrylates oligopolymer 10-40 part;
The two epoxy acrylate oligomer 1-30 of functional group parts;
Light trigger 1-10 part;
Activity is released monomer 10-25 part;
Auxiliary agent 0.5-5 part;
Organic solvent 10-25 part.
Above-mentioned coating, the preferred umber of described light trigger is 5 parts.
Described coating, wherein, described light trigger includes one or more in the following composition: 2-hydroxy-2-methyl-1-phenyl-1-acetone; 1-hydroxyl-cyclohexyl benzophenone; 2,4,6-Three methyl Benzene formyl diphenyl phosphine oxide; Two 2,4,6-Three methyl Benzene formylphenyl phosphine oxide; Benzophenone.
Described coating, wherein, described activity diluting monomer is one or more in Viscoat 295,1,6 one hexanediyl ester, tri (propylene glycol) diacrylate, dipentaerythritol acrylate, the ethoxyquin Viscoat 295.
Described coating, wherein, described auxiliary agent comprises one or more in the following composition: flow agent, wetting agent, defoamer, adhesion promoter.
Described coating, wherein, described organic solvent comprises one or more in the following composition: propylene-glycol ethyl ether acetic ester, propyl carbinol, dimethylbenzene, N-BUTYL ACETATE.
Cardinal principle of the present invention, be that the two keys of this coating C=C in two functional group's perfluoroalkyl acrylate ester oligomers and the two functional group's organic silicon acrylic ester oligopolymer in the radiation curing process participate in radiation curing, finish crosslinking reaction, the two keys of C=C are changed form the C-C singly-bound, internal structure is more stable, thereby make gained paint film quality fine and close more, can prevent effectively that various scribble materials such as oil pen, free ink pen, ink-jet etc. are penetrated in the coating with pollution substance such as grease etc. or base material inside, thereby reduce the cleaning difficulty.
A kind of method for preparing described coating, its method is as follows:
With following each component by weight: i.e. the two perfluoroalkyl acrylate ester oligomer 15-20 of functional group parts, the two organic silicon acrylic ester oligopolymer 3-10 of functional group parts, hexafunctional aliphatic urethane acrylates oligopolymer 10-40 part, the two epoxy acrylate oligomer 1-30 of functional group parts, 5 parts of light triggers, activity diluting monomer 10-25 part, auxiliary agent 0.5-5 part, organic solvent 10-25, add in a mixing bowl, stir, form coating.
Described method wherein, said method comprising the steps of:
A1, the hexafunctional aliphatic urethane acrylates oligopolymer is joined in a mixing bowl;
A2, again two functional group's epoxy acrylate oligomer are joined in a mixing bowl, and the formation mixture that stirs;
A3, two functional group's organic silicon acrylic ester oligopolymer are joined in the rapid mixture that forms of previous step, and stir;
A4, two functional group's perfluoroalkyl acrylate ester oligomers are joined in the rapid mixture that forms of previous step, and stir;
A5, each composition in the activity diluting monomer is joined in the rapid mixture that forms of previous step successively, and stir;
A6, each composition in the light trigger is added in the rapid mixture that forms of previous step successively, and stir and make it dissolving evenly;
In A7, the mixture, and stir the rapid formation of each composition adding previous step in the auxiliary agent;
In A8, the mixture, stirred 10-15 minute, make it evenly to form mixture the rapid formation of each composition adding previous step in the organic solvent.
A kind of anti-soil provided by the present invention and anti-doodling paint, because the two keys participation of this coating C=C in two functional group's perfluoroalkyl acrylate ester oligomers and the two functional group's organic silicon acrylic ester oligopolymer in radiation curing process radiation curing, finish crosslinking reaction, the two keys of C=C are changed form the C-C singly-bound, internal structure is more stable, thereby make gained paint film quality fine and close more, surface tension reaches the 27-33 dynes per centimeter, so just can prevent various scribble materials such as oil pen effectively, free ink pen, ink-jets etc. are penetrated in the coating with pollution substance such as grease etc. or base material inside, reduced the cleaning difficulty, anti-soil and antigraffiti effect are better simultaneously, longer service life, this paint solidification form the The performance test results of paint film referring to Fig. 4 to Fig. 6.
Because this preparation method for coating is simple, only need the prescription each component, mixed in accordance with regulations stirs, and form mixture and get final product, but therefore automatic production, and its production efficiency height, power consumption and raw material consumption are few, and production cost is low.
Description of drawings
Fig. 1 is the flow process signal table that the present invention prepares the coating method;
Fig. 2 is the component formula table of preparation anti-soil of the present invention and anti-doodling paint embodiment;
Fig. 3 is the continuous table of Fig. 2;
Fig. 4 is a coating property test comparison table of the present invention, and wherein, Comparative Examples 1 is the anti-graffiti latex of metope in the existing coating; Comparative Examples 2 is the anti-graffiti baking vanish of metal in the existing coating; Comparative Examples 3 is the general ornamental lacquer in the existing coating, as is used to spray wall, cement plate, metal sheet etc.; " √ " represents that it is functional, and " * " represents its poor performance;
Fig. 5 is the continuous table of Fig. 4;
Fig. 6 is the continuous table of Fig. 5.
Embodiment
Below by a plurality of embodiment and Comparative Examples, to coating of the present invention and preparation method thereof, with and anti-soil and antigraffiti effect be described in further detail.The prescription of embodiment correspondence as shown in Figures 2 and 3, each component is in weight part in the prescription.
Employed light trigger, activity diluting monomer, auxiliary agent and organic solvent among the present invention, be component general in the traditional preparation process technical field of coatings, it also comprises multiple respectively except that following embodiment is employed, employed component is a preferred ingredient in following examples.
With following component: 10.0 parts of hexafunctional aliphatic urethane acrylates oligopolymer; 16.0 parts of two functional group's epoxy acrylate oligomer; 3.0 parts of two functional group's organic silicon acrylic ester oligopolymer; 20.0 parts of two functional group's perfluoroalkyl acrylate ester oligomers; 23.0 parts of activity diluting monomers, wherein 17.0 parts of Viscoat 295s, tri (propylene glycol) diacrylate 6.0.0 part; 5.0 parts of light triggers, wherein, 2-hydroxy-2-methyl-1-phenyl-2.0 parts in 1-acetone, 1-hydroxyl-1.0 parts of cyclohexyl benzophenones, 2.0 parts of benzophenone; 3.0 parts of auxiliary agents; 20.0 parts of organic solvents, wherein, 5.0 parts of propyl carbinols, 5.0 parts of dimethylbenzene, 10.0 parts of N-BUTYL ACETATEs add in a mixing bowl and mix, and stirring and dissolving are even.
In embodiment, the light trigger ratio can wherein, when the light trigger ratio is 5.0 parts, be optimal selection between 1.0 parts to 10.0 parts.
The working method of preparation coating of the present invention, preferably carry out as follows:
1, the hexafunctional aliphatic urethane acrylates oligopolymer is joined in a mixing bowl for 10.0 parts;
2, again two functional group's epoxy acrylate oligomer are joined in a mixing bowl for 16.0 parts, and stir, form mixture;
3,3.0 parts of two functional group's organic silicon acrylic ester oligopolymer are joined in the rapid mixture that forms of previous step, and stir;
4,20.0 parts of two functional group's perfluoroalkyl acrylate ester oligomers are joined in the rapid mixture that forms of previous step, and stir;
5, with activity diluting monomer: 17.0 parts of Viscoat 295s, tri (propylene glycol) diacrylate join in the rapid mixture that forms of previous step for 6.0 parts, and stir;
6, with light trigger; 2-hydroxy-2-methyl-1-phenyl-2.0 parts in 1-acetone, 1-hydroxyl-1.0 parts of cyclohexyl benzophenones, benzophenone add in the rapid mixture that forms of previous step for 2.0 parts, and stirring makes it dissolving evenly;
7,3.0 parts of auxiliary agents are added in the rapid mixture that forms of previous step, and stir;
8, with organic solvent: 5.0 parts of propyl carbinols, 5.0 parts of dimethylbenzene, N-BUTYL ACETATE add in the rapid mixture that forms of previous step for 10.0 parts, stir 10-15 minute, make it evenly to form coating.The present invention prepares the coating method steps can be as shown in Figure 1.
After coating prepares successfully, will test, with coating roller coat, showering or be sprayed on the base material, and this base material be placed 20-100 ℃ of temperature environment flash distillation 0-10 minute before the test its each technical feature in use; Utilize electron beam or UV-light that above-mentioned coating after flash distillation is carried out radiation curing, form cured paint film.
Described flash evaporation technology and radiation curing technology belong to known technology in test coating technology performance technologies field, do not repeat them here.
The cured paint film of described formation is carried out the technical feature test, and its test performance comprises: water tolerance, salt fog resistance, resistance to acids and bases, petrol-resistance, anti-hardness, anti-solvent scouring, sticking power, anti-stickup stripping strength, temperature-change resistance, artificial ageing resistance, stain resistance, stain resistance solvent scouring.
The specific performance test index is as shown in table 1.The comparing result of test such as Fig. 4 are to shown in Figure 6.
Press the 2 corresponding specified components of embodiment among Fig. 2 and Fig. 3 and repeat embodiment 1 and operate accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, the comparing result of test shows that each technical feature of the present invention is good, and is extremely shown in Figure 6 as Fig. 4.
Table 1
Pressing the 3 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that each technical feature of the present invention is good, and is extremely shown in Figure 6 as Fig. 4.
Pressing the 4 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that its each technical feature is good, and is extremely shown in Figure 6 as Fig. 4.
Pressing the 5 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that its each technical feature is good, and is extremely shown in Figure 6 as Fig. 4.
Pressing the 6 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that its each technical feature is good, and is extremely shown in Figure 6 as Fig. 4.
Pressing the 7 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that its each technical feature is good, and is extremely shown in Figure 6 as Fig. 4.
Pressing the 8 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that its each technical feature is good, and is extremely shown in Figure 6 as Fig. 4.
Embodiment 9
Pressing the 9 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that its each technical feature is good, and is extremely shown in Figure 6 as Fig. 4.
Pressing the 10 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, and survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that its each technical feature is good, and is extremely shown in Figure 6 as Fig. 4.
Pressing the 11 corresponding specified components of embodiment among Fig. 2 and Fig. 3 repeats embodiment 1 and operates accordingly, obtain cured paint film, survey its technical feature as described in example 1 above, test index is as shown in table 1, test result shows that its each technical feature is good, and is extremely shown in Figure 6 as Fig. 4.
Comparative Examples 1
Prevent that to general in the existing coating being coated with duck emulsion paint technical feature as described in example 1 above tests, test index is as shown in table 1, and test result shows that its most technical features are good, and minority leaves vestige, and indivedual poor-performings are extremely shown in Figure 6 as Fig. 4.
Comparative Examples 2
The anti-graffiti baking vanish of metal technical feature as described in example 1 above in the existing coating is tested, and test index is as shown in table 1, and test result shows that its most technical features are good, but minority leaves vestige, and is extremely shown in Figure 6 as Fig. 4.
Comparative Examples 3
General ornamental lacquer (being used to spray wall, cement plate, metal sheet or the like) technical feature as described in example 1 above in the existing coating is tested, test index is as shown in table 1, test result shows its technical feature, and some is good, and some is relatively poor, and is extremely shown in Figure 6 as Fig. 4.
Among above-mentioned all embodiment, two functional group's perfluoroalkyl acrylate ester oligomers wherein, two functional group's organic silicon acrylic ester oligopolymer are the effective constituent that mainly contains of the present invention, the two keys of C=C in the radiation curing process in two functional group's perfluoroalkyl acrylate ester oligomers and the two functional group's organic silicon acrylic ester oligopolymer participate in radiation curing, finish crosslinking reaction, the two keys of C=C are changed form the C-C singly-bound, internal structure is more stable, thereby make the densification of gained paint film quality, and therefore make its surface tension reach every centimetre of 27-33 dyne, thereby have permanently effective anti-soil and antigraffiti properties.
Simultaneously, hexafunctional aliphatic urethane acrylates oligopolymer, two functional group's epoxy acrylate oligomer, reactive monomer are to reduce viscosity and improve other physics of paint film, chemical property, as hardness, anti-solvent, speed of response etc.; Light trigger is then as the polymerization of active ingredient initiator system; Auxiliary agent is flow agent, wetting agent, defoamer and adhesion promoter etc., wetting, the surperficial levelling of ground, construction process froth breaking is provided respectively and adds strong adhesive force equivalence fruit; Organic solvent then provides dilution and reduces the viscosity of coating.
Coating provided by the present invention, through general spraying, showering or roller application, have secular anti-soil and antigraffiti properties behind the film-forming, particularly effective especially at greasy dirt, water-color paintbrush, oil pike or other marking pen, mainly as indoor and outdoor decorative wall, curtain, timber, aluminium or other metal base.
Provided by the present invention have anti-soil and an anti-doodling paint, with required each formula constituent mixing and stirring by a certain percentage, forms coating and get final product.Its internal structure densification, in use paint film compact structure, the surface tension of Xing Chenging reaches the 27-33 dynes per centimeter, prevented that effectively various scribble materials such as oil pen, free ink pen, ink-jet etc. are penetrated in the coating with pollution substance such as grease etc. or base material inside, promptly reduced the difficulty of cleaning and the dynamics that scribble adheres to.
Coating provided by the present invention also has the following advantages simultaneously: 1, this coating is through general spraying, pouring Be coated with or roller application, radiation-hardenable reaction, but automated production, the production efficiency height consumes energy and is coated with The material consumption is few, and production cost is low; 2, the paint film quality densification of its reaction formation, two functional group's fluorine propylene Acid esters oligomer, two functional group's organic silicon acrylic ester oligomer participate in the system cross-linking reaction, make it anti-Dirty and anti-graffiti functional effect is better, and the life-span is longer; 3, its surface tension is low, only the 27-33 dyne/ Within the cm range, scribble is difficult for adhering to, easy to clean, quick, as paper handkerchief or cotton get final product Wipe easily the surface scribble, leave no trace.
Claims (8)
1, a kind of have anti-soil and an anti-doodling paint, and this coating is made up of following component by weight:
The two perfluoroalkyl acrylate ester oligomer 15-20 of functional group parts;
The two organic silicon acrylic ester oligopolymer 3-10 of functional group parts;
Hexafunctional aliphatic urethane acrylates oligopolymer 10-40 part;
The two epoxy acrylate oligomer 1-30 of functional group parts;
Light trigger 1-10 part;
Activity diluting monomer 10-25 part;
Auxiliary agent 0.5-5 part;
Organic solvent 10-25 part.
2, coating according to claim 1 is characterized in that, described light trigger is 5 parts.
3, coating according to claim 1 is characterized in that, described light trigger includes one or more in the following composition: 2-hydroxy-2-methyl-1-phenyl-1-acetone; 1-hydroxyl-cyclohexyl benzophenone; 2,4,6-Three methyl Benzene formyl diphenyl phosphine oxide; Two 2,4,6-Three methyl Benzene formylphenyl phosphine oxide; Benzophenone.
4, coating according to claim 1, it is characterized in that, described activity diluting monomer is one or more in Viscoat 295,1,6 one hexanediyl ester, tri (propylene glycol) diacrylate, dipentaerythritol acrylate, the ethoxyquin Viscoat 295.
5, coating according to claim 1 is characterized in that, described auxiliary agent comprises one or more in the following composition: flow agent, wetting agent, defoamer, adhesion promoter.
6, coating according to claim 1 is characterized in that, described organic solvent comprises one or more in the following composition: propylene-glycol ethyl ether acetic ester, propyl carbinol, dimethylbenzene, N-BUTYL ACETATE.
7, a kind of method for preparing the described coating of claim 1, its method is as follows:
With following each component by weight: i.e. the two perfluoroalkyl acrylate ester oligomer 15-20 of functional group parts, the two organic silicon acrylic ester oligopolymer 3-10 of functional group parts, hexafunctional aliphatic urethane acrylates oligopolymer 10-40 part, the two epoxy acrylate oligomer 1-30 of functional group parts, 5 parts of light triggers, activity diluting monomer 10-25 part, auxiliary agent 0.5-5 part, organic solvent 10-25, add in a mixing bowl, stir, form coating.
8, method according to claim 7 is characterized in that, said method comprising the steps of:
A1, the hexafunctional aliphatic urethane acrylates oligopolymer is joined in a mixing bowl;
A2, again two functional group's epoxy acrylate oligomer are joined in a mixing bowl, and the formation mixture that stirs;
A3, two functional group's organic silicon acrylic ester oligopolymer are joined in the rapid mixture that forms of previous step, and stir;
A4, two functional group's perfluoroalkyl acrylate ester oligomers are joined in the rapid mixture that forms of previous step, and stir;
A5, each composition in the activity diluting monomer is joined in the rapid mixture that forms of previous step successively, and stir;
A6, each composition in the light trigger is added in the rapid mixture that forms of previous step successively, and stir and make it dissolving evenly;
In A7, the mixture, and stir the rapid formation of each composition adding previous step in the auxiliary agent;
In A8, the mixture, stirred 10-15 minute, make it evenly to form coating the rapid formation of each composition adding previous step in the organic solvent.
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Family Cites Families (4)
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-
2008
- 2008-07-11 CN CN2008101416019A patent/CN101333347B/en active Active
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