CN106590242A - LED-UV (light-emitting diode-ultraviolet) anti-doodling pollution-resisting coating and preparation method as well as use method thereof - Google Patents
LED-UV (light-emitting diode-ultraviolet) anti-doodling pollution-resisting coating and preparation method as well as use method thereof Download PDFInfo
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- CN106590242A CN106590242A CN201611044437.0A CN201611044437A CN106590242A CN 106590242 A CN106590242 A CN 106590242A CN 201611044437 A CN201611044437 A CN 201611044437A CN 106590242 A CN106590242 A CN 106590242A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The invention discloses an LED-UV (light-emitting diode-ultraviolet) anti-doodling pollution-resisting coating, which can be used to coat the surface, which is polished and cleanly dedusted in advance, of a to-be-coated object through brush coating or spray coating according to the coating weight to 80g/m<2>; photocuring is performed immediately through illuminating by a portable LED-UV lamp for 5 to 8 seconds after the brush coating is finished; the LED-UV anti-doodling pollution-resisting coating is prepared from the following components in parts by weight: 25 to 35 parts of 4.5 functional silicofluoride acrylate resin, 21 to 30 parts of low-energy cured special functional acrylic resin, 10 to 20 parts of 8 functional hyperbranched polyester acrylic resin, 20 to 25 parts of monomer, 4 to 5 parts of photoinitiator, 0.3 to 0.5 part of wetting dispersant, 0.3 to 0.5 part of defoamer and 0.6 to 0.8 part of anti-doodling additive; a paint film has excellent properties of anti-doodling, pollution prevention, easiness in cleaning, water proofing, oil resistance and chemical resistance; the paint film is compact and smooth, and is high in hardness and good in pollution tolerance.
Description
Technical field
The present invention relates to a kind of LED-UV functional coatings, the composition of the anti-graffiti anti-pollution paint of more particularly to a kind of LED-UV
And preparation method thereof and using method.
Background technology
In daily life, on the outer surface such as decorative exterior wall, public transport stop board, communication electric power facility, Jing often suffers aqueouss or oil
Property pen is scrawled and scarifies or put up various small advertisements, is had a strong impact on the attractive in appearance of equipment appearance and integrated environment, is needed sanitationman
Small advertisement paper is arduously rooted out by perching knife, aqueouss or oil pen's scribble, dirt is cleaned with wet towel, is taken time and effort, but can not be complete
Clear all is clean.
In order to solve this phenomenon, many companies research and develop aqueous, oiliness, traditional photocuring and PU double-components etc.
The coating of various anti-graffiti and anti-soil, but all there is many defects in these products.Such as：Aqueous anti-doodling paint paint film richness
Than the difference of oiliness, while having the shortcomings that hardness of paint film is inadequate；The PU double-component oiliness anti-doodling paints time to be done is long, in paint film
Dust is easily stained with dry run, and construction needs to convert firming agent and diluent construction, the VOC emission feature of environmental protection is poor；Traditional UV
Although the coating of photocuring has the advantages that hardness of paint film is high, wearability is good, curing efficiency is high, must adopt in dry run
Cross-linking and curing reaction is completed with high voltage mercury lamp luminous radiation drying equipment, completes to paint film forming solidification, high voltage mercury lamp is due to work(
Rate height (generally 80W/cm), with strong light intensity brightness, (impinge upon surface of the work increases surface of the work temperature to very strong heat radiation
20 degree or sos of degree) and ozone, needs supporting cooling system can be produced when working, it is impossible to use outdoor construction.
LED-UV lamps are a kind of power low (general portable LED-UV curing is 9-12W), heat radiation is little (impinges upon workpiece
Surface increases by 3 degree or so of temperature), ozone free generation, small volume, it is easy to carry, whenever and wherever possible can site operation LDE
Light fixture, availability is high, meet environmental protection and safety requirements.
The content of the invention
The technical problem to be solved is to overcome the deficiencies in the prior art, there is provided a kind of low energy curing efficiency
The good anti-graffiti anti-pollution paints of LED-UV of high, environmentally friendly VOC free discharge, easy construction, anti-graffiti and antifouling property, this coating exist
LED-UV lamps used in solidification dry run, the hardness of paint film height for obtaining, surface slip, good hand touch, good weatherability, while this
The bright preparation method and using method that the anti-graffiti anti-pollution paints of this LED-UV are also provided.
In order to solve the problems, such as techniques discussed above, the present invention is employed the following technical solutions：
A kind of anti-graffiti anti-pollution paint of LED-UV, the anti-graffiti anti-pollution paint of the LED-UV can pass through the side for brushing or spraying
Method, by 50～80g/m2Coating weight, coat in advance polishing the clean coated article body surface face of dedusting, brushing completes to make at once
With the portable LED-UV light irradiations photocuring 5-8 seconds；
The anti-graffiti anti-pollution paint of the LED-UV includes that the component of following parts by weight is made：
Wherein, the fluorine silication acrylate of 4.5 sense is the fluorinated silicone modified oligomer of 4.5 senses；
The monomer is dimethacrylate；
The anti-graffiti auxiliary agent is the modified organic silicon compound with acrylic double bond.
Preferably, described light trigger is 2,4,6 trimethylbenzoyl diphenyl phosphine oxides；
Described defoamer is the high DEGO2500 of enlightening；
EFKA-4010 of the described wetting dispersing agent for EFKA；
It is highly preferred that SPC-1487 of the fluorine silication acrylate of 4.5 sense for Sa Bisi.
Further, 6361-100 of the acrylated hyperbranched polyester resin of 8 sense for Changxing.
ADDITOL of the specific functionality acrylic resin of the low energy solidification for cyanogen specialization workTMLED 01。
It is further preferred that described anti-graffiti auxiliary agent is the ADL-UV131 of An Delong.
A kind of preparation method of the anti-graffiti anti-pollution paint of LED-UV, comprises the steps：
Step one:Under conditions of daylight or ultraviolet light is avoided, by the fluorine silication acrylate of 4.5 senses,
The specific functionality acrylic resin of low energy solidification, the acrylated hyperbranched polyester resin of 8 senses, monomer are added with paint container
In and be uniformly dispersed, add light trigger, wetting dispersing agent under agitation, stir 5 points with 500-800 rev/min of mixing speed
Clock keeps mixed material temperature to be less than 50 DEG C to be up to uniformly dispersed, in whipping process；
Step 2:Defoamer, anti-graffiti auxiliary agent are added, is disperseed more than 15 minutes with 800-1000 rev/min of mixing speed
To being uniformly dispersed, the anti-graffiti anti-pollution paints of LED-UV are obtained.
The using method of the anti-graffiti anti-pollution paint of a kind of LED-UV, by the LED-UV anti-graffiti anti-pollution paint by brushing
Or the method for spraying, by 50～80g/m2Coating weight, coat in advance polishing the clean coated article body surface face of dedusting, brush
Complete to use at once the LED-UV light irradiation photocuring 5-8 seconds.
Preferably, the LED-UV lamps are the portable LED-UV lamps that power is 9-12W.
Compared with prior art, the anti-graffiti anti-pollution paints of LED-UV of the invention, the specific function solidified using low energy
Property the acrylic resin fluorine silication acrylate of 4.5 senses of the collocation with the special photocuring of oil resistivity pen, 8 senses it is super
Branched polyester acrylic resin and anti-graffiti auxiliary agent, monomer (dimethacrylate) and light trigger etc. are rationally
Proportioning, produces with the extremely low anti-graffiti anti-pollution paints of the LED-UV of film formation surface tension force and splendid release, in object
The anti-graffiti anti-pollution paints of the LED-UV are coated on surface, and after the solidification of LED-UV light, gained paint film has extremely excellent to go out
Many lasting anti-scribbles, property anti-pollution and easy to clean, and outstanding water-fast, oily and chemical resistance, it is excellent weather-proof and
Heat stability, UV solidification rates are exceedingly fast, and coating surface densification is smooth, and hardness is high, and resistance to soiling is good, with aqueouss or oil pen upper
After face is scribbled, can be wiped easily with wet cloth, be left no trace, be pasted superincumbent small advertisement paper etc. and easily can also tear, it is right
Write without basis disorderly this society's trouble of patch and, there is provided solution, greatly mitigate the working strength of sanitationman.It is of the present invention
The anti-graffiti anti-pollution paints of LED-UV can be promoted on a large scale using simple.
Specific embodiment
Below by embodiment, technical scheme is further described, each embodiment is only as preferred real
Mode is applied to illustrate technical scheme, limitation of the invention is not constituted.The various components of the present invention are using existing
Commercially available prod.
In following embodiment, the fluorine silication acrylate of 4.5 sense is the fluorinated silicone modified oligomeric of 4.5 senses
Thing, can be in the case where high response be ensured, hardness of paint film is high, good toughness, and thick painting is not ftractureed, and its antifouling principle is side chain
Fluorine carbon bond is incompatible to connect structure in other main chains or side chain and proportion is relatively low so that fluorine carbon key is migrated naturally to coating when coating
Surface, and make molecule independently fill the resin surface of (self-assembly) before solidification, in order to reduce surface tension, increase again
Silicone side-chain radical, makes fluorine carbon molecule form synergism with silicone, and after UV-light cured, its structure is fixed on film most naturally
Upper strata, makes fluorine carbon molecule form nm using the intermolecular incompatible principle of side chain and reaches film resistant from the structure for organizing structure dress
Effect.We contain fluorine and silicon components using which, have low surface energy so as to ensure that after film curing, that is, have it is extremely low into
Film tension and splendid release, paint film have excellent, lasting anti-scribble, physical property anti-pollution and easy to clean, there is provided go out
Many water-fast, oily and chemical resistances, excellent weather-proof and heat stability, and UV solidification rates are exceedingly fast, high rigidity.The present invention
Use the special light-cured resin of SPC-1487 oil resistivity pens of Sa Bisi.
The specific functionality acrylic resin of the low energy solidification can solidify rapidly under the low energy of LED-UV, open
A kind of new paragon for improving surface cure is opened, faster flowing water producing line has been introduced, is highly suitable for low energy curing system, this
The bright ADDITOL for using cyanogen specialization workTM LED 01。
The acrylated hyperbranched polyester resin of 8 sense has that large arch dam, low viscosity, levelling are good, curing rate is fast, table
Surface hardness height, high glaze, high richness, scratch resistant performance, while also having lower shrinkage, pigment wettability is good, resin collocation
The advantages of property is good, other resins are compared, the fluorine silication acrylate of the acrylated hyperbranched polyester resin and 4.5 senses of 8 senses
Resin, the specific functionality acrylic resin of low energy solidification have the crosslink density of the more preferable compatibility and Geng Gao, formation
Film have very high hardness, be conducive to improve permeability resistance thus be conducive to improve antigraffiti properties.Preferably Changxing
6361-100。
The monomer is dimethacrylate (DEGDMA), and the monomer has viscosity low, and diluting power is good, Gu
Change that speed is fast, hardness is good, low skin irritability, and wearability is good, resistance to water is good and the features such as good resistance to impact.
The light trigger is 2,4,6 trimethylbenzoyl diphenyl phosphine oxides (TPO)；
Described wetting dispersing agent is EFKA EFKA-4010；
Described defoamer is the high DEGO2500 of enlightening；
Described anti-graffiti auxiliary agent is the modified organic silicon compound with acrylic double bond, and An Delong developments in science and technology are limited
The ADL-UV131 of company, with the excellent compatibility and levelling ability, has certain deaeration performance, and good hand touch is particularly suited for
Photocuring system, can participate in the crosslinking of UV systems, for improving the adhesion inhibiting properties and antigraffiti properties of system.
The component of embodiment 1-4, the manufacturer of weight and each component and model as shown in Table 1, including but not limited to table
In listed product type, each component may also be employed it is commercially available other have same performance other producers product.
Table one
Embodiment 1
The anti-graffiti anti-pollution paints of LED-UV of the present embodiment are made up of the component of following weight：
The fluorine silication acrylate 25kg of 4.5 senses；The specific functionality acrylic resin 25kg of low energy solidification；
The acrylated hyperbranched polyester resin 19.7kg of 8 senses；Monomer 25kg；Light trigger 4kg；Wetting dispersing agent 0.3kg；Defoamer
0.4kg is anti-graffiti to help 0.6kg；
The weight as shown in embodiment 1 in table one takes each component, and preparation method is in accordance with the following steps：
Step one, under conditions of daylight or ultraviolet light is avoided, according to above-mentioned weight by the fluorine silication third of 4.5 senses
Alkene acid ester resin, the specific functionality acrylic resin of low energy solidification, the acrylated hyperbranched polyester resin of 8 senses and list
Body is added with paint container and being uniformly dispersed, and is then sequentially added light trigger, wetting dispersing agent and is stirred with 500-800 rev/min
Mix speed and 5 minutes are stirred with up to mix homogeneously, keep mixed material temperature to be less than 50 DEG C in whipping process；
Step 2, adds defoamer, anti-graffiti auxiliary agent according to said ratio, with 800-1000 rev/min of mixing speed point
Dissipate 15 minutes, that is, make the anti-graffiti anti-pollution paints of LED-UV, carry out painting liquid performance detection.
By method of the LED-UV anti-graffiti anti-pollution paint by brushing or spray, by 50g/m2Coating weight,
Polishing in advance the clean coated article body of dedusting (decorative exterior wall, public transport stop board, communication electric power facility etc.) surface are coated, is brushed
Complete to use LED-UV light irradiations photocuring 5 seconds immediately.The anti-graffiti anti-pollution paints of LED-UV being obtained in embodiment 1 are applied
Film.In performance test results such as table two shown in 1 corresponding data of embodiment.
LED-UV lamps used in dry run are power low (9-12W), heat radiation is little (impinges upon 3 degree of surface of the work increase
Left and right temperature), ozone free generation, small volume, it is easy to carry, whenever and wherever possible can site operation LDE light fixtures, it is available
Rate is high, meet environmental protection and safety requirements.
Embodiment 2
The fluorine silication acrylate 28kg of 4.5 senses；Specific functionality acrylic acid tree 28kg；8 senses it is hyperbranched
Polyester acrylate resin 15kg；Monomer 22.3kg；Light trigger 5kg；Wetting dispersing agent 0.5kg；Defoamer 0.5kg；It is anti-graffiti
Help 0.7kg；
The weight as shown in embodiment 2 in table one takes each component, repeats the preparation method described in embodiment 1, wherein step one
Middle mixing speed is 600 revs/min, and in step 2, mixing speed is 900 revs/min, you can the LED-UV for obtaining the present invention is anti-graffiti
Anti-pollution paint, carries out painting liquid performance detection.
By method of the LED-UV anti-graffiti anti-pollution paint by brushing or spray, by 60g/m2Coating weight,
Polishing in advance the clean coated article body of dedusting (decorative exterior wall, public transport stop board, communication electric power facility etc.) surface are coated, is brushed
Complete to use LED-UV light irradiations photocuring 6 seconds at once.The anti-graffiti anti-pollution paints of LED-UV being obtained in embodiment 2 are applied
Film.In performance test results such as table two shown in 2 corresponding data of embodiment.
Embodiment 3
The weight as shown in embodiment 3 in table one takes each component, repeats the preparation method described in embodiment 1, wherein step one
Middle mixing speed is 700 revs/min, and in step 2, mixing speed is 1000 revs/min, you can the LED-UV for obtaining the present invention is anti-graffiti
Anti-pollution paint, carries out painting liquid performance detection.
By method of the LED-UV anti-graffiti anti-pollution paint by brushing or spray, by 70g/m2Coating weight,
Polishing in advance the clean coated article body of dedusting (decorative exterior wall, public transport stop board, communication electric power facility etc.) surface are coated, is brushed
Complete to use LED-UV light irradiations photocuring 7 seconds at once.The anti-graffiti anti-pollution paints of LED-UV being obtained in embodiment 3 are applied
Film.In performance test results such as table two shown in 3 corresponding data of embodiment.
Embodiment 4
The fluorine silication acrylate 35kg of 4.5 senses；Specific functionality acrylic acid tree 30kg；8 senses it is hyperbranched
Polyester acrylate resin 15kg；Monomer 20kg；Light trigger 4kg；Wetting dispersing agent 0.4kg；Defoamer 0.3kg；It is anti-graffiti to help
0.6kg；
The weight as shown in embodiment 4 in table one takes each component, repeats the preparation method described in embodiment 1, wherein step one
Middle mixing speed is 800 revs/min, and in step 2, mixing speed is 900 revs/min, you can the LED-UV for obtaining the present invention is anti-graffiti
Anti-pollution paint, carries out painting liquid performance detection.
By method of the LED-UV anti-graffiti anti-pollution paint by brushing or spray, by 80g/m2Coating weight,
Polishing in advance the clean coated article body of dedusting (decorative exterior wall, public transport stop board, communication electric power facility etc.) surface are coated, is brushed
Complete to use LED-UV light irradiations photocuring 8 seconds at once.The anti-graffiti anti-pollution paints of LED-UV being obtained in embodiment 4 are applied
Film.In performance test results such as table two shown in 4 corresponding data of embodiment.
Table two
By table two it will be evident that the anti-graffiti anti-pollution paint environmental protection VOC free discharges of the LED-UV of the various embodiments described above, pass through
After the solidification of low energy LED-UV light, curing performance is good, and paint film has transparency height, gloss is stable, hardness is high, scratch resistance
The characteristics of good, good weatherability, surface slip, good hand touch.
Claims (9)
1. anti-graffiti anti-pollution paints of a kind of LED-UV, it is characterised in that：The anti-graffiti anti-pollution paint of the LED-UV can be by brushing
Or the method for spraying, by 50～80g/m2Coating weight, coat in advance polishing the clean coated article body surface face of dedusting, brush
Complete to use at once the portable LED-UV light irradiations photocuring 5-8 seconds；
The anti-graffiti anti-pollution paint of the LED-UV includes that the component of following parts by weight is made：
Wherein, the fluorine silication acrylate of 4.5 sense is the fluorinated silicone modified oligomer of 4.5 senses；
The monomer is dimethacrylate；
The anti-graffiti auxiliary agent is the modified organic silicon compound with acrylic double bond.
2. anti-graffiti anti-pollution paints of LED-UV according to claim 1, it is characterised in that described light trigger is 2,4,
6 trimethylbenzoyl diphenyl phosphine oxides；
Described defoamer is the high DEGO2500 of enlightening；
EFKA-4010 of the described wetting dispersing agent for EFKA.
3. anti-graffiti anti-pollution paints of LED-UV according to claim 1 and 2, it is characterised in that the fluorine silicon of 4.5 sense
Change SPC-1487 of the acrylate for Sa Bisi.
4. anti-graffiti anti-pollution paints of LED-UV according to claim 1 and 2, it is characterised in that 8 sense it is hyperbranched
6361-100 of the polyester acrylate resin for Changxing.
5. anti-graffiti anti-pollution paints of LED-UV according to claim 1 and 2, it is characterised in that the low energy solidification
ADDITOL of the specific functionality acrylic resin for cyanogen specialization workTMLED 01。
6. anti-graffiti anti-pollution paints of LED-UV according to claim 1 and 2, it is characterised in that described anti-graffiti auxiliary agent
It is the ADL-UV131 of An Delong.
7. the preparation method of the anti-graffiti anti-pollution paint of LED-UV according to claims 1 to 6, it is characterised in that include as
Lower step：
Step one:Under conditions of daylight or ultraviolet light is avoided, by the fluorine silication acrylate of 4.5 senses, mental retardation
Amount solidification specific functionality acrylic resin, the acrylated hyperbranched polyester resin of 8 senses, monomer add with paint container in simultaneously
Be uniformly dispersed, add light trigger, wetting dispersing agent under agitation, with 500-800 rev/min of mixing speed stir 5 minutes with
Up to it is uniformly dispersed, in whipping process, keeps mixed material temperature to be less than 50 DEG C；
Step 2:Defoamer, anti-graffiti auxiliary agent are added, disperses 15 minutes up to divide with 800-1000 rev/min of mixing speed
Dissipate uniform, obtain the anti-graffiti anti-pollution paints of LED-UV.
8. the using method of the anti-graffiti anti-pollution paints of LED-UV according to claim 1-6, it is characterised in that：Will be described
Method of the anti-graffiti anti-pollution paints of LED-UV by brushing or spray, by 50～80g/m2Coating weight, coat in advance polishing
And the clean coated article body surface face of dedusting, brush and complete to use at once the LED-UV light irradiation photocuring 5-8 seconds.
9. the using method of the anti-graffiti anti-pollution paints of LED-UV according to claim 8, it is characterised in that：The LED-UV
Lamp is the portable LED-UV lamps that power is 9-12W.
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Cited By (10)
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| CN107337800A (en) * | 2017-07-11 | 2017-11-10 | 上海乘鹰新材料有限公司 | Anti-soil auxiliary agent and its application in ultraviolet-curing paint |
| CN109575759A (en) * | 2018-11-29 | 2019-04-05 | 深圳市广田环保涂料有限公司 | Modified resistance to boiling hot coating of LED-UV of aeroge and preparation method thereof and application method |
| CN109722089A (en) * | 2018-12-21 | 2019-05-07 | 上海乘鹰新材料有限公司 | Ultraviolet-curing paint anti-pollution auxiliary agent |
| CN110358340A (en) * | 2019-07-09 | 2019-10-22 | 湖南松井新材料股份有限公司 | Super abrasive showering UV coating and its preparation method and application |
| CN113337202A (en) * | 2021-06-30 | 2021-09-03 | 湖南松井新材料股份有限公司 | UV (ultraviolet) finish paint as well as preparation method and application thereof |
| CN114891427A (en) * | 2022-06-17 | 2022-08-12 | 汤臣(江苏)材料科技股份有限公司 | Antifouling and anti-algae coating and preparation method thereof |
| CN115651469A (en) * | 2022-11-17 | 2023-01-31 | 青岛展辰新材料有限公司 | Anti-doodling matte UV-curable finish paint and preparation method and application thereof |
| CN116426207A (en) * | 2023-04-27 | 2023-07-14 | 小森新材料科技有限公司 | UV antibacterial and antiviral finishing paint and preparation method, application and application method thereof |
| CN116515377A (en) * | 2023-05-19 | 2023-08-01 | 广东希贵光固化材料有限公司 | Ultraviolet light curing micro-cement paint |
| CN116515377B (en) * | 2023-05-19 | 2024-04-26 | 广东希贵光固化材料有限公司 | Ultraviolet light curing micro-cement paint |
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| CN101333347A (en) * | 2008-07-11 | 2008-12-31 | 中华制漆（深圳）有限公司 | Antisoil and anti-graffiti coatings and method for preparing same |
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