CN106590242B - Anti-graffiti anti-pollution paints of LED-UV and preparation method thereof and application method - Google Patents
Anti-graffiti anti-pollution paints of LED-UV and preparation method thereof and application method Download PDFInfo
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- CN106590242B CN106590242B CN201611044437.0A CN201611044437A CN106590242B CN 106590242 B CN106590242 B CN 106590242B CN 201611044437 A CN201611044437 A CN 201611044437A CN 106590242 B CN106590242 B CN 106590242B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention discloses a kind of anti-graffiti anti-pollution paints of LED UV, method that can be by brushing or spraying, by 50~80g/m2Coating weight, be coated on polishing and the clean coated article body surface face of dedusting in advance, brush and complete at once using portable LED UV lamps irradiation photocuring 58 seconds；The anti-graffiti anti-pollution paints of LED UV include that the component of following parts by weight is made：The fluorine silication acrylate 25 35 of 4.5 functions；The cured specific functionality acrylic resin of low energy 21 30；The acrylated hyperbranched polyester resin 10 20 of 8 functions；Monomer 20 25；Photoinitiator 45；Wetting dispersing agent 0.3 0.5；Antifoaming agent 0.3 0.5；Anti-graffiti auxiliary agent 0.6 0.8；Paint film has excellent anti-scribble, property anti-pollution, easy to clean, water-fast, oily and chemical resistance, and compact in paint film is smooth, and hardness is high, and resistance to soiling is good.
Description
Technical field
The present invention relates to a kind of LED-UV functional coatings, more particularly to the composition of a kind of anti-graffiti anti-pollution paints of LED-UV
And preparation method thereof and application method.
Background technology
In daily life, often by aqueous or oily on the outer surfaces such as decorative exterior wall, bus stop board, communication electric power facility
Property pen, which scrawls, scarifies or puts up various small advertisements, seriously affects the beauty of equipment appearance and integrated environment, needs sanitationman
Small advertisement paper is arduously rooted out by perching knife, is cleaned aqueous or oil pen scribble, dirt with wet towel, is taken time and effort, it but cannot be complete
Clear all is clean.
In order to solve this phenomenon, many companies research and develop aqueous, oiliness, traditional photocuring and PU two-components etc. in succession
A variety of anti-graffiti and anti-pollution coating, but all there are many defects in these products.Such as：Aqueous anti-doodling paint paint film richness
Than the difference of oiliness, while having the shortcomings that hardness of paint film is inadequate；The PU two-component oiliness anti-doodling paint times to be done are long, in paint film
Dust is easily stained in drying process, and construction needs to convert curing agent and diluent construction, the VOC emission feature of environmental protection is poor；Traditional UV
Although the coating of photocuring has the advantages that hardness of paint film is high, wearability is good, curing efficiency is high, must adopt in the drying process
Cross-linking and curing reaction is completed with high-pressure sodium lamp luminous radiation drying equipment, completes paint film forming solidification, high-pressure sodium lamp is due to work(
Rate is high (generally 80W/cm), and there is strong light intensity brightness, very strong heat radiation (to impinge upon workpiece surface and increase workpiece surface temperature
20 degree or sos of degree) and while working will produce ozone, the mating cooling system of needs, outdoor construction cannot be used.
LED-UV lamps, which are a kind of power low (general portable LED-UV curing is 9-12W), heat radiation is small (impinges upon workpiece
Surface increases by 3 degree or so of temperature), ozone free generation, it is small, easy to carry, whenever and wherever possible can site operation LDE
Lamps and lanterns, availability is high, meets environmental protection and safety requirements.
Invention content
The technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide a kind of low energy curing efficiency
The good anti-graffiti anti-pollution paints of LED-UV of high, environmentally friendly VOC free discharge, easy for construction, anti-graffiti and antifouling property, this coating exist
Cure and uses LED-UV lamps, obtained hardness of paint film height, surface slip, good hand touch, good weatherability, while this hair in drying process
The bright preparation method and application method that the anti-graffiti anti-pollution paints of this LED-UV are also provided.
In order to solve the problems, such as that techniques discussed above, the present invention use following technical scheme：
A kind of anti-graffiti anti-pollution paints of LED-UV, the anti-graffiti anti-pollution paints of LED-UV can be by the sides that brush or spray
Method, by 50~80g/m2Coating weight, be coated in advance polishing and the clean coated article body surface face of dedusting, brush complete make at once
With portable LED-UV light irradiations photocuring 5-8 seconds；
The anti-graffiti anti-pollution paints of LED-UV include that the component of following parts by weight is made：
Wherein, the fluorine silication acrylate of 4.5 function is the fluorinated silicone modified oligomer of 4.5 functions；
The monomer is dimethacrylate；
The anti-graffiti auxiliary agent is the modified organic silicon compound with acrylic double bond.
Preferably, the photoinitiator is 2,4,6 trimethylbenzoyl diphenyl phosphine oxides；
The antifoaming agent is the high DEGO2500 of enlightening；
The wetting dispersing agent is the EFKA-4010 of Efka；
It is highly preferred that the fluorine silication acrylate of 4.5 function is the SPC-1487 of Sa Bisi.
Further, the acrylated hyperbranched polyester resin of 8 function is the 6361-100 in Changxing.
The cured specific functionality acrylic resin of low energy is the ADDITOL of cyanogen specialization workTMLED 01。
It is further preferred that the anti-graffiti auxiliary agent is the ADL-UV131 of An Delong.
A kind of preparation method of the anti-graffiti anti-pollution paints of LED-UV, includes the following steps：
Step 1:Under conditions of avoiding daylight or ultraviolet light, by the fluorine silication acrylate of 4.5 functions,
The cured specific functionality acrylic resin of low energy, the acrylated hyperbranched polyester resin of 8 functions, monomer are added with paint container
In and be uniformly dispersed, photoinitiator, wetting dispersing agent are added under stiring, 5 points are stirred with 500-800 revs/min of mixing speed
Clock in whipping process up to being uniformly dispersed, to keep mixed material temperature to be less than 50 DEG C；
Step 2:Antifoaming agent, anti-graffiti auxiliary agent is added, disperseed 15 minutes with 800-1000 revs/min of mixing speed or more
To being uniformly dispersed, the anti-graffiti anti-pollution paints of LED-UV are obtained.
A kind of application method of the anti-graffiti anti-pollution paints of LED-UV, passes through brushing by the anti-graffiti anti-pollution paints of the LED-UV
Or the method for spraying, by 50~80g/m2Coating weight, be coated in advance polishing and the clean coated article body surface face of dedusting, brush
It completes to use LED-UV light irradiation photocurings at once 5-8 seconds.
Preferably, the LED-UV lamps are the portable LED-UV lamps that power is 9-12W.
Compared with prior art, the anti-graffiti anti-pollution paint of LED-UV of the invention, using the cured specific function of low energy
Property acrylic resin collocation with the fluorine silication acrylate of cured 4.5 function of oil resistivity dedicated optical, 8 functions it is super
Branched polyester acrylic resin and anti-graffiti auxiliary agent, monomer (dimethacrylate) and photoinitiator etc. are reasonable
Proportioning, produces the anti-graffiti anti-pollution paints of LED-UV with extremely low film formation surface tension and splendid release, in object
The anti-graffiti anti-pollution paints of the LED-UV are coated on surface, and after being cured using LED-UV light, gained paint film goes out with extremely excellent
Many lasting anti-scribble, anti-pollution and easy to clean property and outstanding water-fast, oily and chemical resistances, it is excellent weather-proof and
Thermal stability, UV solidification rates are exceedingly fast, and coating surface densification is smooth, and hardness is high, and resistance to soiling is good, with aqueous or oil pen upper
After face is scribbled, it can be wiped, left no trace easily with wet cloth, the small advertisement paper etc. being attached to above can also easily be torn, right
It writes without basis random this society's trouble of pasting and provides solution, greatly mitigate the working strength of sanitationman.It is of the present invention
The anti-graffiti anti-pollution paints of LED-UV can be promoted on a large scale using simply.
Specific implementation mode
Below by embodiment, technical scheme of the present invention is further described, each embodiment is only used as preferred real
Mode is applied to illustrate technical scheme of the present invention, does not constitute limitation of the invention.The various components of the present invention are all made of existing
Commercial product.
In following embodiment, the fluorine silication acrylate of 4.5 function is the fluorinated silicone modified oligomeric of 4.5 functions
Object, can be in the case where ensureing high response, and hardness of paint film is high, good toughness, and thickness is applied and do not cracked, and antifouling principle is side chain
Fluorine carbon bond is incompatible to connect structure and proportion is relatively low in other main chains or side chain so that fluorine carbon key is migrated naturally when coating to coating
Surface, and molecule is made independently to fill (self-assembly) in resin surface before curing, in order to reduce surface tension, and increase
Silicone side-chain radical makes fluorine carbon molecules be formed with silicone and acts synergistically, and after UV-light cured, structure is fixed on film most naturally
Upper layer makes fluorine carbon molecules form nanometer and reaches film resistant from the structure of group structure dress using the intermolecular incompatible principle of side chain
Effect.We contain fluorine and silicon components using it, have low surface energy after film curing to ensure that, that is, have it is extremely low at
Film tension and splendid release, paint film have excellent, lasting anti-scribble, anti-pollution and easy to clean physical property, provide
Many water-fast, oily and chemical resistances, excellent weather-proof and thermal stability, and UV solidification rates are exceedingly fast, high rigidity.The present invention
Using the special light-cured resin of SPC-1487 oil resistivity pens of Sa Bisi.
The cured specific functionality acrylic resin of low energy can cure rapidly under the low energy of LED-UV, open
A kind of new paragon improving surface cure has been opened, faster flowing water producing line has been introduced, is highly suitable for low energy curing system, this hair
The bright ADDITOL using cyanogen specialization workTM LED 01。
The acrylated hyperbranched polyester resin of 8 function have large arch dam, low viscosity, levelling is good, curing rate is fast, table
Surface hardness height, high glaze, high richness, scratch resistant performance, while also there is lower shrinkage, pigment wettability is good, resin collocation
The advantages that property is good, other resins are compared, the acrylated hyperbranched polyester resin of 8 functions and the fluorine silication acrylate of 4.5 functions
The cured specific functionality acrylic resin of resin, low energy has better compatibility and higher crosslink density, formation
Film have very high hardness, be conducive to improve permeability resistance thus be conducive to improve antigraffiti properties.Preferably Changxing
6361-100。
The monomer is dimethacrylate (DEGDMA), which has viscosity low, and diluting power is good, Gu
Change the features such as speed is fast, and hardness is good, low skin irritability, and wearability is good, and water resistance is good and impact resistance is good.
The photoinitiator is 2,4,6 trimethylbenzoyl diphenyl phosphine oxides (TPO)；
The wetting dispersing agent is Efka EFKA-4010；
The antifoaming agent is the high DEGO2500 of enlightening；
The anti-graffiti auxiliary agent is the modified organic silicon compound with acrylic double bond, and An Delong developments in science and technology are limited
The ADL-UV131 of company has excellent compatibility and levelling ability, has certain deaeration performance, good hand touch to be particularly suitable for
Photocuring system can participate in the crosslinking of UV systems, the adhesion inhibiting properties for improving system and antigraffiti properties.
The component of embodiment 1-4, the manufacturer of weight and each component and model are as shown in Table 1, including but not limited to table
In listed product type, the product of other commercially available other producers with same performance can also be used in each component.
Table one
Embodiment 1
The anti-graffiti anti-pollution paints of LED-UV of the present embodiment are grouped as by the group of following weight：
The fluorine silication acrylate 25kg of 4.5 functions；The cured specific functionality acrylic resin 25kg of low energy；
The acrylated hyperbranched polyester resin 19.7kg of 8 functions；Monomer 25kg；Photoinitiator 4kg；Wetting dispersing agent 0.3kg；Antifoaming agent
0.4kg is anti-graffiti to help 0.6kg；
Each component is taken by weight shown in embodiment 1 in table one, preparation method is in accordance with the following steps：
Step 1, under conditions of avoiding daylight or ultraviolet light, according to above-mentioned weight by the fluorine silication third of 4.5 functions
The acrylated hyperbranched polyester resin and list of the cured specific functionality acrylic resin of alkene acid ester resin, low energy, 8 functions
Body is added in paint container and being uniformly dispersed, and then sequentially adds photoinitiator, wetting dispersing agent and is stirred with 500-800 revs/min
It mixes speed and stirs 5 minutes up to being uniformly mixed, to keep mixed material temperature to be less than 50 DEG C in whipping process；
Antifoaming agent, anti-graffiti auxiliary agent is added according to said ratio, with 800-1000 revs/min of mixing speed point in step 2
It dissipates 15 minutes, that is, the anti-graffiti anti-pollution paints of LED-UV is made, carry out paint solution performance detection.
Method by the anti-graffiti anti-pollution paints of the LED-UV by brushing either spraying, by 50g/m2Coating weight,
It is coated on polishing in advance and the clean coated article body of dedusting (decorative exterior wall, bus stop board, communication electric power facility etc.) surface, is brushed
It completes to use LED-UV light irradiations photocuring immediately 5 seconds.The anti-graffiti anti-pollution paints of LED-UV that can be obtained in embodiment 1 apply
Film.In performance test results such as table two shown in 1 corresponding data of embodiment.
The LED-UV lamps used in drying process, which are power low (9-12W), heat radiation is small (impinges upon workpiece surface and increases by 3 degree
Left and right temperature), ozone free generate, it is small, easy to carry, whenever and wherever possible can site operation LDE lamps and lanterns, it is available
Rate is high, meets environmental protection and safety requirements.
Embodiment 2
The fluorine silication acrylate 28kg of 4.5 functions；Specific functionality acrylic acid tree 28kg；8 functions it is hyperbranched
Polyester acrylate resin 15kg；Monomer 22.3kg；Photoinitiator 5kg；Wetting dispersing agent 0.5kg；Antifoaming agent 0.5kg；It is anti-graffiti
Help 0.7kg；
Each component is taken by weight shown in embodiment 2 in table one, repeats preparation method described in embodiment 1, wherein step 1
Middle mixing speed is 600 revs/min, and mixing speed is 900 revs/min in step 2, you can the LED-UV for obtaining the present invention is anti-graffiti
Anti-pollution paint carries out paint solution performance detection.
Method by the anti-graffiti anti-pollution paints of the LED-UV by brushing either spraying, by 60g/m2Coating weight,
It is coated on polishing in advance and the clean coated article body of dedusting (decorative exterior wall, bus stop board, communication electric power facility etc.) surface, is brushed
It completes to use LED-UV light irradiations photocuring at once 6 seconds.The anti-graffiti anti-pollution paints of LED-UV that can be obtained in embodiment 2 apply
Film.In performance test results such as table two shown in 2 corresponding data of embodiment.
Embodiment 3
Each component is taken by weight shown in embodiment 3 in table one, repeats preparation method described in embodiment 1, wherein step 1
Middle mixing speed is 700 revs/min, and mixing speed is 1000 revs/min in step 2, you can the LED-UV for obtaining the present invention is anti-graffiti
Anti-pollution paint carries out paint solution performance detection.
Method by the anti-graffiti anti-pollution paints of the LED-UV by brushing either spraying, by 70g/m2Coating weight,
It is coated on polishing in advance and the clean coated article body of dedusting (decorative exterior wall, bus stop board, communication electric power facility etc.) surface, is brushed
It completes to use LED-UV light irradiations photocuring at once 7 seconds.The anti-graffiti anti-pollution paints of LED-UV that can be obtained in embodiment 3 apply
Film.In performance test results such as table two shown in 3 corresponding data of embodiment.
Embodiment 4
The fluorine silication acrylate 35kg of 4.5 functions；Specific functionality acrylic acid tree 30kg；8 functions it is hyperbranched
Polyester acrylate resin 15kg；Monomer 20kg；Photoinitiator 4kg；Wetting dispersing agent 0.4kg；Antifoaming agent 0.3kg；It is anti-graffiti to help
0.6kg；
Each component is taken by weight shown in embodiment 4 in table one, repeats preparation method described in embodiment 1, wherein step 1
Middle mixing speed is 800 revs/min, and mixing speed is 900 revs/min in step 2, you can the LED-UV for obtaining the present invention is anti-graffiti
Anti-pollution paint carries out paint solution performance detection.
Method by the anti-graffiti anti-pollution paints of the LED-UV by brushing either spraying, by 80g/m2Coating weight,
It is coated on polishing in advance and the clean coated article body of dedusting (decorative exterior wall, bus stop board, communication electric power facility etc.) surface, is brushed
It completes to use LED-UV light irradiations photocuring at once 8 seconds.The anti-graffiti anti-pollution paints of LED-UV that can be obtained in embodiment 4 apply
Film.In performance test results such as table two shown in 4 corresponding data of embodiment.
Table two
By table two it will be evident that the anti-graffiti anti-pollution paint environmental protection VOC free discharges of the LED-UV of the various embodiments described above, pass through
After the solidification of low energy LED-UV light, curing performance is good, and paint film has high transparency, gloss stabilization, hardness height, scratch resistance
Well, the characteristics of good weatherability, surface slip, good hand touch.
Claims (8)
1. a kind of anti-graffiti anti-pollution paints of LED-UV, it is characterised in that：The anti-graffiti anti-pollution paints of LED-UV can pass through brushing
Or the method for spraying, by 50~80g/m2Coating weight, be coated in advance polishing and the clean coated article body surface face of dedusting, brush
It completes to use portable LED-UV light irradiations photocuring at once 5-8 seconds；
The anti-graffiti anti-pollution paints of LED-UV include that the component of following parts by weight is made：
Wherein, the fluorine silication acrylate of 4.5 function is the fluorinated silicone modified oligomer of 4.5 functions；
The monomer is dimethacrylate；
The anti-graffiti auxiliary agent is the modified organic silicon compound with acrylic double bond；
The cured specific functionality acrylic resin of low energy is the ADDITOL of cyanogen specialization workTM LED 01。
2. the anti-graffiti anti-pollution paints of LED-UV according to claim 1, which is characterized in that the photoinitiator is 2,4,
6 trimethylbenzoyl diphenyl phosphine oxides；
The antifoaming agent is the high DEGO2500 of enlightening；
The wetting dispersing agent is the EFKA-4010 of Efka；
3. the anti-graffiti anti-pollution paints of LED-UV according to claim 1 or 2, which is characterized in that the fluorine silicon of 4.5 function
Change the SPC-1487 that acrylate is Sa Bisi.
4. the anti-graffiti anti-pollution paints of LED-UV according to claim 1 or 2, which is characterized in that 8 function it is hyperbranched
Polyester acrylate resin is the 6361-100 in Changxing.
5. the anti-graffiti anti-pollution paints of LED-UV according to claim 1 or 2, which is characterized in that the anti-graffiti auxiliary agent
It is the ADL-UV131 of An Delong.
6. the preparation method of the anti-graffiti anti-pollution paints of LED-UV according to claim 5, which is characterized in that including walking as follows
Suddenly：
Step 1:Under conditions of avoiding daylight or ultraviolet light, by the fluorine silication acrylate of 4.5 functions, low energy
It measures cured specific functionality acrylic resin, the acrylated hyperbranched polyester resin of 8 functions, monomer and is added and match in paint container simultaneously
Be uniformly dispersed, photoinitiator, wetting dispersing agent be added under stiring, with 500-800 revs/min of mixing speed stir 5 minutes with
Up to being uniformly dispersed, mixed material temperature is kept to be less than 50 DEG C in whipping process；
Step 2:Antifoaming agent, anti-graffiti auxiliary agent is added, with 800-1000 revs/min of mixing speed disperse 15 minutes with up to point
It dissipates uniformly, obtains the anti-graffiti anti-pollution paints of LED-UV.
7. according to the application method of the anti-graffiti anti-pollution paints of claim 1-5 any one of them LED-UV, it is characterised in that：It will
Method of the anti-graffiti anti-pollution paints of LED-UV by brushing or spraying, by 50~80g/m2Coating weight, be coated in advance
It polishes and the clean coated article body surface face of dedusting, brushing is completed to use LED-UV light irradiation photocurings at once 5-8 seconds.
8. the application method of the anti-graffiti anti-pollution paints of LED-UV according to claim 7, it is characterised in that：The LED-UV
Lamp is the portable LED-UV lamps that power is 9-12W.
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| CN107337800B (en) * | 2017-07-11 | 2019-10-15 | 上海乘鹰新材料有限公司 | Anti-pollution auxiliary agent and its application in ultraviolet-curing paint |
| CN109575759A (en) * | 2018-11-29 | 2019-04-05 | 深圳市广田环保涂料有限公司 | Modified resistance to boiling hot coating of LED-UV of aeroge and preparation method thereof and application method |
| CN109722089B (en) * | 2018-12-21 | 2020-10-16 | 上海乘鹰新材料有限公司 | Anti-fouling auxiliary agent for ultraviolet curing coating |
| CN110358340B (en) * | 2019-07-09 | 2021-06-22 | 湖南松井新材料股份有限公司 | Ultra-wear-resistant curtain coating UV coating and preparation method and application thereof |
| CN113337202A (en) * | 2021-06-30 | 2021-09-03 | 湖南松井新材料股份有限公司 | UV (ultraviolet) finish paint as well as preparation method and application thereof |
| CN114891427B (en) * | 2022-06-17 | 2023-02-28 | 汤臣(江苏)材料科技股份有限公司 | Antifouling and anti-algae coating and preparation method thereof |
| CN115651469A (en) * | 2022-11-17 | 2023-01-31 | 青岛展辰新材料有限公司 | Anti-doodling matte UV-curable finish paint and preparation method and application thereof |
| CN116426207A (en) * | 2023-04-27 | 2023-07-14 | 小森新材料科技有限公司 | UV antibacterial and antiviral finishing paint and preparation method, application and application method thereof |
| CN116515377B (en) * | 2023-05-19 | 2024-04-26 | 广东希贵光固化材料有限公司 | Ultraviolet light curing micro-cement paint |
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| CN101333347B (en) * | 2008-07-11 | 2010-04-14 | 中华制漆（深圳）有限公司 | Antisoil and anti-graffiti coatings and method for preparing same |
| CN101585990A (en) * | 2009-07-08 | 2009-11-25 | 兰州迅美漆业科技有限公司 | Aqueous anti-graffiti adhesion resistant paint and preparation method thereof |
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