CN108130747A - A kind of silicon rubber leather and its coating process with anti-pollution function - Google Patents

A kind of silicon rubber leather and its coating process with anti-pollution function Download PDF

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Publication number
CN108130747A
CN108130747A CN201810021924.8A CN201810021924A CN108130747A CN 108130747 A CN108130747 A CN 108130747A CN 201810021924 A CN201810021924 A CN 201810021924A CN 108130747 A CN108130747 A CN 108130747A
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parts
pollution function
component
silicon rubber
silicone oil
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Inventor
胥晓群
陶玉红
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Guangdong Tian Yue New Material Ltd By Share Ltd
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Guangdong Tian Yue New Material Ltd By Share Ltd
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Priority to CN201810021924.8A priority Critical patent/CN108130747A/en
Publication of CN108130747A publication Critical patent/CN108130747A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097Release surface, e.g. separation sheets; Silicone papers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042Acrylic polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/14Properties of the materials having chemical properties
    • D06N2209/146Soilproof, soil repellent
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention discloses a kind of silicon rubber leathers with anti-pollution function, are figured by mass parts, and constitutive material includes the component A with the anti-pollution function and component B with anti-pollution function;Component A is made of following raw material:3 parts of 100 200 parts of vinylsiloxane rubber base rubber, 50 70 parts of vinyl fluoride silicone oil, 5 20 parts of containing hydrogen silicone oil, 0.1 0.5 parts of platinum catalyst, 5 20 parts of color pigment, 0.02 0.1 parts of inhibitor and pure water;Component B is made of following raw material:10 30 parts of 100 150 parts of matt handfeel oil, 20 50 parts of vinyl fluoride silicone oil, 15 parts of matt handfeel oil curing agent and acrylic acid modified silicones.The invention also discloses the coating process of the silicon rubber leather with anti-pollution function.Present invention process is simple, and production efficiency is high, and production cost is low, and the obtained silicon rubber leather surface with anti-pollution function is with anti-pollution function is good, easy cleaning and anti-pollution function are lasting.

Description

A kind of silicon rubber leather and its coating process with anti-pollution function
Technical field
The present invention relates to organosilicon and leather manufacture technical fields, and in particular to a kind of silicon rubber skin with anti-pollution function Leather and the coating process for being somebody's turn to do the silicon rubber leather with anti-pollution function.
Background technology
Be widely used in producing daily necessities and industrial goods by people earliest is natural leather, but its limited amount, it is impossible to Meet the needs of people.Therefore, the products such as artificial leather, synthetic leather, regenerated bark occur, and natural leather is replaced with this.But this The phenomenon that imitated leather will appear easy to pollute, difficult cleaning in use a bit, it is difficult to meet people to high-quality life It is required that.
There is part of the manufacturer to pass through surface multi-layer processing to realize the function of surface soiling, but coating process is complicated, former Material price is expensive, surface endurance anti-pollution function is poor.Such as the Chinese invention patent of Publication No. CN 106183256A In, application discloses a kind of waterproof and oilproof anti-pollution function Composite leather fabric, which needs five layer materials of coating that could realize Anti-pollution function, product have the shortcomings that low production efficiency, bad product rate height, high energy consumption, of high cost.
Invention content
It is an object of the present invention to a kind of silicon rubber leather with anti-pollution function, surface are provided regarding to the issue above Have the advantages that good anti-pollution function, easy cleaning and anti-pollution function are lasting.
The present invention also aims to provide a kind of coating process for the silicon rubber leather that should have anti-pollution function, prepare It is simple for process, production efficiency is high, at low cost.
Present invention technical solution used for the above purpose is:
A kind of silicon rubber leather with anti-pollution function, is figured by mass parts, and constitutive material includes having anti-pollution function Component A and with anti-pollution function component B;
Component A is made of following raw material:100-200 parts of vinylsiloxane rubber base rubber, 50-70 parts of vinyl fluoride silicone oil, 3 parts of 5-20 parts of containing hydrogen silicone oil, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor and pure water;
Component B is made of following raw material:100-150 parts of matt handfeel oil, 20-50 parts of vinyl fluoride silicone oil, dumb light hand 1-5 parts and acrylic acid modified silicones 10-30 parts of sense oily curing agent.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.8-2%.
Vinyl fluoride silicon oil viscosity range 500-5000cs, contents of ethylene 0.1-0.5%, fluorine content 1-3%.
The platinum catalyst is 5000ppm, is one in ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution Kind.
The inhibitor is methyl butynol, one or more kinds of in ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
The component A coating layer thicknesses are 0.1-0.5mm.
The component B coating layer thicknesses are 0.01mm-0.05mm.
A kind of coating process of the aforementioned silicon rubber leather with anti-pollution function, includes the following steps:
Step 1: the allotment of component A;
Step 2: the allotment of component B;
Step 3: by the component B coatings with anti-pollution function in release paper or leather paper, will be coated by conveyer belt Silicon rubber be transmitted in continuous tunnel furnace, vulcanize 5-10 minutes at a temperature of 100-140 DEG C, form anti-soiled surface layer;
Step 4: the component A with anti-pollution function is coated on anti-soiled surface layer, by base material cloth pasting on component A, Continuous tunnel furnace is then passed to, is vulcanized 5-10 minutes at a temperature of 100-140 DEG C;
Step 5: release paper or leather paper are removed, the silicon rubber leather with anti-pollution function is obtained.
In step 1, by 100-200 parts of vinylsiloxane rubber base rubber, 50-70 parts of vinyl fluoride silicone oil, containing hydrogen silicone oil 5-20 Part, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor add in 3 parts of pure water, put into planet In dispersator, lead to cooling water, open vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 100-150 parts of matt handfeel oil, 20-50 parts of vinyl fluoride silicone oil, matt handfeel oil curing agent 1- 5 parts, acrylic acid modified silicones 10-30 parts of mixing, disperse 10 minutes in dispersion machine.
Beneficial effects of the present invention are:Present invention process is simple, and production efficiency is high, and production cost is low, and obtained has The silicon rubber leather surface of anti-pollution function has the advantages that good anti-pollution function, easy cleaning and anti-pollution function are lasting.
Specific embodiment
Embodiment 1 present embodiments provides a kind of silicon rubber leather with anti-pollution function, is figured by mass parts, group Include the component A with the anti-pollution function and component B with anti-pollution function into raw material;
Component A is the silicone rubber material with anti-pollution function, and component B is the matt handfeel oil with anti-pollution function;
Component A is made of following raw material:100 parts of vinylsiloxane rubber base rubber, 50 parts of vinyl fluoride silicone oil, containing hydrogen silicone oil 3 parts of 5 parts, 0.1 part of platinum catalyst, 5 parts of color pigment, 0.02 part of inhibitor and pure water;
Component B is made of following raw material:100 parts of matt handfeel oil, 20 parts of vinyl fluoride silicone oil, matt handfeel oil curing 1 part of agent and acrylic acid modified 10 parts of silicones.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.8-2%.
Vinyl fluoride silicon oil viscosity range 500-5000cs, contents of ethylene 0.1-0.5%, fluorine content 1-3%.
The platinum catalyst is 5000ppm, is one in ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution Kind.
The inhibitor is methyl butynol, one or more kinds of in ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
The component A coating layer thicknesses are 0.1-0.5mm.
The component B coating layer thicknesses are 0.01mm-0.05mm.
A kind of coating process of the aforementioned silicon rubber leather with anti-pollution function, includes the following steps:
Step 1: the allotment of component A;
Step 2: the allotment of component B;
Step 3: by the component B coatings with anti-pollution function in release paper or leather paper, will be coated by conveyer belt Silicon rubber be transmitted in continuous tunnel furnace, vulcanize 5-10 minutes at a temperature of 100-140 DEG C, form anti-soiled surface layer;
Step 4: the component A with anti-pollution function is coated on anti-soiled surface layer, by base material cloth pasting on component A, Continuous tunnel furnace is then passed to, is vulcanized 5-10 minutes at a temperature of 100-140 DEG C;
Step 5: release paper or leather paper are removed, the silicon rubber leather with anti-pollution function is obtained.
In step 1,100 parts of vinylsiloxane rubber base rubber, 50 parts of vinyl fluoride silicone oil, 5 parts of containing hydrogen silicone oil, platinum are urged 0.1 part of agent, 5 parts of color pigment, 0.02 part of inhibitor add in 3 parts of pure water, put into planet dispersator, lead to cooling Water opens vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 100 parts of matt handfeel oil, 20 parts of vinyl fluoride silicone oil, 1 part of matt handfeel oil curing agent, propylene Sour 10 parts of mixing of modified silicone resin, disperse 10 minutes in dispersion machine.
Present invention process is simple, and production efficiency is high, and production cost is low, the obtained silicon rubber leather with anti-pollution function Surface has the advantages that good anti-pollution function, easy cleaning and anti-pollution function are lasting.
Embodiment 2 present embodiments provides a kind of silicon rubber leather with anti-pollution function, is figured by mass parts, group Include the component A with the anti-pollution function and component B with anti-pollution function into raw material;
Component A is made of following raw material:200 parts of vinylsiloxane rubber base rubber, 70 parts of vinyl fluoride silicone oil, containing hydrogen silicone oil 3 parts of 20 parts, 0.5 part of platinum catalyst, 20 parts of color pigment, 0.1 part of inhibitor and pure water;
Component B is made of following raw material:150 parts of matt handfeel oil, 50 parts of vinyl fluoride silicone oil, matt handfeel oil curing 5 parts of agent and acrylic acid modified 30 parts of silicones.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.8-2%.
Vinyl fluoride silicon oil viscosity range 500-5000cs, contents of ethylene 0.1-0.5%, fluorine content 1-3%.
The platinum catalyst is 5000ppm, is one in ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution Kind.
The inhibitor is methyl butynol, one or more kinds of in ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
The component A coating layer thicknesses are 0.1-0.5mm.
The component B coating layer thicknesses are 0.01mm-0.05mm.
A kind of coating process of the aforementioned silicon rubber leather with anti-pollution function, includes the following steps:
Step 1: the allotment of component A;
Step 2: the allotment of component B;
Step 3: by the component B coatings with anti-pollution function in release paper or leather paper, will be coated by conveyer belt Silicon rubber be transmitted in continuous tunnel furnace, vulcanize 5-10 minutes at a temperature of 100-140 DEG C, form anti-soiled surface layer;
Step 4: the component A with anti-pollution function is coated on anti-soiled surface layer, by base material cloth pasting on component A, Continuous tunnel furnace is then passed to, is vulcanized 5-10 minutes at a temperature of 100-140 DEG C;
Step 5: release paper or leather paper are removed, the silicon rubber leather with anti-pollution function is obtained.
In step 1,200 parts of vinylsiloxane rubber base rubber, 70 parts of vinyl fluoride silicone oil, 20 parts of containing hydrogen silicone oil, platinum are urged 0.5 part of agent, 20 parts of color pigment, 0.1 part of inhibitor add in 3 parts of pure water, put into planet dispersator, lead to cooling Water opens vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 150 parts of matt handfeel oil, 50 parts of vinyl fluoride silicone oil, 5 parts of matt handfeel oil curing agent, propylene Sour 30 parts of mixing of modified silicone resin, disperse 10 minutes in dispersion machine.
Present invention process is simple, and production efficiency is high, and production cost is low, the obtained silicon rubber leather with anti-pollution function Surface has the advantages that good anti-pollution function, easy cleaning and anti-pollution function are lasting.
Embodiment 3 present embodiments provides a kind of silicon rubber leather with anti-pollution function, is figured by mass parts, group Include the component A with the anti-pollution function and component B with anti-pollution function into raw material;
Component A is made of following raw material:150 parts of vinylsiloxane rubber base rubber, 60 parts of vinyl fluoride silicone oil, containing hydrogen silicone oil 3 parts of 15 parts, 0.3 part of platinum catalyst, 15 parts of color pigment, 0.06 part of inhibitor and pure water;
Component B is made of following raw material:130 parts of matt handfeel oil, 35 parts of vinyl fluoride silicone oil, matt handfeel oil curing 3 parts of agent and acrylic acid modified 20 parts of silicones.
The vinylsiloxane rubber base rubber hardness range 30-70A, contents of ethylene 0.8-2%.
Vinyl fluoride silicon oil viscosity range 500-5000cs, contents of ethylene 0.1-0.5%, fluorine content 1-3%.
The platinum catalyst is 5000ppm, is one in ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution Kind.
The inhibitor is methyl butynol, one or more kinds of in ethynylcyclohexanol, more vinyl polysiloxanes Mixture.
The component A coating layer thicknesses are 0.1-0.5mm.
The component B coating layer thicknesses are 0.01mm-0.05mm.
A kind of coating process of the aforementioned silicon rubber leather with anti-pollution function, includes the following steps:
Step 1: the allotment of component A;
Step 2: the allotment of component B;
Step 3: by the component B coatings with anti-pollution function in release paper or leather paper, will be coated by conveyer belt Silicon rubber be transmitted in continuous tunnel furnace, vulcanize 5-10 minutes at a temperature of 100-140 DEG C, form anti-soiled surface layer;
Step 4: the component A with anti-pollution function is coated on anti-soiled surface layer, by base material cloth pasting on component A, Continuous tunnel furnace is then passed to, is vulcanized 5-10 minutes at a temperature of 100-140 DEG C;
Step 5: release paper or leather paper are removed, the silicon rubber leather with anti-pollution function is obtained.
In step 1,150 parts of vinylsiloxane rubber base rubber, 60 parts of vinyl fluoride silicone oil, 15 parts of containing hydrogen silicone oil, platinum are urged 0.3 part of agent, 15 parts of color pigment, 0.06 part of inhibitor add in 3 parts of pure water, put into planet dispersator, lead to cooling Water opens vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 130 parts of matt handfeel oil, 35 parts of vinyl fluoride silicone oil, 3 parts of matt handfeel oil curing agent, propylene Sour 20 parts of mixing of modified silicone resin, disperse 10 minutes in dispersion machine.
Present invention process is simple, and production efficiency is high, and production cost is low, the obtained silicon rubber leather with anti-pollution function Surface has the advantages that good anti-pollution function, easy cleaning and anti-pollution function are lasting.
The above described is only a preferred embodiment of the present invention, not make limitation in any form to the present invention.Appoint What those skilled in the art, without departing from the scope of the technical proposal of the invention, all using the skill of the disclosure above Art means and technology contents technical solution of the present invention is made many possible changes and modifications or be revised as equivalent variations etc. Imitate embodiment.Therefore every content without departing from technical solution of the present invention, what shape, construction and principle according to the present invention were made etc. Effect variation, should all be covered by protection scope of the present invention.

Claims (10)

1. a kind of silicon rubber leather with anti-pollution function, which is characterized in that figured by mass parts, constitutive material includes having The component A of the anti-pollution function and component B with anti-pollution function;
Component A is made of following raw material:It is 100-200 parts of vinylsiloxane rubber base rubber, 50-70 parts of vinyl fluoride silicone oil, hydrogeneous 3 parts of 5-20 parts of silicone oil, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor and pure water;
Component B is made of following raw material:100-150 parts of matt handfeel oil, 20-50 parts of vinyl fluoride silicone oil, matt handfeel oil 1-5 parts and acrylic acid modified silicones 10-30 parts of curing agent.
2. the silicon rubber leather according to claim 1 with anti-pollution function, which is characterized in that the vinylsiloxane rubber Base rubber hardness range 30-70A, contents of ethylene 0.8-2%.
3. the silicon rubber leather according to claim 1 with anti-pollution function, which is characterized in that vinyl fluoride silicon oil viscosity Range 500-5000cs, contents of ethylene 0.1-0.5%, fluorine content 1-3%.
4. the silicon rubber leather according to claim 1 with anti-pollution function, which is characterized in that the platinum catalyst is 5000ppm is one kind in ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution.
5. the silicon rubber leather according to claim 1 with anti-pollution function, which is characterized in that the inhibitor is methyl One or more kinds of mixture in butynol, ethynylcyclohexanol, more vinyl polysiloxanes.
6. the silicon rubber leather according to claim 1 with anti-pollution function, which is characterized in that the component A applies thickness It spends for 0.1-0.5mm.
7. the silicon rubber leather according to claim 1 with anti-pollution function, which is characterized in that the component B applies thickness It spends for 0.01mm-0.05mm.
8. described in a kind of claim 1 with anti-pollution function silicon rubber leather coating process, which is characterized in that it include with Lower step:
Step 1: the allotment of component A;
Step 2: the allotment of component B;
Step 3: by the component B coatings with anti-pollution function on release paper or leather paper, by conveyer belt by coated silicon Rubber is transmitted in continuous tunnel furnace, is vulcanized 5-10 minutes at a temperature of 100-140 DEG C, is formed anti-soiled surface layer;
Step 4: the component A with anti-pollution function is coated on anti-soiled surface layer, by base material cloth pasting on component A, then Continuous tunnel furnace is sent to, is vulcanized 5-10 minutes at a temperature of 100-140 DEG C;
Step 5: release paper or leather paper are removed, the silicon rubber leather with anti-pollution function is obtained.
9. the coating process of the silicon rubber leather according to claim 8 with anti-pollution function, which is characterized in that step 1 In, by 100-200 parts of vinylsiloxane rubber base rubber, 50-70 parts of vinyl fluoride silicone oil, 5-20 parts of containing hydrogen silicone oil, platinum catalyst 0.1-0.5 parts, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor, add in 3 parts of pure water, put into planet dispersator, Logical cooling water opens vacuum equipment, dispersion stirring 10 minutes.
10. the coating process of the silicon rubber leather according to claim 8 with anti-pollution function, which is characterized in that step In two, 100-150 parts of matt handfeel oil, 20-50 parts of vinyl fluoride silicone oil, 1-5 parts of matt handfeel oil curing agent, acrylic acid are changed Property the mixing of 10-30 parts of silicones, disperse 10 minutes in dispersion machine.
CN201810021924.8A 2018-01-10 2018-01-10 A kind of silicon rubber leather and its coating process with anti-pollution function Pending CN108130747A (en)

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CN108755165A (en) * 2018-07-13 2018-11-06 广东天跃新材料股份有限公司 The silicon rubber synthetic leather and its manufacturing technology of energy releasing negative oxygen ion and far infrared
CN108823340A (en) * 2018-07-13 2018-11-16 广东天跃新材料股份有限公司 Corium silastic polymer synthetic leather and its manufacturing technology
CN108824001A (en) * 2018-08-14 2018-11-16 广东天跃新材料股份有限公司 Vamp silicon rubber synthetic leather and its manufacturing technology of cold-resistant high temperature resistant color inhibition
CN108867096A (en) * 2018-08-14 2018-11-23 广东天跃新材料股份有限公司 The high-performance vamp silicon rubber synthetic leather and its manufacturing technology for antifouling waterproof of breathing freely
CN108894006A (en) * 2018-07-13 2018-11-27 广东天跃新材料股份有限公司 Using foamed silica gel as the silicon rubber synthetic leather and its manufacturing technology of base
CN109023982A (en) * 2018-08-14 2018-12-18 广东天跃新材料股份有限公司 Zero DMF environment-friendly and high-performance silastic polymer synthetic leather and its manufacturing technology
CN109183436A (en) * 2018-11-22 2019-01-11 广东天跃新材料股份有限公司 Apply silicon rubber flannelette synthetic leather and its manufacturing technology on vehicles interior trim
CN114855465A (en) * 2022-03-25 2022-08-05 郑州宇佳汽车用品有限公司 Matte easy-to-clean silica gel product and preparation method thereof
CN114855466A (en) * 2022-03-25 2022-08-05 郑州宇佳汽车用品有限公司 Easy-to-clean coating oil for silica gel leather or silica gel leather, easy-to-clean silica gel leather or silica gel leather and preparation method thereof
CN115584205A (en) * 2022-07-22 2023-01-10 浙江鑫钰新材料有限公司 Novel antibacterial mildew-proof easily-cleaned organic silicon finishing agent and preparation process thereof

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CN108894006A (en) * 2018-07-13 2018-11-27 广东天跃新材料股份有限公司 Using foamed silica gel as the silicon rubber synthetic leather and its manufacturing technology of base
CN108729244A (en) * 2018-07-13 2018-11-02 广东天跃新材料股份有限公司 The silicon rubber synthetic leather and its manufacturing technology of outdoor furniture
CN108755165A (en) * 2018-07-13 2018-11-06 广东天跃新材料股份有限公司 The silicon rubber synthetic leather and its manufacturing technology of energy releasing negative oxygen ion and far infrared
CN108823340A (en) * 2018-07-13 2018-11-16 广东天跃新材料股份有限公司 Corium silastic polymer synthetic leather and its manufacturing technology
WO2020010909A1 (en) * 2018-07-13 2020-01-16 广东天跃新材料股份有限公司 Silicone rubber synthetic leather for outdoor furniture and fabrication technology therefor
CN108823340B (en) * 2018-07-13 2021-02-02 广东天跃新材料股份有限公司 Leather silicone rubber polymer synthetic leather and manufacturing method thereof
CN108729245A (en) * 2018-07-13 2018-11-02 广东天跃新材料股份有限公司 Vehicle seat, decoration silicon rubber synthetic leather and its manufacturing technology
CN108824001A (en) * 2018-08-14 2018-11-16 广东天跃新材料股份有限公司 Vamp silicon rubber synthetic leather and its manufacturing technology of cold-resistant high temperature resistant color inhibition
CN108867096A (en) * 2018-08-14 2018-11-23 广东天跃新材料股份有限公司 The high-performance vamp silicon rubber synthetic leather and its manufacturing technology for antifouling waterproof of breathing freely
CN109023982A (en) * 2018-08-14 2018-12-18 广东天跃新材料股份有限公司 Zero DMF environment-friendly and high-performance silastic polymer synthetic leather and its manufacturing technology
CN109183436A (en) * 2018-11-22 2019-01-11 广东天跃新材料股份有限公司 Apply silicon rubber flannelette synthetic leather and its manufacturing technology on vehicles interior trim
CN114855465A (en) * 2022-03-25 2022-08-05 郑州宇佳汽车用品有限公司 Matte easy-to-clean silica gel product and preparation method thereof
CN114855466A (en) * 2022-03-25 2022-08-05 郑州宇佳汽车用品有限公司 Easy-to-clean coating oil for silica gel leather or silica gel leather, easy-to-clean silica gel leather or silica gel leather and preparation method thereof
CN115584205A (en) * 2022-07-22 2023-01-10 浙江鑫钰新材料有限公司 Novel antibacterial mildew-proof easily-cleaned organic silicon finishing agent and preparation process thereof

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Application publication date: 20180608