CN108914606A - Ship, yacht furniture decoration silicon rubber synthetic leather and its manufacturing technology - Google Patents
Ship, yacht furniture decoration silicon rubber synthetic leather and its manufacturing technology Download PDFInfo
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- CN108914606A CN108914606A CN201810769534.9A CN201810769534A CN108914606A CN 108914606 A CN108914606 A CN 108914606A CN 201810769534 A CN201810769534 A CN 201810769534A CN 108914606 A CN108914606 A CN 108914606A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
- D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/146—Soilproof, soil repellent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of ships, yacht furniture decoration silicon rubber synthetic leather, it includes fire-retardant bass, in being coated with ship, yacht furniture decoration fluid silicone rubber on the fire-retardant bass, ship, yacht furniture decoration surface-treated layer are coated in the surface of the ship, yacht furniture decoration fluid silicone rubber；It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with fluid silicone rubber：80-100 parts of silicon rubber base rubber, 5-10 parts of containing hydrogen silicone oil, 1-3 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor.The present invention has excellent easy to clean and anti-pollution function, has hydrolysis, light shine, heat-resisting, cold-resistant and fire-retardant performance, and clean and environmental protection is durable.
Description
Technical field
The present invention relates to silicon rubber leathers, and in particular to a kind of ship, yacht furniture decoration silicon rubber synthetic leather and should
The manufacturing technology of ship, yacht furniture decoration silicon rubber synthetic leather.
Background technique
At present on international market, ship and yacht interior material have immeasurable development prospect and potential market, and
Ship and yacht interior trim have quite high physical property requirement to synthetic leather material, and common artificial leather material has been unable to reach these and has wanted
It asks.Therefore in ship and yacht interior trim synthetic leather field, need to be developed a kind of high-grade synthetic leather material, this material needs have
Many advantages, such as hydrolysis, light shine, heat-resisting, cold-resistant, fire-retardant, antifouling and easy cleaning.
Traditional synthetic leather is mainly based on PVC synthetic leather and PU synthetic leather.To obtain the good PVC synthesis of texture
Leather, needs to add a large amount of plasticizer, so that PVC synthetic leather is not environmentally.Synthetic leather on sale is still with PU currently on the market
Based on synthetic leather, but due to PU synthetic leather hydrolysis, weatherability, in terms of performance it is poor, so use PU
When synthetic leather is as ship and yacht interior trim synthetic leather material, durability is poor, needs to regularly replace, so it is made into cover more
It uses, facilitates periodic replacement, but the method not can solve root problem, and higher cost.
With Si-O-Si key, helically structure exists on silastic material main chain, and Chemical bond energy is lower, and stability is very
Height has the performances such as excellent hydrolysis, light shine, heat-resisting, cold-resistant, antifouling and easy cleaning, is suitable as ship and yacht pair
The requirement of interior trim synthetic leather material.
Summary of the invention
It is an object of the present invention to a kind of ship, yacht furniture decoration silicon rubber synthetic leather are provided regarding to the issue above,
With hydrolysis, light shine, heat-resisting, cold-resistant, fire-retardant, antifouling and easy cleaning performance, clean and environmental protection is durable for it.
The present invention also aims to provide the manufacturing technology of above-mentioned ship, yacht furniture decoration silicon rubber synthetic leather.
Present invention technical solution used for the above purpose is：
A kind of ship, yacht furniture decoration silicon rubber synthetic leather comprising fire-retardant bass is coated on the fire-retardant bass
There are ship, yacht furniture decoration fluid silicone rubber, is coated in the surface of the ship, yacht furniture decoration fluid silicone rubber
Ship, yacht furniture decoration surface-treated layer；
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with fluid silicone rubber：Silicon rubber base
80-100 parts of glue, 1-3 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, inhibits 5-10 parts of containing hydrogen silicone oil
0.02-0.1 parts of agent.
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with surface-treated layer：Vinyl silicon
100-120 parts oily, 30-50 parts of phenyl vinyl polysiloxane, 10-30 parts of vinyl fluoride silicone oil, 10-20 parts of containing hydrogen silicone oil, silane
3-5 parts of coupling agent, 0.1-0.3 parts of delayed-action activator, 0.5-1 parts of platinum catalyst.
It is figured by mass parts, the silicon rubber base rubber is made of following raw material：50-80 parts of low viscosity vinyl silicone oil, height
50-80 parts of viscosity vinyl silicone oil, 30-50 parts of white carbon black, 10-15 parts of silazane, 30-50 parts of fire-retardant filler, pure water 1-3
Part.
The low viscosity vinyl silicone oil viscosity is 1000-3000cs, contents of ethylene 0.5-1%；
High viscosity vinyl silicone oil viscosity is 50000-100000cs, contents of ethylene 0.05-0.1%；
The fire-retardant filler is inorganic fire retardants, is aluminum oxide, aluminium hydroxide, magnesium hydroxide, antimony oxide and boric acid
One or more kinds of compositions in zinc.
White carbon black is the hydrophilic white carbon black of the precipitation method, and mesh number is 80-100 mesh；
Tackifier are polyurethane-modified dimethyl silicone polymer；
Containing hydrogen silicone oil hydrogen content is 0.55-1.0%；
Platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution；
Silane coupling agent is KH-560, KH-570, KH-151, methyl orthosilicate, ethyl orthosilicate, positive silicic acid propyl ester, first
One or more kinds of mixtures of ethyl triethoxy silicane alkane；
Inhibitor is the mixed of the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes
Close object；
The phenyl vinyl polysiloxane medium vinyl content is 2-4%；
The vinyl fluorine containing silicone oil fluorine content is 3-10%, viscosity 1000-10000cs.
A kind of manufacturing technology of aforementioned ship, yacht furniture decoration silicon rubber synthetic leather comprising following steps：
Step 1: the preparation of ship, yacht furniture decoration fluid silicone rubber；
Step 2: the preparation of ship, yacht furniture decoration surface treating agent；
Step 3: the manufacture of ship, yacht furniture decoration silicon rubber synthetic leather.
In step 1, by 80-100 parts of silicon rubber base rubber, 5-10 parts of containing hydrogen silicone oil, 1-3 parts of tackifier, platinum catalyst
0.1-0.5 parts, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor put into planet dispersator, lead to cooling water, open
Vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 100-120 parts of vinyl silicone oil, 30-50 parts of phenyl vinyl polysiloxane, vinyl fluoride silicone oil
10-30 parts, 10-20 parts of containing hydrogen silicone oil, 3-5 parts of silane coupling agent, 0.1-0.3 parts of delayed-action activator, 0.5-1 parts of platinum catalyst additions
Into high speed disperser, dispersion stirring 30 minutes, after filtering.
In step 3, by ship and yacht furniture decoration surface treating agent coats to leather paper or release paper, then
Be sent in tunnel rate, 100-140 DEG C at a temperature of, toast 5-10 minute, formation ship, at yacht furniture decoration surface
Manage layer；Ship, yacht furniture decoration are coated on ship, on yacht furniture decoration surface-treated layer with fluid silicone rubber, and
Be bonded with fire-retardant bass, then pass to continuous tunnel furnace, 100-140 DEG C at a temperature of vulcanize 5-10 minutes, by release paper or skin
Paper removing is removed from office, ship, yacht furniture decoration silicon rubber leather are obtained.
By 50-80 parts of low viscosity vinyl silicone oil, 50-80 parts of high viscosity vinyl silicone oil, 30-50 parts of white carbon black, silicon nitrogen
10-15 parts of alkane, 30-50 parts of fire-retardant filler, 1-3 parts of pure water be added in kneader room temperature and mediate stirring 3h, then heat to
Then 150 DEG C of kneading 2h vacuumize and are cooled to room temperature after taking off low give up, the silicon rubber base rubber is made.
Beneficial effects of the present invention are：The present invention has selected have V-0 grades to guarantee the anti-flammability of silicon rubber synthetic leather
The bass of flame retardant effect, while being prepared for the fluid silicone rubber that flame retardant effect reaches V-0 grades；It joined low table in treatment agent
Face can phenyl polysiloxane and fluorine containing silicone oil there is hydrolysis, resistance to so that synthetic leather has excellent easy to clean and anti-pollution function
Illumination, heat-resisting, cold-resistant and fire-retardant performance, clean and environmental protection are durable.
Specific embodiment
Embodiment present embodiments provides a kind of ship, yacht furniture decoration silicon rubber synthetic leather comprising fire-retardant shellfish
This is used in being coated with ship, yacht furniture decoration fluid silicone rubber on the fire-retardant bass in the ship, yacht furniture decoration
The surface of fluid silicone rubber is coated with ship, yacht furniture decoration surface-treated layer；
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with fluid silicone rubber：Silicon rubber base
80-100 parts of glue, 1-3 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, inhibits 5-10 parts of containing hydrogen silicone oil
0.02-0.1 parts of agent.
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with surface-treated layer：Vinyl silicon
100-120 parts oily, 30-50 parts of phenyl vinyl polysiloxane, 10-30 parts of vinyl fluoride silicone oil, 10-20 parts of containing hydrogen silicone oil, silane
3-5 parts of coupling agent, 0.1-0.3 parts of delayed-action activator, 0.5-1 parts of platinum catalyst.
It is figured by mass parts, the silicon rubber base rubber is made of following raw material：50-80 parts of low viscosity vinyl silicone oil, height
50-80 parts of viscosity vinyl silicone oil, 30-50 parts of white carbon black, 10-15 parts of silazane, 30-50 parts of fire-retardant filler, pure water 1-3
Part.
The low viscosity vinyl silicone oil viscosity is 1000-3000cs, contents of ethylene 0.5-1%；
High viscosity vinyl silicone oil viscosity is 50000-100000cs, contents of ethylene 0.05-0.1%；
The fire-retardant filler is inorganic fire retardants, is aluminum oxide, aluminium hydroxide, magnesium hydroxide, antimony oxide and boric acid
One or more kinds of compositions in zinc.
White carbon black is the hydrophilic white carbon black of the precipitation method, and mesh number is 80-100 mesh；
Tackifier are polyurethane-modified dimethyl silicone polymer；
Containing hydrogen silicone oil hydrogen content is 0.55-1.0%；
Platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution；
Silane coupling agent is KH-560, KH-570, KH-151, methyl orthosilicate, ethyl orthosilicate, positive silicic acid propyl ester, first
One or more kinds of mixtures of ethyl triethoxy silicane alkane；
Inhibitor is the mixed of the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes
Close object；
The phenyl vinyl polysiloxane medium vinyl content is 2-4%；
The vinyl fluorine containing silicone oil fluorine content is 3-10%, viscosity 1000-10000cs.
A kind of manufacturing technology of aforementioned ship, yacht furniture decoration silicon rubber synthetic leather comprising following steps：
Step 1: the preparation of ship, yacht furniture decoration fluid silicone rubber；
Step 2: the preparation of ship, yacht furniture decoration surface treating agent；
Step 3: the manufacture of ship, yacht furniture decoration silicon rubber synthetic leather.
In step 1, by 80-100 parts of silicon rubber base rubber, 5-10 parts of containing hydrogen silicone oil, 1-3 parts of tackifier, platinum catalyst
0.1-0.5 parts, 5-20 parts of color pigment, 0.02-0.1 parts of inhibitor put into planet dispersator, lead to cooling water, open
Vacuum equipment, dispersion stirring 10 minutes.
In step 2, by 100-120 parts of vinyl silicone oil, 30-50 parts of phenyl vinyl polysiloxane, vinyl fluoride silicone oil
10-30 parts, 10-20 parts of containing hydrogen silicone oil, 3-5 parts of silane coupling agent, 0.1-0.3 parts of delayed-action activator, 0.5-1 parts of platinum catalyst additions
Into high speed disperser, dispersion stirring 30 minutes, after filtering.
In step 3, by ship and yacht furniture decoration surface treating agent coats to leather paper or release paper, then
Be sent in tunnel rate, 100-140 DEG C at a temperature of, toast 5-10 minute, formation ship, at yacht furniture decoration surface
Manage layer；Ship, yacht furniture decoration are coated on ship, on yacht furniture decoration surface-treated layer with fluid silicone rubber, and
Be bonded with fire-retardant bass, then pass to continuous tunnel furnace, 100-140 DEG C at a temperature of vulcanize 5-10 minutes, by release paper or skin
Paper removing is removed from office, ship, yacht furniture decoration silicon rubber leather are obtained.
By 50-80 parts of low viscosity vinyl silicone oil, 50-80 parts of high viscosity vinyl silicone oil, 30-50 parts of white carbon black, silicon nitrogen
10-15 parts of alkane, 30-50 parts of fire-retardant filler, 1-3 parts of pure water be added in kneader room temperature and mediate stirring 3h, then heat to
Then 150 DEG C of kneading 2h vacuumize and are cooled to room temperature after taking off low give up, the silicon rubber base rubber is made.
The present invention has selected the bass with V-0 grades of flame retardant effects, simultaneously to guarantee the anti-flammability of silicon rubber synthetic leather
It is prepared for the fluid silicone rubber that flame retardant effect reaches V-0 grades；Joined in treatment agent low-surface-energy phenyl polysiloxane and
Fluorine containing silicone oil has hydrolysis, light shine, heat-resisting, cold-resistant and resistance so that synthetic leather has excellent easy to clean and anti-pollution function
The performance of combustion, clean and environmental protection are durable.
Embodiment 1 present embodiments provides a kind of ship, yacht furniture decoration silicon rubber synthetic leather comprising fire-retardant
Bass, in being coated with ship, yacht furniture decoration fluid silicone rubber on the fire-retardant bass, in the ship, yacht furniture decoration
Ship, yacht furniture decoration surface-treated layer are coated with the surface of fluid silicone rubber；
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with fluid silicone rubber：Silicon rubber base
80 parts of glue, 5 parts of containing hydrogen silicone oil, 1 part of tackifier, 0.1 part of platinum catalyst, 5 parts of color pigment, 0.02 part of inhibitor.
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with surface-treated layer：Vinyl silicon
100 parts of oil, 30 parts of phenyl vinyl polysiloxane, 10 parts of vinyl fluoride silicone oil, 10 parts of containing hydrogen silicone oil, 3 parts of silane coupling agent, delay
0.1 part of agent, 0.5 part of platinum catalyst.
It is figured by mass parts, the silicon rubber base rubber is made of following raw material：50 parts of low viscosity vinyl silicone oil, high viscosity
50 parts of vinyl silicone oil, 30 parts of white carbon black, 10 parts of silazane, 30 parts of fire-retardant filler, 1 part of pure water.
The low viscosity vinyl silicone oil viscosity is 1000-3000cs, contents of ethylene 0.5-1%；
High viscosity vinyl silicone oil viscosity is 50000-100000cs, contents of ethylene 0.05-0.1%；
The fire-retardant filler is inorganic fire retardants, is aluminum oxide, aluminium hydroxide, magnesium hydroxide, antimony oxide and boric acid
One or more kinds of compositions in zinc.
White carbon black is the hydrophilic white carbon black of the precipitation method, and mesh number is 80-100 mesh；
Tackifier are polyurethane-modified dimethyl silicone polymer；
Containing hydrogen silicone oil hydrogen content is 0.55-1.0%；
Platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution；
Silane coupling agent is KH-560, KH-570, KH-151, methyl orthosilicate, ethyl orthosilicate, positive silicic acid propyl ester, first
One or more kinds of mixtures of ethyl triethoxy silicane alkane；
Inhibitor is the mixed of the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes
Close object；
The phenyl vinyl polysiloxane medium vinyl content is 2-4%；
The vinyl fluorine containing silicone oil fluorine content is 3-10%, viscosity 1000-10000cs.
A kind of manufacturing technology of aforementioned ship, yacht furniture decoration silicon rubber synthetic leather comprising following steps：
Step 1: the preparation of ship, yacht furniture decoration fluid silicone rubber；
Step 2: the preparation of ship, yacht furniture decoration surface treating agent；
Step 3: the manufacture of ship, yacht furniture decoration silicon rubber synthetic leather.
In step 1, by 80 parts of silicon rubber base rubber, 5 parts of containing hydrogen silicone oil, 1 part of tackifier, 0.1 part of platinum catalyst, color
5 parts of pigment, 0.02 part of inhibitor put into planet dispersator, lead to cooling water, open vacuum equipment, dispersion stirring 10 points
Clock.
In step 2, by 100 parts of vinyl silicone oil, 30 parts of phenyl vinyl polysiloxane, 10 parts of vinyl fluoride silicone oil, hydrogeneous
10 parts of silicone oil, 3 parts of silane coupling agent, 0.1 part of delayed-action activator, 0.5 part of platinum catalyst be added in high speed disperser, dispersion stirring
30 minutes, after filtering.
In step 3, by ship and yacht furniture decoration surface treating agent coats to leather paper or release paper, then
Be sent in tunnel rate, 100 DEG C at a temperature of, toast 5 minutes, formed ship, yacht furniture decoration surface-treated layer；It will
Ship, yacht furniture decoration are coated on ship, on yacht furniture decoration surface-treated layer with fluid silicone rubber, and with fire-retardant shellfish
This fitting, then passes to continuous tunnel furnace, 100 DEG C at a temperature of vulcanize 5 minutes, release paper or leather paper are removed, ship is obtained
Oceangoing ship, yacht furniture decoration silicon rubber leather.
By 50 parts of low viscosity vinyl silicone oil, 50 parts of high viscosity vinyl silicone oil, 30 parts of white carbon black, 10 parts of silazane, resistance
30 parts of filler of combustion, 1 part of pure water be added in kneader room temperature and mediate stirring 3h, then heat to 150 DEG C of kneading 2h, then take out
Vacuum take off it is low it is useless after be cooled to room temperature, the silicon rubber base rubber is made.
The present invention has selected the bass with V-0 grades of flame retardant effects, simultaneously to guarantee the anti-flammability of silicon rubber synthetic leather
It is prepared for the fluid silicone rubber that flame retardant effect reaches V-0 grades；Joined in treatment agent low-surface-energy phenyl polysiloxane and
Fluorine containing silicone oil has hydrolysis, light shine, heat-resisting, cold-resistant and resistance so that synthetic leather has excellent easy to clean and anti-pollution function
The performance of combustion, clean and environmental protection are durable.
Embodiment 2 present embodiments provides a kind of ship, yacht furniture decoration silicon rubber synthetic leather comprising fire-retardant
Bass, in being coated with ship, yacht furniture decoration fluid silicone rubber on the fire-retardant bass, in the ship, yacht furniture decoration
Ship, yacht furniture decoration surface-treated layer are coated with the surface of fluid silicone rubber；
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with fluid silicone rubber：Silicon rubber base
100 parts of glue, 10 parts of containing hydrogen silicone oil, 3 parts of tackifier, 0.5 part of platinum catalyst, 20 parts of color pigment, 0.1 part of inhibitor.
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with surface-treated layer：Vinyl silicon
120 parts of oil, 50 parts of phenyl vinyl polysiloxane, 30 parts of vinyl fluoride silicone oil, 20 parts of containing hydrogen silicone oil, 5 parts of silane coupling agent, delay
0.3 part of agent, 1 part of platinum catalyst.
It is figured by mass parts, the silicon rubber base rubber is made of following raw material：80 parts of low viscosity vinyl silicone oil, high viscosity
80 parts of vinyl silicone oil, 50 parts of white carbon black, 15 parts of silazane, 50 parts of fire-retardant filler, 3 parts of pure water.
The low viscosity vinyl silicone oil viscosity is 1000-3000cs, contents of ethylene 0.5-1%；
High viscosity vinyl silicone oil viscosity is 50000-100000cs, contents of ethylene 0.05-0.1%；
The fire-retardant filler is inorganic fire retardants, is aluminum oxide, aluminium hydroxide, magnesium hydroxide, antimony oxide and boric acid
One or more kinds of compositions in zinc.
White carbon black is the hydrophilic white carbon black of the precipitation method, and mesh number is 80-100 mesh；
Tackifier are polyurethane-modified dimethyl silicone polymer；
Containing hydrogen silicone oil hydrogen content is 0.55-1.0%；
Platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution；
Silane coupling agent is KH-560, KH-570, KH-151, methyl orthosilicate, ethyl orthosilicate, positive silicic acid propyl ester, first
One or more kinds of mixtures of ethyl triethoxy silicane alkane；
Inhibitor is the mixed of the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes
Close object；
The phenyl vinyl polysiloxane medium vinyl content is 2-4%；
The vinyl fluorine containing silicone oil fluorine content is 3-10%, viscosity 1000-10000cs.
A kind of manufacturing technology of aforementioned ship, yacht furniture decoration silicon rubber synthetic leather comprising following steps：
Step 1: the preparation of ship, yacht furniture decoration fluid silicone rubber；
Step 2: the preparation of ship, yacht furniture decoration surface treating agent；
Step 3: the manufacture of ship, yacht furniture decoration silicon rubber synthetic leather.
In step 1, by 100 parts of silicon rubber base rubber, 10 parts of containing hydrogen silicone oil, 3 parts of tackifier, 0.5 part of platinum catalyst, color
20 parts of cream pigment, 0.1 part of inhibitor put into planet dispersator, lead to cooling water, open vacuum equipment, dispersion stirring 10
Minute.
In step 2, by 120 parts of vinyl silicone oil, 50 parts of phenyl vinyl polysiloxane, 30 parts of vinyl fluoride silicone oil, hydrogeneous
20 parts of silicone oil, 5 parts of silane coupling agent, 0.3 part of delayed-action activator, 1 part of platinum catalyst be added in high speed disperser, dispersion stirring 30
Minute, after filtering.
In step 3, by ship and yacht furniture decoration surface treating agent coats to leather paper or release paper, then
Be sent in tunnel rate, 140 DEG C at a temperature of, toast 10 minutes, formed ship, yacht furniture decoration surface-treated layer；
Ship, yacht furniture decoration are coated on ship, on yacht furniture decoration surface-treated layer with fluid silicone rubber, and with it is fire-retardant
Bass fitting, then passes to continuous tunnel furnace, 140 DEG C at a temperature of vulcanize 10 minutes, release paper or leather paper are removed, obtained
Ship, yacht furniture decoration silicon rubber leather.
By 80 parts of low viscosity vinyl silicone oil, 80 parts of high viscosity vinyl silicone oil, 50 parts of white carbon black, 15 parts of silazane, resistance
50 parts of filler of combustion, 3 parts of pure water be added in kneader room temperature and mediate stirring 3h, then heat to 150 DEG C of kneading 2h, then take out
Vacuum take off it is low it is useless after be cooled to room temperature, the silicon rubber base rubber is made.
The present invention has selected the bass with V-0 grades of flame retardant effects, simultaneously to guarantee the anti-flammability of silicon rubber synthetic leather
It is prepared for the fluid silicone rubber that flame retardant effect reaches V-0 grades；Joined in treatment agent low-surface-energy phenyl polysiloxane and
Fluorine containing silicone oil has hydrolysis, light shine, heat-resisting, cold-resistant and resistance so that synthetic leather has excellent easy to clean and anti-pollution function
The performance of combustion, clean and environmental protection are durable.
Embodiment 3 present embodiments provides a kind of ship, yacht furniture decoration silicon rubber synthetic leather comprising fire-retardant
Bass, in being coated with ship, yacht furniture decoration fluid silicone rubber on the fire-retardant bass, in the ship, yacht furniture decoration
Ship, yacht furniture decoration surface-treated layer are coated with the surface of fluid silicone rubber；
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with fluid silicone rubber：Silicon rubber base
90 parts of glue, 7.5 parts of containing hydrogen silicone oil, 2 parts of tackifier, 0.3 part of platinum catalyst, 12.5 parts of color pigment, 0.06 part of inhibitor.
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with surface-treated layer：Vinyl silicon
110 parts of oil, 40 parts of phenyl vinyl polysiloxane, 20 parts of vinyl fluoride silicone oil, 15 parts of containing hydrogen silicone oil, 4 parts of silane coupling agent, delay
0.2 part of agent, 0.75 part of platinum catalyst.
It is figured by mass parts, the silicon rubber base rubber is made of following raw material：65 parts of low viscosity vinyl silicone oil, high viscosity
65 parts of vinyl silicone oil, 40 parts of white carbon black, 12.5 parts of silazane, 40 parts of fire-retardant filler, 2 parts of pure water.
The low viscosity vinyl silicone oil viscosity is 1000-3000cs, contents of ethylene 0.5-1%；
High viscosity vinyl silicone oil viscosity is 50000-100000cs, contents of ethylene 0.05-0.1%；
The fire-retardant filler is inorganic fire retardants, is aluminum oxide, aluminium hydroxide, magnesium hydroxide, antimony oxide and boric acid
One or more kinds of compositions in zinc.
White carbon black is the hydrophilic white carbon black of the precipitation method, and mesh number is 80-100 mesh；
Tackifier are polyurethane-modified dimethyl silicone polymer；
Containing hydrogen silicone oil hydrogen content is 0.55-1.0%；
Platinum catalyst is 5000ppm, can be ethyl alcohol, isopropanol, vinyl silicone oil, dimethyl-silicon oil solution；
Silane coupling agent is KH-560, KH-570, KH-151, methyl orthosilicate, ethyl orthosilicate, positive silicic acid propyl ester, first
One or more kinds of mixtures of ethyl triethoxy silicane alkane；
Inhibitor is the mixed of the one or more of methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes
Close object；
The phenyl vinyl polysiloxane medium vinyl content is 2-4%；
The vinyl fluorine containing silicone oil fluorine content is 3-10%, viscosity 1000-10000cs.
A kind of manufacturing technology of aforementioned ship, yacht furniture decoration silicon rubber synthetic leather comprising following steps：
Step 1: the preparation of ship, yacht furniture decoration fluid silicone rubber；
Step 2: the preparation of ship, yacht furniture decoration surface treating agent；
Step 3: the manufacture of ship, yacht furniture decoration silicon rubber synthetic leather.
In step 1, by 90 parts of silicon rubber base rubber, 7.5 parts of containing hydrogen silicone oil, 2 parts of tackifier, 0.3 part of platinum catalyst, color
12.5 parts of cream pigment, 0.06 part of inhibitor put into planet dispersator, lead to cooling water, open vacuum equipment, dispersion stirs
It mixes 10 minutes.
In step 2, by 110 parts of vinyl silicone oil, 40 parts of phenyl vinyl polysiloxane, 20 parts of vinyl fluoride silicone oil, hydrogeneous
15 parts of silicone oil, 4 parts of silane coupling agent, 0.2 part of delayed-action activator, 0.75 part of platinum catalyst be added in high speed disperser, dispersion is stirred
It mixes 30 minutes, after filtering.
In step 3, by ship and yacht furniture decoration surface treating agent coats to leather paper or release paper, then
Be sent in tunnel rate, 120 DEG C at a temperature of, toast 7.5 minutes, formed ship, yacht furniture decoration surface-treated layer；
Ship, yacht furniture decoration are coated on ship, on yacht furniture decoration surface-treated layer with fluid silicone rubber, and with it is fire-retardant
Bass fitting, then passes to continuous tunnel furnace, 120 DEG C at a temperature of vulcanize 7.5 minutes, release paper or leather paper are removed, obtained
To ship, yacht furniture decoration silicon rubber leather.
By 65 parts of low viscosity vinyl silicone oil, 65 parts of high viscosity vinyl silicone oil, 40 parts of white carbon black, 12.5 parts of silazane,
40 parts of fire-retardant filler, 2 parts of pure water be added in kneader room temperature and mediate stirring 3h, then heat to 150 DEG C of kneading 2h, then
It vacuumizes and is cooled to room temperature after taking off low give up, the silicon rubber base rubber is made.
The present invention has selected the bass with V-0 grades of flame retardant effects, simultaneously to guarantee the anti-flammability of silicon rubber synthetic leather
It is prepared for the fluid silicone rubber that flame retardant effect reaches V-0 grades；Joined in treatment agent low-surface-energy phenyl polysiloxane and
Fluorine containing silicone oil has hydrolysis, light shine, heat-resisting, cold-resistant and resistance so that synthetic leather has excellent easy to clean and anti-pollution function
The performance of combustion, clean and environmental protection are durable.
The above described is only a preferred embodiment of the present invention, being not intended to limit the present invention in any form.Appoint
What those skilled in the art, without departing from the scope of the technical proposal of the invention, all using the skill of the disclosure above
Art means and technology contents make many possible changes and modifications to technical solution of the present invention, or be revised as equivalent variations etc.
Imitate embodiment.Therefore anything that does not depart from the technical scheme of the invention, made by shape according to the present invention, construction and principle etc.
Effect variation, should all be covered by protection scope of the present invention.
Claims (10)
1. a kind of ship, yacht furniture decoration silicon rubber synthetic leather, it is characterised in that：It includes fire-retardant bass, fire-retardant in this
Ship, yacht furniture decoration fluid silicone rubber are coated on bass, in the ship, yacht furniture decoration fluid silicone rubber
Surface is coated with ship, yacht furniture decoration surface-treated layer；
It is figured by mass parts, the ship, yacht furniture decoration are made of following raw material with fluid silicone rubber：Silicon rubber base rubber
80-100 parts, 5-10 parts of containing hydrogen silicone oil, 1-3 parts of tackifier, 0.1-0.5 parts of platinum catalyst, 5-20 parts of color pigment, inhibitor
0.02-0.1 parts.
2. ship, yacht furniture decoration silicon rubber synthetic leather according to claim 1, which is characterized in that press mass fraction
It calculates, the ship, yacht furniture decoration are made of following raw material with surface-treated layer：100-120 parts of vinyl silicone oil, phenyl second
30-50 parts of alkenyl silicone resin, 10-30 parts of vinyl fluoride silicone oil, 10-20 parts of containing hydrogen silicone oil, 3-5 parts of silane coupling agent, delayed-action activator
0.1-0.3 parts, 0.5-1 parts of platinum catalyst.
3. ship, yacht furniture decoration silicon rubber synthetic leather according to claim 1, which is characterized in that press mass fraction
It calculates, the silicon rubber base rubber is made of following raw material：50-80 parts of low viscosity vinyl silicone oil, high viscosity vinyl silicone oil 50-80
Part, 30-50 parts of white carbon black, 10-15 parts of silazane, 30-50 parts of fire-retardant filler, 1-3 parts of pure water.
4. ship, yacht furniture decoration silicon rubber synthetic leather according to claim 3, which is characterized in that the low viscosity
Vinyl silicone oil viscosity is 1000-3000cs, contents of ethylene 0.5-1%；
High viscosity vinyl silicone oil viscosity is 50000-100000cs, contents of ethylene 0.05-0.1%；
The fire-retardant filler is inorganic fire retardants, is in aluminum oxide, aluminium hydroxide, magnesium hydroxide, antimony oxide and zinc borate
One or more kinds of compositions.
5. ship, yacht furniture decoration silicon rubber synthetic leather according to claim 2, which is characterized in that the phenyl second
Alkenyl silicone resin medium vinyl content is 2-4%；
The vinyl fluorine containing silicone oil fluorine content is 3-10%, viscosity 1000-10000cs.
6. the manufacturing technology of ship described in a kind of claim 1, yacht furniture decoration silicon rubber synthetic leather, which is characterized in that
It includes the following steps：
Step 1: the preparation of ship, yacht furniture decoration fluid silicone rubber；
Step 2: the preparation of ship, yacht furniture decoration surface treating agent；
Step 3: the manufacture of ship, yacht furniture decoration silicon rubber synthetic leather.
7. the manufacturing technology of ship, yacht furniture decoration silicon rubber synthetic leather according to claim 6, which is characterized in that
In step 1, by 80-100 parts of silicon rubber base rubber, 5-10 parts of containing hydrogen silicone oil, 1-3 parts of tackifier, 0.1-0.5 parts of platinum catalyst,
5-20 parts of color pigment, 0.02-0.1 parts of inhibitor put into planet dispersator, lead to cooling water, open vacuum equipment,
Dispersion stirring 10 minutes.
8. the manufacturing technology of ship, yacht furniture decoration silicon rubber synthetic leather according to claim 7, which is characterized in that
In step 2, by 100-120 parts of vinyl silicone oil, 30-50 parts of phenyl vinyl polysiloxane, 10-30 parts of vinyl fluoride silicone oil, contain
10-20 parts of hydrogen silicone oil, 3-5 parts of silane coupling agent, 0.1-0.3 parts of delayed-action activator, 0.5-1 parts of platinum catalyst be added to high speed dispersion
In machine, dispersion stirring 30 minutes, after filtering.
9. the manufacturing technology of ship, yacht furniture decoration silicon rubber synthetic leather according to claim 8, which is characterized in that
In step 3, by ship and yacht furniture decoration surface treating agent coats to leather paper or release paper, tunnel is then passed to
In road rate, 100-140 DEG C at a temperature of, toast 5-10 minute, formation ship, yacht furniture decoration surface-treated layer；It will
Ship, yacht furniture decoration are coated on ship, on yacht furniture decoration surface-treated layer with fluid silicone rubber, and with fire-retardant shellfish
This fitting, then pass to continuous tunnel furnace, 100-140 DEG C at a temperature of vulcanize 5-10 minute, by release paper or leather paper removing,
Obtain ship, yacht furniture decoration silicon rubber leather.
10. the manufacturing technology of ship, yacht furniture decoration silicon rubber synthetic leather according to claim 7, which is characterized in that
By 50-80 parts of low viscosity vinyl silicone oil, 50-80 parts of high viscosity vinyl silicone oil, 30-50 parts of white carbon black, silazane 10-15
Part, 30-50 parts of fire-retardant filler, 1-3 parts of pure water be added in kneader room temperature and mediate stirring 3h, then heat to 150 DEG C and pinch
2h is closed, then vacuumizes and is cooled to room temperature after taking off low give up, the silicon rubber base rubber is made.
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| CN201810769534.9A CN108914606A (en) | 2018-07-13 | 2018-07-13 | Ship, yacht furniture decoration silicon rubber synthetic leather and its manufacturing technology |
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| CN201810769534.9A CN108914606A (en) | 2018-07-13 | 2018-07-13 | Ship, yacht furniture decoration silicon rubber synthetic leather and its manufacturing technology |
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| CN111172778A (en) * | 2020-01-17 | 2020-05-19 | 江西赛欧特科新材料有限公司 | Organic silicon synthetic leather and manufacturing method thereof |
| CN111676707A (en) * | 2020-06-10 | 2020-09-18 | 浙江康成新材料科技有限公司 | Semi-silicon synthetic leather and preparation method thereof |
| CN113737539A (en) * | 2021-09-08 | 2021-12-03 | 广东天跃新材料股份有限公司 | Organic silicon synthetic leather for furniture decoration of ships and yachts and preparation method thereof |
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Application publication date: 20181130 |