CN107936628A - A kind of preparation method of nano ceramics floor coatings using nano silicon dioxide - Google Patents
A kind of preparation method of nano ceramics floor coatings using nano silicon dioxide Download PDFInfo
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- CN107936628A CN107936628A CN201711227973.9A CN201711227973A CN107936628A CN 107936628 A CN107936628 A CN 107936628A CN 201711227973 A CN201711227973 A CN 201711227973A CN 107936628 A CN107936628 A CN 107936628A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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Abstract
The invention discloses a kind of preparation method of the nano ceramics floor coatings using nano silicon dioxide, comprise the following steps that：Step 1, carries out silicic acid anhydride with silane under the action of catalyst by nano silicon dioxide, obtains semi-finished product；Step 2, the conventional constituents such as filler, pigment are added into semi-finished product and are stirred evenly in high speed dispersor, you can obtain finished product.The method preparation process that the present invention discloses is simple, and the nano ceramics floor coatings of preparation have the characteristics that high rigidity, high antifouling, high fire prevention, high waterproof, height are ageing-resistant, are particularly suitable for public building, prospect of the application is wide.
Description
Technical field
The present invention relates to coating preparation field, is specifically a kind of nano ceramics floor coatings using nano silicon dioxide
Preparation method.
Background technology
Floor coatings are exactly to use epoxy source material as host agent, add pigment, solvent, auxiliary agent curing agent by allotment and
Into floor decorative material, the referred to as floor coatings such as the epoxy oiliness floor paint researched and produced.Floor coatings are for protecting
Ground is protected, plays dust-proof, wear-resisting, cleaning, moisture-proof effect, so wide by modern industry ground, commercial ground, garage floor etc.
It is general to use and promote.
Epoxy flooring coating, acrylic coating and polyurethane coating are as most widely used in existing floor coatings both at home and abroad
Species, since its film forming matter is organic resin, in many aspect Shortcomings, such as hardness, wearability, scratch resistance, anti-
Fire, durability, self-cleaning, resistance to ag(e)ing etc. are not fully up to expectations.Particularly its fire line is very poor, once run into high temperature, naked light
When can produce a large amount of toxic and harmful gas, huge life and property loss is brought to user.
The content of the invention
It is an object of the invention to provide a kind of preparation method of the nano ceramics floor coatings using nano silicon dioxide,
To solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical solution：
A kind of preparation method of nano ceramics floor coatings using nano silicon dioxide, comprises the following steps that：
Step 1, carries out silicic acid anhydride with silane under the action of catalyst by nano silicon dioxide, obtains semi-finished product；
Step 2, the conventional constituents such as filler, pigment are added into semi-finished product and are stirred evenly in high speed dispersor, you can
To finished product.
As the further scheme of the present invention：The particle diameter of nano silicon dioxide is 1-100nm, the ratio table of nano silicon dioxide
Area is 0.002-0.02m2/ g, nano silicon dioxide include but not limited to precipitated silica, fumed silica, alkali
Property colloidal sol silica and acidic sol silica.
As the further scheme of the present invention：Catalyst includes bronsted lowry acids and bases bronsted lowry, and the additive amount of catalyst is nano silicon dioxide
The 1-1000000ppm of weight.
As the further scheme of the present invention：Acid includes but not limited to organic acid and inorganic acid, and organic acid includes but unlimited
In formic acid, acetic acid, propionic acid, butyric acid, octanoic acid, adipic acid, ethanedioic acid, malonic acid, succinic acid, maleic acid, tartaric acid, benzoic acid,
At least one in phenylacetic acid, phthalic acid, terephthalic acid (TPA), valeric acid, caproic acid, capric acid, stearic acid, palmitic acid and acrylic acid
Kind, inorganic acid includes but not limited to hydrochloric acid, nitric acid, boric acid, hydrogen cyanide, hydrogen fluorine (halogen) acid, nitrous acid, high hydracid, hydracid, Asia
At least one of hydracid, hypohalogenous acids and meta-aluminic acid.
As the further scheme of the present invention：Alkali includes but not limited to organic base and inorganic base, and inorganic base includes but unlimited
In caustic soda, solid caustic soda, potassium hydroxide, barium hydroxide, calcium hydroxide, aluminium hydroxide, lithium hydroxide, magnesium hydroxide, hydroxide
It is zinc, Kocide SD, iron hydroxide, lead hydroxide, cobalt hydroxide, chromium hydroxide, zirconium hydroxide, nickel hydroxide, ammonium hydroxide, pure
At least one of alkali, sodium carbonate (water, seven water, ten water), sodium acid carbonate, potassium carbonate and saleratus, organic base include but
It is not limited to triethylamine, triethylene diamine（DABCO）, DBU, DBN, DMAP, pyridine, N-methylmorpholine, tetramethylethylenediamine, TMG
At least one of potassium tert-butoxide/sodium, n-BuLi, KHMDS, NaHMDS and LDA.
As the further scheme of the present invention：The additive amount of silane is the 1-55% of nano silicon dioxide weight, and silane includes
But it is not limited to methyltrimethoxysilane, methyltriethoxysilane, dimethyl diethoxysilane, dimethylformamide dimethyl epoxide silicon
Alkane, triethoxysilane, trimethoxy hydrogen silane, tetraethoxysilane, tetrapropoxysilane, methyl ethylene dimethoxy silicon
Alkane, methyl vinyl diethoxysilane, vinyl silane triisopropoxide, vinyltriethoxysilane, vinyl front three
Oxysilane, vinyl three（'beta '-methoxy ethyoxyl）Silane, N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane, 3-
Aminopropyl trimethoxysilane, 3- aminopropyl triethoxysilanes, N-（2- aminoethyls）- aminopropyltriethoxy dimethoxysilane,
3- aminopropyltriethoxies diethoxy silane, 3- [the third oxygen of (2,3)-epoxy] hydroxypropyl methyl dimethoxysilane, 3- (2,3- epoxies third
Oxygen) hydroxypropyl methyl diethoxy silane, 3- (the third oxygen of 2,3- epoxies) propyl-triethoxysilicane, glycidyl triethoxysilicane
Alkane, β-（3,4- epoxycyclohexyls）Ethyl trimethoxy silane, 3- mercaptopropyl trimethoxysilanes, r- mercapto propyl-triethoxysilicanes
Alkane, r- mercapto hydroxypropyl methyls dimethoxysilane, 3- chloropropyl triethoxysilanes, 3- r-chloropropyl trimethoxyl silanes, 3- chlorine third
Ylmethyl dimethoxysilane, 3- chloropropyls diethoxy silane, dimethoxydiphenylsilane, phenyltriethoxy silane
Alkane, phenyltrimethoxysila,e, methacryloxypropyl trimethoxy silane, heptamethyltrisiloxane, double-[3- (three
Ethyoxyl silicon) propyl group]-at least one of tetrasulfide and hexadecyl trimethoxy silane.
As the further scheme of the present invention：The additive amount of filler is the 5-55% of semi-finished product weight, and filler includes but unlimited
In：Calcium carbonate（Coarse whiting, fine particle calcium carbonate）, blanc fixe（Barium sulfate）, talcum powder, kaolin（China clay）, porous konilite（Titanium dioxide
Silicon）, White Carbon black, blanc fixe, mica powder, at least one of wollastonite and bentonite.
As the further scheme of the present invention：Pigment includes inorganic pigment and organic pigment.
Compared with prior art, the beneficial effects of the invention are as follows：The method preparation process that the present invention discloses is simple, preparation
Nano ceramics floor coatings have the characteristics that high rigidity, high antifouling, high fire prevention, high waterproof, height are ageing-resistant, are particularly suitable for public affairs
Build together and build, prospect of the application is wide.
Embodiment
The technical solution of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of preparation method of nano ceramics floor coatings using nano silicon dioxide, takes 40 parts of nano silicon dioxide, acetic acid 1
Part, 20 parts of dimethoxydiphenylsilane, 20 parts of iron oxide red, is sufficiently mixed by high speed dispersor, adds cetyl
1 part of trimethoxy silane, is heated to 45 degrees Celsius, when continuation high-speed stirred 4-6 is small, you can obtain finished product.
Embodiment 2
A kind of preparation method of nano ceramics floor coatings using nano silicon dioxide, takes 45 parts of nano silicon dioxide, propionic acid 2
Part, 25 parts of methyltrimethoxysilane, 20 parts of titanium dioxide, is sufficiently mixed by high speed dispersor, adds cetyl trimethoxy
1 part of base silane, is heated to 45 degrees Celsius, when continuation high-speed stirred 4-6 is small, you can obtain finished product.
Embodiment 3
A kind of preparation method of nano ceramics floor coatings using nano silicon dioxide, takes 35 parts of nano silicon dioxide, hydrochloric acid 1
Part, 15 parts of methacryloxypropyl trimethoxy silane, 20 parts of iron oxide yellow, is sufficiently mixed by high speed dispersor, added
Enter 1 part of hexadecyl trimethoxy silane, be heated to 45 degrees Celsius, when continuation high-speed stirred 4-6 is small, you can obtain finished product.
Embodiment 4
A kind of preparation method of nano ceramics floor coatings using nano silicon dioxide, takes 46 parts of nano silicon dioxide, butyric acid 1
Part, 20 parts of r- mercapto hydroxypropyl methyls dimethoxysilane, 20 parts of iron oxide yellow, 10 parts of mica powder, is fully mixed by high speed dispersor
Close, add 1 part of hexadecyl trimethoxy silane, be heated to 45 degrees Celsius, when continuation high-speed stirred 4-6 is small, you can obtain into
Product.
Embodiment 5
A kind of preparation method of nano ceramics floor coatings using nano silicon dioxide, takes 30 parts of nano silicon dioxide, butyric acid 1
Part, 3- [the third oxygen of (2,3)-epoxy] 10 parts of hydroxypropyl methyl dimethoxysilane, 20 parts of titanium dioxide, 10 parts of kaolin, passes through at a high speed
Dispersion machine is sufficiently mixed, and adds 1 part of hexadecyl trimethoxy silane, is heated to 45 degrees Celsius, and it is small to continue high-speed stirred 4-6
When, you can obtain finished product.
High rigidity：It is mostly organic coating that terrace, which applies, currently on the market, and such as PU, epoxy, acrylic acid, coating surface hardness is only
There is 1~2H, it is easy to scratch, is damaged.Ceramic coating prepared by the method that the present invention discloses can reach 5~9H, conventional
Friction, scratch and lacquer painting do not injured, so can significantly extend the service life of client.
High resistance to ag(e)ing：Ceramic coating prepared by the method that the present invention discloses mainly is made of inorganic material, therefore
Semipermanent material will not be belonged to as organic coating film easily by ultraviolet, acid rain, automobile exhaust gas, damage by air pollution and aging,
It can be used for outdoor.
Excellent fire protecting performance：It is incombustible that ceramic coating prepared by the method that the present invention discloses possesses inorganic product
Characteristic, is resistant to 300 celsius temperatures, and paint film will not destroy, carbonizes and change colour.Reach A grades of fire protection requirements.
Excellent self-cleaning：Ceramic coating prepared by the method that the present invention discloses is not easy to adhere to most of pollutants
Matter, remains magnificent appearance.The processed terrace of ceramic coating prepared by the method disclosed with the present invention has very well
Self-cleaning effect.It is dirty if any surface, it can be cleaned using any washing product, such as washing powder, cleaning solution, it is broken without worrying
Bad lacquer painting.
High-environmental：Ceramic coating prepared by the method that the present invention discloses is different from organic coating, does not contain a huge sum of money
Belong to, there is good environmental-protecting performance, it is nonflammable, pernicious gas will not be produced after high-temp combustion.
Adhesive force is good：Ceramic coating prepared by the method that the present invention discloses not only has in film forming between cement matrix
" anchoring " adhewsive action of physics, while the surface hydroxyl such as the surface hydroxyl of nano particle and ground cement, the grains of sand carries out chemistry
Condensation reaction, more has nanoparticle penetration to cement inner capillary tube and produces chemical bond therewith, therefore film and ground base material
Adhesive force is stronger.
Resistance to marring is good：The paint film of ceramic coating prepared by the method that the present invention discloses has high hardness, because
This its adhesion strength is splendid, particularly suitable for crowded public building.
Balance：Ceramic coating prepared by the method that the present invention discloses is prepared using hybridization technique, therefore film
Rigidity and flexibility obtain optimum balance.
Multicolour：Ceramic coating prepared by the method that the present invention discloses can provide multiple colors, can be in certain model
Interior adjusting glossiness is enclosed, the appearance such as plain color, modelled after an antique, parian can be provided, meet public building to color and light
The different requirements in pool, more wide space is provided to designer.
Excellent application property：Ceramic coating construction prepared by the method that the present invention discloses is simple, especially for tide
Wet ground such as underground parking etc., being completely dried without waiting for ground to construct.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.
Claims (8)
1. the preparation method of a kind of nano ceramics floor coatings using nano silicon dioxide, it is characterised in that specific steps are such as
Under：
Step 1, carries out silicic acid anhydride with silane under the action of catalyst by nano silicon dioxide, obtains semi-finished product；
Step 2, the conventional constituents such as filler, pigment are added into semi-finished product and are stirred evenly in high speed dispersor, you can
To finished product.
2. the preparation method of the nano ceramics floor coatings according to claim 1 using nano silicon dioxide, its feature
It is, the particle diameter of the nano silicon dioxide is 1-100nm, and the specific surface area of nano silicon dioxide is 0.002-0.02m2/ g,
Nano silicon dioxide includes but not limited to precipitated silica, fumed silica, alkaline sol silica and acidity
Colloidal sol silica.
3. the preparation method of the nano ceramics floor coatings according to claim 1 using nano silicon dioxide, its feature
It is, the catalyst includes bronsted lowry acids and bases bronsted lowry, and the additive amount of catalyst is the 1-1000000ppm of nano silicon dioxide weight.
4. the preparation method of the nano ceramics floor coatings according to claim 3 using nano silicon dioxide, its feature
Be, it is described acid include but not limited to organic acid and inorganic acid, organic acid include but not limited to formic acid, acetic acid, propionic acid, butyric acid,
Octanoic acid, adipic acid, ethanedioic acid, malonic acid, succinic acid, maleic acid, tartaric acid, benzoic acid, phenylacetic acid, phthalic acid, to benzene
At least one of dioctyl phthalate, valeric acid, caproic acid, capric acid, stearic acid, palmitic acid and acrylic acid, inorganic acid includes but not limited to salt
In acid, nitric acid, boric acid, hydrogen cyanide, hydrogen fluorine (halogen) acid, nitrous acid, high hydracid, hydracid, halous acid, hypohalogenous acids and meta-aluminic acid
It is at least one.
5. the preparation method of the nano ceramics floor coatings according to claim 3 using nano silicon dioxide, its feature
It is, the alkali includes but not limited to organic base and inorganic base, and inorganic base includes but not limited to caustic soda, solid caustic soda, hydroxide
Potassium, barium hydroxide, calcium hydroxide, aluminium hydroxide, lithium hydroxide, magnesium hydroxide, zinc hydroxide, Kocide SD, iron hydroxide, hydrogen
Lead oxide, cobalt hydroxide, chromium hydroxide, zirconium hydroxide, nickel hydroxide, ammonium hydroxide, soda ash, sodium carbonate (water, seven water, ten
Water), sodium acid carbonate, at least one of potassium carbonate and saleratus, organic base includes but not limited to triethylamine, triethylene diamine
（DABCO）, DBU, DBN, DMAP, pyridine, N-methylmorpholine, tetramethylethylenediamine, TMG potassium tert-butoxides/sodium, n-BuLi,
At least one of KHMDS, NaHMDS and LDA.
6. the preparation method of the nano ceramics floor coatings according to claim 1 using nano silicon dioxide, its feature
It is, the additive amount of the silane is the 1-55% of nano silicon dioxide weight, and silane includes but not limited to methyl trimethoxy epoxide silicon
Alkane, methyltriethoxysilane, dimethyl diethoxysilane, dimethyldimethoxysil,ne, triethoxysilane, trimethoxy
Base hydrogen silane, tetraethoxysilane, tetrapropoxysilane, methylvinyldimethoxysilane, methyl ethylene diethoxy
Silane, vinyl silane triisopropoxide, vinyltriethoxysilane, vinyltrimethoxysilane, vinyl three（β-first
Epoxide ethyoxyl）Silane, N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane, 3- aminopropyl trimethoxysilanes, 3- ammonia
Propyl-triethoxysilicane, N-（2- aminoethyls）- aminopropyltriethoxy dimethoxysilane, 3- aminopropyltriethoxy diethoxy silicon
Alkane, 3- [the third oxygen of (2,3)-epoxy] hydroxypropyl methyl dimethoxysilane, 3- (the third oxygen of 2,3- epoxies) hydroxypropyl methyl diethoxy silicon
Alkane, 3- (the third oxygen of 2,3- epoxies) propyl-triethoxysilicane, glycidyl triethoxysilane, β-（3,4- epoxycyclohexyls）Second
Base trimethoxy silane, 3- mercaptopropyl trimethoxysilanes, r- mercaptopropyltriethoxysilanes, r- mercapto hydroxypropyl methyl dimethoxys
Silane, 3- chloropropyl triethoxysilanes, 3- r-chloropropyl trimethoxyl silanes, 3- chloropropylmethyldimethoxysilanes, 3- chlorine
Hydroxypropyl methyl diethoxy silane, dimethoxydiphenylsilane, phenyl triethoxysilane, phenyltrimethoxysila,e, first
Base acryloxypropyl trimethoxy silane, heptamethyltrisiloxane, double-[3- (triethoxysilicane) propyl group]-tetrasulfide
At least one of with hexadecyl trimethoxy silane.
7. the preparation method of the nano ceramics floor coatings according to claim 1 using nano silicon dioxide, its feature
It is, the additive amount of the filler is the 5-55% of semi-finished product weight, and filler includes but not limited to：Calcium carbonate（Coarse whiting, fine particle calcium carbonate）、
Blanc fixe（Barium sulfate）, talcum powder, kaolin（China clay）, porous konilite（Silica）, White Carbon black, sulfate precipitate
At least one of barium, mica powder, wollastonite and bentonite.
8. the preparation method of the nano ceramics floor coatings according to claim 1 using nano silicon dioxide, its feature
It is, the pigment includes inorganic pigment and organic pigment.
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Cited By (9)
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| CN108659586A (en) * | 2018-05-26 | 2018-10-16 | 湖南凯斯利新材料有限公司 | A kind of long-acting automatically cleaning aqueous inorganic ceramic coating and preparation method thereof |
| CN108659581A (en) * | 2018-04-27 | 2018-10-16 | 成都今天化工有限公司 | A method of preparing super abrasive nano-titanium porcelain coating |
| CN108659585A (en) * | 2018-05-24 | 2018-10-16 | 成都今天化工有限公司 | A method of preparing anti-moss nano-titanium porcelain coating |
| CN109096806A (en) * | 2018-08-20 | 2018-12-28 | 成都今天化工有限公司 | A method of preparing graphene modified Nano titanium porcelain coating |
| CN109181436A (en) * | 2018-09-28 | 2019-01-11 | 湖南凯斯利新材料有限公司 | A kind of aqueous inorganic nano ceramics fire prevention floor coatings and its application method |
| CN109266180A (en) * | 2018-09-28 | 2019-01-25 | 湖南凯斯利新材料有限公司 | A kind of extra-weather-proof wear-resisting rail vehicle carriage coating system and its application |
| CN109735153A (en) * | 2019-01-08 | 2019-05-10 | 广州凌玮科技股份有限公司 | A kind of preparation method of calcium ion-exchanged silica rust resisting pigment |
| CN109943116A (en) * | 2019-03-19 | 2019-06-28 | 陈基木 | The aqueous resistant protective agent of inorganic mineral and its production technology |
| CN115558376A (en) * | 2022-10-20 | 2023-01-03 | 上海正欧实业有限公司 | Wear-resistant floor coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108659581A (en) * | 2018-04-27 | 2018-10-16 | 成都今天化工有限公司 | A method of preparing super abrasive nano-titanium porcelain coating |
| CN108659585A (en) * | 2018-05-24 | 2018-10-16 | 成都今天化工有限公司 | A method of preparing anti-moss nano-titanium porcelain coating |
| CN108659586A (en) * | 2018-05-26 | 2018-10-16 | 湖南凯斯利新材料有限公司 | A kind of long-acting automatically cleaning aqueous inorganic ceramic coating and preparation method thereof |
| CN109096806A (en) * | 2018-08-20 | 2018-12-28 | 成都今天化工有限公司 | A method of preparing graphene modified Nano titanium porcelain coating |
| CN109181436A (en) * | 2018-09-28 | 2019-01-11 | 湖南凯斯利新材料有限公司 | A kind of aqueous inorganic nano ceramics fire prevention floor coatings and its application method |
| CN109266180A (en) * | 2018-09-28 | 2019-01-25 | 湖南凯斯利新材料有限公司 | A kind of extra-weather-proof wear-resisting rail vehicle carriage coating system and its application |
| CN109735153A (en) * | 2019-01-08 | 2019-05-10 | 广州凌玮科技股份有限公司 | A kind of preparation method of calcium ion-exchanged silica rust resisting pigment |
| CN109735153B (en) * | 2019-01-08 | 2021-05-07 | 广州凌玮科技股份有限公司 | Preparation method of calcium ion-exchanged silicon dioxide antirust pigment |
| CN109943116A (en) * | 2019-03-19 | 2019-06-28 | 陈基木 | The aqueous resistant protective agent of inorganic mineral and its production technology |
| CN115558376A (en) * | 2022-10-20 | 2023-01-03 | 上海正欧实业有限公司 | Wear-resistant floor coating and preparation method thereof |
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