CN108129076A - A kind of method for preparing nano ceramics lacquer - Google Patents
A kind of method for preparing nano ceramics lacquer Download PDFInfo
- Publication number
- CN108129076A CN108129076A CN201810017386.5A CN201810017386A CN108129076A CN 108129076 A CN108129076 A CN 108129076A CN 201810017386 A CN201810017386 A CN 201810017386A CN 108129076 A CN108129076 A CN 108129076A
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- Prior art keywords
- acid
- nano ceramics
- hydroxide
- silane
- lacquer
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00008—Obtaining or using nanotechnology related materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
Abstract
The invention discloses a kind of methods for preparing nano ceramics lacquer, are as follows：Nano silicon dioxide is carried out silicic acid anhydride with silane under catalysts conditions, obtains nano ceramics resin by step 1；Step 2 will add in filler and pigment and disperse in high speed dispersor, you can obtains finished product in nano ceramics resin.Its main film forming matter of lacquer prepared by the present invention and binding agent are nano ceramics resin, the main component of nano ceramics resin is nano silicon dioxide, it is essentially identical with the ingredient of lithotome, it can be rated as the mineral varnish of real meaning, there is high rigidity, antifouling, fire prevention, waterproof, ageing-resistant, be particularly suitable for public building.
Description
Technical field
The present invention relates to paint field, specifically a kind of method for preparing nano ceramics lacquer.
Background technology
Coating is to be coated in the body surface protected or decorated, and can be with being applied in the entitled paint of Chinese tradition
Object forms the continuous film of firm attachment, typically based on resin or oil or lotion, adds or does not add pigment, filler,
Add corresponding additive, the thick liquid being formulated with organic solvent or water.Coating is in the production and life of people using very
More, lacquer is exactly wherein common one kind.
Lacquer is the coating that a kind of decorative effect exactly likes marble, granite.The main natural stone for using a variety of colors
Powder is formulated, applied to the imitative stone effect of external wall, therefore also known as liquid stone.The master of existing lacquer currently on the market
Want film forming matter and binding agent be mostly styrene-acrylic emulsion, pure-acrylic emulsion, silicone acrylic emulsion or acrylic resin, alkyd resin, epoxy resin,
Fluorocarbon resin etc., the natural stone-powder for being equipped with a variety of colors are applied to external wall to reach imitative stone effect.These are dazzling
So-called lacquer be only appearance as lacquer, essence or organic coating.Since its film forming matter and binding agent is have
Machine resin, it is not fully up to expectations in many aspect Shortcomings, such as hardness, fire line, durability, self-cleaning, resistance to ag(e)ing, it is special
It is not that its fire line is very poor, can produces a large amount of toxic and harmful gas when high temperature, open fire is encountered, huge life is brought to user
Property loss.
Invention content
The purpose of the present invention is to provide a kind of method for preparing nano ceramics lacquer, to solve in above-mentioned background technology
The problem of proposition.
To achieve the above object, the present invention provides following technical solution：
A kind of method for preparing nano ceramics lacquer, is as follows：
Nano silicon dioxide is carried out silicic acid anhydride with silane under catalysts conditions, obtains nano ceramics resin by step 1；
Step 2 will add in filler and pigment and disperse in high speed dispersor, you can obtains finished product in nano ceramics resin.
As further embodiment of the present invention：The grain size of nano silicon dioxide be 1-100nm, the ratio table of nano silicon dioxide
Area is 25-500m2/ g, it is molten that nano silicon dioxide includes but not limited to precipitated silica, fumed silica, alkalinity
Glue silica and acidic sol silica.
As further embodiment of the present invention：Catalyst includes bronsted lowry acids and bases bronsted lowry, and the additive amount of catalyst is nano silicon dioxide
The 1-1000000ppm of weight.
As further embodiment of the present invention：Acid includes but not limited to organic acid and inorganic acid, and organic acid includes but unlimited
In formic acid, acetic acid, propionic acid, butyric acid, octanoic acid, adipic acid, ethanedioic acid, malonic acid, succinic acid, maleic acid, tartaric acid, benzoic acid,
At least one in phenylacetic acid, phthalic acid, terephthalic acid (TPA), valeric acid, caproic acid, capric acid, stearic acid, palmitic acid and acrylic acid
Kind, inorganic acid includes but not limited to hydrochloric acid, nitric acid, boric acid, hydrogen cyanide, hydrogen fluorine (halogen) acid, nitrous acid, high hydracid, hydracid, Asia
At least one of hydracid, hypohalogenous acids and meta-aluminic acid, alkali include but not limited to organic base and inorganic base, and inorganic base includes but unlimited
In caustic soda, solid caustic soda, potassium hydroxide, barium hydroxide, calcium hydroxide, aluminium hydroxide, lithium hydroxide, magnesium hydroxide, hydroxide
It is zinc, Kocide SD, iron hydroxide, lead hydroxide, cobalt hydroxide, chromium hydroxide, zirconium hydroxide, nickel hydroxide, ammonium hydroxide, pure
At least one of alkali, sodium carbonate (water, seven water, ten water), sodium bicarbonate, potassium carbonate and saleratus, organic base include but
It is not limited to triethylamine, triethylene diamine（DABCO）, DBU, DBN, DMAP, pyridine, N-methylmorpholine, tetramethylethylenediamine, TMG
At least one of potassium tert-butoxide/sodium, n-BuLi, KHMDS, NaHMDS and LDA.
As further embodiment of the present invention：The additive amount of silane is the 1-55% of nano silicon dioxide weight, and silane includes
But it is not limited to methyltrimethoxysilane, methyltriethoxysilane, dimethyl diethoxysilane, dimethylformamide dimethyl oxygroup silicon
Alkane, triethoxysilane, trimethoxy hydrogen silane, tetraethoxysilane, tetrapropoxysilane, methyl ethylene dimethoxy silicon
Alkane, methyl vinyl diethoxysilane, vinyl silane triisopropoxide, vinyltriethoxysilane, vinyl front three
Oxysilane, vinyl three（'beta '-methoxy ethyoxyl）Silane, N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane, 3-
Aminopropyl trimethoxysilane, 3- aminopropyl triethoxysilanes, N-（2- aminoethyls）Aminopropyltriethoxy dimethoxysilane,
3- aminopropyltriethoxies diethoxy silane, 3- [the third oxygen of (2,3)-epoxy] hydroxypropyl methyl dimethoxysilane, 3- (2,3- epoxies third
Oxygen) hydroxypropyl methyl diethoxy silane, 3- (the third oxygen of 2,3- epoxies) propyl-triethoxysilicane, glycidyl triethoxysilicane
Alkane, β-（3,4- epoxycyclohexyls）Ethyl trimethoxy silane, 3- mercaptopropyl trimethoxysilanes, r- mercapto propyl-triethoxysilicanes
Alkane, r- mercapto hydroxypropyl methyls dimethoxysilane, 3- chloropropyl triethoxysilanes, 3- r-chloropropyl trimethoxyl silanes, 3- chlorine third
Ylmethyl dimethoxysilane, 3- chloropropyls diethoxy silane, dimethoxydiphenylsilane, phenyltriethoxy silane
Alkane, phenyltrimethoxysila,e, methacryloxypropyl trimethoxy silane, heptamethyltrisiloxane, double-[3- (three
Ethyoxyl silicon) propyl]-at least one of tetrasulfide and hexadecyl trimethoxy silane.
As further embodiment of the present invention：The additive amount of filler is the 5-55% of nano ceramics weight resin, and filler includes
But it is not limited to calcium carbonate（Coarse whiting, fine particle calcium carbonate）, blanc fixe（Barium sulfate）, talcum powder, kaolin（China clay）, porous konilite
（Silica）, White Carbon black, blanc fixe, mica powder, wollastonite, at least one in all kinds of color sands of bentonite and glass microballoon
Kind.
As further embodiment of the present invention：All kinds of color sands of bentonite include but not limited to natural colour sand, burning colorful sand and
Color sand is dyed, glass microballoon includes but not limited to hollow glass micropearl and solid glass micro-bead.
As further embodiment of the present invention：Pigment includes inorganic pigment and organic pigment.
As further embodiment of the present invention：Glass microballoon includes but not limited to colorful glass microbead and flint glass is micro-
Pearl.
Compared with prior art, the beneficial effects of the invention are as follows：Its main film forming matter of lacquer prepared by the present invention and viscous
Knot agent is nano ceramics resin, and the main component of nano ceramics resin is nano silicon dioxide, basic with the ingredient of lithotome
It is identical, it can be rated as the mineral varnish of real meaning, there is high rigidity, antifouling, fire prevention, waterproof, ageing-resistant, be particularly suitable for public affairs
It builds together and builds.
Specific embodiment
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
40 parts of nano silicon dioxide, 1 part of acetic acid are taken, 20 parts of dimethoxydiphenylsilane is sufficiently mixed by high speed dispersor,
1 part of hexadecyl trimethoxy silane is added in, is heated to 45 degree, continues high-speed stirred 4-6 hours, it is then net with supercentrifuge
Change, obtain nano ceramics resin.By nano ceramics resin, 320 mesh silicon powders, methyltrimethoxysilane, 80-100 mesh color sand,
60 mesh silica flours, 80 mesh silica flours, titanium dioxide, nano silicon dioxide and iron oxide red are with 45:20:2:10:20:30:15:2:5
Mass ratio be sufficiently mixed and get product in high speed dispersor.
Embodiment 2
40 parts of nano silicon dioxide, 1 part of acetic acid are taken, 20 parts of dimethoxydiphenylsilane is sufficiently mixed by high speed dispersor,
1 part of hexadecyl trimethoxy silane is added in, is heated to 45 degree, continues high-speed stirred 4-6 hours, it is then net with supercentrifuge
Change, obtain nano ceramics resin.By nano ceramics resin, 320 mesh silicon powders, methyltrimethoxysilane, 80-100 mesh color sand,
60 mesh silica flours, 80 mesh silica flours, barium sulfate, nano silicon dioxide and iron oxide yellow are with 55:20:2:10:25:30:10:2:5
Mass ratio be sufficiently mixed and get product in high speed dispersor.
Embodiment 3
40 parts of nano silicon dioxide, 1 part of acetic acid are taken, 20 parts of dimethoxydiphenylsilane is sufficiently mixed by high speed dispersor,
1 part of hexadecyl trimethoxy silane is added in, is heated to 45 degree, continues high-speed stirred 4-6 hours, it is then net with supercentrifuge
Change, obtain nano ceramics resin.By nano ceramics resin, 320 mesh silicon powders, methyltrimethoxysilane, 80-100 mesh color sand,
60 mesh silica flours, 80 mesh silica flours, 320 mesh aluminium oxide and nano silicon dioxide are with 55:20:2:5:35:20:10:2 mass ratio
It is sufficiently mixed and gets product in high speed dispersor.
Embodiment 4
40 parts of nano silicon dioxide, 1 part of acetic acid are taken, 20 parts of dimethoxydiphenylsilane is sufficiently mixed by high speed dispersor,
1 part of hexadecyl trimethoxy silane is added in, is heated to 45 degree, continues high-speed stirred 4-6 hours, it is then net with supercentrifuge
Change, obtain nano ceramics resin.By nano ceramics resin, 1000 mesh silicon powders, methyltrimethoxysilane, 20-40 mesh sliver,
60 mesh silica flours, 80 mesh silica flours, 320 mesh aluminium oxide and nano silicon dioxide are with 65:20:4:5:35:30:10:2 mass ratio
It is sufficiently mixed and gets product in high speed dispersor.
High rigidity：Lacquer is mostly organic resin for film forming matter, such as PU, epoxy, acrylic acid, paint film table currently on the market
Surface hardness is not high.Nano ceramics lacquer case hardness prepared by the method that the present invention discloses can reach 5~9H, general hardships
Sleet is not injured with the lacquer painting for thinking operation pair, can significantly extend the service life of client in this way.
High resistance to ag(e)ing：Nano ceramics lacquer film forming matter or filler prepared by the method that the present invention discloses is main
Be made of inorganic material, thus will not as the other types of lacquer of organic binder easily by ultraviolet light, acid rain, vapour
Vehicle exhaust gas, damage by air pollution and aging belong to semipermanent material, particularly suitable for outdoor.
Excellent fire protecting performance：Nano ceramics lacquer prepared by the method that the present invention discloses possesses inorganic product and does not burn
Characteristic, be resistant to 300 DEG C of high temperature, paint film will not destroy, carbonizes and change colour, and reach A grades of fire protection requirements.
Excellent self-cleaning：Nano ceramics lacquer prepared by the method that the present invention discloses is not easy to adhere to most of pollutants
Matter remains magnificent appearance, and the nano ceramics lacquer prepared with the method that the present invention discloses has fine self-cleaning effect, such as
Have that surface is dirty, self cleaning or can be cleaned by nature rain drop erosion using any washing product, such as washing powder is washed
Liquid etc. is washed, without worrying that lacquer painting destroys.
High-environmental：Nano ceramics lacquer prepared by the method that the present invention discloses is different from organic coating, does not contain weight
Metal has good environmental-protecting performance, nonflammable, and pernicious gas will not be generated after high-temp combustion.
Adhesive force：Nano ceramics lacquer prepared by the method that the present invention discloses not only has in film forming between cement matrix
" anchoring " adhewsive action of physics, while the surface hydroxyls such as the surface hydroxyl of nano particle and ground cement, the grains of sand carry out chemistry
Condensation reaction more has nanoparticle penetration to cement inner capillary tube and generates chemical bond therewith, therefore the cement such as film and metope
The adhesive force of base material is stronger.
Balance：Nanometer pottery lacquer prepared by the method that the present invention discloses is prepared using hybridization technique, therefore film
Rigidity and flexibility obtain optimum balance.
Multicolour：Nano ceramics lacquer prepared by the method that the present invention discloses can provide multiple colors, can be certain
In the range of adjust glossiness, the appearances such as plain color, modelled after an antique, parian can be provided, meet public building to color and
The different requirements of gloss, more wide space is provided to designer.
Application property：The method construction of the present invention is simple.
It is obvious to a person skilled in the art that the present invention is not limited to the details of above-mentioned exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requirement rather than above description limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in each embodiment can also be properly combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (9)
- A kind of 1. method for preparing nano ceramics lacquer, which is characterized in that be as follows：Nano silicon dioxide is carried out silicic acid anhydride with silane under catalysts conditions, obtains nano ceramics resin by step 1；Step 2 will add in filler and pigment and disperse in high speed dispersor, you can obtains finished product in nano ceramics resin.
- 2. the method according to claim 1 for preparing nano ceramics lacquer, which is characterized in that the nano silicon dioxide Grain size for 1-100nm, the specific surface area of nano silicon dioxide is 25-500m2/ g, nano silicon dioxide include but not limited to heavy Shallow lake method silica, fumed silica, alkaline sol silica and acidic sol silica.
- 3. the method according to claim 1 for preparing nano ceramics lacquer, which is characterized in that the catalyst includes acid And alkali, the additive amount of catalyst are the 1-1000000ppm of nano silicon dioxide weight.
- 4. the method according to claim 3 for preparing nano ceramics lacquer, which is characterized in that the acid includes but unlimited In organic acid and inorganic acid, organic acid includes but not limited to formic acid, acetic acid, propionic acid, butyric acid, octanoic acid, adipic acid, ethanedioic acid, third Diacid, succinic acid, maleic acid, tartaric acid, benzoic acid, phenylacetic acid, phthalic acid, terephthalic acid (TPA), valeric acid, caproic acid, capric acid, At least one of stearic acid, palmitic acid and acrylic acid, inorganic acid include but not limited to hydrochloric acid, nitric acid, boric acid, hydrogen cyanide, hydrogen At least one of fluorine (halogen) acid, nitrous acid, high hydracid, hydracid, halous acid, hypohalogenous acids and meta-aluminic acid, alkali includes but not limited to Organic base and inorganic base, inorganic base include but not limited to caustic soda, solid caustic soda, potassium hydroxide, barium hydroxide, calcium hydroxide, hydrogen Aluminium oxide, lithium hydroxide, magnesium hydroxide, zinc hydroxide, Kocide SD, iron hydroxide, lead hydroxide, cobalt hydroxide, hydroxide Chromium, zirconium hydroxide, nickel hydroxide, ammonium hydroxide, soda ash, sodium carbonate (water, seven water, ten water), sodium bicarbonate, potassium carbonate and carbon At least one of potassium hydrogen phthalate, organic base include but not limited to triethylamine, triethylene diamine（DABCO）, DBU, DBN, DMAP, pyrrole In pyridine, N-methylmorpholine, tetramethylethylenediamine, TMG potassium tert-butoxides/sodium, n-BuLi, KHMDS, NaHMDS and LDA at least It is a kind of.
- 5. the method according to claim 1 for preparing nano ceramics lacquer, which is characterized in that the additive amount of the silane For the 1-55% of nano silicon dioxide weight, silane include but not limited to methyltrimethoxysilane, methyltriethoxysilane, Dimethyl diethoxysilane, dimethyldimethoxysil,ne, triethoxysilane, trimethoxy hydrogen silane, tetraethoxy-silicane Alkane, tetrapropoxysilane, methylvinyldimethoxysilane, methyl vinyl diethoxysilane, three isopropyl oxygen of vinyl Base silane, vinyltriethoxysilane, vinyltrimethoxysilane, vinyl three（'beta '-methoxy ethyoxyl）Silane, N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane, 3- aminopropyl trimethoxysilanes, 3- aminopropyl triethoxysilanes, N-（2- aminoethyls）Aminopropyltriethoxy dimethoxysilane, 3- aminopropyltriethoxies diethoxy silane, 3- [(2,3)-epoxies third Oxygen] hydroxypropyl methyl dimethoxysilane, 3- (the third oxygen of 2,3- epoxies) hydroxypropyl methyl diethoxy silane, 3- (the third oxygen of 2,3- epoxies) Propyl-triethoxysilicane, glycidyl triethoxysilane, β-（3,4- epoxycyclohexyls）Ethyl trimethoxy silane, 3- mercaptos Propyl trimethoxy silicane, r- mercaptopropyltriethoxysilanes, r- mercapto hydroxypropyl methyls dimethoxysilane, three ethoxy of 3- chloropropyls Base silane, 3- r-chloropropyl trimethoxyl silanes, 3- chloropropylmethyldimethoxysilanes, 3- chloropropyl diethoxy silicon Alkane, dimethoxydiphenylsilane, phenyl triethoxysilane, phenyltrimethoxysila,e, methacryloxypropyl three Methoxy silane, heptamethyltrisiloxane, double-[3- (triethoxysilicane) propyl]-tetrasulfide and hexadecyl trimethoxy At least one of silane.
- 6. the method according to claim 1 for preparing nano ceramics lacquer, which is characterized in that the additive amount of the filler For the 5-55% of nano ceramics weight resin, filler includes but not limited to calcium carbonate（Coarse whiting, fine particle calcium carbonate）, blanc fixe（Barium sulfate）、 Talcum powder, kaolin（China clay）, porous konilite（Silica）, it is White Carbon black, blanc fixe, mica powder, wollastonite, swollen At least one of all kinds of color sands of profit soil and glass microballoon.
- 7. the method according to claim 6 for preparing nano ceramics lacquer, which is characterized in that all kinds of coloured silks of bentonite Sand include but not limited to natural colour sand, burning colorful sand and dyeing color sand, glass microballoon include but not limited to hollow glass micropearl and Solid glass micro-bead.
- 8. the method according to claim 1 for preparing nano ceramics lacquer, which is characterized in that the pigment includes inorganic Pigment and organic pigment.
- 9. the method according to claim 6 for preparing nano ceramics lacquer, which is characterized in that the glass microballoon includes But it is not limited to colorful glass microbead and flint glass microballon.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810017386.5A CN108129076A (en) | 2018-01-09 | 2018-01-09 | A kind of method for preparing nano ceramics lacquer |
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| CN201810017386.5A CN108129076A (en) | 2018-01-09 | 2018-01-09 | A kind of method for preparing nano ceramics lacquer |
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Cited By (4)
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| CN109021823A (en) * | 2018-08-23 | 2018-12-18 | 上海金力泰化工股份有限公司 | A kind of ceramic coating and its application method with true stone effect |
| CN110218027A (en) * | 2019-06-17 | 2019-09-10 | 济宁学院 | One kind is using glass microballoon as aggregate automatically cleaning lacquer and preparation method thereof |
| CN111792921A (en) * | 2020-06-23 | 2020-10-20 | 浙江艺玛材料科技有限公司 | Preparation method of ceramic plate and ceramic plate prepared by using same |
| CN114702844A (en) * | 2022-05-19 | 2022-07-05 | 北京安优伟业科技开发有限公司 | Method for preparing nano ceramic heat-insulating reflective coating |
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| CN109021823A (en) * | 2018-08-23 | 2018-12-18 | 上海金力泰化工股份有限公司 | A kind of ceramic coating and its application method with true stone effect |
| CN110218027A (en) * | 2019-06-17 | 2019-09-10 | 济宁学院 | One kind is using glass microballoon as aggregate automatically cleaning lacquer and preparation method thereof |
| CN111792921A (en) * | 2020-06-23 | 2020-10-20 | 浙江艺玛材料科技有限公司 | Preparation method of ceramic plate and ceramic plate prepared by using same |
| CN114702844A (en) * | 2022-05-19 | 2022-07-05 | 北京安优伟业科技开发有限公司 | Method for preparing nano ceramic heat-insulating reflective coating |
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Application publication date: 20180608 |