CN108659581A - A method of preparing super abrasive nano-titanium porcelain coating - Google Patents
A method of preparing super abrasive nano-titanium porcelain coating Download PDFInfo
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- CN108659581A CN108659581A CN201810392518.2A CN201810392518A CN108659581A CN 108659581 A CN108659581 A CN 108659581A CN 201810392518 A CN201810392518 A CN 201810392518A CN 108659581 A CN108659581 A CN 108659581A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Abstract
The invention discloses a kind of methods preparing super abrasive nano-titanium porcelain coating, are as follows：Nano silicon dioxide, nano-titanium oxide are carried out silicic acid anhydride with silane under catalysts conditions, obtain a nanometer titanium porcelain resin by step 1；Step 2 will be added titanium alloy fiber, filler and pigment and disperse in high speed dispersor, you can obtains finished product in nanometer titanium porcelain resin.Its main film forming matter of super abrasive nano-titanium porcelain coating and binder prepared by the present invention is nanometer titanium porcelain resin, the main component of nanometer titanium porcelain resin is nano silicon dioxide, titanium dioxide, have the characteristics that super abrasive, high rigidity, antifouling, fire prevention, waterproof, ageing-resistant, antibacterial, is particularly suitable for public building inner-outer wall and ground.
Description
Technical field
The present invention relates to paint field, specifically a kind of method for preparing super abrasive nano-titanium porcelain coating.
Background technology
Coating, in the entitled paint of Chinese tradition, be coated in the body surface being protected or decorated, and can with applied
Object forms the continuous film of firm attachment, typically based on resin or oil or lotion, adds or do not add pigment, filler,
Add corresponding additive, the thick liquid being formulated with organic solvent or water.Coating is in the production and life of people using very
More, building coating is exactly wherein common one kind.
Building coating is that one kind integrates decoration and the coating of function.Building coating is divided into interior wall, exterior wall and ground
Coating.The main film forming matter of existing building coating and binder are mostly styrene-acrylic emulsion, pure-acrylic emulsion, the third breast of silicon currently on the market
Liquid or acrylic resin, alkyd resin, epoxy resin, fluorocarbon resin etc. are equipped with various fillers, pigment is applied to building inside and outside wall
With ground to reach specific function and decorative effect.These dazzling building coatings are essentially all organic coating.
Since its film forming matter and binder are organic resin, in many aspect Shortcomings, such as wearability, hardness, fire line, durable
Property, self-cleaning, resistance to ag(e)ing, antibiotic property etc. are not fully up to expectations, and especially its wearability is very poor, the fields such as terrace to client with
Carry out many puzzlements.
Invention content
The purpose of the present invention is to provide a kind of methods preparing super abrasive nano-titanium porcelain coating, to solve above-mentioned background skill
The problem of being proposed in art.
To achieve the above object, the present invention provides the following technical solutions：
A method of super abrasive nano-titanium porcelain coating is prepared, is as follows：
Nano silicon dioxide, nano-titanium dioxide are carried out silicic acid anhydride with silane under catalysts conditions, obtained by step 1
Nanometer titanium porcelain resin；
Step 2 will be added titanium alloy fiber, filler and pigment and disperse in high speed dispersor, i.e., in nanometer titanium porcelain resin
Finished product can be obtained.
As a further solution of the present invention：The grain size of nano silicon dioxide is 1-100nm, the ratio table of nano silicon dioxide
Area is 25-500m2/ g, nano silicon dioxide include but not limited to precipitated silica, fumed silica, alkalinity it is molten
Glue silica and acidic sol silica.
As a further solution of the present invention：The grain size of nano-titanium dioxide is 1-100nm, the ratio table of nano-titanium dioxide
Area is 25-500m2/ g, nano-titanium dioxide include but not limited to precipitated titania, fumed titanium dioxide, alkalinity it is molten
Glue titanium dioxide and acidic sol titanium dioxide.
As a further solution of the present invention：Catalyst includes bronsted lowry acids and bases bronsted lowry, and the additive amount of catalyst is nano silicon dioxide
The 1-1000000ppm of weight.
As a further solution of the present invention：Acid includes but not limited to organic acid and inorganic acid, and organic acid includes but unlimited
In formic acid, acetic acid, propionic acid, butyric acid, octanoic acid, adipic acid, ethanedioic acid, malonic acid, succinic acid, maleic acid, tartaric acid, benzoic acid,
At least one in phenylacetic acid, phthalic acid, terephthalic acid (TPA), valeric acid, caproic acid, capric acid, stearic acid, palmitic acid and acrylic acid
Kind, inorganic acid includes but not limited to hydrochloric acid, nitric acid, boric acid, hydrogen cyanide, hydrogen fluorine (halogen) acid, nitrous acid, high hydracid, hydracid, Asia
At least one of hydracid, hypohalogenous acids and meta-aluminic acid, alkali include but not limited to organic base and inorganic base, and inorganic base includes but unlimited
In caustic soda, solid caustic soda, potassium hydroxide, barium hydroxide, calcium hydroxide, aluminium hydroxide, lithium hydroxide, magnesium hydroxide, hydroxide
It is zinc, Kocide SD, iron hydroxide, lead hydroxide, cobalt hydroxide, chromium hydroxide, zirconium hydroxide, nickel hydroxide, ammonium hydroxide, pure
At least one of alkali, sodium carbonate (water, seven water, ten water), sodium bicarbonate, potassium carbonate and saleratus, organic base include but
It is not limited to triethylamine, triethylene diamine（DABCO）, DBU, DBN, DMAP, pyridine, N-methylmorpholine, tetramethylethylenediamine, TMG
At least one of potassium tert-butoxide/sodium, n-BuLi, KHMDS, NaHMDS and LDA.
As a further solution of the present invention：The additive amount of silane is the 1-55% of nano silicon dioxide weight, and silane includes
But it is not limited to methyltrimethoxysilane, methyltriethoxysilane, dimethyl diethoxysilane, dimethylformamide dimethyl oxygroup silicon
Alkane, triethoxysilane, trimethoxy hydrogen silane, tetraethoxysilane, tetrapropoxysilane, methyl ethylene dimethoxy silicon
Alkane, methyl vinyl diethoxysilane, vinyl silane triisopropoxide, vinyltriethoxysilane, vinyl front three
Oxysilane, vinyl three（'beta '-methoxy ethyoxyl）Silane, N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane, 3-
Aminopropyl trimethoxysilane, 3- aminopropyl triethoxysilanes, N-（2- aminoethyls）Aminopropyltriethoxy dimethoxysilane,
3- aminopropyltriethoxies diethoxy silane, 3- [the third oxygen of (2,3)-epoxy] hydroxypropyl methyl dimethoxysilane, 3- (2,3- epoxies third
Oxygen) hydroxypropyl methyl diethoxy silane, 3- (the third oxygen of 2,3- epoxies) propyl-triethoxysilicane, glycidyl triethoxysilicane
Alkane, β-（3,4- epoxycyclohexyls）Ethyl trimethoxy silane, 3- mercaptopropyl trimethoxysilanes, r- mercapto propyl-triethoxysilicanes
Alkane, r- mercapto hydroxypropyl methyls dimethoxysilane, 3- chloropropyl triethoxysilanes, 3- r-chloropropyl trimethoxyl silanes, 3- chlorine third
Ylmethyl dimethoxysilane, 3- chloropropyls diethoxy silane, dimethoxydiphenylsilane, phenyltriethoxy silane
Alkane, phenyltrimethoxysila,e, methacryloxypropyl trimethoxy silane, heptamethyltrisiloxane, double-[3- (three
Ethyoxyl silicon) propyl]-at least one of tetrasulfide and hexadecyl trimethoxy silane.
As a further solution of the present invention：The additive amount of titanium alloy fiber is the 0.1-5% of nanometer titanium porcelain weight resin.
As a further solution of the present invention：The additive amount of filler is the 5-55% of nanometer titanium porcelain weight resin, and filler includes
But it is not limited to calcium carbonate（Coarse whiting, fine particle calcium carbonate）, blanc fixe（Barium sulfate）, talcum powder, kaolin（China clay）, porous konilite
（Silica）, White Carbon black, blanc fixe, mica powder, wollastonite, at least one in all kinds of color sands of bentonite and glass microballoon
Kind.
As a further solution of the present invention：All kinds of color sands of bentonite include but not limited to natural colour sand, burning colorful sand and
Color sand is dyed, glass microballoon includes but not limited to hollow glass micropearl and solid glass micro-bead.
As a further solution of the present invention：Pigment includes inorganic pigment and organic pigment.
As a further solution of the present invention：Glass microballoon includes but not limited to that colorful glass microbead and flint glass are micro-
Pearl.
Compared with prior art, the beneficial effects of the invention are as follows：Its master of super abrasive nano-titanium porcelain coating prepared by the present invention
It is nanometer titanium porcelain resin to want film forming matter and binder, and the main component of nanometer titanium porcelain resin is nano silicon dioxide, nano oxidized
Titanium has the characteristics that super abrasive, high rigidity, antifouling, fire prevention, waterproof, ageing-resistant, antibacterial, is particularly suitable for public building.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
Take 40 parts of nano silicon dioxide, 5 parts of nano-titanium oxide, 1 part of acetic acid, 20 parts of dimethoxydiphenylsilane passes through high speed
Dispersion machine is sufficiently mixed, and 1 part of hexadecyl trimethoxy silane is added, and is heated to 45 degree, continues high-speed stirred 4-6 hours, so
It is purified afterwards with supercentrifuge, obtains a nanometer titanium porcelain resin.By nanometer titanium porcelain resin, titanium alloy fiber, 320 mesh silicon powders, first
Base trimethoxy silane, 80-100 mesh color sand, 60 mesh silica flours, 80 mesh silica flours, titanium dioxide, nano silicon dioxide and iron oxide
It is red with 45:0.5:2:10:20:30:15:2:5 mass ratio is sufficiently mixed in high speed dispersor to get product.
Embodiment 2
Take 40 parts of nano silicon dioxide, 10 parts of nano-titanium oxide, 1 part of acetic acid, 20 parts of dimethoxydiphenylsilane passes through high speed
Dispersion machine is sufficiently mixed, and 1 part of hexadecyl trimethoxy silane is added, and is heated to 45 degree, continues high-speed stirred 4-6 hours, so
It is purified afterwards with supercentrifuge, obtains a nanometer titanium porcelain resin.By nanometer titanium porcelain resin, titanium alloy fiber, 320 mesh silicon powders, first
Base trimethoxy silane, 80-100 mesh color sand, 60 mesh silica flours, 80 mesh silica flours, barium sulfate, nano silicon dioxide and iron oxide
Huang is with 55:0.3:2:10:25:30:10:2:5 mass ratio is sufficiently mixed in high speed dispersor to get product.
Embodiment 3
Take 40 parts of nano silicon dioxide, 15 parts of nano-titanium oxide, 1 part of acetic acid, 20 parts of dimethoxydiphenylsilane passes through high speed
Dispersion machine is sufficiently mixed, and 1 part of hexadecyl trimethoxy silane is added, and is heated to 45 degree, continues high-speed stirred 4-6 hours, so
It is purified afterwards with supercentrifuge, obtains a nanometer titanium porcelain resin.By nanometer titanium porcelain resin, titanium alloy fiber, 320 mesh silicon powders, first
Base trimethoxy silane, 80-100 mesh color sand, 60 mesh silica flours, 80 mesh silica flours, 320 mesh aluminium oxide and nano silicon dioxide with
55:1:2:5:35:20:10:2 mass ratio is sufficiently mixed in high speed dispersor to get product.
Embodiment 4
Take 40 parts of nano silicon dioxide, 3 parts of nano-titanium oxide, 1 part of acetic acid, 20 parts of dimethoxydiphenylsilane passes through high speed
Dispersion machine is sufficiently mixed, and 1 part of hexadecyl trimethoxy silane is added, and is heated to 45 degree, continues high-speed stirred 4-6 hours, so
It is purified afterwards with supercentrifuge, obtains a nanometer titanium porcelain resin.By nanometer titanium porcelain resin, titanium alloy fiber, 1000 mesh silicon powders, first
Base trimethoxy silane, 20-40 mesh sliver, 60 mesh silica flours, 80 mesh silica flours, 320 mesh aluminium oxide and nano silicon dioxide with
65:0.6:4:5:35:30:10:2 mass ratio is sufficiently mixed in high speed dispersor to get product.
Super wear resistance：Super abrasive nano-titanium porcelain coating surface abrasion resistance prepared by the method that the present invention discloses is applied higher than general
Material, can significantly extend the service life of client.
High rigidity：Building coating is mostly using organic resin as film forming matter currently on the market, such as PU, epoxy, acrylic acid, paint
Film surface hardness is not high.Super abrasive nano-titanium porcelain coating case hardness prepared by the method that the present invention discloses can reach 5~9H,
General wind and frost sleet and think that the lacquer painting of operation pair does not injure, can significantly extend the service life of client in this way.
Resistance to ag(e)ing：Super abrasive nano-titanium porcelain coating prepared by method that the present invention discloses no matter film forming matter or filler master
To be made of inorganic material, thus will not as the other types of filler of organic binder easily by ultraviolet light, acid rain, vapour
Vehicle exhaust gas, damage by air pollution and aging belong to semipermanent material, particularly suitable for outdoor.
Excellent fire protecting performance：Super abrasive nano-titanium porcelain coating prepared by the method that the present invention discloses possesses inorganic product not
Aptitude to burn is resistant to 300 DEG C of high temperature, and paint film will not destroy, carbonizes and change colour, and reach A grades of fire protection requirements.
Excellent self-cleaning：Super abrasive nano-titanium porcelain coating prepared by the method that the present invention discloses is not easy to adhere to most of dirts
Contaminate substance, remain magnificent appearance, the super abrasive nano-titanium porcelain coating prepared with the method that discloses of the present invention have it is fine from
Clean effect, it is dirty if any surface, by nature rain drop erosion can self cleaning, or cleaned using any washing product, such as
Washing powder, cleaning solution etc. do not have to worry that lacquer painting destroys.
High-environmental：Super abrasive nano-titanium porcelain coating prepared by the method that the present invention discloses is different from organic coating, is free of
There is heavy metal, there is good environmental-protecting performance, it is nonflammable, pernicious gas is not will produce after high-temp combustion.
Adhesive force：Super abrasive nano-titanium porcelain coating prepared by method that the present invention discloses in film forming between cement matrix not
Only " anchoring " adhewsive action of physics, while the surface hydroxyls such as the surface hydroxyl of nano particle and ground cement, the grains of sand carry out
Chemical condensation reacts, and more has nanoparticle penetration to cement inner capillary tube and generates chemical bond therewith, therefore film and metope etc.
The adhesive force of cement matrix is stronger.
Antibiotic property：Super abrasive nano-titanium porcelain coating prepared by the method that the present invention discloses contains nano-titanium oxide, nano oxygen
Change titanium has certain antibiotic property under the action of ultraviolet light.
Application property：The method construction of the present invention is simple.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (11)
1. a kind of method preparing super abrasive nano-titanium porcelain coating, which is characterized in that be as follows：
Nano silicon dioxide, nano-titanium oxide are carried out silicic acid anhydride with silane under catalysts conditions, are received by step 1
Rice titanium porcelain resin；
Step 2 will be added titanium alloy fiber, filler and pigment and disperse in high speed dispersor, i.e., in nanometer titanium porcelain resin
Finished product can be obtained.
2. the method according to claim 1 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the nano-silica
The grain size of SiClx is 1-100nm, and the specific surface area of nano silicon dioxide is 25-500m2/ g, nano silicon dioxide include but unlimited
In precipitated silica, fumed silica, alkaline sol silica and acidic sol silica.
3. the method according to claim 1 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the nano-silica
The grain size for changing titanium is 1-100nm, and the specific surface area of nano-titanium dioxide is 25-500m2/ g, nano-titanium dioxide include but unlimited
In precipitated titania, fumed titanium dioxide, alkaline sol titanium dioxide and acidic sol titanium dioxide.
4. the method according to claim 1 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the catalyst packet
Bronsted lowry acids and bases bronsted lowry is included, the additive amount of catalyst is the 1-1000000ppm of nano silicon dioxide weight.
5. it is according to claim 3 prepare super abrasive nano-titanium porcelain coating method, which is characterized in that the acid include but
It is not limited to organic acid and inorganic acid, organic acid includes but not limited to formic acid, acetic acid, propionic acid, butyric acid, octanoic acid, adipic acid, second two
Acid, malonic acid, succinic acid, maleic acid, tartaric acid, benzoic acid, phenylacetic acid, phthalic acid, terephthalic acid (TPA), valeric acid, caproic acid,
At least one of capric acid, stearic acid, palmitic acid and acrylic acid, inorganic acid include but not limited to hydrochloric acid, nitric acid, boric acid, hydrogen cyanogen
At least one of acid, hydrogen fluorine (halogen) acid, nitrous acid, high hydracid, hydracid, halous acid, hypohalogenous acids and meta-aluminic acid, alkali include but
It is not limited to organic base and inorganic base, inorganic base includes but not limited to caustic soda, solid caustic soda, potassium hydroxide, barium hydroxide, hydroxide
Calcium, aluminium hydroxide, lithium hydroxide, magnesium hydroxide, zinc hydroxide, Kocide SD, iron hydroxide, lead hydroxide, cobalt hydroxide, hydrogen
Chromium oxide, zirconium hydroxide, nickel hydroxide, ammonium hydroxide, soda ash, sodium carbonate (water, seven water, ten water), sodium bicarbonate, potassium carbonate
At least one of with saleratus, organic base includes but not limited to triethylamine, triethylene diamine（DABCO）、DBU、DBN、
In DMAP, pyridine, N-methylmorpholine, tetramethylethylenediamine, TMG potassium tert-butoxides/sodium, n-BuLi, KHMDS, NaHMDS and LDA
At least one.
6. the method according to claim 1 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the silane adds
Dosage is the 1-55% of nano silicon dioxide weight, and silane includes but not limited to methyltrimethoxysilane, methyltriethoxy silane
Alkane, dimethyl diethoxysilane, dimethyldimethoxysil,ne, triethoxysilane, trimethoxy hydrogen silane, tetraethoxy
Silane, tetrapropoxysilane, methylvinyldimethoxysilane, methyl vinyl diethoxysilane, three isopropyl of vinyl
Oxysilane, vinyltriethoxysilane, vinyltrimethoxysilane, vinyl three（'beta '-methoxy ethyoxyl）Silane,
N- (β-aminoethyl)-γ-aminopropyltrimethoxysilane, 3- aminopropyl trimethoxysilanes, 3- aminopropyl-triethoxy silicon
Alkane, N-（2- aminoethyls）Aminopropyltriethoxy dimethoxysilane, 3- aminopropyltriethoxies diethoxy silane, 3- [(2,3)-epoxies
Third oxygen] hydroxypropyl methyl dimethoxysilane, 3- (the third oxygen of 2,3- epoxies) hydroxypropyl methyl diethoxy silane, 3- (2,3- epoxies third
Oxygen) propyl-triethoxysilicane, glycidyl triethoxysilane, β-（3,4- epoxycyclohexyls）Ethyl trimethoxy silane,
3- mercaptopropyl trimethoxysilanes, r- mercaptopropyltriethoxysilanes, r- mercapto hydroxypropyl methyls dimethoxysilane, 3- chloropropyls three
Ethoxysilane, 3- r-chloropropyl trimethoxyl silanes, 3- chloropropylmethyldimethoxysilanes, 3- chloropropyl diethoxies
Silane, dimethoxydiphenylsilane, phenyl triethoxysilane, phenyltrimethoxysila,e, methacryloxypropyl
Trimethoxy silane, heptamethyltrisiloxane, double-[3- (triethoxysilicane) propyl]-tetrasulfide and cetyl trimethoxy
At least one of base silane.
7. the method according to claim 1 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the titanium alloy is fine
The additive amount of dimension is 0.1%-5%.
8. the method according to claim 1 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the filler adds
Dosage is the 5-55% of nanometer titanium porcelain weight resin, and filler includes but not limited to calcium carbonate（Coarse whiting, fine particle calcium carbonate）, blanc fixe（Sulfuric acid
Barium）, talcum powder, kaolin（China clay）, porous konilite（Silica）, White Carbon black, blanc fixe, mica powder, silicon ash
At least one of all kinds of color sands of stone, bentonite and glass microballoon.
9. the method according to claim 6 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the bentonite is each
Class color sand includes but not limited to natural colour sand, burning colorful sand and dyeing color sand, and glass microballoon includes but not limited to that hollow glass is micro-
Pearl and solid glass micro-bead.
10. the method according to claim 1 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the pigment packet
Include inorganic pigment and organic pigment.
11. the method according to claim 6 for preparing super abrasive nano-titanium porcelain coating, which is characterized in that the glass is micro-
Pearl includes but not limited to colorful glass microbead and flint glass microballon.
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Cited By (3)
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| CN109796842A (en) * | 2018-12-19 | 2019-05-24 | 洛阳双瑞防腐工程技术有限公司 | A kind of water-base epoxy abrasion-proof terrace coating and the preparation method and application thereof |
| EP3708617A1 (en) * | 2019-03-14 | 2020-09-16 | Tata Consultancy Services Limited | Composition and method for preparation of hydrophobic coating |
| CN112266637A (en) * | 2020-09-30 | 2021-01-26 | 徐玲 | Nano antibacterial antiseptic hydrosol coating composition |
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