CN104109439A - Heat preserving really stone paint and preparation method thereof - Google Patents

Heat preserving really stone paint and preparation method thereof Download PDF

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Publication number
CN104109439A
CN104109439A CN201410363216.4A CN201410363216A CN104109439A CN 104109439 A CN104109439 A CN 104109439A CN 201410363216 A CN201410363216 A CN 201410363216A CN 104109439 A CN104109439 A CN 104109439A
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mineral varnish
true mineral
natvosol
hollow glass
insulation
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CN201410363216.4A
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CN104109439B (en
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许绍凰
蓝文烽
项椿烨
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ZHANGZHOU SANDELI PAINT & COATING Co Ltd
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ZHANGZHOU SANDELI PAINT & COATING Co Ltd
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Abstract

The invention discloses a heat preserving really stone paint and a preparation method thereof. The heat preserving really stone paint is prepared from the following components in parts by weight: 150-200 parts of a silicone acrylic emulsion, 450-500 parts of natural colored sand, 150-200 parts of hollow glass beads, 5-8 parts of hydroxyethyl cellulose, 200-250 parts of tap water and 35-50 parts of an auxiliary. By combining the silicone acrylic emulsion, the natural colored sand and the hollow glass beads, the heat preserving really stone paint disclosed by the invention has stabilities such as excellent weather resistance, tarnish resistance, temperature change resistance and ageing resistance and heat preserving performance as well as color diversification. In addition, the preparation method disclosed by the invention does not need grinding. Only dispersion is needed to prepare a product paint, so that the paint is simple in production process.

Description

True mineral varnish of a kind of insulation and preparation method thereof
Technical field
The present invention relates to building coating technical field, disclose especially true mineral varnish of a kind of insulation and preparation method thereof.
Background technology
Along with science technology and society expanding economy, the development of building coating industry is also with rapid changepl. never-ending changes and improvements.True mineral varnish because of its preparation technology simple, lucuriant in design true to nature, easy construction, through once spraying just can obtain the advantages such as decorative effect that stereoscopic sensation is very strong, the application percentage in construction work is more and more higher.Traditional true mineral varnish is mainly emphasized water tolerance, stain resistance, preservative property, ageing-resistant, but pays close attention to not aspect heat-insulating property.Variation along with social life level, people require more and more environmental protection for inhabitation, low-carbon green life is also familiar with by people gradually and accepts, open less or do not exploit warm household electrical appliances, saves energy for we such one per capita the country of resource scarcity seem particularly important, using the true mineral varnish of insulation is to realize this desirable reasonable approach.
Patent CN103275579A discloses true mineral varnish of a kind of insulation and preparation method thereof, main raw material is ACRYLIC EMULSION and pearlstone, common ACRYLIC EMULSION make the weathering resistance of final true mineral varnish and stability not good, and the water-intake rate of pearlstone is high and poor water resistance, cause the heat-insulating property in true mineral varnish later stage to reduce, easy to crack, workability is poor.
Be directed to this, in prior art, also exist employing organosilicon crylic acid latex and hollow glass microbead as the coating of raw material, for example patent CN101712835A discloses a kind of heat reflection paint with hollow glass microballoon, it is comprised of surface layer and priming paint, therefore execute that man-hour requirement is two-layer could realize its heat-reflecting heat-insulating and the diversified effect of color, and composite function nano material and hollow high molecular polymer cost in its raw material are high, are unfavorable for the competition of coating products.Patent CN101671523A discloses a kind of aqueous flame-retardant and thermal-insulated coating, by emulsion, fire retardant, titanium dioxide, hollow glass micropearl, water and auxiliary agent, formed, emulsion can be organosilicon crylic acid latex, although contain merger emulsion and hollow glass micropearl in this coating, but its color is dull, does not present color variation.In addition, the water-borne heat-insulating marble coating of patent CN102093798A is also cannot variation on color.The waterproof heat-insulating coating of patent CN102702904A is except organosilicon crylic acid latex and hollow glass micro-ball, and auxiliary packing also needs talcum powder, kaolin, wilkinite, mica powder, far infrared ceramic powder and xylogen etc., and the intensity of final coating may affect to some extent.Finally, the thermal insulating coating of patent CN102391754A adopts two coated hollow glass beads, glass microballon has been carried out to modification, has increased the cost of coating, and same in the variation of color defect to some extent.
Therefore a kind of weathering resistance of demand, resistance toly stain, ageing-resistant and temp. variation resistant equistability excellent, color is diversified and with low cost, the true mineral varnish of the easy insulation of construction, so true mineral varnish could have good competitive edge on Coating Market.
Summary of the invention
The object of the present invention is to provide the true mineral varnish of a kind of insulation, its weathering resistance, resistance toly stain, ageing-resistant and temp. variation resistant equistability excellence and color variation, simultaneously with low cost, construct simple and easy.
Another object of the present invention is to provide a kind of preparation method who is incubated true mineral varnish, and this preparation method grinds without process, only needs can be made into finished product paint through high speed dispersion, and production technique is simple, and production and operating efficiency are high, with low cost.
The invention provides the true mineral varnish of a kind of insulation, press mass fraction, by following component, formed: organosilicon crylic acid latex 150-200 part, natural colour sand 450-500 part, hollow glass microbead 150-200 part, Natvosol 5-8 part, tap water 200-250 part, auxiliary agent 35-50 part.
Described organosilicon crylic acid latex is that the organosilane monomer and the acrylic monomer that contain unsaturated link(age) are coated the emulsion of the nucleocapsid structure being polymerized by nucleocapsid.Wherein organosilane monomer can be vinyl silicon monomer such as vinyltrimethoxy silane, vinyltriethoxysilane etc., or (methyl) acryloxy silicon monomer such as (methyl) acryloxy Trimethoxy silane, (methyl) acryloxy triethoxyl silane etc.Acrylic monomer wherein can be (methyl) vinylformic acid, (methyl) acrylate methyl esters, (methyl) ethyl propenoate, (methyl) butyl acrylate, (methyl) Octyl acrylate, (methyl) stearyl acrylate ester etc.
Above-mentioned organosilicon crylic acid latex combines organosilyl high thermal resistance, weathering resistance, chemical-resistant, and hydrophobicity, surface can the low contaminative that is difficult for, the high tint retention of acrylic resin, snappiness, tack are a kind of high weather-proof, high water-fast, resistant to pollution environment-friendly type building emulsions.
Described natural colour sand is to be processed through multiple working procedures such as selected, broken, pulverizing, classification, packings by ores such as marble or grouan, has firm wear-resisting, waterproof, anticorrosion, nontoxic, cohesive force is strong, the feature such as lucuriant in design.And its addition is very large, can make the color that is incubated true mineral varnish product present fabulous variation.
Described hollow glass microbead is that a kind of ball of hollow is Powdered, excellent performance, broad-spectrum Ultralight new inorganic non-metallic materials, and it will become the main flow of 21st century advanced composite material, and its particle diameter is between 2-125um; It has lightweight, volume is large, thermal conductivity is low, ultimate compression strength is high, oil absorbency is low, dispersiveness and good fluidity, chemical stability high, is the high quality filler of thermal insulation coatings, has improved widely the heat-insulating property of true mineral varnish.
Described Natvosol is to use highly pure gossypin as raw material, after alkaline purification, uses through professional etherificate and obtains, and be a kind of tensio-active agent of non-ionic type, there is good anti-splashing property, contribute to improve operating efficiency and saving color.
Described auxiliary agent is comprised of wetting dispersing agent, sanitas, membrane-forming agent, freeze proof stablizer.Sanitas refers to natural or synthetic chemical composition, can postpone coating and cause owing to affected by external factor the corruption that microorganism growth or chemical transformation cause; Can be phenylformic acid and salt thereof, phenylcarbinol, oxybenzene ester class, Sorbic Acid, chlorxylone etc.Wetting dispersing agent has surperficial parents' molecular structure, in interface direction, qualitative absorption occurs, and reduces the surface tension of liquid, and it act as fine-particle pigments and fillers dispersed in base-material; It can be mineral-type, organic and high score subclass, such as trisodium phosphate, tertiary sodium phosphate, silicate, alkyl aryl sulfonate, fatty acid amide derivant sulfuric ester, alkylphenol polyoxyethylene, polycarboxylate, poly-(methyl) acrylic acid derivative, polyether derivative etc.; Preferably polycarboxylate, is more preferably poly carboxylic acid sodium.Freeze proof stablizer can play the effect of frost protection and stable storing, can be propylene glycol, ethylene glycol etc., preferably propylene glycol.Membrane-forming agent claims again coalescing aid, can promote macromolecular compound plastic flow and recoverable deformation, improve coalescent performance, can make the material of coating film forming sclerosis within the scope of more extensive construction temperature, can be polyvinyl alcohol, sodium alginate, carbomer, xanthan gum etc., preferably polyethylene alcohol.
It is main body that the true mineral varnish of insulation of the present invention has adopted organosilicon crylic acid latex, hollow glass microbead and natural colour sand, through form paint film after dry, the ability with good weather resistance, anti-stain characteristic, chemical resistance and insulation, auxiliary agent add the over-all properties that can further improve coating.And the two be combined with of hollow glass microbead and natural colour sand, can effectively control the surface temperature of coating system, coating temperature-change resistance is excellent, make the ageing resistance of coating better simultaneously, and then play the effect of insulation, environmental protection and energy saving, improve the hot comfort of environment, can extend the life-span of coating simultaneously.
The present invention also provides the preparation method of the true mineral varnish of above-mentioned insulation, comprise the following steps: in mixing vessel, add tap water, under stirring, add Natvosol, until add auxiliary agent and stir after the abundant swelling of Natvosol, then limit stirring adds below organosilicon crylic acid latex, natural colour sand, hollow glass microbead and stirs.
Preferably, described mixing vessel, for joining paint can, stirs and adopts stirrer, and it is 25-30 minute that Natvosol adds the time of rear swelling; Adding churning time after organosilicon crylic acid latex, natural colour sand, hollow glass microbead is 25-30 minute; Mixing speed is 1000-1200 rpm.
Preferred, when adding tap water, add sanitas, after the abundant swelling of Natvosol, add wetting dispersing agent, freeze proof stablizer, membrane-forming agent.
The constructional method of the described true mineral varnish of insulation, comprises the following steps:
1, spraying seal coat: select lower kettle spray gun, pressure is 4-6kg/m 2, spraying twice, every all over interval 1 hour, the about 30um of thickness, under normal temperature dry 8 hours.
2, the true mineral varnish of spray coating heat preservation: select true mineral varnish spray gun, air-pressure controlling is at 5-7kg/m 2, the about 2-3mm of coat-thickness, certainly dry can sclerosis completely for 7 days.
Beneficial effect of the present invention has:
1, adopt the combination of organosilicon crylic acid latex, natural colour sand and hollow glass microbead, make final coating there is weathering resistance, resistance to staining property and temp. variation resistant, ageing-resistant equistability, and good heat insulating, color variation.
2, the preparation method of the true mineral varnish of insulation of the present invention is simple and easy, with low cost, and form of construction work is also simple and easy.
Embodiment
By specific embodiments of the invention given below and comparing embodiment, can further be well understood to the present invention, but they not limitation of the invention.The part not describing in detail in specific embodiment and comparing embodiment is to adopt prior art, known technology means and industry standard to obtain.
If do not specialize, the conventional means that the technique means adopting in embodiment is well known to those skilled in the art, the reagent adopting and product are also and can business obtain.The source of agents useful for same, trade(brand)name, to be necessary to list its moiety person, are all indicated when occurring first.
Reflectivity: U.S. Filmetrics, the F10-RT-UVX reflectance test instrument of Inc. company carries out precision measurement.
Resistance to coating temperature sex change: the many will CZ-A-150D in Taiwan can journey try constant temperature and humid test machine set temperature humidity and set test duration temperature-change resistance test condition and test.
Cohesive strength: the DeFelsko board drawing force tester of imported from America carries out precision measurement.
Artificial weathering ageing resistance: the Q-SUN-XE-3 type photo-stability testing case that U.S. Q=LAB company produces arranges light wave at 340nm, irradiance 0.51W/m 2, 63 ℃ of illumination temperatures, humidity is carried out continuity artificial weathering ageing resistance 80% and is tested 500h.
Each measuring technology index following (table 1):
Table 1
embodiment 1
Be incubated each component that true mineral varnish adopts following weight part: tap water 200 weight parts, preservative benzoic acid 1 weight part, Natvosol 5 weight parts, wetting dispersing agent poly carboxylic acid sodium 5 weight parts, antifreeze stablizer propylene glycol 15 weight parts, membrane-forming agent polyvinyl alcohol 8 weight parts, organosilicon crylic acid latex 150 weight parts, natural colour sand 450 weight parts, hollow glass microbead 150 weight parts.
Its preparation method, comprises the following steps:
Within joining paint can, drop into tap water, sanitas, with stirrer with 1000 rpms of stirrings of rotating speed, add while stirring Natvosol, until the abundant swelling of Natvosol, time is 25 minutes, then adds successively wetting dispersing agent, antifreeze stablizer, membrane-forming agent and stir with same rotating speed, then add organosilicon crylic acid latex while stirring, natural colour sand, hollow glass microbead stir, time is 25 minutes, can pack.The constructional method of the true mineral varnish of described insulation, comprises the following steps:
1, spraying seal coat: select lower kettle spray gun, pressure is 4kg/m 2, spraying twice, every all over interval 1 hour, the about 30um of thickness, under normal temperature dry 8 hours.
2, the true mineral varnish of spray coating heat preservation: select true mineral varnish spray gun, air-pressure controlling is at 4-7kg/m 2, the about 2mm of coat-thickness, certainly dry can sclerosis completely for 7 days.
embodiment 2
Be incubated each component that true mineral varnish adopts following weight part: tap water 220 weight parts, sanitas Sorbic Acid 1.5 weight parts, Natvosol 7 weight parts, wetting dispersing agent polyoxyethylene 6 weight parts, antifreeze stablizer ethylene glycol 18 weight parts, membrane-forming agent polyvinyl alcohol 10 weight parts, organosilicon crylic acid latex 180 weight parts, natural colour sand 480 weight parts, hollow glass microbead 180 weight parts.
Preparation method and constructional method are substantially the same manner as Example 1, difference while being preparation method stirrer rotating speed be 1100 rpms, Natvosol swelling time is 28 minutes, adding churning time after organosilicon crylic acid latex is 30 minutes.
embodiment 3
Be incubated each component that true mineral varnish adopts following weight part: tap water 250 weight parts, sanitas methyl hydroxybenzoate 2 weight parts, Natvosol 8 weight parts, wetting dispersing agent polyoxyethylene nonylphenol ether 7 weight parts, antifreeze stablizer propylene glycol 25 weight parts, membrane-forming agent sodium alginate 12 weight parts, organosilicon crylic acid latex 200 weight parts, natural colour sand 500 weight parts, hollow glass microbead 200 weight parts.
Preparation method and constructional method are substantially the same manner as Example 1, difference while being preparation method stirrer rotating speed be 1200 rpms, Natvosol swelling time is 30 minutes, adding churning time after organosilicon crylic acid latex is 30 minutes.
comparative example 1
Be incubated each component that true mineral varnish adopts following weight part: tap water 200 weight parts, preservative benzoic acid 1 weight part, Natvosol 5 weight parts, wetting dispersing agent poly carboxylic acid sodium 5 weight parts, antifreeze stablizer propylene glycol 15 weight parts, membrane-forming agent polyvinyl alcohol 8 weight parts, organosilicon crylic acid latex 150 weight parts, hollow glass microbead 600 weight parts.Preparation method is identical with constructional method and embodiment 1.
ratio is compared with 2
Be incubated each component that true mineral varnish adopts following weight part: tap water 200 weight parts, preservative benzoic acid 1 weight part, Natvosol 5 weight parts, wetting dispersing agent poly carboxylic acid sodium 5 weight parts, antifreeze stablizer propylene glycol 15 weight parts, membrane-forming agent polyvinyl alcohol 8 weight parts, organosilicon crylic acid latex 150 weight parts, natural colour sand 600 weight parts.Preparation method is identical with constructional method and embodiment 1.
comparative example 3
Be incubated each component that true mineral varnish adopts following weight part: tap water 200 weight parts, preservative benzoic acid 1 weight part, Natvosol 5 weight parts, wetting dispersing agent poly carboxylic acid sodium 5 weight parts, antifreeze stablizer propylene glycol 15 weight parts, membrane-forming agent polyvinyl alcohol 8 weight parts, organosilicon crylic acid latex 150 weight parts, natural colour sand 450 weight parts, pearlstone 150 weight parts.Preparation method is identical with constructional method and embodiment 1.
True mineral varnish to each embodiment and comparative example is tested, and the results of property obtaining is as follows:
Embodiment the performance test results following (table 2):
Table 2
Comparative example the performance test results following (table 3):
Table 3
Above disclosed is only the preferred embodiments of the present invention, certainly can not limit with this interest field of the present invention, and the equivalent variations of therefore doing according to the present patent application the scope of the claims, still belongs to the scope that the present invention is contained.

Claims (10)

1. the true mineral varnish of insulation, by mass fraction, is comprised of following component: organosilicon crylic acid latex 150-200 part, natural colour sand 450-500 part, hollow glass microbead 150-200 part, Natvosol 5-8 part, tap water 200-250 part, auxiliary agent 35-50 part.
2. the true mineral varnish of insulation according to claim 1, is characterized in that: described organosilicon crylic acid latex is the emulsion with nucleocapsid structure that organosilane monomer and acrylic monomer are polymerized.
3. the true mineral varnish of insulation according to claim 1, is characterized in that: described hollow glass microbead is that ball is Powdered, particle diameter is 2-125 μ m.
4. the true mineral varnish of insulation according to claim 1 and 2, is characterized in that: described natural colour sand is to be processed through the operation of selected, broken, pulverizing, classification, packing by marble or grouan.
5. the true mineral varnish of insulation according to claim 1 and 2, is characterized in that: described auxiliary agent is comprised of wetting dispersing agent, sanitas, membrane-forming agent, freeze proof stablizer.
6. prepare the method that is incubated true mineral varnish described in claim 1-4 any one for one kind, it is characterized in that: comprise the steps: to add tap water in mixing vessel, under stirring, add Natvosol, until add auxiliary agent and stir after the abundant swelling of Natvosol, then limit stirring adds below organosilicon crylic acid latex, natural colour sand, hollow glass microbead and stirs.
7. method according to claim 5, is characterized in that: described mixing vessel is for joining paint can; Stir and adopt stirrer to carry out.
8. method according to claim 5, is characterized in that: the time of Natvosol swelling is 25-30 minute; Adding churning time after organosilicon crylic acid latex, natural colour sand, hollow glass microbead is 25-30 minute.
9. method according to claim 5, is characterized in that: mixing speed is 1000-1200 rpm.
10. method according to claim 5, is characterized in that: when adding tap water, add sanitas, add wetting dispersing agent, freeze proof stablizer, membrane-forming agent after the abundant swelling of Natvosol.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104356810A (en) * 2014-11-21 2015-02-18 苏州大乘环保建材有限公司 Reflective thermal insulation real stone paint
CN104449135A (en) * 2014-11-21 2015-03-25 苏州大乘环保建材有限公司 Preparation method of reflective insulation type really stone paint
CN104496269A (en) * 2014-12-17 2015-04-08 亚士漆(上海)有限公司 Heat insulating real stone paint and preparation method thereof
CN104789074A (en) * 2015-05-06 2015-07-22 武汉德美涂料股份有限公司 Novel natural stone paint and preparation method thereof
CN104927541A (en) * 2015-06-23 2015-09-23 陈良伢 Reflecting heat-insulation type real stone paint and preparation technology thereof
CN105038373A (en) * 2015-08-31 2015-11-11 贵州耐尔福顺成建材有限公司 True stone paint and production method thereof
CN105219198A (en) * 2015-10-30 2016-01-06 广东筑龙涂料有限公司 A kind of heat-insulating, fire-preventing stone-like coating
CN105255290A (en) * 2015-11-27 2016-01-20 上海炫杰环保涂料有限公司 Heat insulation mineral varnish and preparation method thereof
CN105255292A (en) * 2015-09-15 2016-01-20 李茂英 Nanometer modified real stone paint base material
CN105400342A (en) * 2015-11-27 2016-03-16 宁波双人新材料有限公司 Functional really stone paint and preparation method thereof
CN105482026A (en) * 2016-01-06 2016-04-13 上海墨传新材料科技有限公司 Water-soluble acrylic resin spherical particles and preparation method thereof
CN105542599A (en) * 2016-01-05 2016-05-04 南宁太空节能科技有限公司 Heat preservation and heat insulation environment-friendly plastic spraying coating and preparation method thereof
CN105567021A (en) * 2015-04-16 2016-05-11 湖南省金海科技有限公司 Water-based cold-pigment multifunctional heat-insulating true stone paint for exterior wall and preparation method thereof
CN105820681A (en) * 2016-05-17 2016-08-03 杭州美多乐环保新材料有限公司 Reflective thermal-insulation real stone paint and preparation method thereof
CN105925102A (en) * 2016-05-11 2016-09-07 济宁赛德丽新材料有限公司 Stone paint mixed with glass beads and preparing method of stone paint
CN105949911A (en) * 2016-05-11 2016-09-21 济宁赛德丽新材料有限公司 Nano self-cleaning type stone-like coating and preparation method thereof
CN106519865A (en) * 2016-11-29 2017-03-22 安徽美琳建筑材料有限公司 Quick-dry stone-like coating special for interior architecture wall surfaces
CN109111803A (en) * 2018-06-25 2019-01-01 滁州麦斯特新型建材有限公司 A kind of natural real stone paint of color stable and preparation method thereof
CN109336455A (en) * 2018-09-06 2019-02-15 新华盛节能科技股份有限公司 A kind of colored cladding hollow ceramic microspheres material and preparation method thereof
CN112759985A (en) * 2021-01-27 2021-05-07 上海无想新材料科技有限公司 Colored sand coating and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102093798A (en) * 2009-12-14 2011-06-15 庄成才 Water-borne heat-insulating marble coating and preparation method thereof
WO2011154596A1 (en) * 2010-06-07 2011-12-15 Tikkurila Oyj Manufacturing of stone coating
CN102533038A (en) * 2011-12-19 2012-07-04 河南省德嘉丽科技开发有限公司 Natural stone paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102093798A (en) * 2009-12-14 2011-06-15 庄成才 Water-borne heat-insulating marble coating and preparation method thereof
WO2011154596A1 (en) * 2010-06-07 2011-12-15 Tikkurila Oyj Manufacturing of stone coating
CN102533038A (en) * 2011-12-19 2012-07-04 河南省德嘉丽科技开发有限公司 Natural stone paint

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
刘成楼: "保温隔热花岗岩涂料的研制", 《上海涂料》 *
姜佳丽: "《涂料配方设计》", 31 July 2012, 北京:化学工业出版社 *
曹同玉 等: "《聚合物乳液合成原理性能及应用》", 30 April 2007, 北京:化学工业出版社 *
陈泽森 等: "《水性建筑涂料生产技术》", 31 January 2007, 北京:中国纺织出版社 *

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CN104449135A (en) * 2014-11-21 2015-03-25 苏州大乘环保建材有限公司 Preparation method of reflective insulation type really stone paint
CN104356810B (en) * 2014-11-21 2016-09-21 苏州大乘环保建材有限公司 A kind of true mineral varnish of reflection heat-insulating type
CN104356810A (en) * 2014-11-21 2015-02-18 苏州大乘环保建材有限公司 Reflective thermal insulation real stone paint
CN104449135B (en) * 2014-11-21 2017-02-01 苏州大乘环保建材有限公司 Preparation method of reflective insulation type really stone paint
CN104496269A (en) * 2014-12-17 2015-04-08 亚士漆(上海)有限公司 Heat insulating real stone paint and preparation method thereof
CN105567021A (en) * 2015-04-16 2016-05-11 湖南省金海科技有限公司 Water-based cold-pigment multifunctional heat-insulating true stone paint for exterior wall and preparation method thereof
CN105567021B (en) * 2015-04-16 2017-12-26 湖南省金海科技有限公司 A kind of aqueous cold pigment multifunctional thermal-insulation exterior wall true stone paint and preparation method thereof
CN104789074A (en) * 2015-05-06 2015-07-22 武汉德美涂料股份有限公司 Novel natural stone paint and preparation method thereof
CN104927541A (en) * 2015-06-23 2015-09-23 陈良伢 Reflecting heat-insulation type real stone paint and preparation technology thereof
CN105038373A (en) * 2015-08-31 2015-11-11 贵州耐尔福顺成建材有限公司 True stone paint and production method thereof
CN105255292A (en) * 2015-09-15 2016-01-20 李茂英 Nanometer modified real stone paint base material
CN105219198A (en) * 2015-10-30 2016-01-06 广东筑龙涂料有限公司 A kind of heat-insulating, fire-preventing stone-like coating
CN105219198B (en) * 2015-10-30 2017-12-12 广东筑龙涂料有限公司 A kind of heat-insulating, fire-preventing stone-like coating
CN105400342A (en) * 2015-11-27 2016-03-16 宁波双人新材料有限公司 Functional really stone paint and preparation method thereof
CN105255290A (en) * 2015-11-27 2016-01-20 上海炫杰环保涂料有限公司 Heat insulation mineral varnish and preparation method thereof
CN105542599A (en) * 2016-01-05 2016-05-04 南宁太空节能科技有限公司 Heat preservation and heat insulation environment-friendly plastic spraying coating and preparation method thereof
CN105482026A (en) * 2016-01-06 2016-04-13 上海墨传新材料科技有限公司 Water-soluble acrylic resin spherical particles and preparation method thereof
CN105925102A (en) * 2016-05-11 2016-09-07 济宁赛德丽新材料有限公司 Stone paint mixed with glass beads and preparing method of stone paint
CN105949911A (en) * 2016-05-11 2016-09-21 济宁赛德丽新材料有限公司 Nano self-cleaning type stone-like coating and preparation method thereof
CN105925102B (en) * 2016-05-11 2018-07-06 山东赛德丽新材料股份有限公司 A kind of lacquer for blending glass microballoon and preparation method thereof
CN105820681A (en) * 2016-05-17 2016-08-03 杭州美多乐环保新材料有限公司 Reflective thermal-insulation real stone paint and preparation method thereof
CN106519865A (en) * 2016-11-29 2017-03-22 安徽美琳建筑材料有限公司 Quick-dry stone-like coating special for interior architecture wall surfaces
CN109111803A (en) * 2018-06-25 2019-01-01 滁州麦斯特新型建材有限公司 A kind of natural real stone paint of color stable and preparation method thereof
CN109336455A (en) * 2018-09-06 2019-02-15 新华盛节能科技股份有限公司 A kind of colored cladding hollow ceramic microspheres material and preparation method thereof
CN109336455B (en) * 2018-09-06 2021-10-26 新华盛节能科技股份有限公司 Colored coated hollow ceramic microsphere material and preparation method thereof
CN112759985A (en) * 2021-01-27 2021-05-07 上海无想新材料科技有限公司 Colored sand coating and preparation method and application thereof

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