CN108300274A - A kind of UV-curable waterborne anti-fingerprint paint and preparation method thereof - Google Patents
A kind of UV-curable waterborne anti-fingerprint paint and preparation method thereof Download PDFInfo
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- CN108300274A CN108300274A CN201710767455.XA CN201710767455A CN108300274A CN 108300274 A CN108300274 A CN 108300274A CN 201710767455 A CN201710767455 A CN 201710767455A CN 108300274 A CN108300274 A CN 108300274A
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- fingerprint
- curable waterborne
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
Abstract
The invention discloses a kind of UV-curable waterborne anti-fingerprint paints and preparation method thereof, belong to coating processing technique field.The coating, by percentage to the quality, component includes：Anti-pollution resin 12~22%；UV-curable waterborne oligomer 12~44%；UV-curable monomer 5~20%；Photoinitiator 1~5%；Levelling agent 0.05~0.2%；Wetting agent 0.05~0.2%；Coalescents 0~10%；Deionized water 20~69%.The present invention is based on fluorine-containing or siliceous anti-pollution resin and aquosity ultraviolet light oligomer, pass through certain preparation process, aquosity ultraviolet light (UV) curing fingerprint resistant coating obtained, using water as decentralized medium, have the characteristics that smell is low, nonflammable, VOC content is low, washable, and the succession UV paint solidification times are short, production efficiency is high, low power consumption and other advantages meet the requirement of environmentally protective laws and regulations；The coating obtained by the coating has many advantages, such as that anti-fingerprint excellent effect, persistence are strong.
Description
Technical field
The present invention relates to coating processing technique fields, and in particular to a kind of UV-curable waterborne anti-fingerprint paint and its system
Preparation Method.
Background technology
Nearly 20 years, 3C (computer Computer, communication Communication and consumer electronics product Consumer
Electronics) electronic product is grown rapidly at home, from daily luxury goods to daily necessities, then arrives daily consumables,
Dosage is increasing, and the competition in industry is also increasingly stronger.Consider from cost and performance synthesis, the shell of 3C Product is mostly using modeling
Gum base materials, corresponding painting effect also have received widespread attention, and beautiful appearance, comfortable feel and durable performance are got over
To get over the favor by consumers.Among these, due to the electronic products such as mobile phone, tablet computer be completely transformed into it is touch
Operation, fuselage and screen surface are contacted with finger for a long time, and fingerprint and sweat are easily adhered on its surface, are influenced apparent same
When can also slowly erosion surface coating, reduce its performance, so surface anti-fingerprint effect slowly become consumer it is needed for.
Currently, in coating industry, ultraviolet light (UV) is coating material solidified because its hardening time is short, and production efficiency is high, low energy consumption
Many advantages, such as and be widely applied very much, either it is domestic still in the world, annual output coating material solidified UV is all year by year
Increase.For thermal sensitivity plastic basis material, UV is coating material solidified only need UV illumination 1-5min can rapid curing film forming, behaviour
Work is easy, low energy consumption, without having to worry about base material heated problem on deformation.103073934 B of patent CN disclose a kind of for PMMA bases
The ultraviolet light curing fingerprint resistant coating of material, using the common of fluorin modified crylic acid esters resin and fluorine-silicon modified acrylic esters resin
Effect, obtains the anti-fingerprint effect of coating.103571314 B of patent CN use a kind of hyperbranched oligomer of fluorine richness, collocation
High functionality UV resins and UV monomers provide high rigidity anti-fingerprint coating for PET base material.101891991 B of patent CN use fluorine
Based on carbon resin, and ultra-low surface energy surface is further built using nano particle, to provide high rigidity anti-finger for steel plate
Line coating.
However, above-mentioned anti-fingerprint paint, still needs to a large amount of solvents, to obtain preferable coating application performance and apparent, to ring
All there is potential tremendous influence, and gradually increasing with people's environmental consciousness in border and construction personnel, laws and regulations it is gradual
Increase sternly, it is very urgent to develop really energy-saving and environment-friendly coating.The coating material solidified combination tradition UV curing technologies of aquosity ultraviolet light (UV)
The advantages of with water paint both techniques, using water as decentralized medium, with smell is low, nonflammable, VOC content is low, can water
The features such as washing, and the succession UV paint solidification times are short, production efficiency is high, and low power consumption and other advantages meet environmentally protective laws and regulations
Requirement.Therefore, how to improve UV-curable waterborne coatings coating is made to have anti-fingerprint effect is those skilled in the art
Problem to be solved.
Invention content
It is existing to overcome the purpose of the present invention is to provide a kind of energy-saving and environment-friendly paint with excellent anti-fingerprint effect
Anti-fingerprint paint tremendous influence caused by there are problems that a large amount of organic solvents to environment and construction personnel.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of UV-curable waterborne anti-fingerprint paint, by percentage to the quality, component includes：
Preferably, the anti-pollution resin be organosilicon light-cured resin, Organic fluoride light-cured resin, fluorocarbon resin,
At least one of fluorine silicon resin, nano modification resin.
Preferably, the UV-curable waterborne oligomer is aqueous polyurethane acrylate, waterborne polyester propylene
At least one in acid esters, aqueous acrylic modified acrylate, waterborne epoxy acrylate, waterborne, polycarbonate acrylate
Kind.
In view of comprehensive performance, more preferably, the UV-curable waterborne oligomer is watersoluble polyurethane acrylic acid
At least one of ester, waterborne, polycarbonate acrylate.
Preferably, the UV-curable monomer is trimethylolpropane trimethacrylate, three hydroxyl first of ethoxylation
Base propane triacrylate, propoxylation trimethylolpropane trimethacrylate, glycerol tri-acrylate, tripropylene glycol two
Acrylate, hexanediyl ester, pentaerythritol triacrylate, pentaerythritol tetraacrylate, neopentyl glycol dipropyl
At least one of olefin(e) acid ester, ethoxylated neopentylglycol diacrylate, 1,3 butyleneglycol diacrylate.
Preferably, the photoinitiator is water-soluble cracking type free radical photo-initiation, water-soluble hydrogen-abstraction freedom
At least one of base photoinitiator.
Preferably, the levelling agent is silicone levelling agent or fluorinated levelling agent.
Preferably, the wetting agent is organic silicon wetting agent or polyacrylate wetting agent.
Preferably, the coalescents are ethyl alcohol, ethylene glycol, propylene glycol, butanediol, diethylene glycol ether, diethyl
At least one of glycol butyl ether, diacetone alcohol, propylene glycol monomethyl ether, propylene-glycol ethyl ether, propandiol butyl ether.
Preferably, the UV-curable waterborne anti-fingerprint paint, by percentage to the quality, component includes：
Further preferably, the anti-pollution resin be the trade mark be UA-888 (middle mountain outstanding person thing reach at Fine Chemical Co., Ltd) or
Organosilicon light-cured resin, the UA-1020 of B-818/B-828/B-868 (Guangdong Boxing science and technology new material Science and Technology Ltd.)
The nano modification resin of (middle mountain outstanding person thing reaches Fine Chemical Co., Ltd), B-864 (the limited public affairs of Guangdong Boxing science and technology new material science and technology
Department) at least one of Organic fluoride light-cured resin；
The UV-curable waterborne oligomer is aqueous polyurethane acrylate UCECOATTM7210、
UCECOATTM7200, waterborne epoxy acrylate RS 7604 (Jiaxing sharp stone), (Jiaxing is sharp by waterborne polyester acrylate RS 7614
At least one of stone)；
The UV-curable monomer is trimethylolpropane trimethacrylate, ethoxylated trimethylolpropane 3 third
Olefin(e) acid ester, propoxylation trimethylolpropane trimethacrylate, glycerol tri-acrylate, tri (propylene glycol) diacrylate or
Hexanediyl ester；
The photoinitiator is 2- hydroxy-2-methyl -1- phenyl -1- acetone；
The levelling agent is BYK162 or BYK333；
The wetting agent is BYK346 or TEGO270；
The coalescents are propylene glycol monomethyl ether or diacetone alcohol.
The present invention also provides a kind of methods preparing the UV-curable waterborne anti-fingerprint paint, including following step
Suddenly：
(1) anti-pollution resin, UV-curable monomer, photoinitiator and coalescents are mixed, in 500~1000r/min
5~10min of lower stirring obtains once mixture to being uniformly mixed；
(2) under agitation, UV-curable waterborne oligomer is added into once mixture, in 500~1000r/
10~15min is stirred under min to being uniformly mixed, and deionized water, wetting agent, levelling agent is added, at 1000~3000r/min
Disperse 0.5~1h, filtering, discharging obtain the UV-curable waterborne anti-fingerprint paint.
The present invention also provides the construction methods of the UV-curable waterborne anti-fingerprint paint, including：By the coating
It is coated in substrate, to get anti-fingerprint coating after ultraviolet light cures.The cured condition of ultraviolet light is：Light intensity is 20mW/cm2,
Time is 1min.
Compared with prior art, the advantageous effect that the present invention has：
The present invention passes through certain preparation work based on fluorine-containing or siliceous anti-pollution resin and aquosity ultraviolet light oligomer
Skill, aquosity ultraviolet light (UV) curing fingerprint resistant coating obtained, in conjunction with traditional UV curing technologies and water paint both techniques
Advantage has the characteristics that smell is low, nonflammable, VOC content is low, washable using water as decentralized medium, and inherits UV coating
Hardening time is short, and production efficiency is high, and low power consumption and other advantages meet the requirement of environmentally protective laws and regulations.
The coating obtained by coating of the present invention has many advantages, such as that anti-fingerprint excellent effect, persistence are strong.
Specific implementation mode
With reference to embodiment, the invention will be further described.
Embodiment 1-5
Coating is carried out according to the formulation for coating material of table 1, specific preparation flow is as follows：
(1) anti-pollution resin, UV-curable monomer, photoinitiator and coalescents are mixed, in 500~1000r/min
5~10min of lower stirring obtains once mixture to being uniformly mixed；
(2) under agitation, UV-curable waterborne oligomer is added into once mixture, in 500~1000r/
10~15min is stirred under min to being uniformly mixed, and deionized water, wetting agent, levelling agent is added, at 1000~3000r/min
Disperse 0.5~1h, filtering, discharging obtain the UV-curable waterborne anti-fingerprint paint.
Table 1
Comparative example 1-3
Coating is carried out according to the formulation for coating material of table 2, preparation flow is the same as embodiment 1-5.
Table 2
Application examples
Coating prepared by above-described embodiment and comparative example sprays, on showering or roller coating plastic rubber substrate, is with light intensity
20mW/cm2Ultraviolet light curing 1min, obtain anti-fingerprint coating, properties of product are shown in Table 3.
Performance test methods are as follows：
1, adhesive force
Hundred lattice are drawn, with 600 adhesive tape tests of 3M 3 times.
2, pencil hardness
With Mitsubishi's pencil, tested at 750g.
3, fingerprint resistance energy
(1) one layer of vaseline is applied on the coating after curing, it is 90% to be placed on relative humidity, the environment that temperature is 50 DEG C
In, it is wiped afterwards with non-dust cloth for 24 hours, using the coating of uncoated vaseline as standard sample, the coating △ E values after test experiments, △ E<3
Then judge OK；
(2) it is write on coating with oil pen, is wiped with non-dust cloth, record can be by time of oil pen's trace wiped clean
Number, number>50 judge OK.
Table 3
Claims (10)
1. a kind of UV-curable waterborne anti-fingerprint paint, which is characterized in that by percentage to the quality, component includes：
2. UV-curable waterborne anti-fingerprint paint as described in claim 1, which is characterized in that the anti-pollution resin is to have
At least one of machine silicon light-cured resin, Organic fluoride light-cured resin, fluorocarbon resin, fluorine silicon resin, nano modification resin.
3. UV-curable waterborne anti-fingerprint paint as described in claim 1, which is characterized in that the aquosity ultraviolet light is solid
Change oligomer is aqueous polyurethane acrylate, waterborne polyester acrylate, aqueous acrylic modified acrylate, water-base epoxy
At least one of acrylate, waterborne, polycarbonate acrylate.
4. UV-curable waterborne anti-fingerprint paint as described in claim 1, which is characterized in that the ultraviolet light solidification is single
Body is trimethylolpropane trimethacrylate, ethoxylated trimethylolpropane triacrylate, propoxylation trihydroxy methyl third
Alkane triacrylate, glycerol tri-acrylate, tri (propylene glycol) diacrylate, hexanediyl ester, pentaerythrite
Triacrylate, pentaerythritol tetraacrylate, neopentylglycol diacrylate, ethoxylated neopentylglycol diacrylate,
At least one of 1,3 butyleneglycol diacrylate.
5. UV-curable waterborne anti-fingerprint paint as described in claim 1, which is characterized in that the photoinitiator is water
At least one of dissolubility cracking type free radical photo-initiation, water-soluble hydrogen-abstraction free radical photo-initiation.
6. UV-curable waterborne anti-fingerprint paint as described in claim 1, which is characterized in that the levelling agent is organic
Silicon class levelling agent or fluorinated levelling agent.
7. UV-curable waterborne anti-fingerprint paint as described in claim 1, which is characterized in that the wetting agent is organic
Silicon class wetting agent or polyacrylate wetting agent.
8. UV-curable waterborne anti-fingerprint paint as described in claim 1, which is characterized in that the coalescents are second
Alcohol, ethylene glycol, propylene glycol, butanediol, diethylene glycol ether, butyl, diacetone alcohol, propylene glycol monomethyl ether, propylene glycol
At least one of ether, propandiol butyl ether.
9. such as claim 1-8 any one of them UV-curable waterborne anti-fingerprint paints, which is characterized in that with quality percentage
Than meter, component includes：
10. such as the preparation method of claim 1-9 any one of them UV-curable waterborne anti-fingerprint paints, feature exists
In including the following steps：
(1) anti-pollution resin, UV-curable monomer, photoinitiator and coalescents are mixed, is stirred at 500~1000r/min
5~10min is mixed to being uniformly mixed, obtains once mixture；
(2) under agitation, UV-curable waterborne oligomer is added into once mixture, at 500~1000r/min
10~15min is stirred to being uniformly mixed, deionized water, wetting agent, levelling agent is added, disperses at 1000~3000r/min
0.5~1h, filtering obtain the UV-curable waterborne anti-fingerprint paint.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641455A (en) * | 2017-09-27 | 2018-01-30 | 芜湖春风新材料有限公司 | A kind of automotive upholstery anti-fingerprint UV coating, preparation method and applications |
| CN109294417A (en) * | 2018-09-28 | 2019-02-01 | 韶关市合众化工有限公司 | A kind of modified hydrophobic UV insulated paint of high rigidity of waterborne organic silicon |
| CN110003852A (en) * | 2019-04-18 | 2019-07-12 | 中山市安可玻璃防爆膜有限公司 | UV (ultraviolet) adhesive glue and preparation method thereof |
| CN110105877A (en) * | 2019-05-29 | 2019-08-09 | 无锡卡秀堡辉涂料有限公司 | Colored coating of a kind of easy clean ultraviolet light solidification of aqueous anti-fingerprint and preparation method thereof |
| CN111363400A (en) * | 2020-04-29 | 2020-07-03 | 无锡卡秀堡辉涂料有限公司 | Water-based one-coating baking-free silver ultraviolet curing coating and preparation method thereof |
| CN112625482A (en) * | 2020-12-25 | 2021-04-09 | 惠州市韵点新材料科技股份有限公司 | High-ductility UV (ultraviolet) curing water-based paint |
| CN112662307A (en) * | 2020-12-25 | 2021-04-16 | 惠州市韵点新材料科技股份有限公司 | UV-cured water-based vacuum sputtering coating |
| CN112795302A (en) * | 2021-01-14 | 2021-05-14 | 昆山三越油墨有限公司 | Water-based ultraviolet-curing antibacterial and anti-fouling material for touch surface and preparation method thereof |
| CN113045929A (en) * | 2021-03-20 | 2021-06-29 | 中山市中益油墨涂料有限公司 | Anti-fouling UV-LED offset printing ink and preparation method thereof |
| CN113817403A (en) * | 2021-08-16 | 2021-12-21 | 上海金力泰化工股份有限公司 | Water-based stain-resistant additive UV coating and preparation method and application thereof |
| CN114207062A (en) * | 2019-08-01 | 2022-03-18 | 阿克佐诺贝尔国际涂料股份有限公司 | UV-curable aqueous coating composition for easy-clean coatings |
| CN114599748A (en) * | 2019-10-15 | 2022-06-07 | 阿克佐诺贝尔国际涂料股份有限公司 | Water-based UV curable coating compositions for easy-clean coatings |
| CN114891435A (en) * | 2022-06-30 | 2022-08-12 | 湖南松井新材料股份有限公司 | Preparation method of water-based UV-cured wear-resistant anti-fouling matte coating and coating film |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641455B (en) * | 2017-09-27 | 2019-12-24 | 芜湖春风新材料有限公司 | Anti-fingerprint UV coating for automotive interior parts, and preparation method and application thereof |
| CN107641455A (en) * | 2017-09-27 | 2018-01-30 | 芜湖春风新材料有限公司 | A kind of automotive upholstery anti-fingerprint UV coating, preparation method and applications |
| CN109294417A (en) * | 2018-09-28 | 2019-02-01 | 韶关市合众化工有限公司 | A kind of modified hydrophobic UV insulated paint of high rigidity of waterborne organic silicon |
| CN110003852A (en) * | 2019-04-18 | 2019-07-12 | 中山市安可玻璃防爆膜有限公司 | UV (ultraviolet) adhesive glue and preparation method thereof |
| CN110105877A (en) * | 2019-05-29 | 2019-08-09 | 无锡卡秀堡辉涂料有限公司 | Colored coating of a kind of easy clean ultraviolet light solidification of aqueous anti-fingerprint and preparation method thereof |
| CN114207062A (en) * | 2019-08-01 | 2022-03-18 | 阿克佐诺贝尔国际涂料股份有限公司 | UV-curable aqueous coating composition for easy-clean coatings |
| US11920052B2 (en) | 2019-08-01 | 2024-03-05 | Akzo Nobel Coatings International B.V. | Waterborne, UV curable coating composition for easy-clean coatings |
| CN114207062B (en) * | 2019-08-01 | 2023-04-28 | 阿克佐诺贝尔国际涂料股份有限公司 | UV curable aqueous coating composition for easy-to-clean coatings |
| CN114599748A (en) * | 2019-10-15 | 2022-06-07 | 阿克佐诺贝尔国际涂料股份有限公司 | Water-based UV curable coating compositions for easy-clean coatings |
| CN114599748B (en) * | 2019-10-15 | 2023-09-15 | 阿克佐诺贝尔国际涂料股份有限公司 | Water-based UV curable coating composition for easy-to-clean coatings |
| CN111363400A (en) * | 2020-04-29 | 2020-07-03 | 无锡卡秀堡辉涂料有限公司 | Water-based one-coating baking-free silver ultraviolet curing coating and preparation method thereof |
| CN112662307A (en) * | 2020-12-25 | 2021-04-16 | 惠州市韵点新材料科技股份有限公司 | UV-cured water-based vacuum sputtering coating |
| CN112625482A (en) * | 2020-12-25 | 2021-04-09 | 惠州市韵点新材料科技股份有限公司 | High-ductility UV (ultraviolet) curing water-based paint |
| CN112795302A (en) * | 2021-01-14 | 2021-05-14 | 昆山三越油墨有限公司 | Water-based ultraviolet-curing antibacterial and anti-fouling material for touch surface and preparation method thereof |
| CN113045929A (en) * | 2021-03-20 | 2021-06-29 | 中山市中益油墨涂料有限公司 | Anti-fouling UV-LED offset printing ink and preparation method thereof |
| CN113817403A (en) * | 2021-08-16 | 2021-12-21 | 上海金力泰化工股份有限公司 | Water-based stain-resistant additive UV coating and preparation method and application thereof |
| CN114891435A (en) * | 2022-06-30 | 2022-08-12 | 湖南松井新材料股份有限公司 | Preparation method of water-based UV-cured wear-resistant anti-fouling matte coating and coating film |
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| CN108300274B (en) | 2020-08-25 |
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Effective date of registration: 20220909 Address after: Xinzhai Industrial Zone, Xiaoyue Town, Shangyu District, Shaoxing City, Zhejiang Province, 312300 Patentee after: ZHEJIANG UVCHEM SPECIAL COATINGS Co.,Ltd. Address before: 312369 Hangzhou Shangyu economic and Technological Development Zone, Shaoxing, Zhejiang Patentee before: ZHEJIANG YOUTAI NEW MATERIAL TECHNOLOGY CO.,LTD. |
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