CN101250340A - Ultraviolet light curing fingerprint resistant paint - Google Patents
Ultraviolet light curing fingerprint resistant paint Download PDFInfo
- Publication number
- CN101250340A CN101250340A CNA2008100272551A CN200810027255A CN101250340A CN 101250340 A CN101250340 A CN 101250340A CN A2008100272551 A CNA2008100272551 A CN A2008100272551A CN 200810027255 A CN200810027255 A CN 200810027255A CN 101250340 A CN101250340 A CN 101250340A
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- CN
- China
- Prior art keywords
- ultraviolet light
- resistant paint
- light curing
- urethane acrylate
- fingerprint resistant
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
The invention discloses ultraviolet light curing anti-fingerprint paint, which comprises components with percentage by weight of 5-25 wt% high function aliphatic polyurethane acrylic ester, 10-30 wt% acrylic ester modified by fluorine, 5-20 w% large molecular resin, 10-25 wt% trifunctionanal function aliphatic polyurethane acrylic ester, 5-15 wt% double function acrylic ester, 1-5 wt% photo initiator, 15-40 wt% diluent and 0.01-1 wt% auxiliary agent, wherein high function aliphatic polyurethane acrylic provides hardness and high abrasion resistance, acrylic ester modified by fluorine is formed by grafting fluorine monomer with acrylic ester. The anti-fingerprint paint can permanently reduce the surface tension of painting film, and eliminates the generation of fingerprints.
Description
Technical field
The present invention relates to a kind of ultraviolet-curing paint, relate in particular to the coating of the anti-fingerprint protection in digital product surface.
Background technology
Portable type electronic product has become fast-moving consumer goods, more and more becomes the part of people's life, and is also more and more higher to appearance requirement.Mobile phone,, portable type electronic products such as laptop computer, MP3, digital camera, often need catch and touch, shell is as bright as a sixpence after application, in case be stained with fingerprint, hand perspiration, body wet goods spot then be difficult to remove clean, has influenced the attractive in appearance of product,
Chinese patent CN CN1778851 be the anti-fingerprint coating in a kind of surface it comprise: one is formed at hydrophobic nano material coating, oleophobic property nano-material coating or super two thin nano-material coating of substrate surface to be coated.Wherein, this hydrophobic nano material coating comprises polymer nanofiber, organosilicon nano coating and super hydrophobic material, the super two thin nano materials of preferred employing.In addition, the thickness of this hydrophobic nano material coating, oleophobic property nano-material coating or super two thin nano-material coatings is below 1 micron, is preferably in 0.1～0.5 micrometer range.The present invention does not contain heavy metal chromium, do not need through acid or alkaline purification, and is favourable to protection environment and maintenance HUMAN HEALTH,
Summary of the invention
The invention provides the problem that another solves the anti-fingerprint of digital product surface energy.
The technical solution adopted in the present invention is: a kind of ultraviolet light curing fingerprint resistant paint, and its weight percent consists of: high official's energy aliphatic urethane acrylate 5～25wt%; Fluorin modified crylic acid ester 10～30wt%, macromolecular resin 5～20wt%; Trifunctional aliphatic urethane acrylate 10～25wt%; Two functional acrylates, 5～15wt%; Light trigger 1～5wt%; Thinner 15～40wt%; Auxiliary agent 0.01～1wt%.
Further: in the above-mentioned ultraviolet light curing fingerprint resistant paint, described light trigger is one or more in phenyl-phosphonite diethyl ester, benzophenone, α monohydroxy isopropyl benzene ketone, the α monohydroxy phenylcyclohexane ketone, and these light triggers have higher light sensitivity and thermostability; Described thinner is one or more in hexanediyl ester, neopentyl glycol diacrylate enzyme, the Viscoat 295, auxiliary agent commonly used has auxiliary agents such as stopper, defoamer, flow agent and color stuffing, their main effect is to improve coating property, increase the UV photosensitive perception, reduce difficulty of construction.
Above-mentioned ultraviolet light curing fingerprint resistant paint, preferred weight percent prescription consists of: high official's energy aliphatic urethane acrylate 10～20wt%, fluorin modified crylic acid ester 18～28wt%, macromolecular resin 8～18wt%, trifunctional aliphatic urethane acrylate 15～20wt%, two functional acrylates, 7～12wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%.
The plastic shell that above-mentioned ultraviolet light curing fingerprint resistant paint is applied to portable type electronic products such as mobile phone, laptop computer, MP3, digital camera is decorated protection.Described high official can provide hardness and high abrasion by aliphatic urethane acrylate; The fluorin modified crylic acid ester is that fluorine monomer and acrylic ester grafted reaction form, and can forever reduce film coated surface tension force, eliminates fingerprint and produces.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Embodiment
Following examples are that ultraviolet light curing fingerprint resistant paint is preferably filled a prescription; these prescriptions are the indefiniteness embodiment; it just is used to specify the present invention, and those skilled in the art can be protection scope of the present invention according to thinking of the present invention and the prescription that the proportioning of selecting materials filters out fully.
Embodiment 1
A kind of ultraviolet light curing fingerprint resistant paint, its weight percent consists of: high official's energy aliphatic urethane acrylate 20wt%, fluorin modified crylic acid ester 28wt%, macromolecular resin 8wt%, trifunctional aliphatic urethane acrylate 15wt%, two functional acrylate 7wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%, in this ultraviolet light curing fingerprint resistant paint, described light trigger is the phenyl-phosphonite diethyl ester, thinner is a hexanediyl ester, adds usual auxiliaries.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Embodiment 2
A kind of ultraviolet light curing fingerprint resistant paint, its weight percent consists of: high official's energy aliphatic urethane acrylate 12wt%, fluorin modified crylic acid ester 20wt%, macromolecular resin 10wt%, trifunctional aliphatic urethane acrylate 16wt%, two functional acrylate 8wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%, in this ultraviolet light curing fingerprint resistant paint, light trigger is a benzophenone, thinner is a neopentyl glycol diacrylate enzyme, adds usual auxiliaries.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Embodiment 3
A kind of ultraviolet light curing fingerprint resistant paint, its weight percent consists of: high official's energy aliphatic urethane acrylate 14wt%, fluorin modified crylic acid ester 22wt%, macromolecular resin 12wt%, trifunctional aliphatic urethane acrylate 17wt%, two functional acrylate 9wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%, in this ultraviolet light curing fingerprint resistant paint, light trigger is a α monohydroxy isopropyl benzene ketone, thinner is a Viscoat 295, adds usual auxiliaries.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Embodiment 4
A kind of ultraviolet light curing fingerprint resistant paint, its weight percent consists of: high official's energy aliphatic urethane acrylate 16wt%, fluorin modified crylic acid ester 22wt%, macromolecular resin 12wt%, trifunctional aliphatic urethane acrylate 17wt%, two functional acrylate 9wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%, in this ultraviolet light curing fingerprint resistant paint, light trigger is a phenyl-phosphonite, thinner is a hexanediyl ester, adds usual auxiliaries.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Embodiment 5
A kind of ultraviolet light curing fingerprint resistant paint, its weight percent consists of: high official's energy aliphatic urethane acrylate 17wt%, fluorin modified crylic acid ester 25wt%, macromolecular resin 14wt%, trifunctional aliphatic urethane acrylate 18wt%, two functional acrylate 9wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%, in this ultraviolet light curing fingerprint resistant paint, light trigger is the phenyl-phosphonite diethyl ester, thinner is a hexanediyl ester, adds usual auxiliaries.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Embodiment 6
A kind of ultraviolet light curing fingerprint resistant paint, its weight percent consists of: high official's energy aliphatic urethane acrylate 8wt%, fluorin modified crylic acid ester 20wt%, macromolecular resin 12wt%, trifunctional aliphatic urethane acrylate 17wt%, two functional acrylate 10wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%, in ultraviolet light curing fingerprint resistant paint, light trigger is the phenyl-phosphonite diethyl ester, thinner is a hexanediyl ester, adds usual auxiliaries.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Embodiment 7
A kind of ultraviolet light curing fingerprint resistant paint, its weight percent consists of: high official's energy aliphatic urethane acrylate 20wt%, fluorin modified crylic acid ester 11wt%, macromolecular resin 10wt%, trifunctional aliphatic urethane acrylate 12wt%, two functional acrylate 11wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%, in this ultraviolet light curing fingerprint resistant paint, light trigger is the phenyl-phosphonite diethyl ester, thinner is a hexanediyl ester, adds usual auxiliaries.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Embodiment 8
A kind of ultraviolet light curing fingerprint resistant paint, its weight percent consists of: high official's energy aliphatic urethane acrylate 20wt%, fluorin modified crylic acid ester 22wt%, macromolecular resin 6wt%, trifunctional aliphatic urethane acrylate 12wt%, two functional acrylate 12wt%, light trigger 2～4wt%, thinner 20～38wt%, auxiliary agent 0.1～0.8wt%, in this ultraviolet light curing fingerprint resistant paint, light trigger is the phenyl-phosphonite diethyl ester, thinner is a hexanediyl ester, adds usual auxiliaries.
The plastic shell of the portable type electronic product of handling with above-mentioned ultraviolet light curing fingerprint resistant paint has the following advantages the plastic shell lamp:
1, You Yi anti-fingerprint, surperficial bond angle reaches more than 130;
2, excellent abrasive, the wear-resisting test of RCA reaches more than 800 times;
3, hardness is good, reaches more than the pencil hardness 2H.
Claims (3)
1, a kind of ultraviolet light curing fingerprint resistant paint, weight percent consists of: high official's energy aliphatic urethane acrylate 5～25wt%, fluorin modified crylic acid ester 10～30wt%, macromolecular resin 5～20wt%, trifunctional aliphatic urethane acrylate 10～25wt%, two functional acrylates, 5～15wt%, light trigger 1～5wt%, thinner 15～40wt%, auxiliary agent 0.01～1wt%.
2, ultraviolet light curing fingerprint resistant paint as claimed in claim 1 is characterized in that: described light trigger is one or more in phenyl-phosphonite diethyl ester, benzophenone, α monohydroxy isopropyl benzene ketone, the α monohydroxy phenylcyclohexane ketone;
Described thinner is one or more in hexanediyl ester, neopentyl glycol diacrylate enzyme, the Viscoat 295.
3, ultraviolet light curing fingerprint resistant paint as claimed in claim 2, weight percent consists of: high official's energy aliphatic urethane acrylate 5～25wt%, fluorin modified crylic acid ester 10～30wt%, macromolecular resin 5～20wt%, trifunctional aliphatic urethane acrylate 10～25wt%, two functional acrylates, 5～15wt%, light trigger 1～5wt%, thinner 15～40wt%, auxiliary agent 0.01～1wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100272551A CN101250340A (en) | 2008-04-03 | 2008-04-03 | Ultraviolet light curing fingerprint resistant paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100272551A CN101250340A (en) | 2008-04-03 | 2008-04-03 | Ultraviolet light curing fingerprint resistant paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101250340A true CN101250340A (en) | 2008-08-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008100272551A Pending CN101250340A (en) | 2008-04-03 | 2008-04-03 | Ultraviolet light curing fingerprint resistant paint |
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|---|---|
| CN (1) | CN101250340A (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634267A (en) * | 2012-04-12 | 2012-08-15 | 番禺南沙殷田化工有限公司 | Antifouling and anti-fingerprint coating composite capable of being applied to touch screen panel and preparation method of antifouling and anti-fingerprint coating |
| CN103073934A (en) * | 2012-12-28 | 2013-05-01 | 上海维凯化学品有限公司 | Ultraviolet curing anti-fingerprint coating for acrylic and composite material base material thereof |
| CN103540256A (en) * | 2013-09-27 | 2014-01-29 | 上海维凯化学品有限公司 | Ultraviolet-curing high-hardness fingerprint-resistant coating for PMMA (Polymethyl Methacrylate) and composite base material of PMMA |
| CN103540255A (en) * | 2013-09-27 | 2014-01-29 | 上海维凯化学品有限公司 | Ultraviolet curable anti-fingerprint coating composition with printability |
| CN103571314A (en) * | 2013-09-27 | 2014-02-12 | 上海维凯化学品有限公司 | Ultraviolet curing high-hardness anti-fingerprint coating composition for polyethylene glycol terephthalate (PET) base material |
| CN104893542A (en) * | 2015-05-26 | 2015-09-09 | 深圳市中联讯科技有限公司 | Anti-fingerprint coating and spraying method thereof |
| CN105623477A (en) * | 2016-03-17 | 2016-06-01 | 柳州市凯佰化工有限公司 | Anti-fingerprint ultraviolet curing high-gloss varnish |
| CN105907287A (en) * | 2016-05-16 | 2016-08-31 | 四川龙华光电薄膜股份有限公司 | Anti-ultraviolet anti-glare anti-fingerprint hardness-increasing coating liquid composition, coating and preparation method of coating |
| CN107118684A (en) * | 2017-06-13 | 2017-09-01 | 深圳市美丽华油墨涂料有限公司 | A kind of coating material solidified and preparation method thereof the applications of anti-soil type UV |
| CN107254207A (en) * | 2017-06-19 | 2017-10-17 | 北京航空航天大学 | A kind of ultraviolet light solidification super-hydrophobic transparent wear-resistant coating and preparation method thereof |
| CN107974153A (en) * | 2017-12-12 | 2018-05-01 | 深圳雅联实业有限公司 | A kind of high temperature resistant dumb light UV coating |
| CN108300274A (en) * | 2017-08-31 | 2018-07-20 | 浙江佑泰新材料科技有限公司 | A kind of UV-curable waterborne anti-fingerprint paint and preparation method thereof |
| CN108384438A (en) * | 2018-03-14 | 2018-08-10 | 湖南宏泰新材料有限公司 | A kind of resistance to steel wool anti-fingerprint nanometer UV coating of anodic oxidation |
| CN108774456A (en) * | 2018-06-28 | 2018-11-09 | 南昌航空大学 | A kind of preparation method of photocuring rare-earth europium modified rosin acid composite polymer material |
| CN108977039A (en) * | 2018-08-07 | 2018-12-11 | 太仓佩琦涂料有限公司 | dual cure UV varnish |
| CN109836992A (en) * | 2019-01-28 | 2019-06-04 | 宁波富纳新材料科技有限公司 | A kind of ultraviolet curing type is for antifouling hardening lower shrinkage coating of metal base and preparation method thereof |
| CN110434038A (en) * | 2019-08-03 | 2019-11-12 | 协荣精密器件(东莞)有限公司 | A kind of coating process of mobile phone glass dorsal shield |
| CN112480807A (en) * | 2020-11-10 | 2021-03-12 | 江苏理想光学科技有限公司 | Coating liquid capable of forming hardened layer through post UV curing and formable hardened film |
-
2008
- 2008-04-03 CN CNA2008100272551A patent/CN101250340A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634267A (en) * | 2012-04-12 | 2012-08-15 | 番禺南沙殷田化工有限公司 | Antifouling and anti-fingerprint coating composite capable of being applied to touch screen panel and preparation method of antifouling and anti-fingerprint coating |
| CN103073934A (en) * | 2012-12-28 | 2013-05-01 | 上海维凯化学品有限公司 | Ultraviolet curing anti-fingerprint coating for acrylic and composite material base material thereof |
| CN103073934B (en) * | 2012-12-28 | 2015-07-22 | 上海维凯光电新材料有限公司 | Ultraviolet curing anti-fingerprint coating for acrylic and composite material base material thereof |
| CN103540256A (en) * | 2013-09-27 | 2014-01-29 | 上海维凯化学品有限公司 | Ultraviolet-curing high-hardness fingerprint-resistant coating for PMMA (Polymethyl Methacrylate) and composite base material of PMMA |
| CN103540255A (en) * | 2013-09-27 | 2014-01-29 | 上海维凯化学品有限公司 | Ultraviolet curable anti-fingerprint coating composition with printability |
| CN103571314A (en) * | 2013-09-27 | 2014-02-12 | 上海维凯化学品有限公司 | Ultraviolet curing high-hardness anti-fingerprint coating composition for polyethylene glycol terephthalate (PET) base material |
| CN103540255B (en) * | 2013-09-27 | 2016-03-16 | 上海维凯光电新材料有限公司 | There is the ultraviolet light curing fingerprint resistant coating composition of impressionability energy |
| CN103540256B (en) * | 2013-09-27 | 2016-04-13 | 上海维凯光电新材料有限公司 | The anti-fingerprint coating of ultraviolet light polymerization high rigidity of acrylic and composite material base thereof |
| CN104893542A (en) * | 2015-05-26 | 2015-09-09 | 深圳市中联讯科技有限公司 | Anti-fingerprint coating and spraying method thereof |
| CN105623477A (en) * | 2016-03-17 | 2016-06-01 | 柳州市凯佰化工有限公司 | Anti-fingerprint ultraviolet curing high-gloss varnish |
| CN105907287A (en) * | 2016-05-16 | 2016-08-31 | 四川龙华光电薄膜股份有限公司 | Anti-ultraviolet anti-glare anti-fingerprint hardness-increasing coating liquid composition, coating and preparation method of coating |
| CN107118684A (en) * | 2017-06-13 | 2017-09-01 | 深圳市美丽华油墨涂料有限公司 | A kind of coating material solidified and preparation method thereof the applications of anti-soil type UV |
| CN107254207A (en) * | 2017-06-19 | 2017-10-17 | 北京航空航天大学 | A kind of ultraviolet light solidification super-hydrophobic transparent wear-resistant coating and preparation method thereof |
| CN107254207B (en) * | 2017-06-19 | 2019-07-05 | 北京航空航天大学 | A kind of ultraviolet light solidification super-hydrophobic transparent wear-resistant coating and preparation method thereof |
| CN108300274A (en) * | 2017-08-31 | 2018-07-20 | 浙江佑泰新材料科技有限公司 | A kind of UV-curable waterborne anti-fingerprint paint and preparation method thereof |
| CN108300274B (en) * | 2017-08-31 | 2020-08-25 | 浙江佑泰新材料科技有限公司 | Water-based ultraviolet-curing anti-fingerprint coating and preparation method thereof |
| CN107974153A (en) * | 2017-12-12 | 2018-05-01 | 深圳雅联实业有限公司 | A kind of high temperature resistant dumb light UV coating |
| CN108384438A (en) * | 2018-03-14 | 2018-08-10 | 湖南宏泰新材料有限公司 | A kind of resistance to steel wool anti-fingerprint nanometer UV coating of anodic oxidation |
| CN108774456A (en) * | 2018-06-28 | 2018-11-09 | 南昌航空大学 | A kind of preparation method of photocuring rare-earth europium modified rosin acid composite polymer material |
| CN108977039A (en) * | 2018-08-07 | 2018-12-11 | 太仓佩琦涂料有限公司 | dual cure UV varnish |
| CN109836992A (en) * | 2019-01-28 | 2019-06-04 | 宁波富纳新材料科技有限公司 | A kind of ultraviolet curing type is for antifouling hardening lower shrinkage coating of metal base and preparation method thereof |
| CN110434038A (en) * | 2019-08-03 | 2019-11-12 | 协荣精密器件(东莞)有限公司 | A kind of coating process of mobile phone glass dorsal shield |
| CN110434038B (en) * | 2019-08-03 | 2022-03-22 | 协荣精密器件(东莞)有限公司 | Coating process of mobile phone glass back shell |
| CN112480807A (en) * | 2020-11-10 | 2021-03-12 | 江苏理想光学科技有限公司 | Coating liquid capable of forming hardened layer through post UV curing and formable hardened film |
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Open date: 20080827 |