CN110003852A - UV (ultraviolet) adhesive glue and preparation method thereof - Google Patents
UV (ultraviolet) adhesive glue and preparation method thereof Download PDFInfo
- Publication number
- CN110003852A CN110003852A CN201910311370.XA CN201910311370A CN110003852A CN 110003852 A CN110003852 A CN 110003852A CN 201910311370 A CN201910311370 A CN 201910311370A CN 110003852 A CN110003852 A CN 110003852A
- Authority
- CN
- China
- Prior art keywords
- parts
- weight
- glue
- mixture
- auxiliary agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003292 glue Substances 0.000 title claims abstract description 26
- 239000000853 adhesive Substances 0.000 title abstract description 3
- 230000001070 adhesive effect Effects 0.000 title abstract description 3
- 238000002360 preparation method Methods 0.000 title description 7
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 239000003999 initiator Substances 0.000 claims abstract description 17
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 238000000016 photochemical curing Methods 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 abstract description 22
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000009776 industrial production Methods 0.000 abstract description 3
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 238000012682 free radical photopolymerization Methods 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920006942 ABS/PC Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
- C09J201/02—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
Abstract
The invention discloses UV (ultraviolet) adhesive glue which comprises the following raw materials in parts by weight: 5-80 parts of at least one oligomer capable of free radical photopolymerization; and 5-80 parts of a light-curing monomer; 0.1-20 parts of a mixture of various free radical initiators, and 0-10 parts of an auxiliary agent. Compared with common glue, the glue has the advantages that: 1. environmental protection, and the uv glue is used as solvent-free, realizes the zero release of industrial production. 2. Energy is saved, and a low-energy LED cold light source is used for solidification. 3. The performance is higher, and the viscidity is very good.
Description
Technical field
The present invention relates to a kind of UV to paste glue and preparation method thereof.
Background technique
Glue of the existing use on plastic basis material is usually acrylic glue, and acrylic glue is solvent type acrylic glue
Adhesive is used in the materials such as PS/PMMA/ABS/PC respectively, is mainly used in plastic toy, glues between plastic cement handicraft etc.
It connects, there is excellent followability；Preliminary bonding is quickly, widely used.Then existing acrylic glue still has the following deficiencies:
1. can not achieve industrial production zero-emission, it is unfavorable for environmental protection；The energy consumed when 2. solidifying is high, not energy-efficient；3. being wanted for bonding
High plastic products are sought, peeling force is still too low.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of environmental protection and energy saving, performance height, also very high UV pastes peeling force
Glue and preparation method thereof.
In order to solve the above technical problems, the present invention adopts the following technical scheme:
A kind of UV stickup glue, composition includes the raw material of following parts by weight: it is low at least can to carry out radical photopolymerization containing one kind
5-80 parts of polymers；5-80 parts of photo-curing monomer of radical photopolymerization can be at least carried out containing one kind；A variety of radical initiators are mixed
0.1 ~ 20 part of object is closed, also includes the auxiliary agent that parts by weight are 0 ~ 10 part in component.
Further, composition includes the raw material of following parts by weight: 80 parts of light-cured resin are gathered with that can carry out free radical light
5 parts of the photo-curing monomer of conjunction；0.1 part of a variety of radical initiator mixtures also include that parts by weight are 1 part and help in component
Agent.Further, composition includes the raw material of following parts by weight: the photocuring list of radical photopolymerization can be at least carried out containing one kind
40 parts of body；10 parts of a variety of radical initiator mixtures also include the auxiliary agent that parts by weight are 5 parts in component.
Further, composition includes the raw material of following parts by weight: at least containing one kind can carry out 80 parts of light-cured resin and
It can carry out 5 parts of photo-curing monomer of radical photopolymerization；0.1 part of a variety of radical initiator mixtures also include in component
The auxiliary agent that parts by weight are 1 part.
Further, a kind of UV pastes the production method of glue, comprising the following steps:
1) light-cured resin and photo polymerization monomer is uniform, form mixture；
2) radical initiator and auxiliary agent are added to the mixture in step 1；
3) mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Beneficial effects of the present invention are that compare existing acrylic glue advantageous: 1, environmentally friendly, uv glue uses as without molten
Industrial production zero-emission is realized in agent.2, energy saving, solidified using low energy LED.3, performance is higher, and peeling force is very high.
Specific embodiment
Embodiment 1:
A kind of UV stickup glue, composition includes the raw material of following parts by weight: at least can carry out radical photopolymerization containing one kind
80 parts of photo-curing monomer；20 parts of a variety of radical initiator mixtures also include the auxiliary agent that parts by weight are 10 parts in component.Its
Preparation method includes the following steps:
Step 1: by 5 parts of light-cured resin and 80 parts of uniform stirrings of photo polymerization monomer, mixture is formed；Step 2: will be a variety of
20 parts and 10 parts of auxiliary agent mixtures being added in step 1 of radical initiator mixture are stirred.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Embodiment 2:
A kind of UV stickup glue, composition includes the raw material of following parts by weight: can carry out 80 parts of radical photopolymerization oligomer；With
40 parts of photo-curing monomer of radical photopolymerization can be at least carried out containing one kind；10 parts of a variety of radical initiator mixtures, component
In also include parts by weight be 5 parts of auxiliary agent.Preparation method includes the following steps:
Step 1: by 40 parts of light-cured resin and 40 parts of uniform stirrings of photo polymerization monomer, mixture is formed；Step 2: will be a variety of
10 parts and 5 parts of auxiliary agent mixtures being added in step 1 of radical initiator mixture are stirred.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Embodiment 3:
A kind of UV stickup glue, composition includes the raw material of following parts by weight: it is low at least can to carry out radical photopolymerization containing one kind
80 parts of polymers and it can carry out 5 parts of photo-curing monomer of radical photopolymerization；0.1 part of a variety of radical initiator mixtures, component
In also include parts by weight be 1 part of auxiliary agent.Preparation method includes the following steps:
Step 1: by 80 parts of light-cured resin and 5 parts of uniform stirrings of photo polymerization monomer, mixture is formed；Step 2: will be a variety of
0.1 part and 1 part of auxiliary agent mixture being added in step 1 of radical initiator mixture is stirred.
Step 3: mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Above-described embodiment one is carried out peeling force experiment by applicant to obtain: peeling force can be transferred to 5000kgf or more；
Zero-emission, power saving 50%: general solidification energy consumption 500-600kw/h now only uses 200-300kw/h.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work, should be covered by the scope of protection of the present invention.
Claims (5)
1. a kind of UV pastes glue, it is characterised in that: it forms the raw material including following parts by weight: can at least be carried out certainly containing one kind
By 5-80 parts of base photopolymerization oligomer；5-80 parts of photo-curing monomer of radical photopolymerization can be at least carried out containing one kind；It is a variety of from
It also include the auxiliary agent that parts by weight are 0 ~ 10 part by 0.1 ~ 20 part of base initiator mixture, in component.
2. a kind of UV as described in claim 1 pastes glue, it is characterised in that: it forms the raw material including following parts by weight:
It can carry out 80 parts of radical photopolymerization oligomer；5 parts of photo-curing monomer of radical photopolymerization can be at least carried out containing one kind；From
20 parts of a variety of radical initiator mixtures also include the auxiliary agent that parts by weight are 10 parts in component.
3. a kind of UV as described in claim 1 pastes glue, it is characterised in that: it forms the raw material including following parts by weight:
It can carry out 80 parts of radical photopolymerization oligomer；40 parts of photo-curing monomer of radical photopolymerization can be at least carried out containing one kind；
10 parts of a variety of radical initiator mixtures also include the auxiliary agent that parts by weight are 5 parts in component.
4. a kind of UV as described in claim 1 pastes glue, it is characterised in that: it forms the raw material including following parts by weight:
At least containing a kind of 5 parts of photo-curing monomer for can carrying out 80 parts of light-cured resin and radical photopolymerization being carried out；A variety of free radicals
0.1 part of initiator mixture, also include the auxiliary agent that parts by weight are 1 part in component.
5. the production method that a kind of UV as described in claim 1 pastes glue, which comprises the following steps:
1) light-cured resin and photo polymerization monomer is uniform, form mixture；
2) radical initiator auxiliary agent is added to the mixture in step 1；
3) mixture middling speed is dispersed 2 hours in step 2, and filtering obtains inorganic agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910311370.XA CN110003852A (en) | 2019-04-18 | 2019-04-18 | UV (ultraviolet) adhesive glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910311370.XA CN110003852A (en) | 2019-04-18 | 2019-04-18 | UV (ultraviolet) adhesive glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110003852A true CN110003852A (en) | 2019-07-12 |
Family
ID=67172707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910311370.XA Pending CN110003852A (en) | 2019-04-18 | 2019-04-18 | UV (ultraviolet) adhesive glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110003852A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105308082A (en) * | 2013-06-06 | 2016-02-03 | 迪睿合株式会社 | Photocurable resin composition and image display device production method |
| CN108047963A (en) * | 2017-12-27 | 2018-05-18 | 张家港康得新光电材料有限公司 | Photocuring glue |
| CN108300274A (en) * | 2017-08-31 | 2018-07-20 | 浙江佑泰新材料科技有限公司 | A kind of UV-curable waterborne anti-fingerprint paint and preparation method thereof |
-
2019
- 2019-04-18 CN CN201910311370.XA patent/CN110003852A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105308082A (en) * | 2013-06-06 | 2016-02-03 | 迪睿合株式会社 | Photocurable resin composition and image display device production method |
| CN108300274A (en) * | 2017-08-31 | 2018-07-20 | 浙江佑泰新材料科技有限公司 | A kind of UV-curable waterborne anti-fingerprint paint and preparation method thereof |
| CN108047963A (en) * | 2017-12-27 | 2018-05-18 | 张家港康得新光电材料有限公司 | Photocuring glue |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 528000 card 2, building B, 166 Weimin Road, Dongsheng Town, Zhongshan City, Guangdong Province Applicant after: Guangdong Anke Technology Co.,Ltd. Address before: 528000 card 2, building B, 166 Weimin Road, Dongsheng Town, Zhongshan City, Guangdong Province Applicant before: ZHONGSHAN ANKE GLASS BURSTING DISK Co.,Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190712 |