CN104530991B - A kind of aqueous photo-curing binding agent and the application in glass-cutting is processed thereof - Google Patents
A kind of aqueous photo-curing binding agent and the application in glass-cutting is processed thereof Download PDFInfo
- Publication number
- CN104530991B CN104530991B CN201410817519.9A CN201410817519A CN104530991B CN 104530991 B CN104530991 B CN 104530991B CN 201410817519 A CN201410817519 A CN 201410817519A CN 104530991 B CN104530991 B CN 104530991B
- Authority
- CN
- China
- Prior art keywords
- glass
- binding agent
- curing
- methyl
- aqueous photo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
Abstract
The present invention relates to a kind of aqueous photo-curing binding agent and the application in glass-cutting is processed thereof.Described aqueous photo-curing binding agent in parts by mass, including the water-soluble resins of 65 75 parts, 10 30 parts of water-soluble polymerizable monofunctional monomer, 5 15 parts of water-soluble polymerizable bifunctionality monomers, 12 20 parts of water solublity bifunctionality monomeric oligomeric things, the light trigger of 15 parts, 15 parts of foaming agent, auxiliary agents of 15 parts.Compared with prior art, aqueous photo-curing binding agent of the present invention is combined after corresponding using method is applied to glass-cutting, owing to the water-soluble binder of base and solidification is harder, what when being possible to prevent to cut, lateral forces produced in glass collapses angle phenomenon, thus both improve the efficiency of glass-cutting processing, improve again product yield.
Description
Technical field
The invention belongs to technical field of adhesive, it particularly relates to a kind of aqueous photo-curing binding agent and
Application in glass-cutting processing.
Background technology
Binding agent is to have sticking material, can be linked together by the material that two kinds separate by its viscosity.?
In the epoch of science and technology fast development, binding agent has become the most indispensable auxiliary that numerous industrialized production is important
Material.The binding agent in the past always used usually contains the solvent such as solvent, water, therefore, is being coated with by this binding agent
After being distributed in substrate surface etc., in the operation removed by solvent contained in this binding agent, need the substantial amounts of time,
Become the reason making the production efficiency of final products reduce.Ultraviolet light curing adhesive and other binding agents
Ratio, has storage cycle long, solvent-free, the strong points such as abnormal smells from the patient is low after solidification process and solidification, more prominent advantage
It is that solidification rate is fast, curable at ambient temperature, pollution-free, easily operation and less energy consumption.These advantages make its electronics,
Being used widely in the fields such as optics, medical treatment, precision instrument, is particularly suited for glass and plastics etc. and is difficult to be heated
With occasions such as high-speed production.
Glass application in commercial production and daily life widely, such as ito glass, liquid crystal display glass
Glass, they typically require and apply to after cutting processing on all kinds of electronics.At present, in liquid crystal display industry,
When thin slice plate glass (0.33mm-1.5mm) is cut, general employing diamant such as diamant, diamond cutter etc.
Cut.Such as, Chinese patent (CN 103755134A) discloses a kind of glass cutting machine, the end of including
Seat, and the column being fixed on base, column is arranged with the first cantilever rotated for axle center with this column,
The end of the first cantilever is arranged with can be fixed along the second cantilever of the first cantilever radial expansion, the end of the second cantilever
The output shaft having motor chuck, the bottom of motor chuck to be provided with cutter head and motor is attached.Use above method,
Once can only cut a piece of, cutting efficiency is the lowest.And, for thin slice plate glass, itself belong to frangible
Product, with conventional cutting method, when volume production and yields is relatively low.
For ease of operation and raising efficiency, people dream up and divided glass carry out overlapping cutting.Existing folded
Close in cutting technique, often need to be by glass and binding agent (majority is UV adhesive tape) close adhesion.But, UV glue
Band is softer, when thickness of glass is relatively thin, may result in glass and occurs collapsing angle phenomenon, so that under product yield
Fall.Though additionally, ultraviolet light curing adhesive also exists plurality of advantages, but owing to its cohesive is relatively strong, once gluing
On just be difficult to remove.
Summary of the invention
For solving above-mentioned technical problem, the invention provides a kind of adhesiveness aqueous photo-curing strong, easily hardening and glue
Mixture and the application in glass-cutting is processed thereof.
A kind of aqueous photo-curing binding agent of the present invention, described binding agent in parts by mass, including 65-75
The water-soluble resin of part, 10-30 part water-soluble polymerizable monofunctional monomer, the double official of 5-15 part water-soluble polymerizable
Energy degree monomer, 12-20 part water solublity bifunctionality monomeric oligomeric thing, the light trigger of 1-5 part, 1-5 part foaming agent,
The auxiliary agent of 1-5 part.
A kind of aqueous photo-curing binding agent of the present invention, described water-soluble resin by PVP,
Poly-alkyl (methyl) 2-(Acryloyloxy)ethanol, formula are NVP and the alkyl (methyl) third of Ia
The copolymer of e pioic acid methyl ester, formula are alkyl (methyl) 2-(Acryloyloxy)ethanol and alkyl (methyl) propylene of Ib
The acid copolymer of methyl ester, formula are NVP and alkyl (methyl) 2-(Acryloyloxy)ethanol of Ic
One or more compositions in copolymer；Wherein R1、R2、R3、R4Represent hydrogen atom independently or there is 1-4
The alkyl of individual carbon atom, and 80≤x+y≤120,80≤m+n≤120,80≤e+f≤120；
A kind of aqueous photo-curing binding agent of the present invention, described water-soluble polymerizable monofunctional monomer is N-
Vinyl pyrrolidone, ethoxy (methyl) acrylate, hydroxypropyl (methyl) acrylate, polyhydroxy second
Base (methyl) acrylic ester compound, polyhydroxy (methyl) acrylic ester compound, multi-hydroxy ethyl polyhydroxy
Propyl group (methyl) acrylic ester compound, ether compound, one in acrylamide and derivant thereof or
Multiple.
A kind of aqueous photo-curing binding agent of the present invention, described multi-hydroxy ethyl (methyl) esters of acrylic acid
Compound formula is IIa, and described many hydroxypropyls (methyl) acrylic ester compound formula is IIb, described polyhydroxy second
Quito hydroxypropyl (methyl) acrylic ester compound formula is IIc；Wherein R1、R2、R3Represent hydrogen independently
Atom or methyl, and x and y, m and n, the integer of expression 1-10 independently；
A kind of aqueous photo-curing binding agent of the present invention, described ether compound be diethylene glycol dimethyl ether, two
Ethylene glycol, butyl, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol two fourth
One or more in ether, dimethyl ether, dipropylene glycol diethyl ether, dipropylene glycol butyl oxide；Described
Acrylamide derivative is methylol (methyl) acrylamide.
A kind of aqueous photo-curing binding agent of the present invention, described water-soluble polymerizable bifunctionality monomer is for using
One or more in the polyglycols double methacrylate compounds that general formula III a, IIIb or IIIc represent；Wherein
R1、R2、R3、R4、R5、R6Represent hydrogen atom or methyl, and m and n, table independently independently
Show the integer of 2-20, the integer of x and y expression 1-10 independently；
A kind of aqueous photo-curing binding agent of the present invention, described water solublity bifunctionality monomeric oligomeric thing is for using
One or more in the poly-polyglycols double methacrylate compounds that formula IVa, IVb or IVc represent；Its
Middle R1、R2、R3、R4、R5、R6Represent hydrogen atom or methyl, and m and n independently, independently
Represent the integer of 2-20, the integer of x and y expression 1-10 independently, a, b, c expression independently
The integer of 2-10；
A kind of aqueous photo-curing binding agent of the present invention, described azo foaming agent be azodiisobutyronitrile,
One in azoformic acid isopropyl ester, diethyl azodiformate, two azoaminobenzenes, Barium azodicarboxylate
Or it is multiple；Described light trigger is 2,4,6-trimethylbenzoy-dipheny phosphine oxide, double (the 2,4,6-front three of phenyl
Base benzoyl) phosphine oxide, one or more in double 2,6-bis-fluoro-3-pyrroles phenyl titanocenes；Described auxiliary agent is
2,6 di t butyl phenol.
A kind of aqueous photo-curing binding agent of the present invention application in glass-cutting is processed, described glass is cut
Cut concretely comprising the following steps of processing: 1) glass base is provided, glass base is coated with aqueous photo-curing bonding
Agent, is placed in glass to be cut on aqueous photo-curing binding agent, is subsequently placed to exposure curing under uviol lamp；2)
After exposure curing, layer even spread aqueous photo-curing binding agent on a glass, it is then covered by another block glass
Plate, continues to be positioned over exposure curing under uviol lamp；3) repetitive operation step 2), finally compound glass plate is bonded
Together, and be fixed in glass base；4) glass being fixed on base is cut；5) solvent is dissolving cured
Aqueous photo-curing binding agent, obtain glass finished-product.
A kind of aqueous photo-curing binding agent of the present invention application in glass-cutting is processed, described exposure is solid
Change and use ultraviolet source curing to solidify；It is to be dissolved by water that described solvent dissolves.
Compound glass can be bondd, just after ultraviolet light polymerization by aqueous photo-curing binding agent of the present invention
In the same cutting of compound glass, being placed in the hot water of 50-70 DEG C by glass, the foaming agent in binding agent is heated point
Solve, the sheet glass of bonding can be peeled off, after glass is peeled away, because resin used and copolymer and monomer are
Water miscible, the light solidifying coating of glass surface can be removed after washing thus obtain the clean glass of well cutting
Glass.Compared with prior art, aqueous photo-curing binding agent of the present invention combines corresponding using method should
After glass-cutting, owing to the water-soluble binder of base and solidification is harder, side force when being possible to prevent to cut
Act on glass and produce collapse angle phenomenon, thus both improve the efficiency of glass-cutting processing, improve again product
Product yield.
Accompanying drawing explanation
Fig. 1: use the schematic diagram carrying out glass-cutting processing of aqueous photo-curing binding agent；A-glass base, B-
Aqueous photo-curing binding agent, C-glass to be cut, D are glass cutting machine.
Detailed description of the invention
And add in glass-cutting aqueous photo-curing binding agent of the present invention below in conjunction with specific embodiment
Application in work is described further, but protection scope of the present invention is not limited to this.
Embodiment 1
By 70g poly N-vinyl pyrrolidone, 10g hydroxyethyl meth acrylate, 5g diethylene glycol bis-methyl
Acrylate, 12g oligomer polyethyleneglycol diacrylate, 1g azoformic acid isopropyl ester, 1g 2,4,6-front three
Base benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 2
By 70g poly N-vinyl pyrrolidone, 10g HPMA, 5g diethylene glycol bis-methyl
Acrylate, 12g oligomer polyethyleneglycol diacrylate, 1g diethyl azodiformate, 1g 2,4,6-front three
Base benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 3
By 70g poly N-vinyl pyrrolidone, 10g HPMA, 5g diethylene glycol bis-methyl
Acrylate, 12g oligomer polyethyleneglycol diacrylate, 1g azodiisobutyronitrile, 1g 2,4,6-trimethylbenzene
Formoxyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, the most at room temperature
Lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 4
By 70g poly hydroxy ethyl acrylate, 10g hydroxyethyl meth acrylate, 5g diethylene glycol bis-methyl-prop
Olefin(e) acid ester, 12g oligomer polypropyleneglycol diacrylate, 1g diethyl azodiformate, 1g 2,4,6-trimethyl
Benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds, it is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 5
By 70g Poly(Hydroxyethyl Methacrylate), 10g hydroxyethyl meth acrylate, 5g dipropylene glycol methacrylate
Ester, 12g oligomer polypropyleneglycol diacrylate, 1g diethyl azodiformate, 1g 2,4,6-trimethylbenzene first
Acyl group-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds, it is sequentially added in single port flask, the most at room temperature
Lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 6
By 65g poly N-vinyl pyrrolidone, 15g hydroxyethyl meth acrylate, the double methyl of 5g dipropylene glycol
Acrylate, 10g oligomer polypropyleneglycol diacrylate, 2g diethyl azodiformate, 2g 2,4,6-front three
Base benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds, it is sequentially added in single port flask, then exists
Under room temperature, lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 7
By 65g poly hydroxy ethyl acrylate, 15g hydroxyethyl meth acrylate, the double methyl-prop of 5g dipropylene glycol
Olefin(e) acid ester, 10g oligomer polypropyleneglycol diacrylate, 2g diethyl azodiformate, 2g 2,4,6-trimethyl
Benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds, it is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 8
By 68g poly N-vinyl pyrrolidone, 20g hydroxyethyl meth acrylate, 10g diethylene glycol bis-methyl
Acrylate, 15g oligomer polyethyleneglycol diacrylate, 2g azoformic acid isopropyl ester, 2g 2,4,6-front three
Base benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 9
By 65g poly hydroxy ethyl acrylate, 20g hydroxyethyl meth acrylate, 10g diethylene glycol bis-methyl
Acrylate, 15g oligomer polyethyleneglycol diacrylate, 2g azoformic acid isopropyl ester, 2g 2,4,6-front three
Base benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 10
By 65g poly N-vinyl pyrrolidone, 22g hydroxyethyl meth acrylate, 12g diethylene glycol bis-methyl
Acrylate, 20g oligomer polyethyleneglycol diacrylate, 3g azoformic acid isopropyl ester, 2g 2,4,6-front three
Base benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 11
By 65g poly hydroxy ethyl acrylate, 22g hydroxyethyl meth acrylate, 12g diethylene glycol bis-methyl
Acrylate, 20g oligomer polyethyleneglycol diacrylate, 3g azoformic acid isopropyl ester, 2g double 2,6-bis-
Fluoro-3-pyrroles's phenyl titanocenes, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, the most at room temperature
Lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 12
By 75g poly N-vinyl pyrrolidone, 22g hydroxyethyl meth acrylate, the double methyl of 12g dipropylene glycol
Acrylate, 20g oligomer polypropyleneglycol diacrylate, 3g azoformic acid isopropyl ester, 2g 2,4,6-front three
Base benzoyl-diphenyl phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 13
By 75g poly hydroxy ethyl acrylate, 22g hydroxyethyl meth acrylate, 12g diethylene glycol bis-methyl
Acrylate, 20g oligomer polypropyleneglycol diacrylate, 3g azodiisobutyronitrile, 2g double 2, the fluoro-3-of 6-bis-
Pyrroles's phenyl titanocenes, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, and the most at room temperature lucifuge is stirred
Mix 3h, obtain aqueous photo-curing binding agent.
Embodiment 14
By 75g NVP, 22g hydroxy ethyl methacrylate, 12g diethylene glycol methacrylate
Ester, 20g oligomer polypropyleneglycol diacrylate, 3g azodiisobutyronitrile, double (2,4, the 6-trimethylbenzenes of 2g phenyl
Formoxyl) phosphine oxide, 1g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, and the most at room temperature lucifuge is stirred
Mix 3h, obtain aqueous photo-curing binding agent.
Embodiment 15
By 30g poly hydroxy ethyl acrylate, 30g hydroxyethyl meth acrylate, 15g diethylene glycol bis-methyl
Acrylate, 20g oligomer polyethyleneglycol diacrylate, 5g azoformic acid isopropyl ester, 5g 2,4,6-front three
Base benzoyl-diphenyl phosphine oxide, 2g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room
Temperature lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 16
By 70g NVP, 30g hydroxyethyl meth acrylate, 15g diethylene glycol bis-methyl-prop
Olefin(e) acid ester, 20g oligomer polyethyleneglycol diacrylate, 5g azoformic acid isopropyl ester, 5g 2,4,6-trimethyl
Benzoyl-diphenyl phosphine oxide, 2g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room temperature
Lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 17
By 70g NVP, 30g hydroxy ethyl methacrylate, 15g dipropylene glycol methacrylate
Ester, 20g oligomer polyethyleneglycol diacrylate, 5g azodiisobutyronitrile, double (2,4, the 6-trimethylbenzenes of 5g phenyl
Formoxyl) phosphine oxide, 2g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, and the most at room temperature lucifuge is stirred
Mix 3h, obtain aqueous photo-curing binding agent.
Embodiment 18
By 70g NVP, 30g ethoxy first acrylate, 15g diethylene glycol bis-metering system
Acid esters, 20g oligomer polyethyleneglycol diacrylate, 5g azodiisobutyronitrile, 5g 2,4,6-trimethylbenzoyl
Base-diphenyl phosphine oxide, 5g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, the most at room temperature lucifuge
Stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 19
By 70g poly hydroxy ethyl acrylate, 30g hydroxy ethyl methacrylate, the double metering system of 15g dipropylene glycol
Acid esters, 20g oligomer polyethyleneglycol diacrylate, 5g azodiisobutyronitrile, 5g 2,4,6-trimethylbenzoyl
Base-diphenyl phosphine oxide, 5g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, the most at room temperature lucifuge
Stirring 3h, obtains aqueous photo-curing binding agent.
Embodiment 20
By 75g poly hydroxy ethyl acrylate, 30g hydroxy ethyl methacrylate, the double metering system of 15g dipropylene glycol
Acid esters, 20g oligomer polyethyleneglycol diacrylate, 5g diethyl azodiformate, 5g phenyl double (2,4,6-
Trimethylbenzoyl) phosphine oxide, 5g 2,6-DI-tert-butylphenol compounds is sequentially added in single port flask, then in room temperature
Lower lucifuge stirring 3h, obtains aqueous photo-curing binding agent.
Use embodiment 1-20 gained aqueous photo-curing binding agent to carry out glass-cutting processing respectively, concretely comprise the following steps:
1) provide a glass base, glass base is coated with aqueous photo-curing binding agent, by 2mm to be cut
Thick glass is placed on aqueous photo-curing binding agent, is subsequently placed to ultraviolet source curing and is exposed solidification；
2) after exposure curing, layer even spread aqueous photo-curing binding agent on a glass, it is then covered by another block glass
Glass plate, continues to be positioned over exposure curing under uviol lamp；3) repetitive operation step 2), finally by totally 40 layers of glass
Plate is bonded together, and is fixed in glass base；4) glass being fixed on base is cut；5) with water-soluble
Solve the aqueous photo-curing binding agent of solidification, obtain glass finished-product.Quality examination finds, with embodiment 1-20 gained
Aqueous photo-curing binding agent carries out the glass that cutting processing obtains, and all also meets the requirements without collapsing angle and cutting accuracy.
And, in addition to the glass corresponding to embodiment 1,5,8,13 has 1-2 block and glass fiber occurs, other embodiments is equal
Without occurring.
Compound glass can be bondd after ultraviolet light polymerization by aqueous photo-curing binding agent of the present invention, it is simple to
The same cutting of compound glass, is placed on glass in the hot water of 50-70 DEG C, the foaming agent decomposes in binding agent,
The sheet glass of bonding can be peeled off, after glass is peeled away, because resin used and copolymer and monomer are water-soluble
Property, the light solidifying coating of glass surface can be removed after washing thus obtain the clean glass of well cutting.
Compared with prior art, aqueous photo-curing binding agent of the present invention is combined corresponding using method to be applied to
After glass-cutting, owing to the water-soluble binder of base and solidification is harder, lateral forces when being possible to prevent to cut
Produce in glass collapses angle phenomenon, thus has both improve the efficiency of glass-cutting processing, improves again product good
Rate.
Claims (8)
1. an aqueous photo-curing binding agent, it is characterised in that described binding agent in parts by mass, including 65-75
The water-soluble resin of part, 10-30 part water-soluble polymerizable monofunctional monomer, the double official of 5-15 part water-soluble polymerizable
Energy degree monomer, 12-20 part water solublity bifunctionality monomeric oligomeric thing, the light trigger of 1-5 part, 1-5 part foaming agent,
The auxiliary agent of 1-5 part；
Described water-soluble resin is by PVP, poly-alkyl (methyl) 2-(Acryloyloxy)ethanol, formula
NVP and the copolymer of alkyl (methyl) acrylic acid methyl ester., formula for Ia are the alkyl of Ib
(methyl) 2-(Acryloyloxy)ethanol and the copolymer of alkyl (methyl) acrylic acid methyl ester., formula are the N-ethylene of Ic
Base ketopyrrolidine and one or more compositions in the copolymer of alkyl (methyl) 2-(Acryloyloxy)ethanol；Wherein R1、
R2、R3、R4Represent hydrogen atom independently or there is the alkyl of 1-4 carbon atom, and 80≤x+y≤120,
80≤m+n≤120,80≤e+f≤120；
A kind of aqueous photo-curing binding agent the most according to claim 1, it is characterised in that described water solublity
Polymerizable monofunctional degree monomer is NVP, ethoxy (methyl) acrylate, hydroxypropyl (first
Base) acrylate, multi-hydroxy ethyl (methyl) acrylic ester compound, the many hydroxypropyls of multi-hydroxy ethyl (methyl)
One or more in acrylic ester compound, ether compound, acrylamide and derivant thereof.
A kind of aqueous photo-curing binding agent the most according to claim 2, it is characterised in that described polyhydroxy second
Base (methyl) acrylic ester compound formula is IIa, described multi-hydroxy ethyl many hydroxypropyls (methyl) acrylic acid
Ester type compound formula is IIc；Wherein R1、R3Represent hydrogen atom or methyl, and x, m and n independently,
The integer of expression 1-10 independently；
A kind of aqueous photo-curing binding agent the most according to claim 1, it is characterised in that described water solublity
Polymerizable bifunctionality monomer is the polyglycols double methacrylate compounds that general formula III a, IIIb or IIIc represent
In one or more；Wherein R1、R2、R3、R4、R5、R6Represent hydrogen atom or methyl independently, and
M and n, the integer of expression 2-20 independently, the integer of x and y expression 1-10 independently；
A kind of aqueous photo-curing binding agent the most according to claim 1, it is characterised in that described water solublity
Bifunctionality monomeric oligomeric thing is the poly-polyglycols double methacrylate class chemical combination that formula IVa, IVb or IVc represent
One or more in thing；The wherein integer of m and n expression 2-20 independently, x and y is independently
Represent the integer of 1-10, the integer of a, b, c expression 2-10 independently；
A kind of aqueous photo-curing binding agent the most according to claim 1, it is characterised in that described foaming agent
For azodiisobutyronitrile, azoformic acid isopropyl ester, diethyl azodiformate, two azoaminobenzenes, azo
One or more in dioctyl phthalate barium；Described light trigger be 2,4,6-trimethylbenzoy-dipheny phosphine oxide,
One in phenyl double (2,4,6-trimethylbenzoyl) phosphine oxide, double 2,6-bis-fluoro-3-pyrroles phenyl titanocenes or
Multiple；Described auxiliary agent is 2,6 di t butyl phenol.
A kind of aqueous photo-curing binding agent the most according to claim 1 application in glass-cutting is processed,
It is characterized in that, concretely comprising the following steps of described glass-cutting processing: 1) provide a glass base, at glass bottom
It is coated with aqueous photo-curing binding agent on seat, glass to be cut is placed on aqueous photo-curing binding agent, puts subsequently
It is placed in exposure curing under uviol lamp；2) after exposure curing, layer even spread aqueous photo-curing bonding on a glass
Agent, is then covered by another block glass plate, continues to be positioned over exposure curing under uviol lamp；3) repetitive operation step
2), finally compound glass plate is bonded together, and is fixed in glass base；4) cutting is fixed on base
Glass；5) the aqueous photo-curing binding agent that solvent is dissolving cured, obtains glass finished-product.
A kind of aqueous photo-curing binding agent the most according to claim 7 application in glass-cutting is processed,
It is characterized in that, described exposure curing uses ultraviolet source curing to solidify；It is logical that described solvent dissolves
Cross water to dissolve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410817519.9A CN104530991B (en) | 2014-12-24 | 2014-12-24 | A kind of aqueous photo-curing binding agent and the application in glass-cutting is processed thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410817519.9A CN104530991B (en) | 2014-12-24 | 2014-12-24 | A kind of aqueous photo-curing binding agent and the application in glass-cutting is processed thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104530991A CN104530991A (en) | 2015-04-22 |
| CN104530991B true CN104530991B (en) | 2016-08-24 |
Family
ID=52846634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410817519.9A Active CN104530991B (en) | 2014-12-24 | 2014-12-24 | A kind of aqueous photo-curing binding agent and the application in glass-cutting is processed thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104530991B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111499178A (en) * | 2020-03-31 | 2020-08-07 | 东莞泰升玻璃有限公司 | Glass cutting process |
| CN111732333A (en) * | 2020-06-16 | 2020-10-02 | 湖南艾凯瑞斯智能科技有限公司 | Glass optical filter cutting method |
| CN114180822B (en) * | 2021-12-08 | 2024-03-12 | 华天慧创科技（西安）有限公司 | Cutting method of wafer-level stacked structure optical glass |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102807835A (en) * | 2012-05-23 | 2012-12-05 | 烟台信友电子有限公司 | Hydrolysable ultraviolet curing adhesive and method for preparing same |
| TW201313861A (en) * | 2011-08-05 | 2013-04-01 | Denki Kagaku Kogyo Kk | Adhesive composition for temporary fixing |
| CN103642400A (en) * | 2013-11-29 | 2014-03-19 | 烟台德邦科技有限公司 | Temporary adhesive for solar energy crystal support and glass and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2808290B2 (en) * | 1988-11-22 | 1998-10-08 | 株式会社スリーボンド | Adhesive composition for temporary fixing |
-
2014
- 2014-12-24 CN CN201410817519.9A patent/CN104530991B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201313861A (en) * | 2011-08-05 | 2013-04-01 | Denki Kagaku Kogyo Kk | Adhesive composition for temporary fixing |
| CN102807835A (en) * | 2012-05-23 | 2012-12-05 | 烟台信友电子有限公司 | Hydrolysable ultraviolet curing adhesive and method for preparing same |
| CN103642400A (en) * | 2013-11-29 | 2014-03-19 | 烟台德邦科技有限公司 | Temporary adhesive for solar energy crystal support and glass and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104530991A (en) | 2015-04-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101146837B (en) | Adherent composition and method of temporarily fixing member therewith | |
| CN108047965A (en) | A kind of preparation method of optical cement, optics of liquids adhesive and Curved screen optical adhesive tape | |
| CN104530991B (en) | A kind of aqueous photo-curing binding agent and the application in glass-cutting is processed thereof | |
| CN107502211A (en) | Transparent double face adhesive sheet, the laminated body for forming image display device, the manufacture method and image display device of the laminated body | |
| CN102516893A (en) | Adherent composition and method of temporarily fixing member therewith | |
| CN105860863B (en) | Color conversion coatings film and back light unit including the color conversion coatings film and display equipment | |
| CN102686622B (en) | Resin composition and adhesive agent | |
| TW201425051A (en) | Optical film with adhesive on both sides and method for fabrication of image display device employing same | |
| WO2008108390A1 (en) | Photocurable composition and cured product using the same | |
| CN101472962A (en) | Resin composition, and temporary fixation method and surface protection method for member to be processed each using the resin composition | |
| KR20170086514A (en) | Photocurable resin composition | |
| US20190085221A1 (en) | Cationic pressure sensitive adhesive uv cured by medium mercury bulbs | |
| CN103354831A (en) | Cationic polymerizable adhesive and polarizing plate obtained using same | |
| JP2013194082A (en) | Uv curable composition, adhesive and polarizing plate | |
| JP2005076017A (en) | Photocurable resin composition | |
| CN104449428B (en) | A kind of aqueous photo-curing binding agent for glass-cutting processing | |
| CN108300332A (en) | A kind of photocuring pressure sensitive adhesive, preparation method and pressure sensitive adhesive tape | |
| CN102892796A (en) | Composition and adhesive | |
| CN109554150B (en) | UV degradable super-transparent biological adhesive and preparation method thereof | |
| CN103627350A (en) | Dual-curing pressure sensitive adhesive | |
| CN109852271A (en) | Bonding sheet | |
| CN109852267A (en) | Bonding sheet | |
| TW201636407A (en) | Optical adhesive composition, optical adhesive film and optical laminate | |
| EP4263737A1 (en) | Composition including monomer with a carboxylic acid group, monomer with a hydroxyl group, a cycloalkyl monomer, and crosslinker and related articles and methods | |
| CN108219717A (en) | Emulsion paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An aqueous light curing adhesive and its application in glass cutting Effective date of registration: 20211210 Granted publication date: 20160824 Pledgee: China Construction Bank Jingmen jinlongquan sub branch Pledgor: HUBEI GURUN TECHNOLOGY Co.,Ltd. Registration number: Y2021420000138 |