CN105778577B - A kind of preparation method of energy storage luminescent ceramics coating - Google Patents
A kind of preparation method of energy storage luminescent ceramics coating Download PDFInfo
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- CN105778577B CN105778577B CN201610149378.7A CN201610149378A CN105778577B CN 105778577 B CN105778577 B CN 105778577B CN 201610149378 A CN201610149378 A CN 201610149378A CN 105778577 B CN105778577 B CN 105778577B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The present invention relates to a kind of preparation methods of energy storage luminescent ceramics coating, energy storage luminescent ceramics coating includes the raw material of following parts by weight: component A: 30-90 parts of colloidal silica, 10-30 parts of nano alumina sol, 0-20 parts of filler, 0.2-5 parts of catalyst, 1-60 parts of water；B component: 30-70 parts of organic siliconresin, 10-30 parts of organic solvent, 5-20 parts of binder, 2-10 parts of auxiliary agent；Energy-accumulating luminous powder 50-90 parts of component C, 0-50 parts of solvent；First A, B, component C are configured respectively when preparation, then it is uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally press (A+B): C is added in C=1:0.1-1:0.8 weight ratio, cures 4-6h on twin-roll machine with 20-150r/min speed scroll, forms product.Coating of the invention has the function of the characteristic for also having from main light emission outside high temperature resistant, environmental protection, self-cleaning essence of ceramic coating etc.; wide range of applications; the preparation method technical maturity simultaneously; it is suitble to lot-size metaplasia to produce; have many advantages, such as to be novel energy-saving environment-friendly material that there is important economic value.
Description
Technical field
The present invention is to belong to field of new materials, is related to a kind of preparation of energy storage luminescent ceramics coating, is particularly applicable in traffic
Safety devices field, such as bus platform, station, subway station.
Background technique
With the development of China Transportation Industry, traffic safety facilities are also required more stringent.Environment-friendly and energy-efficient product
Important need as social development.
In recent years, the development of ceramic coating is applied in multiple fields, wear-resisting, high temperature resistant, high intensity, super thin
The advantages that water, can replace traditional enamel product to a certain degree.The autonomous characteristics of luminescence of energy-accumulating luminous powder has also been transported in traffic
Defeated field many aspects are applied, and have been obtained the abundant of all circles from the performances such as main light emission, environmental protection and energy saving, pollution-free and have been agreed
It is fixed.Currently on the market there are no occur having many advantages, such as simultaneously ceramic coating and meanwhile can also be literary from the product of main light emission
Offer and patent in also have not been reported, which can play a significant role in the underground installations such as subway station, have extensive city
Field prospect.
Summary of the invention
It is an object of the invention to: a kind of energy storage luminescent ceramics coating is developed, makes it while there is the characteristic of ceramic coating,
There is energy-saving and environment-friendly autonomous illumination effect again.And to meet that production is simple with manufacture craft, it is suitble to the need of large-scale production
It will be with the requirement of client.
To achieve the goals above, the invention provides the following technical scheme:
A kind of energy storage luminescent ceramics coating, is configured by three components, the raw material including following parts by weight:
Component A:
B component:
Component C
Energy-accumulating luminous powder 50-90 parts
0-50 parts of solvent；
The preparation method of the energy storage luminescent ceramics coating, the specific steps are as follows: first respectively by A, B, component C when preparation
It configures, is then uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally press (A+B): C=1:0.1-1:0.8 weight ratio adds
Enter C, 4-6h is cured with 20-150r/min speed scroll on twin-roll machine, forms product.
Preferably, the concentration of the colloidal silica and nano alumina sol is 1-30%, and partial size is 20-
60nm。
Preferably, the filler is one of quartz, mica powder, talcum powder, kaolin, titanium dioxide or multiple combinations
It forms.
Preferably, the catalyst is acid-base modifier, for one in glacial acetic acid, formic acid, acetic acid, stearic acid, oleic acid
Kind or multiple combinations.
Preferably, the organic siliconresin is methoxy base trichlorosilane, dimethyldichlorosilane, in phenyl trichlorosilane
It is one or more pass through modified resin.
Preferably, the binder is methyl methacrylate, butyl acrylate, acrylonitrile emulsion, organosilicone elastic
One of body, third adhesive of vinegar a variety of mix.
Preferably, the auxiliary agent include one of dispersing agent, levelling agent, wetting agent, defoaming agent or multiple combinations and
At, the organic solvent be one of ethyl alcohol, methanol, acetone, ethyl acetate, ethylene glycol or it is a variety of mix, it is described
Solvent be one of tap water, deionized water, ethyl alcohol, acetone or a variety of mix.
Preferably, the energy-accumulating luminous powder is long afterglow class luminescent powder, for one in aluminate serial, silicate series
Kind or a variety of be combined.
Preferably, the construction method of the energy storage luminescent ceramics coating, the specific steps are as follows:
A. with paint
Be uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally press (A+B): C=1:0.1~1:0.8 weight ratio is added
C cures 4~6h on twin-roll machine with the speed scroll of 20~150r/m；
B. the surface treatment of workpiece
Workpiece carries out blasting treatment, removes rusty stain, the spot on surface after oil removing；The workpiece of blasting treatment is before application
5~10min is preheated in 50~60 DEG C of environment；
C. it constructs
Gas or airless spraying or electrostatic spraying mode has been taken to spray to energy storage luminescent ceramics coating on workpiece；
D. solidify
Under the conditions of 150~220 DEG C, solidify 10~30min.
Profitable effect of the invention is:
1, the energy storage luminescent ceramics coating prepared has high temperature resistant, wear-resisting, super-hydrophobic, high-intensitive, noninflammability, is suitble to more necks
Domain application；
2, the energy storage luminescent ceramics coating prepared can be from main light emission, energy conservation and environmental protection.
3, simple production process, no complicated procedures of forming produce stable product quality, have a good application prospect.
Specific embodiment
Below with reference to embodiment, the present invention will be further explained:
Embodiment 1
A kind of energy storage luminescent ceramics coating, which is characterized in that configured by three components, the original including following parts by weight
Material:
Component A:
B component:
Component C
50 parts of energy-accumulating luminous powder
1 part of solvent.
Embodiment 2
A kind of energy storage luminescent ceramics coating, which is characterized in that configured by three components, the original including following parts by weight
Material:
Component A:
B component:
Component C
70 parts of energy-accumulating luminous powder
20 parts of solvent.
Embodiment 3
A kind of energy storage luminescent ceramics coating, which is characterized in that configured by three components, the original including following parts by weight
Material:
Component A:
B component:
Component C
90 parts of energy-accumulating luminous powder
50 parts of solvent.
Wherein, in embodiment 1-3:
The concentration of the colloidal silica and nano alumina sol is 1-30%, and partial size is 20-60nm.
The filler is that one of quartz, mica powder, talcum powder, kaolin, titanium dioxide or multiple combinations form.
The catalyst is acid-base modifier, is one of glacial acetic acid, formic acid, acetic acid, stearic acid, oleic acid or a variety of
Combination.
The organic siliconresin is one of methoxy base trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane
Or it is a variety of by modified resin.
The binder is methyl methacrylate, butyl acrylate, acrylonitrile emulsion, elastomer silicone, vinegar third
One of adhesive a variety of mixes.
The auxiliary agent includes that one of dispersing agent, levelling agent, wetting agent, defoaming agent or multiple combinations form, described
Organic solvent be one of ethyl alcohol, methanol, acetone, ethyl acetate, ethylene glycol or it is a variety of mix, the solvent is
One of tap water, deionized water, ethyl alcohol, acetone a variety of mix.
The energy-accumulating luminous powder is long afterglow class luminescent powder, is one of aluminate serial, silicate series or more
Kind is combined.
Embodiment 4
The preparation method of energy storage luminescent ceramics coating in embodiment 1-3, the specific steps are as follows: when preparation first respectively by A,
B, component C configures, and is then uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally by (A+B): C=1:0.1-1:0.8 weight
Amount cures 4-6h on twin-roll machine than C is added with 20-150r/min speed scroll, forms product.
Embodiment 5
The construction method of energy storage luminescent ceramics coating in embodiment 1-3, the specific steps are as follows:
A. with paint
Be uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally press (A+B): C=1:0.1~1:0.8 weight ratio is added
C cures 4~6h on twin-roll machine with the speed scroll of 20~150r/m；
B. the surface treatment of workpiece
Workpiece carries out blasting treatment, removes rusty stain, the spot on surface after oil removing；The workpiece of blasting treatment is before application
5~10min is preheated in 50~60 DEG C of environment；
C. it constructs
Gas or airless spraying or electrostatic spraying mode has been taken to spray to energy storage luminescent ceramics coating on workpiece；
D. solidify
Under the conditions of 150~220 DEG C, solidify 10~30min.
Embodiment 6
In order to better illustrate the energy storage luminescent ceramics coating with excellent luminescent properties, by the energy-accumulating luminous pottery of preparation
Porcelain coating is coated on steel plate and is tested, and test result is as shown in table 1.
The twilight sunset of 1 reflex reflection energy-accumulating luminous paint of table is tested
Claims (9)
1. a kind of preparation method of energy storage luminescent ceramics coating is used to prepare energy storage luminescent ceramics coating, the energy-accumulating luminous pottery
Porcelain coating is configured by three components, the raw material including following parts by weight:
Component A:
B component:
Component C
Energy-accumulating luminous powder 50-90 parts
0-50 parts of solvent；
It is characterized in that, specific step is as follows: first A, B, component C are configured respectively when preparation, then press A:B=1:0.5-1:
3 weight ratios are uniformly dispersed, and finally press (A+B): C is added in C=1:0.1-1:0.8 weight ratio, with 20-150r/min on twin-roll machine
Speed scroll cures 4-6h, forms product.
2. the preparation method of energy storage luminescent ceramics coating according to claim 1, which is characterized in that described is nano oxidized
The concentration of silica solution and nano alumina sol is 1-30%, and partial size is 20-60nm.
3. the preparation method of energy storage luminescent ceramics coating according to claim 1, which is characterized in that the filler is stone
One of English, mica powder, talcum powder, kaolin, titanium dioxide or multiple combinations form.
4. the preparation method of energy storage luminescent ceramics coating according to claim 1, which is characterized in that the catalyst is
Acid-base modifier is one of glacial acetic acid, formic acid, acetic acid, stearic acid, oleic acid or multiple combinations.
5. the preparation method of energy storage luminescent ceramics coating according to claim 1, which is characterized in that the organosilicon tree
Rouge is one of methoxy base trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane or the modified resin of a variety of processes.
6. the preparation method of energy storage luminescent ceramics coating according to claim 1, which is characterized in that the binder is
One of methyl methacrylate, butyl acrylate, acrylonitrile emulsion, elastomer silicone, third adhesive of vinegar are a variety of mixed
It closes.
7. the preparation method of energy storage luminescent ceramics coating according to claim 1, which is characterized in that the auxiliary agent includes
One of dispersing agent, levelling agent, wetting agent, defoaming agent or multiple combinations form, the organic solvent be ethyl alcohol, methanol,
One of acetone, ethyl acetate, ethylene glycol or it is a variety of mix, the solvent be tap water, deionized water, ethyl alcohol,
One of acetone a variety of mixes.
8. the preparation method of energy storage luminescent ceramics coating according to claim 1, which is characterized in that described is energy-accumulating luminous
Powder is long afterglow class luminescent powder, for one of aluminate serial, silicate series or a variety of is combined.
9. the preparation method of energy storage luminescent ceramics coating according to claim 1, which is characterized in that specific step is as follows:
A. with paint
Be uniformly dispersed by A:B=1:0.5-1:3 weight ratio, finally press (A+B): C is added in C=1:0.1~1:0.8 weight ratio,
4~6h is cured with the speed scroll of 20~150r/m on twin-roll machine；
B. the surface treatment of workpiece
Workpiece carries out blasting treatment, removes rusty stain, the spot on surface after oil removing；The workpiece of blasting treatment will be before application
50~60 DEG C of environment preheats 5~10min；
C. it constructs
Gas or airless spraying or electrostatic spraying mode has been taken to spray to energy storage luminescent ceramics coating on workpiece；
D. solidify
Under the conditions of 150~220 DEG C, solidify 10~30min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610149378.7A CN105778577B (en) | 2016-03-16 | 2016-03-16 | A kind of preparation method of energy storage luminescent ceramics coating |
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| CN201610149378.7A CN105778577B (en) | 2016-03-16 | 2016-03-16 | A kind of preparation method of energy storage luminescent ceramics coating |
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| CN105778577A CN105778577A (en) | 2016-07-20 |
| CN105778577B true CN105778577B (en) | 2019-04-09 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108084752B (en) * | 2017-12-27 | 2020-08-07 | 河北省交通规划设计院 | Inorganic water-based energy-storage luminescent coating for tunnel and preparation method thereof |
| CN110643358A (en) * | 2019-09-29 | 2020-01-03 | 五行科技股份有限公司 | Novel cross-linking modified energy-storage luminescent powder for coating and preparation method thereof |
| CN111019517B (en) * | 2019-12-26 | 2021-09-10 | 江门市安诺特炊具制造有限公司 | Water-based ceramic coating and preparation method thereof |
| CN111484354A (en) * | 2020-06-05 | 2020-08-04 | 嘉应学院 | High-hardness long-afterglow luminescent coating for enamel ceramic product and preparation method thereof |
| CN111995949A (en) * | 2020-07-14 | 2020-11-27 | 陈子辉 | High-temperature-resistant coating and preparation method thereof |
| CN114806252A (en) * | 2021-01-19 | 2022-07-29 | 杭州路丽新材料有限公司 | Road coating material and spraying process |
| CN113527920B (en) * | 2021-07-06 | 2022-06-21 | 浙江大学杭州国际科创中心 | Inorganic lithium ion battery diaphragm coating and preparation method thereof |
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| CN1062538C (en) * | 1998-06-26 | 2001-02-28 | 山东伦博实业集团有限公司 | Energy accumulating luminous glaze and its preparing technology |
| KR20100045348A (en) * | 2008-10-23 | 2010-05-03 | 노찬우 | Light emitting and slip-stop paint for road and method for painting the road |
| CN102690536B (en) * | 2011-03-21 | 2016-09-14 | 上海宜瓷龙新材料股份有限公司 | A kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation method thereof |
| TWI548722B (en) * | 2011-12-01 | 2016-09-11 | 蕭一修 | Photo-luminance coating, glass and applications thereof |
| CN104804480A (en) * | 2014-01-28 | 2015-07-29 | 上海复先材料科技有限公司 | Three dimensional ceramic coating, and preparation method and application thereof |
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Effective date of registration: 20210205 Address after: 239500 ten Tan modern industrial park, Quanjiao, Chuzhou, Anhui Patentee after: ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Patentee after: CHINA MERCHANTS CHONGQING COMMUNICATIONS RESEARCH & DESIGN INSTITUTE Co.,Ltd. Address before: 239500 ten Tan modern industrial park, Quanjiao, Chuzhou, Anhui Patentee before: ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. |
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Address after: 239500 ten Tan modern industrial park, Quanjiao, Chuzhou, Anhui Patentee after: Anhui Zhongyi New Material Technology Co.,Ltd. Patentee after: CHINA MERCHANTS CHONGQING COMMUNICATIONS RESEARCH & DESIGN INSTITUTE Co.,Ltd. Address before: 239500 ten Tan modern industrial park, Quanjiao, Chuzhou, Anhui Patentee before: ANHUI ZHONGYI NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Patentee before: CHINA MERCHANTS CHONGQING COMMUNICATIONS RESEARCH & DESIGN INSTITUTE Co.,Ltd. |
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