CN104893577A - Cracking preventing paint - Google Patents
Cracking preventing paint Download PDFInfo
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- CN104893577A CN104893577A CN201510341666.8A CN201510341666A CN104893577A CN 104893577 A CN104893577 A CN 104893577A CN 201510341666 A CN201510341666 A CN 201510341666A CN 104893577 A CN104893577 A CN 104893577A
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- crack resistence
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C09D161/14—Modified phenol-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of paint coatings, in particular to cracking preventing paint. The cracking preventing paint comprises components in parts by mass as follows: 20-30 parts of modified rosin resin, 15-20 parts of tung oil, 3.2-4.8 parts of epoxy resin solidifying glue, 12-18 parts of hydroxylated acrylic resin, 10-15 parts of glycerin, 16-18 parts of soybean plant short-oil alkyd resin, 0.2-0.8 parts of an antifoaming agent, 0.2-0.8 parts of a leveling agent and 0.2-0.6 parts of a moisture-proof agent. The cracking preventing paint adopting the technical scheme has the benefits as follows: the epoxy resin solidifying glue and the soybean plant short-oil alkyd resin are added, a mixture of silica gel, anhydrous cupric sulfate and iron powder is taken as the moisture-proof agent, so that the viscidity of the paint is enhanced, the paint cannot fall off after applied to a wall and cannot crack, and most of the raw materials are organic, green, energy-saving, safe and harmless to human.
Description
Technical field
The present invention relates to paint technical field, especially a kind of crack resistence paint.
Background technology
Before the history of painting can trace back to more than 4000 year, China working people just utilizes vegetables oil (as tung oil, Chinese catalpa oil) and natural raw lacquer to cover with paint, lacquer, colour wash, etc. tool face at that time, and solid rear formation has the film of protectiveness.B.C. 1500, in France and Hispanic cavern, paint was for drawing and decoration.B.C. 1500, Egyptian's dyestuff such as indigo and madder manufactured blue and red pigment, but this paint is still far from perfect.In 18th century, due to the exploitation to Semen Lini oil and zinc oxide, paint industry is developed rapidly.In 20th century, painting technology has had significant development, has occurred that clinging power is larger, the paint of higher, fire-retardant, the anticorrosive shades of colour high with thermostability of glossiness.Along with scientific technological advance, the rapid development of petrochemical complex and organic synthesis industry especially in recent decades, many new oil paint materials are come out one after another.Current paint has more than several thousand kinds, and the past is to paint Classification And Nomenclature very disunity.Chemical industry department of China, now to paint classification based on its main film forming substance, paint is divided into 18 large classes.By whitewashing position classification, be mainly divided into wall paint, metallic paint, wood lacquer.Wall paint comprises exterior wall paint, interior wall paint and end face paint, mainly emulsion paint; Metallic paint is enamel paint mainly; Wood lacquer mainly contains pyroxylin(e)finish, Polyester Paint etc.
But existing paint also exists meets water, meets the technical deficiencies such as high temperature is easy to crack.
Summary of the invention
The object of the invention is: overcome deficiency of the prior art, provide a kind of and meet water, chance high temperature is not easy to crack, the rational crack resistence paint of composition proportion.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows:
A crack resistence paint, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 20-30 part, tung oil 15-20 part, epoxy resin freezing plastic 3.2-4.8 part, Hydroxylated acrylic resin 12-18 part, glycerol 10-15 part, soybean plants short oil class Synolac 16-18 part, defoamer 0.2-0.8 part, flow agent 0.2-0.8 part, non-blushing thinner 0.2-0.6 part.
Further, described modified rosin resin is modified phenolic resins.
Further, the mass parts of described defoamer is composed as follows: methacrylate polymers 10-20 part, aromatic hydrocarbon 8-12 part, naphthenic hydrocarbon 20-35 part, connect alkane 50-70 part, described methacrylate polymers with the carbonatoms of the alkyl alkyl methacrylate that is 1-20 for Component units.
Further, the mass parts of described defoamer is composed as follows: methacrylate polymers 12 parts, 10 parts, aromatic hydrocarbon, 25 parts, naphthenic hydrocarbon, even alkane 60 parts.
Further, the molecular-weight average of described methacrylate polymers is 28-45 ten thousand.
Further, the mass parts of described flow agent is composed as follows: butyl acrylate 6-8 part, polyether modified siloxane 3-8 part, tetrasodium pyrophosphate 3-6 part, epoxy resin 4-8 part, glycidyl methacrylate 20-40 part.
Further, the mass parts of described flow agent is composed as follows: butyl acrylate 7 parts, polyether modified siloxane 6 parts, tetrasodium pyrophosphate 5 parts, epoxy resin 6 parts, glycidyl methacrylate 30 parts.
Further, the mixture of silica gel, anhydrous cupric sulfate and iron powder selected by described non-blushing thinner, and its mass ratio is 1:1-4:2-6.
Further, the mass ratio of described silica gel, anhydrous cupric sulfate and iron powder is 1:2.5:3.
Further, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 25 parts, tung oil 18 parts, epoxy resin freezing plastic 4 parts, Hydroxylated acrylic resin 15 parts, glycerol 12 parts, soybean plants short oil class Synolac 17 parts, defoamer 0.5 part, flow agent 0.5 part, non-blushing thinner 0.4 part.
The beneficial effect of technical scheme of the present invention is adopted to be: to the invention provides a kind of anticracking paint, with the addition of epoxy resin freezing plastic, soybean plants short oil class Synolac, with the mixture of silica gel, anhydrous cupric sulfate and iron powder as non-blushing thinner, paint viscosity can be made to strengthen be coated with can not come off on the wall, there will not be crackle, employing raw material mostly is organic raw material green, energy-conservation, safety is harmless to people.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1
A crack resistence paint, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 20 parts, tung oil 15 parts, epoxy resin freezing plastic 3.2 parts, Hydroxylated acrylic resin 12 parts, glycerol 10 parts, soybean plants short oil class Synolac 16 parts, defoamer 0.2 part, flow agent 0.2 part, non-blushing thinner 0.2 part.
Wherein, described modified rosin resin is modified phenolic resins.
Wherein, the mass parts of described defoamer is composed as follows: methacrylate polymers 10 parts, 8 parts, aromatic hydrocarbon, 20 parts, naphthenic hydrocarbon, connect alkane 50 parts, described methacrylate polymers with the carbonatoms of the alkyl alkyl methacrylate that is 1-20 for Component units.
Wherein, the molecular-weight average of described methacrylate polymers is 28-30 ten thousand.
Wherein, the mass parts of described flow agent is composed as follows: butyl acrylate 6 parts, polyether modified siloxane 3 parts, tetrasodium pyrophosphate 3 parts, epoxy resin 4 parts, glycidyl methacrylate 20 parts.
Wherein, the mixture of silica gel, anhydrous cupric sulfate and iron powder selected by described non-blushing thinner, and its mass ratio is 1:1:2.
Embodiment 2
A crack resistence paint, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 22 parts, tung oil 16 parts, epoxy resin freezing plastic 3.5 parts, Hydroxylated acrylic resin 13 parts, glycerol 12 parts, soybean plants short oil class Synolac 16.5 parts, defoamer 0.3 part, flow agent 0.3 part, non-blushing thinner 0.3 part.
Wherein, described modified rosin resin is modified phenolic resins.
Wherein, the mass parts of described defoamer is composed as follows: methacrylate polymers 12 parts, 10 parts, aromatic hydrocarbon, 24 parts, naphthenic hydrocarbon, connect alkane 53 parts, described methacrylate polymers with the carbonatoms of the alkyl alkyl methacrylate that is 1-20 for Component units.
Wherein, the molecular-weight average of described methacrylate polymers is 30-35 ten thousand.
Wherein, the mass parts of described flow agent is composed as follows: butyl acrylate 6.8 parts, polyether modified siloxane 4 parts, tetrasodium pyrophosphate 4 parts, epoxy resin 5 parts, glycidyl methacrylate 25 parts.
Wherein, the mixture of silica gel, anhydrous cupric sulfate and iron powder selected by described non-blushing thinner, and its mass ratio is 1:2:3.
Embodiment 3
A crack resistence paint, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 25 parts, tung oil 18 parts, epoxy resin freezing plastic 4 parts, Hydroxylated acrylic resin 15 parts, glycerol 12 parts, soybean plants short oil class Synolac 17 parts, defoamer 0.5 part, flow agent 0.5 part, non-blushing thinner 0.4 part.
Wherein, described modified rosin resin is modified phenolic resins.
Wherein, the mass parts of described defoamer is composed as follows: methacrylate polymers 12 parts, 10 parts, aromatic hydrocarbon, 25 parts, naphthenic hydrocarbon, connect alkane 60 parts, described methacrylate polymers with the carbonatoms of the alkyl alkyl methacrylate that is 1-20 for Component units.
Wherein, the molecular-weight average of described methacrylate polymers is 30-45 ten thousand.
Wherein, the mass parts of described flow agent is composed as follows: butyl acrylate 7 parts, polyether modified siloxane 6 parts, tetrasodium pyrophosphate 5 parts, epoxy resin 6 parts, glycidyl methacrylate 30 parts.
Wherein, the mixture of silica gel, anhydrous cupric sulfate and iron powder selected by described non-blushing thinner, and its mass ratio is 1:2.5:3.
Embodiment 4
A crack resistence paint, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 28 parts, tung oil 18 parts, epoxy resin freezing plastic 4.5 parts, hydroxyl 0.7 part, flow agent 0.7 part, non-blushing thinner 0.5 part.
Wherein, described modified rosin resin is modified phenolic resins.
Wherein, the mass parts of described defoamer is composed as follows: methacrylate polymers 18 parts, 10 parts, aromatic hydrocarbon, 32 parts, naphthenic hydrocarbon, connect alkane 65 parts, described methacrylate polymers with the carbonatoms of the alkyl alkyl methacrylate that is 1-20 for Component units.
Wherein, the molecular-weight average of described methacrylate polymers is 28-45 ten thousand.
Wherein, the mass parts of described flow agent is composed as follows: butyl acrylate 7.5 parts, polyether modified siloxane 7 parts, tetrasodium pyrophosphate 5 parts, epoxy resin 7 parts, glycidyl methacrylate 36 parts.
Wherein, the mixture of silica gel, anhydrous cupric sulfate and iron powder selected by described non-blushing thinner, and its mass ratio is 1:3:4.
Embodiment 5
A crack resistence paint, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 30 parts, tung oil 20 parts, epoxy resin freezing plastic 4.8 parts, Hydroxylated acrylic resin 18 parts, glycerol 15 parts, soybean plants short oil class Synolac 18 parts, defoamer 0.8 part, flow agent 0.8 part, non-blushing thinner 0.6 part.
Wherein, described modified rosin resin is modified phenolic resins.
Wherein, the mass parts of described defoamer is composed as follows: methacrylate polymers 20 parts, 12 parts, aromatic hydrocarbon, 35 parts, naphthenic hydrocarbon, connect alkane 70 parts, described methacrylate polymers with the carbonatoms of the alkyl alkyl methacrylate that is 1-20 for Component units.
Wherein, the molecular-weight average of described methacrylate polymers is 35-45 ten thousand.
Wherein, the mass parts of described flow agent is composed as follows: butyl acrylate 8 parts, polyether modified siloxane 8 parts, tetrasodium pyrophosphate 6 parts, epoxy resin 8 parts, glycidyl methacrylate 40 parts.
Wherein, the mixture of silica gel, anhydrous cupric sulfate and iron powder selected by described non-blushing thinner, and its mass ratio is 1:4:6.
Embodiment 3 is preferred implementation.
Performance test:
Performance test is carried out to crack resistence obtained in embodiment 1-5 in the present invention paint.Detected result is in table 1.
Table 1
Although above-described embodiment describes in detail technical scheme of the present invention, but technical scheme of the present invention is not limited to above embodiment, when not departing from thought of the present invention and aim, claims limited range of the present invention all will be fallen into any change that technical scheme of the present invention is done.
Claims (10)
1. a crack resistence paint, it is characterized in that, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 20-30 part, tung oil 15-20 part, epoxy resin freezing plastic 3.2-4.8 part, Hydroxylated acrylic resin 12-18 part, glycerol 10-15 part, soybean plants short oil class Synolac 16-18 part, defoamer 0.2-0.8 part, flow agent 0.2-0.8 part, non-blushing thinner 0.2-0.6 part.
2. a kind of crack resistence paint according to claim 1, is characterized in that: described modified rosin resin is modified phenolic resins.
3. a kind of crack resistence paint according to claim 1, it is characterized in that, the mass parts of described defoamer is composed as follows: methacrylate polymers 10-20 part, aromatic hydrocarbon 8-12 part, naphthenic hydrocarbon 20-35 part, connect alkane 50-70 part, described methacrylate polymers with the carbonatoms of the alkyl alkyl methacrylate that is 1-20 for Component units.
4. a kind of crack resistence paint according to claim 3, it is characterized in that, the mass parts of described defoamer is composed as follows: methacrylate polymers 12 parts, 10 parts, aromatic hydrocarbon, 25 parts, naphthenic hydrocarbon, even alkane 60 parts.
5. a kind of crack resistence paint according to claim 3, it is characterized in that, the molecular-weight average of described methacrylate polymers is 28-45 ten thousand.
6. a kind of crack resistence paint according to claim 1, it is characterized in that, the mass parts of described flow agent is composed as follows: butyl acrylate 6-8 part, polyether modified siloxane 3-8 part, tetrasodium pyrophosphate 3-6 part, epoxy resin 4-8 part, glycidyl methacrylate 20-40 part.
7. a kind of crack resistence paint according to claim 6, it is characterized in that, the mass parts of described flow agent is composed as follows: butyl acrylate 7 parts, polyether modified siloxane 6 parts, tetrasodium pyrophosphate 5 parts, epoxy resin 6 parts, glycidyl methacrylate 30 parts.
8. a kind of crack resistence paint according to claim 1, it is characterized in that: the mixture of silica gel, anhydrous cupric sulfate and iron powder selected by described non-blushing thinner, its mass ratio is 1:1-4:2-6.
9. a kind of crack resistence paint according to claim 8, is characterized in that: the mass ratio of described silica gel, anhydrous cupric sulfate and iron powder is 1:2.5:3.
10. a kind of crack resistence paint according to claim 1, it is characterized in that, the mass parts of described crack resistence paint is composed as follows: modified rosin resin 25 parts, tung oil 18 parts, epoxy resin freezing plastic 4 parts, Hydroxylated acrylic resin 15 parts, glycerol 12 parts, soybean plants short oil class Synolac 17 parts, defoamer 0.5 part, flow agent 0.5 part, non-blushing thinner 0.4 part.
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CN201510341666.8A CN104893577A (en) | 2015-06-18 | 2015-06-18 | Cracking preventing paint |
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CN201510341666.8A CN104893577A (en) | 2015-06-18 | 2015-06-18 | Cracking preventing paint |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105482708A (en) * | 2015-12-16 | 2016-04-13 | 无锡福镁轻合金科技有限公司 | Waterproof paint for thin plates |
CN106318092A (en) * | 2016-08-22 | 2017-01-11 | 安徽宇瑞环保建设有限公司 | Anti-cracking environment-friendly paint |
CN106867407A (en) * | 2017-04-24 | 2017-06-20 | 浙江凯晨工贸有限公司 | A kind of environment-friendly type bamboo and wood processing oil paint and preparation method thereof |
CN107189690A (en) * | 2017-07-05 | 2017-09-22 | 合肥片美环保科技有限公司 | A kind of anticracking environment-friendly type paint and preparation method thereof |
CN107201111A (en) * | 2017-04-18 | 2017-09-26 | 安徽华辉塑业科技股份有限公司 | A kind of perambulator steelwork topical oil paint preparation method |
CN107267067A (en) * | 2017-06-28 | 2017-10-20 | 安徽慕曼德家具有限公司 | A kind of furniture environment protection oil paint |
CN107746630A (en) * | 2017-11-08 | 2018-03-02 | 肇庆高新区国专科技有限公司 | A kind of crack resistence automotive paints |
CN108587277A (en) * | 2018-04-28 | 2018-09-28 | 嘉宝莉化工集团股份有限公司 | A kind of environmentally protective spray paint of anti-cracking type and preparation method thereof |
CN109666386A (en) * | 2017-10-14 | 2019-04-23 | 梁秋云 | A kind of alkyd resin composite exterior wall coating |
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CN103881573A (en) * | 2013-10-28 | 2014-06-25 | 东南大学 | Anti-cracking paint |
CN104327733A (en) * | 2014-10-17 | 2015-02-04 | 青岛克立克信息技术有限公司 | Anti-cracking paint with stable property |
CN104559417A (en) * | 2015-01-22 | 2015-04-29 | 南通顺阳化工有限公司 | Paint leveling agent |
CN104559615A (en) * | 2013-10-21 | 2015-04-29 | 湖州市南浔祥龙木业制造厂 | Environment-friendly and anti-cracking paint and preparation method thereof |
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2015
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Patent Citations (7)
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CN1676554A (en) * | 2004-03-30 | 2005-10-05 | 日本诺普科助剂有限公司 | Defoaming agent |
CN1903969A (en) * | 2005-07-31 | 2007-01-31 | 吴世和 | Inorganic waterproof moisture proof agent |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105482708A (en) * | 2015-12-16 | 2016-04-13 | 无锡福镁轻合金科技有限公司 | Waterproof paint for thin plates |
CN106318092A (en) * | 2016-08-22 | 2017-01-11 | 安徽宇瑞环保建设有限公司 | Anti-cracking environment-friendly paint |
CN107201111A (en) * | 2017-04-18 | 2017-09-26 | 安徽华辉塑业科技股份有限公司 | A kind of perambulator steelwork topical oil paint preparation method |
CN106867407A (en) * | 2017-04-24 | 2017-06-20 | 浙江凯晨工贸有限公司 | A kind of environment-friendly type bamboo and wood processing oil paint and preparation method thereof |
CN106867407B (en) * | 2017-04-24 | 2019-04-23 | 浙江凯晨工贸有限公司 | A kind of bamboo and wood processing oil paint and preparation method thereof |
CN107267067A (en) * | 2017-06-28 | 2017-10-20 | 安徽慕曼德家具有限公司 | A kind of furniture environment protection oil paint |
CN107189690A (en) * | 2017-07-05 | 2017-09-22 | 合肥片美环保科技有限公司 | A kind of anticracking environment-friendly type paint and preparation method thereof |
CN109666386A (en) * | 2017-10-14 | 2019-04-23 | 梁秋云 | A kind of alkyd resin composite exterior wall coating |
CN107746630A (en) * | 2017-11-08 | 2018-03-02 | 肇庆高新区国专科技有限公司 | A kind of crack resistence automotive paints |
CN108587277A (en) * | 2018-04-28 | 2018-09-28 | 嘉宝莉化工集团股份有限公司 | A kind of environmentally protective spray paint of anti-cracking type and preparation method thereof |
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Application publication date: 20150909 |