CN106867407A - A kind of environment-friendly type bamboo and wood processing oil paint and preparation method thereof - Google Patents
A kind of environment-friendly type bamboo and wood processing oil paint and preparation method thereof Download PDFInfo
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- CN106867407A CN106867407A CN201710272397.3A CN201710272397A CN106867407A CN 106867407 A CN106867407 A CN 106867407A CN 201710272397 A CN201710272397 A CN 201710272397A CN 106867407 A CN106867407 A CN 106867407A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of environment-friendly type bamboo and wood processing oil paint and preparation method thereof,Paint component includes 40 60 parts of natural resin by weight,5 10 parts of titanium dioxide,8 12 parts of white carbon,10 20 parts of turpentine oil,10 25 parts of polyethyleneimine,10 20 parts of nano-zinc oxide powder,5 15 parts of cellulose acetate,8 12 parts of adhesive,10 20 parts of modified Nano diatomite in powder,10 25 parts of sodium carboxymethylcellulose,14 parts of levelling agent,8 17 parts of 5 15 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane,Preparation process is simple of the present invention,Preparation process is environment friendly and pollution-free,Obtained paint environment-protecting asepsis,With moisture resistance waterproof,Anti-aging,Wear-resisting the characteristics of,It is coated on bamboo and wood products surface,The service life of bamboo and wood products can be extended.
Description
Technical field
The present invention relates to bamboo and wood processing oil paint preparing technical field, specially a kind of environment-friendly type bamboo and wood processing oil paint and
Its preparation method.
Background technology
It with bamboo is the product of manufacture of processing raw material that bamboo and wood products refers to, mostly commodity, such as chopsticks, chopsticks cage, chopping block, cool
Seat, tea cup mat, curtain etc., also bamboo flooring popular in recent years and bamboo furniture etc., some values are higher, such as bamboo carving
Handicraft.The bamboo and wood products for processing needs to coat one layer of paint on its surface, and bamboo and wood products of the prior art paints
Environmental-protecting performance is poor, wear-resisting, anti-scratch effect is poor, causes bamboo and wood products's service life short.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly type bamboo and wood processing oil paint and preparation method thereof, to solve the above-mentioned back of the body
The problem proposed in scape technology.
To achieve the above object, the present invention provides following technical scheme:A kind of environment-friendly type bamboo and wood processing oil paint, paint group
Part includes natural resin 40-60 parts, titanium dioxide 5-10 parts, white carbon 8-12 parts, turpentine oil 10-20 parts, poly- second by weight
10-25 parts of alkene imines, nano-zinc oxide powder 10-20 parts, cellulose acetate 5-15 parts, adhesive 8-12 parts, modified Nano silicon
10-20 parts of diatomaceous earth powder, sodium carboxymethylcellulose 10-25 parts, levelling agent 1-4 parts, 5-15 parts of bean plant short oil class alkyd resin
And modified polyorganosiloxane 8-17 parts.
Preferably, preferred composition proportion is:50 parts of natural resin, 8 parts of titanium dioxide, 10 parts of white carbon, 15 parts of turpentine oil,
17 parts of polyethyleneimine, 15 parts of nano-zinc oxide powder, 10 parts of cellulose acetate, 10 parts of adhesive, modified Nano diatomite in powder
15 parts, 17 parts of sodium carboxymethylcellulose, 3 parts of levelling agent, 10 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane
13 parts.
Preferably, its preparation method is comprised the following steps:
It is A, natural resin, titanium dioxide, white carbon, nano-zinc oxide powder, modified Nano diatomite in powder, bean plant is short
It is stirred in addition stirred tank after the mixing of oils alkyd resin, stir speed (S.S.) is 1000-2000 revs/min, mixing time is
10min-30min, obtains mixture A;
B, addition turpentine oil, polyethyleneimine, cellulose acetate, adhesive in mixture A, add grinder after mixing
Middle grinding 20-40min, obtains mixture B;
C, afterwards will mixture B add kneading machine in knead, melting temperature be 55 DEG C -75 DEG C, mixing time is 10min-
30min;30min is stood after being slowly cooled to room temperature afterwards;
D, it is last sodium carboxymethylcellulose, levelling agent are sequentially added in the mixture that step C is obtained, be modified poly- silica
Alkane, adds heating vessel in heating after mixing, be stirred continuously in heating process;Constant temperature 20min, is again heated to after being heated to 50 DEG C
Constant temperature 10min after 80 DEG C, after being slowly cooled to room temperature afterwards, stands 1h, that is, obtain environment protection oil paint.
Compared with prior art, the beneficial effects of the invention are as follows:Preparation process is simple of the present invention, preparation process environmental protection are without dirt
Dye, obtained paint environment-protecting asepsis, with moisture resistance waterproof, anti-aging, it is wear-resisting the characteristics of, be coated on bamboo and wood products surface, can
Extend the service life of bamboo and wood products, the titanium dioxide of addition can further enhance the antiseptic property of paint;The nano oxygen of addition
Changing zinc, modified Nano diatomite in powder has functions that antibacterial bacteriostatic, the anti-enzyme of taste of dispelling, can extend the storage time 2 years of paint with
On;The sodium carboxymethylcellulose of addition, it can be ensured that the stability and uniformity of paint viscosity, so as to improve paint application efficiency
More than 30%;In addition, being added with bean plant short oil class alkyd resin in the present invention, it is prevented from bamboo and wood products's surface paint and opens
Split;The modified polyorganosiloxane of addition can further improve the anti-wear performance and anti-scratch performance of paint.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
The present invention provides following technical scheme:A kind of environment-friendly type bamboo and wood processing oil paint, paint component is wrapped by weight
Include natural resin 40-60 parts, titanium dioxide 5-10 parts, white carbon 8-12 parts, turpentine oil 10-20 parts, polyethyleneimine 10-25 parts,
Nano-zinc oxide powder 10-20 parts, cellulose acetate 5-15 parts, adhesive 8-12 parts, 10-20 parts of modified Nano diatomite in powder,
Sodium carboxymethylcellulose 10-25 parts, levelling agent 1-4 parts, 5-15 parts of bean plant short oil class alkyd resin and the poly- silica that is modified
Alkane 8-17 parts.
Embodiment one:
Paint component includes 40 parts of natural resin, 5 parts of titanium dioxide, 8 parts of white carbon, 10 parts of turpentine oil, poly- by weight
10 parts of aziridine, 10 parts of nano-zinc oxide powder, 5 parts of cellulose acetate, 8 parts of adhesive, 10 parts of modified Nano diatomite in powder,
8 parts of 10 parts of sodium carboxymethylcellulose, 1 part of levelling agent, 5 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane.
The preparation method of the present embodiment is comprised the following steps:
It is A, natural resin, titanium dioxide, white carbon, nano-zinc oxide powder, modified Nano diatomite in powder, bean plant is short
It is stirred in addition stirred tank after the mixing of oils alkyd resin, stir speed (S.S.) is 1000 revs/min, mixing time is
10minmin, obtains mixture A;
B, addition turpentine oil, polyethyleneimine, cellulose acetate, adhesive in mixture A, add grinder after mixing
Middle grinding 20min, obtains mixture B;
C, afterwards will mixture B add kneading machine in knead, melting temperature be 55 DEG C, mixing time is 10min;Delay afterwards
30min is stood after slow cool down to room temperature;
D, it is last sodium carboxymethylcellulose, levelling agent are sequentially added in the mixture that step C is obtained, be modified poly- silica
Alkane, adds heating vessel in heating after mixing, be stirred continuously in heating process;Constant temperature 20min, is again heated to after being heated to 50 DEG C
Constant temperature 10min after 80 DEG C, after being slowly cooled to room temperature afterwards, stands 1h, that is, obtain environment protection oil paint.
Embodiment two:
Paint component by weight include 60 parts of natural resin, 10 parts of titanium dioxide, 12 parts of white carbon, 20 parts of turpentine oil,
25 parts of polyethyleneimine, 20 parts of nano-zinc oxide powder, 15 parts of cellulose acetate, 12 parts of adhesive, modified Nano diatomite in powder
20 parts, 25 parts of sodium carboxymethylcellulose, 4 parts of levelling agent, 15 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane
17 parts.
The preparation method of the present embodiment is comprised the following steps:
It is A, natural resin, titanium dioxide, white carbon, nano-zinc oxide powder, modified Nano diatomite in powder, bean plant is short
It is stirred in addition stirred tank after the mixing of oils alkyd resin, stir speed (S.S.) is 2000 revs/min, and mixing time is 30min, is obtained
To mixture A;
B, addition turpentine oil, polyethyleneimine, cellulose acetate, adhesive in mixture A, add grinder after mixing
Middle grinding 40min, obtains mixture B;
C, afterwards will mixture B add kneading machine in knead, melting temperature be 75 DEG C, mixing time is 30min;Delay afterwards
30min is stood after slow cool down to room temperature;
D, it is last sodium carboxymethylcellulose, levelling agent are sequentially added in the mixture that step C is obtained, be modified poly- silica
Alkane, adds heating vessel in heating after mixing, be stirred continuously in heating process;Constant temperature 20min, is again heated to after being heated to 50 DEG C
Constant temperature 10min after 80 DEG C, after being slowly cooled to room temperature afterwards, stands 1h, that is, obtain environment protection oil paint.
Embodiment three:
Paint component includes 45 parts of natural resin, 6 parts of titanium dioxide, 9 parts of white carbon, 12 parts of turpentine oil, poly- by weight
12 parts of aziridine, 12 parts of nano-zinc oxide powder, 6 parts of cellulose acetate, 9 parts of adhesive, 12 parts of modified Nano diatomite in powder,
9 parts of 12 parts of sodium carboxymethylcellulose, 2 parts of levelling agent, 7 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane.
The preparation method of the present embodiment is comprised the following steps:
It is A, natural resin, titanium dioxide, white carbon, nano-zinc oxide powder, modified Nano diatomite in powder, bean plant is short
It is stirred in addition stirred tank after the mixing of oils alkyd resin, stir speed (S.S.) is 1200 revs/min, and mixing time is 12min, is obtained
To mixture A;
B, addition turpentine oil, polyethyleneimine, cellulose acetate, adhesive in mixture A, add grinder after mixing
Middle grinding 25min, obtains mixture B;
C, afterwards will mixture B add kneading machine in knead, melting temperature be 60 DEG C, mixing time is 15min;Delay afterwards
30min is stood after slow cool down to room temperature;
D, it is last sodium carboxymethylcellulose, levelling agent are sequentially added in the mixture that step C is obtained, be modified poly- silica
Alkane, adds heating vessel in heating after mixing, be stirred continuously in heating process;Constant temperature 20min, is again heated to after being heated to 50 DEG C
Constant temperature 10min after 80 DEG C, after being slowly cooled to room temperature afterwards, stands 1h, that is, obtain environment protection oil paint.
Example IV:
Paint component includes 55 parts of natural resin, 9 parts of titanium dioxide, 11 parts of white carbon, 18 parts of turpentine oil, poly- by weight
22 parts of aziridine, 18 parts of nano-zinc oxide powder, 14 parts of cellulose acetate, 11 parts of adhesive, modified Nano diatomite in powder 18
Part, 22 parts of sodium carboxymethylcellulose, 3 parts of levelling agent, 14 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane 15
Part.
The preparation method of the present embodiment is comprised the following steps:
It is A, natural resin, titanium dioxide, white carbon, nano-zinc oxide powder, modified Nano diatomite in powder, bean plant is short
It is stirred in addition stirred tank after the mixing of oils alkyd resin, stir speed (S.S.) is 1800 revs/min, and mixing time is 25min, is obtained
To mixture A;
B, addition turpentine oil, polyethyleneimine, cellulose acetate, adhesive in mixture A, add grinder after mixing
Middle grinding 35min, obtains mixture B;
C, afterwards will mixture B add kneading machine in knead, melting temperature be 70 DEG C, mixing time is 25min;Delay afterwards
30min is stood after slow cool down to room temperature;
D, it is last sodium carboxymethylcellulose, levelling agent are sequentially added in the mixture that step C is obtained, be modified poly- silica
Alkane, adds heating vessel in heating after mixing, be stirred continuously in heating process;Constant temperature 20min, is again heated to after being heated to 50 DEG C
Constant temperature 10min after 80 DEG C, after being slowly cooled to room temperature afterwards, stands 1h, that is, obtain environment protection oil paint.
Embodiment five:
Paint component includes 52 parts of natural resin, 7 parts of titanium dioxide, 11 parts of white carbon, 16 parts of turpentine oil, poly- by weight
20 parts of aziridine, 16 parts of nano-zinc oxide powder, 8 parts of cellulose acetate, 9 parts of adhesive, 16 parts of modified Nano diatomite in powder,
15 parts of 15 parts of sodium carboxymethylcellulose, 3 parts of levelling agent, 8 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane.
The preparation method of the present embodiment is comprised the following steps:
It is A, natural resin, titanium dioxide, white carbon, nano-zinc oxide powder, modified Nano diatomite in powder, bean plant is short
It is stirred in addition stirred tank after the mixing of oils alkyd resin, stir speed (S.S.) is 1000-2000 revs/min, mixing time is
10min-30min, obtains mixture A;
B, addition turpentine oil, polyethyleneimine, cellulose acetate, adhesive in mixture A, add grinder after mixing
Middle grinding 20-40min, obtains mixture B;
C, afterwards will mixture B add kneading machine in knead, melting temperature be 55 DEG C -75 DEG C, mixing time is 10min-
30min;30min is stood after being slowly cooled to room temperature afterwards;
D, it is last sodium carboxymethylcellulose, levelling agent are sequentially added in the mixture that step C is obtained, be modified poly- silica
Alkane, adds heating vessel in heating after mixing, be stirred continuously in heating process;Constant temperature 20min, is again heated to after being heated to 50 DEG C
Constant temperature 10min after 80 DEG C, after being slowly cooled to room temperature afterwards, stands 1h, that is, obtain environment protection oil paint.
Embodiment six:
Paint component includes 50 parts of natural resin, 8 parts of titanium dioxide, 10 parts of white carbon, 15 parts of turpentine oil, poly- by weight
17 parts of aziridine, 15 parts of nano-zinc oxide powder, 10 parts of cellulose acetate, 10 parts of adhesive, modified Nano diatomite in powder 15
Part, 17 parts of sodium carboxymethylcellulose, 3 parts of levelling agent, 10 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane 13
Part.
The preparation method of the present embodiment is comprised the following steps:
It is A, natural resin, titanium dioxide, white carbon, nano-zinc oxide powder, modified Nano diatomite in powder, bean plant is short
It is stirred in addition stirred tank after the mixing of oils alkyd resin, stir speed (S.S.) is 1500 revs/min, and mixing time is 20min, is obtained
To mixture A;
B, addition turpentine oil, polyethyleneimine, cellulose acetate, adhesive in mixture A, add grinder after mixing
Middle grinding 30min, obtains mixture B;
C, afterwards will mixture B add kneading machine in knead, melting temperature be 65 DEG C, mixing time is 20min;Delay afterwards
30min is stood after slow cool down to room temperature;
D, it is last sodium carboxymethylcellulose, levelling agent are sequentially added in the mixture that step C is obtained, be modified poly- silica
Alkane, adds heating vessel in heating after mixing, be stirred continuously in heating process;Constant temperature 20min, is again heated to after being heated to 50 DEG C
Constant temperature 10min after 80 DEG C, after being slowly cooled to room temperature afterwards, stands 1h, that is, obtain environment protection oil paint.
Preparation process is simple of the present invention, preparation process are environment friendly and pollution-free, obtained paint environment-protecting asepsis, with moisture resistance anti-
Water, anti-aging, it is wear-resisting the characteristics of, be coated on bamboo and wood products surface, the service life of bamboo and wood products, the titanium white of addition can be extended
Powder can further enhance the antiseptic property of paint;The nano zine oxide of addition, modified Nano diatomite in powder have antibacterial bacteriostatic,
Effect of the anti-enzyme of taste of dispelling, can extend the storage time of paint;The sodium carboxymethylcellulose of addition, it can be ensured that paint viscosity
Stability and uniformity, so as to improve paint application efficiency;In addition, being added with bean plant short oil class alkyd tree in the present invention
Fat, is prevented from bamboo and wood products's surface oil paint cracking;The modified polyorganosiloxane of addition can further improve the wearability of paint
Can be with anti-scratch performance.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (3)
1. a kind of environment-friendly type bamboo and wood processing oil paint, it is characterised in that:Paint component includes natural resin 40-60 by weight
Part, titanium dioxide 5-10 parts, white carbon 8-12 parts, turpentine oil 10-20 parts, polyethyleneimine 10-25 parts, nano-zinc oxide powder
10-20 parts, cellulose acetate 5-15 parts, adhesive 8-12 parts, 10-20 parts of modified Nano diatomite in powder, sodium carboxymethylcellulose
10-25 parts, levelling agent 1-4 parts, 5-15 parts and modified polyorganosiloxane 8-17 parts of bean plant short oil class alkyd resin.
2. a kind of environment-friendly type bamboo and wood processing oil paint according to claim 1, it is characterised in that:Preferred composition proportion
For:50 parts of natural resin, 8 parts of titanium dioxide, 10 parts of white carbon, 15 parts of turpentine oil, 17 parts of polyethyleneimine, nano-zinc oxide powder
15 parts, 10 parts of cellulose acetate, 10 parts of adhesive, 15 parts of modified Nano diatomite in powder, 17 parts of sodium carboxymethylcellulose, levelling agent
13 parts of 3 parts, 10 parts of bean plant short oil class alkyd resin and modified polyorganosiloxane.
3. a kind of preparation method of the environment-friendly type bamboo and wood processing oil paint described in claim 1 is realized, it is characterised in that:It is prepared
Method is comprised the following steps:
A, by natural resin, titanium dioxide, white carbon, nano-zinc oxide powder, modified Nano diatomite in powder, bean plant short oil class
It is stirred in addition stirred tank after alkyd resin mixing, stir speed (S.S.) is 1000-2000 revs/min, and mixing time is 10min-
30min, obtains mixture A;
B, addition turpentine oil, polyethyleneimine, cellulose acetate, adhesive in mixture A, grind after mixing in addition grinder
Mill 20-40min, obtains mixture B;
C, afterwards will mixture B add kneading machine in knead, melting temperature be 55 DEG C -75 DEG C, mixing time is 10min-
30min;30min is stood after being slowly cooled to room temperature afterwards;
D, sodium carboxymethylcellulose, levelling agent, modified polyorganosiloxane are finally sequentially added in the mixture that step C is obtained, mixed
Heating vessel in heating is added after conjunction, is stirred continuously in heating process;Constant temperature 20min after being heated to 50 DEG C, is again heated to 80 DEG C
Constant temperature 10min, after being slowly cooled to room temperature afterwards, stands 1h afterwards, that is, obtain environment protection oil paint.
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CN108395795A (en) * | 2018-04-13 | 2018-08-14 | 合肥市晨雷思建筑材料科技有限公司 | A kind of high-performance environmentally-friendly type paint and preparation method thereof |
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CN108264847A (en) * | 2017-12-06 | 2018-07-10 | 奉化市春光扑克彩印厂 | A kind of glazing slurry of playing card and preparation method thereof |
CN108395795A (en) * | 2018-04-13 | 2018-08-14 | 合肥市晨雷思建筑材料科技有限公司 | A kind of high-performance environmentally-friendly type paint and preparation method thereof |
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