CN105254210B - A kind of many color stone paints of environment-friendly type and preparation method thereof - Google Patents
A kind of many color stone paints of environment-friendly type and preparation method thereof Download PDFInfo
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- CN105254210B CN105254210B CN201510820887.3A CN201510820887A CN105254210B CN 105254210 B CN105254210 B CN 105254210B CN 201510820887 A CN201510820887 A CN 201510820887A CN 105254210 B CN105254210 B CN 105254210B
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- montmorillonite
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- 239000004575 stone Substances 0.000 title claims abstract description 32
- 239000003973 paint Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 62
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 62
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 propyl lycine Chemical compound 0.000 claims abstract description 22
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 21
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 20
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 20
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 19
- 239000000049 pigment Substances 0.000 claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000007789 sealing Methods 0.000 claims abstract description 11
- 239000012467 final product Substances 0.000 claims abstract description 8
- 238000000527 sonication Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000003513 alkali Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 8
- 239000010438 granite Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000002604 ultrasonography Methods 0.000 description 5
- 238000005034 decoration Methods 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Abstract
The invention discloses many color stone paints of a kind of environment-friendly type and preparation method thereof, many color stone paints of the environment-friendly type are made up of the following raw material according to weight portion：30 45 parts of montmorillonite, 5 15 parts of tetraethyl orthosilicate, 15 parts of pigment, 28 45 parts of thermosetting acrylic resin, 15 parts of cetyl azochlorosulfonate propyl lycine.To the water that 8 10 times of montmorillonite quality is added in montmorillonite, ultrasonically treated, prepared montmorillonite presoma is then carried out.Tetraethyl orthosilicate is inserted in montmorillonite presoma, 30 60min of sealing stirring are carried out at 70 80 DEG C；Then 10 20min are irradiated under infrared lamp again, the montmorillonite solution of pretreatment is obtained.1 2h of stirring is sealed during pigment, thermosetting acrylic resin, cetyl azochlorosulfonate propyl lycine sequentially added into the montmorillonite solution of pretreatment, at 45 50 DEG C, room temperature is down to and is obtained final product many color stone paints of environment-friendly type.All characteristics of the present invention with top-grade building coating, more extremely strong water resistance, alkali resistance, crack resistance and the characteristic such as the feature of environmental protection and weather resistance and adhesive property.
Description
Technical field
The present invention relates to technical field of coatings, specifically a kind of many color stone paints of environment-friendly type and preparation method thereof.
Background technology
As China's economy flourishes rapidly, Living consumption is continuously available improvement, the requirement to quality of life
More and more higher, the quality requirements to itself house are also more and more stricter.People no longer meet simple decoration, more to concern
The graceful generous energy-conserving and environment-protective attractive in appearance, ornament materials of decoration in house.Therefore the painting to being played an important role in house decoraton
Material, people are also strict to its performance requirement.China lives to build portion and also allows for this developing direction, is this in 11th Five-Year
The developing direction for emphasizing coating variety in coating program for the development of science and technology again and again is " three high and one low ", i.e. high-decoration, high-weatherability, Gao Gong
The coating variety of energy property and low stain, this is embodied in Coating Industry in Our Country development, is also China's painting from now on
Material industry continues the direction developed.
During colorful stone-like coating is art coatings, the very big class coating of manufacture difficulty is also called stone-like coating, is to use
Coating imitates stone material, and imitative to do lithotome, its effect is vivid, either texture, or color is all close to lithotome.Such as mesh
Preceding common artificial granite paint kind mainly has：The true mineral varnish of natural real stone paint, artificial granite, oiliness multicolor finish, color piece are applied
Material.Although as an alternative the true mineral varnish of one of product and the true mineral varnish of artificial granite on decorative effect some approach, properties of product
There is preferably performance, but because its primary raw material is natural colour sand, can not follow one's bent in color selection, and product is in itself
The shortcomings of splitting resistance difference stain resistance is not enough, and simulation quality is poor is still suffered from, can only the least a portion of application for substituting granite.Oiliness
Multicolor finish contains organic solvent, harmful, has been eliminated.
The content of the invention
There is preferable water resistance, alkali resistance, crack resistance and weather resistance it is an object of the invention to provide one kind
With many color stone paints of the environment-friendly type of adhesive property and preparation method thereof, to solve the problems, such as to be proposed in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of many color stone paints of environment-friendly type, are made up of the following raw material according to weight portion：Montmorillonite 30-45 parts, positive silicic acid
Tetra-ethyl ester 5-15 parts, pigment 1-5 parts, thermosetting acrylic resin 28-45 parts, 1-5 parts of cetyl azochlorosulfonate propyl lycine.
As further scheme of the invention：The many color stone paints of environment-friendly type, by the following raw material group according to weight portion
Into：Montmorillonite 35-40 parts, tetraethyl orthosilicate 8-12 parts, pigment 2-4 parts, thermosetting acrylic resin 35-40 parts, hexadecane
2-4 parts of base azochlorosulfonate propyl lycine.
As further scheme of the invention：The many color stone paints of environment-friendly type, by the following raw material group according to weight portion
Into：38 parts of montmorillonite, 10 parts of tetraethyl orthosilicate, 3 parts of pigment, 38 parts of thermosetting acrylic resin, cetyl sulfopropyl are sweet
3 parts of dish alkali.
The preparation method of many color stone paints of environment-friendly type, comprises the following steps：
1) to the water that 8-10 times of montmorillonite quality is added in montmorillonite, ultrasonically treated, prepared montmorillonite forerunner is then carried out
Body, ultrasonically treated condition：Ultrasonic power is 150W, and sonication treatment time is 60min；
2) tetraethyl orthosilicate is inserted in montmorillonite presoma, sealing stirring 30-60min is carried out at 70-80 DEG C；So
10-20min is irradiated under infrared lamp again afterwards, the montmorillonite solution of pretreatment is obtained；
3) pigment, thermosetting acrylic resin, cetyl azochlorosulfonate propyl lycine are sequentially added the montmorillonite of pretreatment
Stirring 1-2h is sealed in solution, at 45-50 DEG C, room temperature is down to and is obtained final product many color stone paints of environment-friendly type.
Compared with prior art, the beneficial effects of the invention are as follows：
Excellent stability of the present invention, spreading rate environment friendly decorative material high, its product service life was up to more than 10 years
The preferable substitute such as true mineral varnish of marble, granite, sliver, product properties are excellent, both met environmental protection and energy saving requirement, and
High-grade wall decoration requirement can be reached, is a kind of environment protecting building paint of great potential.
The present invention makes montmorillonite layering, high degree of dispersion by ultrasonically treated, and it is changed using tetraethyl orthosilicate
Property, then mixed with thermosetting acrylic resin, pigment, cetyl azochlorosulfonate propyl lycine, it is uniformly suspended within illiteracy
In de- stone solution, the copolymer of the controllable macromolecule liquid colloidal of colourful, granular size is formd, it not only has height
All characteristics of shelves building coating, more extremely strong water resistance, alkali resistance, crack resistance and the feature of environmental protection and weather resistance and viscous
The characteristics such as knot performance.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of many color stone paints of environment-friendly type are made up of the following raw material according to weight portion：Montmorillonite
30 parts, 5 parts of tetraethyl orthosilicate, 1 part of pigment, 28 parts of thermosetting acrylic resin, 1 part of cetyl azochlorosulfonate propyl lycine.System
When standby, to the water that 8 times of montmorillonite quality is added in montmorillonite, ultrasonically treated, prepared montmorillonite presoma, at ultrasound is then carried out
Manage bar part：Ultrasonic power is 150W, and sonication treatment time is 60min.Tetraethyl orthosilicate is inserted in montmorillonite presoma,
Sealing stirring 30min is carried out at 70 DEG C；Then 10min is irradiated under infrared lamp again, the montmorillonite solution of pretreatment is obtained.By face
Material, thermosetting acrylic resin, cetyl azochlorosulfonate propyl lycine are sequentially added in the montmorillonite solution of pretreatment, close at 45 DEG C
Envelope stirring 1h, is down to room temperature and obtains final product many color stone paints of environment-friendly type.
Embodiment 2
In the embodiment of the present invention, a kind of many color stone paints of environment-friendly type are made up of the following raw material according to weight portion：Montmorillonite
45 parts, 15 parts of tetraethyl orthosilicate, 5 parts of pigment, 45 parts of thermosetting acrylic resin, 5 parts of cetyl azochlorosulfonate propyl lycine.System
When standby, to the water that 10 times of montmorillonite quality is added in montmorillonite, ultrasonically treated, prepared montmorillonite presoma, ultrasound are then carried out
Treatment conditions：Ultrasonic power is 150W, and sonication treatment time is 60min.Tetraethyl orthosilicate is inserted in montmorillonite presoma,
Sealing stirring 60min is carried out at 80 DEG C；Then 20min is irradiated under infrared lamp again, the montmorillonite solution of pretreatment is obtained.Will
Pigment, thermosetting acrylic resin, cetyl azochlorosulfonate propyl lycine are sequentially added in the montmorillonite solution of pretreatment, at 50 DEG C
Sealing stirring 2h, is down to room temperature and obtains final product many color stone paints of environment-friendly type.
Embodiment 3
In the embodiment of the present invention, a kind of many color stone paints of environment-friendly type are made up of the following raw material according to weight portion：Montmorillonite
35 parts, 8 parts of tetraethyl orthosilicate, 2 parts of pigment, 35 parts of thermosetting acrylic resin, 2 parts of cetyl azochlorosulfonate propyl lycine.System
When standby, to the water that 8.5 times of montmorillonite quality is added in montmorillonite, ultrasonically treated, prepared montmorillonite presoma, ultrasound are then carried out
Treatment conditions：Ultrasonic power is 150W, and sonication treatment time is 60min.Tetraethyl orthosilicate is inserted in montmorillonite presoma,
Sealing stirring 40min is carried out at 73 DEG C；Then 13min is irradiated under infrared lamp again, the montmorillonite solution of pretreatment is obtained.Will
Pigment, thermosetting acrylic resin, cetyl azochlorosulfonate propyl lycine are sequentially added in the montmorillonite solution of pretreatment, at 46 DEG C
Sealing stirring 1.2h, is down to room temperature and obtains final product many color stone paints of environment-friendly type.
Embodiment 4
In the embodiment of the present invention, a kind of many color stone paints of environment-friendly type are made up of the following raw material according to weight portion：Montmorillonite
40 parts, 12 parts of tetraethyl orthosilicate, 4 parts of pigment, 40 parts of thermosetting acrylic resin, 4 parts of cetyl azochlorosulfonate propyl lycine.System
When standby, to the water that 10 times of montmorillonite quality is added in montmorillonite, ultrasonically treated, prepared montmorillonite presoma, ultrasound are then carried out
Treatment conditions：Ultrasonic power is 150W, and sonication treatment time is 60min.Tetraethyl orthosilicate is inserted in montmorillonite presoma,
Sealing stirring 50min is carried out at 78 DEG C；Then 17min is irradiated under infrared lamp again, the montmorillonite solution of pretreatment is obtained.Will
Pigment, thermosetting acrylic resin, cetyl azochlorosulfonate propyl lycine are sequentially added in the montmorillonite solution of pretreatment, at 49 DEG C
Sealing stirring 1.5h, is down to room temperature and obtains final product many color stone paints of environment-friendly type.
Embodiment 5
In the embodiment of the present invention, a kind of many color stone paints of environment-friendly type are made up of the following raw material according to weight portion：Montmorillonite
38 parts, 10 parts of tetraethyl orthosilicate, 3 parts of pigment, 38 parts of thermosetting acrylic resin, 3 parts of cetyl azochlorosulfonate propyl lycine.System
When standby, to the water that 9 times of montmorillonite quality is added in montmorillonite, ultrasonically treated, prepared montmorillonite presoma, at ultrasound is then carried out
Manage bar part：Ultrasonic power is 150W, and sonication treatment time is 60min.Tetraethyl orthosilicate is inserted in montmorillonite presoma,
Sealing stirring 45min is carried out at 75 DEG C；Then 15min is irradiated under infrared lamp again, the montmorillonite solution of pretreatment is obtained.By face
Material, thermosetting acrylic resin, cetyl azochlorosulfonate propyl lycine are sequentially added in the montmorillonite solution of pretreatment, close at 47 DEG C
Envelope stirring 1.5h, is down to room temperature and obtains final product many color stone paints of environment-friendly type.
Five above-mentioned embodiments are according to JG/T4342-2012 aqueous colorfuls building coating (non-resilient), JG/T24-2000
The technical requirements of synthetic resin sand textured building coating (W types (external application)), and will not carry out it is ultrasonically treated, remaining step with implement
Example 5 consistent as a comparison case 1, will be added without tetraethyl orthosilicate, remaining step consistent with embodiment 5 as a comparison case 2, and it is surveyed
Test result is as shown in table 1.
Table 1
As can be known from the above table, treatment of the ultrasonically treated and tetraethyl orthosilicate to montmorillonite make the present invention have water resistance,
Alkali resistance good and excellent weather resistance and adhesive property.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires to be limited rather than described above, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (3)
1. the preparation method of many color stone paints of a kind of environment-friendly type, it is characterised in that many color stone paints of environment-friendly type are by following according to weight
Measure the raw material composition of part：Montmorillonite 30-45 parts, tetraethyl orthosilicate 5-15 parts, pigment 1-5 parts, thermosetting acrylic resin 28-
45 parts, 1-5 parts of cetyl azochlorosulfonate propyl lycine；Its preparation method is comprised the following steps：
1) to the water that 8-10 times of montmorillonite quality is added in montmorillonite, ultrasonically treated, prepared montmorillonite presoma is then carried out, is surpassed
Sonication condition：Ultrasonic power is 150W, and sonication treatment time is 60min；
2) tetraethyl orthosilicate is inserted in montmorillonite presoma, sealing stirring 30-60min is carried out at 70-80 DEG C；Then again
10-20min is irradiated under infrared lamp, the montmorillonite solution of pretreatment is obtained；
3) pigment, thermosetting acrylic resin, cetyl azochlorosulfonate propyl lycine are sequentially added the montmorillonite solution of pretreatment
In, stirring 1-2h is sealed at 45-50 DEG C, it is down to room temperature and obtains final product many color stone paints of environment-friendly type.
2. the preparation method of many color stone paints of environment-friendly type according to claim 1, it is characterised in that the environment-friendly type is colorful
Stone coating is made up of the following raw material according to weight portion：Montmorillonite 35-40 parts, tetraethyl orthosilicate 8-12 parts, pigment 2-4 parts,
Thermosetting acrylic resin 35-40 parts, 2-4 parts of cetyl azochlorosulfonate propyl lycine.
3. the preparation method of many color stone paints of environment-friendly type according to claim 2, it is characterised in that the environment-friendly type is colorful
Stone coating is made up of the following raw material according to weight portion：38 parts of montmorillonite, 10 parts of tetraethyl orthosilicate, 3 parts of pigment, thermosetting third
38 parts of olefin(e) acid resin, 3 parts of cetyl azochlorosulfonate propyl lycine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510820887.3A CN105254210B (en) | 2015-11-24 | 2015-11-24 | A kind of many color stone paints of environment-friendly type and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510820887.3A CN105254210B (en) | 2015-11-24 | 2015-11-24 | A kind of many color stone paints of environment-friendly type and preparation method thereof |
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| CN105254210A CN105254210A (en) | 2016-01-20 |
| CN105254210B true CN105254210B (en) | 2017-05-31 |
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| CN107325674A (en) * | 2017-06-08 | 2017-11-07 | 惠安县灿鑫新材料科技有限公司 | A kind of environmental protection coating material of weatherability and preparation method thereof |
| CN108191307B (en) * | 2017-12-25 | 2020-10-09 | 厦门市固力克节能科技有限公司 | Anti-drop graphene stone-like paint and preparation method thereof |
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| CN1206299C (en) * | 2003-03-26 | 2005-06-15 | 武汉理工大学 | Nano modified polymer-based roof waterproof paint and its production process |
| CN102127354A (en) * | 2010-12-16 | 2011-07-20 | 大连晟禾科技发展有限公司 | Water-based paint highly simulating granite and marble and preparation method thereof |
| CN102807792A (en) * | 2011-05-30 | 2012-12-05 | 天津天涂豪邦涂料有限公司 | Aqueous stone-like paint and preparation method thereof |
| CN104178013A (en) * | 2014-09-09 | 2014-12-03 | 江苏美亿晨新材料科技有限公司 | Environment-friendly water-based nano varnish and preparation method |
| CN104761990B (en) * | 2015-04-28 | 2017-03-01 | 重庆卡勒斯通科技有限公司 | A kind of imitative stone material nano paint and its processing technology |
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Denomination of invention: The invention relates to an environment-friendly polychromatic stone coating and a preparation method thereof Effective date of registration: 20220321 Granted publication date: 20170531 Pledgee: China Everbright Bank Limited by Share Ltd. Xiamen branch Pledgor: XIAMEN GULIKE ENERGY SAVING TECHNOLOGY Co.,Ltd. Registration number: Y2022980002826 |
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Date of cancellation: 20231201 Granted publication date: 20170531 Pledgee: China Everbright Bank Limited by Share Ltd. Xiamen branch Pledgor: XIAMEN GULIKE ENERGY SAVING TECHNOLOGY Co.,Ltd. Registration number: Y2022980002826 |