CN104817916A - Water-in-water colorful paint and preparation method thereof - Google Patents
Water-in-water colorful paint and preparation method thereof Download PDFInfo
- Publication number
- CN104817916A CN104817916A CN201510229224.4A CN201510229224A CN104817916A CN 104817916 A CN104817916 A CN 104817916A CN 201510229224 A CN201510229224 A CN 201510229224A CN 104817916 A CN104817916 A CN 104817916A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- water
- granulation
- toning
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a water-in-water colorful paint and a preparation method thereof. The water-in-water colorful paint includes a color toning emulsion and a granulation emulsion, wherein the granulation emulsion is in a continuous phase and is prepared by adding sodium tetraborate into a synthetic resin silicone acrylic emulsion with stirring uniformly; and the color toning emulsion is in a dispersed phase and is prepared by adding hydroxyethyl cellulose into a polyvinyl acetate co-polymer emulsion with stirring uniformly. The preparation method includes the steps of preparing the color toning emulsion, the granulation emulsion and elastic latex paints in various colors, adding the elastic latex paints into the color toning emulsion with stirring uniformly, and adding a mixture of the color toning emulsion and the elastic latex paints into the granulation emulsion with stirring uniformly. The water-in-water colorful paint is prepared with the granulation emulsion as the continuous phase and the color toning emulsion as the dispersed phase to form a two-phase emulsion. The preparation method is simple and is controllable in hardness of prepared granules. The paint is clear in color and is excellent in storage stability.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of water-water multicolor finish and preparation method thereof.
Background technology
Water-water multicolor finish is the high-tech coating products of full water-based, many colors, environment-friendly type, is mainly used in imitative various natural marble, has high fidelity, and have fabulous sticking power and elasticity, and its suspended weights is only 1/20th of true mineral varnish.The water-repellancy of water-water multicolor finish and weathering resistance are all better than true mineral varnish, both modern environmental protection and energy saving consciousness had been embodied, turn improve decoration grade, compare with stone materials such as grouan, water-water multicolor finish has good application property, not only shorten the duration to a great extent, reduce engineering cost, and more colorful simulated effect can be drawn out according to the design of oneself.
Exactly because the superiority that above-mentioned water-water multicolor finish highlights in coating industry and creativeness, therefore approve by increasing insider, the R&D force of water-water multicolor finish grew stronger day by day over the past two years, but the producer of real grasp water-water multicolor finish technology is very few.And the water-water multicolor finish manufacture craft of most of manufacturer production is loaded down with trivial details, poor storage stability, cost is relatively high, is difficult to left-hand seat actually operating.Therefore our factory is through repetition test, finally successfully have developed good stability, manufactures simple two phase emulsions, is made that color is various, simulated effect good, the water-water multicolor finish of good springiness by external phase emulsion and disperse phase emulsion.
Summary of the invention
The object of the invention is to provide a kind of water-water multicolor finish and preparation method thereof, make it allocate easily, good stability, good springiness, convenient construction.
For solving the problem, the invention provides a kind of water-water multicolor finish, comprise toning emulsion and granulation emulsion, wherein, described granulation emulsion is external phase emulsion, and the preparation method of granulation emulsion stirs for adding sodium tetraborate in synthetic resins organosilicon crylic acid latex; Described toning emulsion is disperse phase emulsion, and the preparation method of toning emulsion stirs for adding Natvosol in Vinyl Acetate Copolymer copolymer emulsion.
Further, every kilogram of synthetic resins organosilicon crylic acid latex adds 3-5 gram of sodium tetraborate; 5-15 gram of Natvosol is added in every kilogram of Vinyl Acetate Copolymer copolymer emulsion.
The present invention also provides the preparation method of above-mentioned multicolor finish, A. in synthetic resins organosilicon crylic acid latex, first add sodium tetraborate stir and form granulation emulsion, add in Vinyl Acetate Copolymer copolymer emulsion Natvosol stir formed toning emulsion, ordinary elasticity emulsion paint is recalled required color on demand;
B. the elastic emulsion paint of the shades of colour modulated is joined in proportion respectively in toning emulsion, and the elastic emulsion paint of often kind of color is stirred with toning emulsion respectively;
C. granulation emulsion is poured in stirred vessel, then the emulsion of the shades of colour mixed in step B is poured in granulation emulsion in order respectively, stirring-granulating.
Further, the massfraction of the titanium white in described elastic emulsion paint is greater than 10%.
Further, described step B Elastic emulsion paint is 1:9 with the additional proportion of toning emulsion.
Further, also containing sand in described toning emulsion, sand is 35:65-40:60 with the ratio of toning emulsion; The emulsion and the mixture of sand and the ratio of granulation emulsion of mixing colours during granulation is 2:1.
Adopt granulation emulsion as external phase, toning emulsion as disperse phase, two kinds of emulsions can be allocated respectively and can carry out mixed preparing according to different demands, the water-water multicolor finish manufacture method adopting this two phase emulsion to prepare is simple, the particle made, soft durometer can control, look grain is clear, and stability in storage is strong, and solves the technical barrier of rear thickening.
Select Vinyl Acetate Copolymer copolymer emulsion to do reactant and can be reacted into gel with sodium tetraborate, and there is lower film-forming temperature, low temperature flexibility, and high adhesive force, can cracking resistance, Natvosol is selected to do hardness regulator in granulation emulsion, gel controllability can be solved, make gel hard soft suitable.
There is good application property, can reduction of erection time greatly, reduce engineering cost, and can allow and build Designerss by constructing to the perfection of water-water multicolor finish, more can show a kind of beyond thought grouan simulated effect, make it have decorative, the thick and heavy property of texture of grouan.
Embodiment
Embodiment 1
The invention provides a kind of water-water multicolor finish, comprise toning emulsion and granulation emulsion, wherein, described granulation emulsion is external phase emulsion, and the preparation method of external phase emulsion stirs for adding sodium tetraborate in synthetic resins organosilicon crylic acid latex; Described toning emulsion is disperse phase emulsion, and the preparation method of disperse phase emulsion stirs for adding Natvosol in Vinyl Acetate Copolymer copolymer emulsion.
According to required color, hardness, two kinds of emulsions can be allocated during use.Sodium tetraborate can be used as the gelifying agent reacted with Vinyl Acetate Copolymer copolymer emulsion, select Vinyl Acetate Copolymer copolymer emulsion to do reactant and can be reacted into gel with sodium tetraborate, and there is lower film-forming temperature, low temperature flexibility, and high adhesive force, can cracking resistance, select Natvosol to do hardness regulator in granulation emulsion, gel controllability can be solved, make gel hard soft suitable.
Preferably, every kilogram of synthetic resins organosilicon crylic acid latex adds 3-5 gram of sodium tetraborate; Add 5-15 gram of Natvosol in every kilogram of Vinyl Acetate Copolymer copolymer emulsion, add-on can regulate the requirement of hardness according to client.
The present invention also provides the preparation method of above-mentioned multicolor finish, A. in synthetic resins organosilicon crylic acid latex, first add sodium tetraborate stir and form granulation emulsion, add in Vinyl Acetate Copolymer copolymer emulsion Natvosol stir formed toning emulsion, ordinary elasticity emulsion paint is recalled required color on demand;
B. the elastic emulsion paint of the shades of colour modulated is joined in proportion respectively in toning emulsion, and the elastic emulsion paint of often kind of color is stirred with toning emulsion respectively, require the color of the elastic emulsion paint selecting to add according to client's model, described elastic emulsion paint is 1:9 with the mass ratio of toning emulsion;
The titanium white content of elastic emulsion paint can not be too low, and preferably, titanium white content answers > 10%, and the too low toning emulsion of titanium white content easily waters down colored paint, causes the dry rear and actual color deviation of color grain, be unfavorable for color matching.
C. granulation emulsion is poured in stirred vessel, then the emulsion of the shades of colour mixed in step B is poured in granulation emulsion in order respectively, stirring-granulating;
According to the size of made particle, the mixed emulsion of set-up procedure B and the ratio of granulation emulsion,
Middle grain: mixed emulsion and granulation emulsion ratio 1:0.4-0.6,
Middle granule and particle: mixed emulsion and granulation emulsion ratio 1:1-1.2.
The particle of different size needs independent granulation.
Embodiment 2
The key distinction part of the present embodiment and embodiment 1 is, employing carbon black color paste directly replaces the elastic emulsion paint in step B, and carbon black color paste is 1:99 with the mass ratio of toning emulsion, can by color furnishing black.
Embodiment 3
The key distinction part of the present embodiment and embodiment 1 is, also containing sand in described toning emulsion, sand is 35:65-40:60 with the mass ratio of toning emulsion, and because the particle diameter of sand is different, this is than regular meeting slightly difference; The emulsion and the mixture of sand and the mass ratio of granulation emulsion of mixing colours during granulation is 2:1.
The above; it is only preferred embodiment of the present invention; not do any pro forma restriction to the present invention, those skilled in the art utilize the technology contents of above-mentioned announcement to make a little simple modification, equivalent variations or modification, all drop in protection scope of the present invention.
Claims (6)
1. a water-water multicolor finish, is characterized in that, comprise toning emulsion and granulation emulsion, wherein, described granulation emulsion is external phase emulsion, and the preparation method of granulation emulsion stirs for adding sodium tetraborate in synthetic resins organosilicon crylic acid latex; Described toning emulsion is disperse phase emulsion, and the preparation method of toning emulsion stirs for adding Natvosol in Vinyl Acetate Copolymer copolymer emulsion.
2. water-water multicolor finish according to claim 1, is characterized in that, every kilogram of synthetic resins organosilicon crylic acid latex adds 3-5 gram of sodium tetraborate; 5-15 gram of Natvosol is added in every kilogram of Vinyl Acetate Copolymer copolymer emulsion.
3. the preparation method of water-water multicolor finish according to claim 1, is characterized in that,
A. in synthetic resins organosilicon crylic acid latex, first add sodium tetraborate stir and form granulation emulsion, in Vinyl Acetate Copolymer copolymer emulsion, add Natvosol stir and form toning emulsion, ordinary elasticity emulsion paint is recalled required color on demand;
B. the elastic emulsion paint of the shades of colour modulated is joined in proportion respectively in toning emulsion, and the elastic emulsion paint of often kind of color is stirred with toning emulsion respectively;
C. granulation emulsion is poured in stirred vessel, then the emulsion of the shades of colour mixed in step B is poured in granulation emulsion in order respectively, stirring-granulating.
4. the preparation method of water-water multicolor finish according to claim 3, is characterized in that, the massfraction of the titanium white in described elastic emulsion paint is greater than 10%.
5. the preparation method of water-water multicolor finish according to claim 3, is characterized in that, described step B Elastic emulsion paint is 1:9 with the additional proportion of toning emulsion.
6. the preparation method of water-water multicolor finish according to claim 3, is characterized in that, also containing sand in described toning emulsion, sand is 35:65-40:60 with the ratio of toning emulsion; The emulsion and the mixture of sand and the ratio of granulation emulsion of mixing colours during granulation is 2:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510229224.4A CN104817916B (en) | 2015-05-07 | 2015-05-07 | A kind of water-in-water multicolor coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510229224.4A CN104817916B (en) | 2015-05-07 | 2015-05-07 | A kind of water-in-water multicolor coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104817916A true CN104817916A (en) | 2015-08-05 |
| CN104817916B CN104817916B (en) | 2017-05-31 |
Family
ID=53728409
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510229224.4A Active CN104817916B (en) | 2015-05-07 | 2015-05-07 | A kind of water-in-water multicolor coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104817916B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255268A (en) * | 2015-10-28 | 2016-01-20 | 漳州三德利油漆涂料有限公司 | Nanometer-anion functional water-in-water inner wall coating and preparing method thereof |
| CN105694640A (en) * | 2016-01-29 | 2016-06-22 | 烟台同化防水保温工程有限公司 | Multifunctional water-in-water multicolor coating and production method thereof |
| CN107022270A (en) * | 2017-05-16 | 2017-08-08 | 威海新元化工有限公司 | A kind of preparation method of fluorinated silicone modified stone similar paint |
| CN107365518A (en) * | 2017-08-31 | 2017-11-21 | 白建宏 | A kind of preparation method of colorful parian paint |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004083840A (en) * | 2002-02-07 | 2004-03-18 | Sk Kaken Co Ltd | Multiply colored pattern-coating material composition |
| CN102643587A (en) * | 2012-03-21 | 2012-08-22 | 深圳市嘉达节能环保科技有限公司 | Water-in water type colorful thermal insulation coating and preparation method thereof |
| CN102690567A (en) * | 2012-06-01 | 2012-09-26 | 安徽省金盾涂料有限责任公司 | Aqueous multicolor paint and preparation method thereof |
| CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
| CN103421394A (en) * | 2013-08-22 | 2013-12-04 | 海洋化工研究院有限公司 | Preparation method and application of functional water-based heat-radiative color paint |
-
2015
- 2015-05-07 CN CN201510229224.4A patent/CN104817916B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004083840A (en) * | 2002-02-07 | 2004-03-18 | Sk Kaken Co Ltd | Multiply colored pattern-coating material composition |
| CN102643587A (en) * | 2012-03-21 | 2012-08-22 | 深圳市嘉达节能环保科技有限公司 | Water-in water type colorful thermal insulation coating and preparation method thereof |
| CN102690567A (en) * | 2012-06-01 | 2012-09-26 | 安徽省金盾涂料有限责任公司 | Aqueous multicolor paint and preparation method thereof |
| CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
| CN103421394A (en) * | 2013-08-22 | 2013-12-04 | 海洋化工研究院有限公司 | Preparation method and application of functional water-based heat-radiative color paint |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255268A (en) * | 2015-10-28 | 2016-01-20 | 漳州三德利油漆涂料有限公司 | Nanometer-anion functional water-in-water inner wall coating and preparing method thereof |
| CN105694640A (en) * | 2016-01-29 | 2016-06-22 | 烟台同化防水保温工程有限公司 | Multifunctional water-in-water multicolor coating and production method thereof |
| CN105694640B (en) * | 2016-01-29 | 2018-05-25 | 烟台同化防水保温工程有限公司 | A kind of production method of Mobyneb water-in-water multicolor coating |
| CN107022270A (en) * | 2017-05-16 | 2017-08-08 | 威海新元化工有限公司 | A kind of preparation method of fluorinated silicone modified stone similar paint |
| CN107365518A (en) * | 2017-08-31 | 2017-11-21 | 白建宏 | A kind of preparation method of colorful parian paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104817916B (en) | 2017-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105601166B (en) | A kind of lacquer of temperature variation resistant construction and preparation method thereof | |
| CN101591491B (en) | Full water-borne granite multicolor paint and preparation method thereof | |
| CN103254720B (en) | A kind of low-temperature setting aqueous glass paint and preparation method thereof | |
| CN104817916A (en) | Water-in-water colorful paint and preparation method thereof | |
| CN102643587A (en) | Water-in water type colorful thermal insulation coating and preparation method thereof | |
| CN110540783B (en) | Matte water-in-water base paint, preparation method and matte water-in-water coating | |
| CN103254710A (en) | Scraping water-in-water multi-color paint and preparation method thereof | |
| CN103849280A (en) | Preparation method of ultra-stable high-weather-resistance water-in-water granite-like multicolor paint | |
| CN107142020B (en) | A kind of environment-friendly imitation stone texture artistic floors coating and preparation method thereof | |
| CN106280806A (en) | A kind of aqueous reflective insulation water burnt-in sand imitates bush-hammered face coating and preparation method thereof | |
| CN106280817A (en) | Aqueous colorful luminous paint and preparation method thereof | |
| CN107573791A (en) | A kind of environment-friendly type inner wall face sealing wax | |
| CN101343436A (en) | Novel water-covering water gorgeous paint and preparation thereof | |
| CN105086554A (en) | Artistic pigment and preparation method thereof | |
| CN102807792A (en) | Aqueous stone-like paint and preparation method thereof | |
| CN104761967A (en) | W/W sand brick-containing rock coating | |
| CN102584114A (en) | Tile-like sand wall-textured coating for exterior walls and preparation method thereof | |
| CN103030335A (en) | Colored rock paint and preparation method thereof | |
| CN102690550A (en) | Production process of water-based colorful paint | |
| CN104745027A (en) | Multicolor stone-like paint with soft color particles as well as preparation method and applying method thereof | |
| CN102311691A (en) | Novel colorful wall paint | |
| CN101723705A (en) | Fully water based granite multicolor paint | |
| CN105038456A (en) | Imitative amphibole granite colorful coating and preparation method thereof | |
| CN107573788A (en) | A kind of true mineral varnish coating of exterior wall | |
| CN102181196A (en) | Water-in-water colorful stone simulated paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a water in water colorful coating and a preparation method thereof Effective date of registration: 20211119 Granted publication date: 20170531 Pledgee: Yantai anjiali New Material Technology Co.,Ltd. Pledgor: YANTAI ANJIALI COATINGS TECHNOLOGY CO.,LTD. Registration number: Y2021980012871 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220505 Granted publication date: 20170531 Pledgee: Yantai anjiali New Material Technology Co.,Ltd. Pledgor: YANTAI ANJIALI COATINGS TECHNOLOGY CO.,LTD. Registration number: Y2021980012871 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |