CN104761967A - W/W sand brick-containing rock coating - Google Patents

W/W sand brick-containing rock coating Download PDF

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Publication number
CN104761967A
CN104761967A CN201510104472.6A CN201510104472A CN104761967A CN 104761967 A CN104761967 A CN 104761967A CN 201510104472 A CN201510104472 A CN 201510104472A CN 104761967 A CN104761967 A CN 104761967A
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China
Prior art keywords
agent
water
deionized water
paint
glue solution
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Pending
Application number
CN201510104472.6A
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Chinese (zh)
Inventor
许良前
苌光贾
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Anhui Province Shellfish Lives In Peace Energy-Saving Building Materials Science And Technology Ltd
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Anhui Province Shellfish Lives In Peace Energy-Saving Building Materials Science And Technology Ltd
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Application filed by Anhui Province Shellfish Lives In Peace Energy-Saving Building Materials Science And Technology Ltd filed Critical Anhui Province Shellfish Lives In Peace Energy-Saving Building Materials Science And Technology Ltd
Priority to CN201510104472.6A priority Critical patent/CN104761967A/en
Publication of CN104761967A publication Critical patent/CN104761967A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a W/W sand brick-containing rock coating, which is composed of 25-35 parts by weight of a continuous phase and 65-75 parts by weight of a dispersing phase. The dispersing phase is composed of a basic paint, a colored paint and a protective glue solution and the dispersing phase is composed of protective glue and deionized water. The basic paint is prepared from deionized water, a dispersing agent, a wetting agent, a defoaming agent, a sterilizing agent, glycol, a film-forming aid, a thickening agent, a pH value regulator, rutile titanium dioxide, kaolin, silicone acrylic emulsion, a modifying agent and a protective glue solution. The colored paint is prepared from the basic paint and quartz sand. The continuous phase is prepared from the silicone acrylic emulsion, a film-forming aid, ethylene glycol, a sterilizing agent, a modifying agent and deionized water. The coating not only can form a glaze marble-like effect but also can form a burning stone effect, is simple in construction, allows one-step spray moulding. A building material finish product sprayed by the coating is plain and elegant in appearance, has a natural and smooth texture of granite, which is completely naturally formed, and is super strong in contaminant resistance and self-cleaning performance.

Description

A kind of water-water is containing sanded brick rock coating
Technical field
The present invention relates to a kind of skin decorative paint, particularly relate to a kind of water-water containing sanded brick rock coating.
Background technology
Along with China buildings is fast-developing, people require more and more higher to buildings, and decoration of exterior wall is usually decorated by modes such as natural granite are cladding.Granite is a kind of natural stone material, belongs to magmatite, is widely used in the outdoor facing of building.But granite cost is very expensive and tellurian resource is more limited, and has public danger at external wall as facing, not easily big area or external wall of high-rise building are shown consideration for and are established use, and thus its application is limited to.In order to buildings can reach the luxurious effect of granitic outward appearance, in recent years, imitated granitic material is constantly gushed out, because the many opposite sex of granitic color make imitating technology very complicated, people need a kind of imitated easy coating to simplify the complicacy of imitating technology, under this background, true mineral varnish and multicolor finish arise at the historic moment, to replace cladding marble and to paste facing tile.True mineral varnish is the coating that a kind of decorative effect exactly likes marble, grouan.The natural stone-powder of main employing shades of colour is formulated.Buildings after true mineral varnish finishing, has natural real natural colour, gives elegance, harmony, serious aesthetic feeling, be suitable for the indoor and outdoor decoration of all kinds of buildings.Particularly decorate on curved-surface building thing, vivid, there is a kind of effect of back to nature.But its coating surface is coarse, uneven, both do not had the texture that natural granite is beautiful, also do not have the feel of stone material and inhale ash, laying dust, color is single, and resistance to soiling is poor; Multicolor finish is then with pigment to adjust colour particles, after coating, due to uneven, there is dispersion and multiple color decorative pattern can be obtained, stereoscopic sensation is strong, gloss is graceful, appearance tactile impression is good relief-type coating.But do embossment coating or imitative burnt stone effect with multicolor finish, exist on the one hand because pigment is selected improper, make multicolor finish generation colour particles interpenetrate and alter look phenomenon, so that rear thickening, cause multicolor finish to go bad the problem of dyeing; On the other hand, construction is comparatively complicated, first must could spray multicolor finish with after true mineral varnish bottoming.
Summary of the invention
The object of the present invention is to provide one can do exiting surface marble class effect, can make burnt stone effect again and easy construction, the water-water of a spray mo(u)lding is containing sanded brick rock coating.
Its technical scheme is: a kind of water-water containing sanded brick rock coating, is characterized in that it is made up of the external phase of following weight part and disperse phase, external phase: 25-35, disperse phase: 65-75;
Wherein, disperse phase is made up of base paint, colored paint and protecting glue solution:
Described protecting glue solution is formulated by the composition of following weight part: protecting glue 6-8, deionized water 92-94;
Described base paint is formulated by the composition of following weight part: deionized water 45-55, dispersion agent 0.4-0.7, wetting agent 0.05-0.15, defoamer 0.3-0.5, sterilant 0.1-0.2, ethylene glycol 0.5-1.5, film coalescence aid 0.5-0.7, thickening material 0.4-0.6, pH value conditioning agent 0.1-0.4, rutile titanium white powder 0.5-1.5, kaolin 9-11, organosilicon crylic acid latex 35-45, properties-correcting agent 0.7-0.9, protecting glue solution 5-7;
Described colored paint is formulated by the composition of following weight part: base paint 50-67, quartz sand 33-50;
External phase is formulated by the composition of following weight part: organosilicon crylic acid latex 20-30, film coalescence aid 1-2, ethylene glycol 1-2, sterilant 0.1-0.15, properties-correcting agent 0.3-0.4, deionized water 2-3.
Water-water contains a preparation method for sanded brick rock coating,
1) disperse phase is prepared
1. the preparation of protecting glue solution: by the weight proportion of above-mentioned protecting glue solution, protecting glue and deionized water are placed in after reactor disperses 25min, 600 revs/min of stirring and dissolving are not to having particle completely;
2. the preparation of base paint: by the weight proportion of above-mentioned base paint, adjusts viscosity to 90-120KU deionized water, dispersion agent, wetting agent, defoamer, sanitas, rutile titanium white powder, kaolin, thickening material, pH value conditioning agent, ethylene glycol, film coalescence aid, organosilicon crylic acid latex, properties-correcting agent and colloidal solution;
3. the preparation of colored paint: by the weight proportion of above-mentioned colored paint, by base paint and color sand mix and blend;
4. in protecting glue solution, above-mentioned colored paint is added, obtained disperse phase;
2) lacquering, by disperse phase and external phase mix and blend by weight proportion, obtains water-water containing sanded brick rock coating.
Its beneficial effect is: water-water of the present invention contains sanded brick rock coating with water-based organosilicon crylic acid latex for external phase, replace the pigment of multicolor finish as filler with sand, incorporate the physical change of material and the multinomial conversion of chemical reaction, the water-base resin of liquid state is refined the jellied hydrate colour particle of parcel, and be suspended in equably in water-based emulsion, the multipolymer of the macromolecular liquid glue that final formation granular size is random, exiting surface marble class effect can be done, the effect of burnt stone can be made again and easy construction, a spray mo(u)lding.The building finished product crossed through paint spay-coating of the present invention highlights simple beautiful, flower hilllock texture, natural and tripping, completely blends, has superpower contamination resistance and self-cleaning function.The defect that it existed laying dust after both having overcome the spraying of true mineral varnish, color is single, resistance to soiling is poor etc., solve again multicolor finish colour particles easily occurs to interpenetrate and alter look, so that the even rotten dyeing of rear thickening and imitative burnt stone effect must spray the problems such as numerous and diverse operational procedure of multicolor finish again with the first bottoming of true mineral varnish, and its raw material is easy to get, make easily, cost is lower, is a kind of ideal height emulation water-based art coatings.
Embodiment
Embodiment 1.A kind of water-water is containing the preparation of sanded brick rock coating:
1) disperse phase is prepared:
Get the protecting glue of 6.8kg, the deionized water of 93.2kg, be placed in after reactor disperses 25min, 600 revs/min of stirring and dissolving to there is no particle completely, obtained protecting glue solution;
Get the deionized water of 48kg, the poly carboxylic acid sodium dispersion agent of 0.60kg, the non-ionic surfactant wetting agent of 0.12kg, the aliphatic hydrocarbon of 0.45kg and emulsifying agent mixture foam killer defoamer, the N-methyl-isothiazol quinoline ketone of 0.18kg and 5-chlorine one isothiazolinone mixed bactericide, the rutile titanium white powder of 0.9kg, the 4000 order calcined kaolins of 9.5kg, 30,000 viscosity hydroxyethyl celluloses (non-associative thickener) of 0.6kg, the pH value conditioning agent of 0.2kg, the ethylene glycol of 1kg, the film coalescence aid of 0.7kg, the organosilicon crylic acid latex of 42kg, the non-ionic associative type rheology modifier of 0.7kg, the protecting glue solution of 7kg, adjust viscosity to 90-120KU, obtained base paint, sterilant wherein must use by after the dilution proportion of 1:10 with water, and non-ionic associative type rheology modifier uses after must being mixed with the aqueous solution of 2% with deionized water,
Get the base paint of 50kg, the color sand of 80-120 order of 50kg, obtained colored paint;
Get the colored paint of 64.3kg, add the protecting glue solution of 35.7kg, obtained disperse phase;
2) lacquering, get the disperse phase of 70kg and the organosilicon crylic acid latex by 20kg, the film coalescence aid of 1kg, the ethylene glycol of 1kg, the non-ionic associative type rheology modifier of 0.3kg, the sterilant of 0.1kg, the external phase that the deionized water of 2kg is formed mixes, slow stirring (no thoroughfare dispersion impeller high speed shear), obtains water-water containing sanded brick rock coating.
Embodiment 2.A kind of water-water is containing the preparation of sanded brick rock coating:
1) disperse phase is prepared:
Get the protecting glue of 8kg, the deionized water of 92kg, be placed in after reactor disperses 30min, 600 revs/min of stirring and dissolving to there is no particle completely, obtained protecting glue solution;
Get the deionized water of 50kg, the poly carboxylic acid sodium dispersion agent of 0.60kg, the non-ionic surfactant wetting agent of 0.1kg, the aliphatic hydrocarbon of 0.4kg and emulsifying agent mixture foam killer, the N-methyl-isothiazol quinoline ketone of 0.15kg and 5-chlorine one isothiazolinone mixed bactericide, the rutile titanium white powder of 1.0kg, the 4000 order calcined kaolins of 10.5kg, 30,000 viscosity hydroxyethyl celluloses (non-associative thickener) of 0.4kg, AMP-95 (the 2-amino-2-methyl-1-propanol of 0.2kg, pH value conditioning agent), the ethylene glycol of 1kg, the film coalescence aid of 0.6kg, the organosilicon crylic acid latex of 42kg, the non-ionic associative type rheology modifier of 0.7kg, the protecting glue solution of 6kg, adjust viscosity to 80-100KU, obtained base paint, sterilant wherein must use by after the dilution proportion of 1:10 with water, and non-ionic associative type rheology modifier uses after must being mixed with the aqueous solution of 2% with deionized water,
Get the base paint of 67kg, the color sand of 80-120 order of 33kg, obtained colored paint;
Get the colored paint of 63kg, add the protecting glue solution of 37kg, obtained disperse phase;
2) lacquering, get the disperse phase of 60kg and the organosilicon crylic acid latex by 25kg, 1.25kg film coalescence aid, the ethylene glycol of 1kg, the alkali swelling type thickening material of 0.3kg, the sterilant of 0.1kg, the external phase that the deionized water of 3kg is formed mixes, slow stirring (no thoroughfare dispersion impeller high speed shear), obtains water-water containing sanded brick rock coating.

Claims (3)

1. water-water is containing a sanded brick rock coating, it is characterized in that it is made up of the external phase of following weight part and disperse phase, external phase: 25-35, disperse phase: 65-75;
Wherein, disperse phase is made up of base paint, colored paint and protecting glue solution:
Described protecting glue solution is formulated by the composition of following weight part: protecting glue 6-8, deionized water 92-94;
Described base paint is formulated by the composition of following weight part: deionized water 45-55, dispersion agent 0.4-0.7, wetting agent 0.05-0.15, defoamer 0.3-0.5, sterilant 0.1-0.2, ethylene glycol 0.5-1.5, film coalescence aid 0.5-0.7, thickening material 0.4-0.6, pH value conditioning agent 0.1-0.4, rutile titanium white powder 0.5-1.5, kaolin 9-11, organosilicon crylic acid latex 35-45, properties-correcting agent 0.7-0.9, protecting glue solution 5-7;
Described colored paint is formulated by the composition of following weight part: base paint 50-67, quartz sand 33-50;
External phase is formulated by the composition of following weight part: organosilicon crylic acid latex 20-30, film coalescence aid 1-2, ethylene glycol 1-2, sterilant 0.1-0.15, properties-correcting agent 0.3-0.4, deionized water 2-3.
2. a kind of water-water according to claim 1 is containing sanded brick rock coating, it is characterized in that: described defoamer is aliphatic hydrocarbon and emulsifying agent mixture foam killer; Sterilant is N-methyl-isothiazol quinoline ketone and 5-chlorine one isothiazolinone mixed bactericide; Thickening material is the non-associative thickener of Natvosol or alkali swelling type; Properties-correcting agent is non-ionic associative type rheology modifier.
3. a kind of water-water according to claim 1 and 2 is containing sanded brick rock coating, it is characterized in that its preparation method is as follows:
1) disperse phase is prepared
1. the preparation of protecting glue solution: by the weight proportion of above-mentioned protecting glue solution, protecting glue and deionized water are placed in after reactor disperses 25min, 600 revs/min of stirring and dissolving are not to having particle completely;
2. the preparation of base paint: by the weight proportion of above-mentioned base paint, adjusts viscosity to 90-120KU deionized water, dispersion agent, wetting agent, defoamer, sanitas, rutile titanium white powder, kaolin, thickening material, pH value conditioning agent, ethylene glycol, film coalescence aid, organosilicon crylic acid latex, properties-correcting agent and colloidal solution;
3. the preparation of colored paint: by the weight proportion of above-mentioned colored paint, by base paint and color sand mix and blend;
4. in protecting glue solution, above-mentioned colored paint is added, obtained disperse phase;
2) lacquering: by disperse phase and external phase mix and blend by weight proportion, obtains water-water containing sanded brick rock coating.
CN201510104472.6A 2015-03-10 2015-03-10 W/W sand brick-containing rock coating Pending CN104761967A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510104472.6A CN104761967A (en) 2015-03-10 2015-03-10 W/W sand brick-containing rock coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510104472.6A CN104761967A (en) 2015-03-10 2015-03-10 W/W sand brick-containing rock coating

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590274A (en) * 2016-12-09 2017-04-26 泉州市长兴化工材料有限公司 3D (three-dimensional) litchi surface source stone paint and preparation method thereof
CN107603384A (en) * 2017-09-11 2018-01-19 河北晨阳工贸集团有限公司 Kitchen water-water suit and its preparation method and application
CN108912903A (en) * 2017-04-26 2018-11-30 沪宝新材料科技(上海)股份有限公司 A kind of heat-insulated multicolor finish of water burnt-in sand and preparation method thereof
CN109096832A (en) * 2018-06-25 2018-12-28 河北晨阳工贸集团有限公司 A kind of colorful stone coating and preparation method thereof
CN110655348A (en) * 2019-10-08 2020-01-07 河北惠驰装饰材料有限公司 Water-based real stone multicolor paint
CN111484778A (en) * 2019-01-28 2020-08-04 嘉兴市威纳建材有限公司 Cross-linking reaction type sand-in-water colorful granite stone-like coating and preparation method thereof
CN116333537A (en) * 2023-02-22 2023-06-27 山东青巢新型建材有限公司 Fireproof sand-in-water multicolor art paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103254710A (en) * 2013-04-11 2013-08-21 三棵树涂料股份有限公司 Scraping water-in-water multi-color paint and preparation method thereof
CN103254709A (en) * 2013-04-11 2013-08-21 三棵树涂料股份有限公司 Two-component emulsion water-in-water multi-color paint and preparation method thereof
CN104194457A (en) * 2014-08-29 2014-12-10 亚士漆(上海)有限公司 Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof
CN104312351A (en) * 2014-11-17 2015-01-28 广西启利新材料科技股份有限公司 Sand-in-water colorful imitation stone paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103254710A (en) * 2013-04-11 2013-08-21 三棵树涂料股份有限公司 Scraping water-in-water multi-color paint and preparation method thereof
CN103254709A (en) * 2013-04-11 2013-08-21 三棵树涂料股份有限公司 Two-component emulsion water-in-water multi-color paint and preparation method thereof
CN104194457A (en) * 2014-08-29 2014-12-10 亚士漆(上海)有限公司 Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof
CN104312351A (en) * 2014-11-17 2015-01-28 广西启利新材料科技股份有限公司 Sand-in-water colorful imitation stone paint

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590274A (en) * 2016-12-09 2017-04-26 泉州市长兴化工材料有限公司 3D (three-dimensional) litchi surface source stone paint and preparation method thereof
CN108912903A (en) * 2017-04-26 2018-11-30 沪宝新材料科技(上海)股份有限公司 A kind of heat-insulated multicolor finish of water burnt-in sand and preparation method thereof
CN107603384A (en) * 2017-09-11 2018-01-19 河北晨阳工贸集团有限公司 Kitchen water-water suit and its preparation method and application
CN109096832A (en) * 2018-06-25 2018-12-28 河北晨阳工贸集团有限公司 A kind of colorful stone coating and preparation method thereof
CN111484778A (en) * 2019-01-28 2020-08-04 嘉兴市威纳建材有限公司 Cross-linking reaction type sand-in-water colorful granite stone-like coating and preparation method thereof
CN110655348A (en) * 2019-10-08 2020-01-07 河北惠驰装饰材料有限公司 Water-based real stone multicolor paint
CN116333537A (en) * 2023-02-22 2023-06-27 山东青巢新型建材有限公司 Fireproof sand-in-water multicolor art paint and preparation method thereof

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Application publication date: 20150708