CN104745027A - Multicolor stone-like paint with soft color particles as well as preparation method and applying method thereof - Google Patents
Multicolor stone-like paint with soft color particles as well as preparation method and applying method thereof Download PDFInfo
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- CN104745027A CN104745027A CN201510124185.1A CN201510124185A CN104745027A CN 104745027 A CN104745027 A CN 104745027A CN 201510124185 A CN201510124185 A CN 201510124185A CN 104745027 A CN104745027 A CN 104745027A
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- paint
- imitative stone
- water
- stir
- look grain
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention belongs to the technical field of paint and in particular relates to multicolor stone-like paint with soft color particles as well as a preparation method and applying method thereof. The paint comprises 250-300 parts of 8% protective adhesive water solution, 250-350 parts of colored paint, 350-400 parts of continuous phase emulsion and 10-30 parts of thickening agent B by weight. The multicolor stone-like paint has the beneficial effects that the multicolor stone-like paint is water-based environment-friendly granite-like paint, not only can be prepared in random colors to achieve the effects of most natural granite and has degree of simulation as high as 90-95% but also is low in cost, is safe to use and convenient to construct, is simple in flow and can be used in construction of concave-convex surfaces compared with natural granite; the multicolor stone-like paint has higher degree of simulation and better texture than ordinary multicolor paint.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of colorful imitative stone soft look grain coating being applicable to external wall and preparation method thereof and method of application.
Background technology
The sense organ of exterior finish to building of building plays an important role, and the finishing material of present exterior wall mainly contains following several: emulsion paint, true mineral varnish, aluminium-plastic panel, clad aluminium, cement plate, ceramic tile, glass, stone material etc.Wherein, best with natural ornamental stone decorative effect, and durable and enjoy great popularity.But use natural ornamental stone to come with some shortcomings: natural granite, marmorean decorative pattern and color category are limited, and can have any different between different geographical; Natural granite, marble own wt are comparatively large, external wall uses and has the risk dropped; Lithotome is limited resources, day by day reduces, and overexploitation can damage environment.
Because people adopt the coating of natural-like stone to replace its decorative effect.Although current common multicolor finish on the market can be accomplished with natural granite effect close in color, its surface tactile sensation is larger with natural granite gap all the time.
Summary of the invention
In order to solve the problem, the object of the present invention is to provide a kind of colorful imitative stone soft look grain coating, on this coating paint exterior wall, not only color is close to the decorative effect of lithotome to make decorated body of wall, and texture is also close to the decorative effect of lithotome.
Two of object of the present invention there is provided the preparation method of described colorful imitative stone soft look grain coating.
Three of object of the present invention there is provided the method for application of described colorful imitative stone soft look grain coating.
The present invention is achieved through the following technical solutions:
A kind of colorful imitative stone soft look grain coating, comprises the following raw material according to listed as parts by weight:
Described colored paint is at least two kinds of color toner base paint mixtures, the preferred mixture adjusted red base paint 100 ~ 120 parts, tune grey base paint 180 ~ 210 parts and adjust yellow base paint 180 ~ 210 parts, more close with lithotome in such proportioning color; But do not limit the collocation of other color.Described thickening material B is hydrophobically-modified alkali swelling type thickening material.
Preferably, described 8% insured's glue solution stirs modulation in 8 ~ 15 minutes by the protecting glue of the water of 920 parts calculated by total amount part and 80 parts and forms under 450 ~ 550rpm; In this formula system, 8% is optimum proportion, if resize ratio, the coated situation of colorful color dot is different, then color dot effect out also can be different.Protecting glue is the wilkinite of organic carboxyl acid modification, mainly protects the independence of each look grain, is not interacted, and preferably goodly inspires confidence in sincere GTS.
Wherein, described external phase emulsion comprises the following raw material according to listed as parts by weight:
The preparation method of external phase emulsion is:
First by described emulsion and 46.2% water, stir 3 ~ 8 minutes under 250 ~ 350rpm, adding the water of the film coalescence aid of described amount, antifreezing agent, defoamer, sanitas, linking agent and remainder, stirring 20 ~ 30 minutes under 700 ~ 900rpm, obtained described external phase emulsion.
Preferably, described color-mixed base paint comprises the following raw material according to listed as parts by weight:
Described thickening material A is Natvosol.
Wherein said emulsion is pure-acrylic emulsion, and preferred Ahmedabad is rich: 996AD.The preferred propylene glycol of antifreezing agent, the preferred alcohol ester 12 of film coalescence aid, the preferred mineral oil antifoam agent of defoamer, the preferred broad spectrum type sanitas of sanitas, the preferred deionized water of water.
Preferably, the preparation method of described color-mixed base paint:
First former for the basis of described amount paint, aqueous color paste, emulsion are stirred 8 ~ 15 minutes under 450 ~ 550rpm;
Add thickening material A, defoamer, film coalescence aid and antifreezing agent again, adjusting rotary speed stirs 10 ~ 20 minutes under 550 ~ 650rpm; Wherein thickening material A needs slowly to add.
Finally add sanitas and the water of described amount, stir 10 ~ 20 minutes under 550 ~ 650rpm, obtained described color-mixed base paint.
Preferably, described colored paint comprises the following raw material according to listed as parts by weight:
The preparation method of the former paint in basis is:
First by the water of the thickening material A and 87.3% of described amount, stir 3 ~ 8 minutes under 350 ~ 450rpm;
Add the water of the pH adjusting agent of described amount, dispersion agent, defoamer, sanitas, kaolin and remainder again, stir 20 ~ 30 minutes under 700 ~ 1000rpm, the former paint in obtained described basis.The preferred AMP-95 of PH conditioning agent.
The method of colorful imitative stone soft look grain coating:
First 8% insured's glue solution of described amount and colored paint are stirred 3 ~ 8 minutes under 50 ~ 150rpm, sieve;
Add the external phase emulsion of described amount, thickening material B again, stir 3 ~ 8 minutes under 50 ~ 150rpm, obtained described colorful imitative stone soft look grain coating.
Preferably, described external phase emulsion, thickening material B need slowly to add.
The method of application of described colorful imitative stone soft look grain coating, concrete:
Step one, batch scrape exterior wall putty one time, dry 5 ~ 8 days;
Step 2, roller coating or spraying exterior wall seal coat one time, dry 5 ~ 8 hours;
Step 3, roller coating or the real color bottom paint twice of spraying water-based, dry 5 ~ 8 hours;
Step 4, spray described colorful imitative stone soft look grain coating twice, dry 10 ~ 15 hours;
Step 5, spraying water-based finishing varnish one time, dry 5 ~ 8 hours; Apply complete.
The present invention is aqueous, environmental protective artificial granite paint, not only arbitrarily can prepare the effect of color and most of natural granite, because adding quartz sand in formula, so fidelity can up to 90% ~ 95%, compared with natural granite low, the use safety of cost, easy construction, flow process simple, can construct at convex-concave surface; And fidelity is higher compared with common multicolor finish, texture is better.Adherence, hardness, weathering resistance etc. all show excellence.Promote the decorative effect of external wall and reduce use cost, replacing natural granite, marble, solving the shortcomings such as grouan high cost, poor stability, effect limitednumber; Meanwhile, compared with common multicolor finish, greatly promote surface tactile sensation and fidelity.
concrete embodiment
Below in conjunction with embodiment, the present invention is described in further detail, understands the present invention to help those skilled in the art.
Embodiment 1
A, 8% insured's glue solution preparation
By 920kg deionized water and 80kg protecting glue, 500rpm in stirrer stirs 10 minutes, obtains described 8% insured's glue solution.
B, the former paint preparation in basis
First deionized water 440kg, thickening material A 8kg are placed in stirrer 300rpm and stir 5 minutes;
Drop into dispersion agent 13kg, defoamer 9kg, sanitas 11kg, kaolin 450kg, pH adjusting agent 5kg and water 64kg again, heighten stirring velocity and stir 25 minutes to 800rpm.
C, base paint are mixed colours
Adjust red base paint: by the basis former paint 180kg, the water-based redness slurry 15kg and emulsion 568kg that obtain, stir 5 minutes in 300rpm; Drop into thickening material A 200kg, defoamer 3kg again, film coalescence aid 7kg, antifreezing agent 20kg stir 15 minutes in 600rpm; Finally add sanitas 1kg and water 6kg, stir 150 minutes in 600rpm, obtain adjusting red base paint.
Adjust yellow base paint: by the basis former paint 180kg, the water-based yellow pulp 15kg and emulsion 568kg that obtain, stir 5 minutes in 300rpm; Drop into thickening material A 200kg, defoamer 3kg again, film coalescence aid 7kg, antifreezing agent 20kg stir 15 minutes in 600rpm; Finally add sanitas 1kg and water 6kg, stir 150 minutes in 600rpm, obtain adjusting yellow base paint.
Adjust black base paint: by the basis former paint 180kg, the aqueous black paste 15kg and emulsion 568kg that obtain, stir 5 minutes in 300rpm; Drop into thickening material A 200kg, defoamer 3kg again, film coalescence aid 7kg, antifreezing agent 20kg stir 15 minutes in 600rpm; Finally add sanitas 1kg and water 6kg, stir 150 minutes in 600rpm, obtain adjusting black base paint.
D, external phase emulsion are prepared
First by emulsion 380kg and water 210kg, stir 5 minutes in 300rpm;
Then add film coalescence aid 7kg, antifreezing agent 14kg, defoamer 5kg, sanitas 4kg, linking agent 135kg and water 245kg, 800rpm and stir 25 minutes, obtained described external phase emulsion.
The preparation of E, colorful imitative stone soft look grain coating
First by 8% insured's glue solution 290kg, adjust black base paint 100kg, adjust yellow base paint 100kg, adjust red base paint 100kg, stir 5 minutes under 100rpm; Sieve and become the particle of desired shape size;
Then add external phase emulsion 390kg, thickening material B 20kg, 100rpm stirs 5 minutes.Obtain the colorful imitative stone of final finished soft look grain coating.
Embodiment 2
A, 8% insured's glue solution preparation
By 920kg deionized water and 80kg protecting glue, 450rpm in stirrer stirs 15 minutes, obtains described 8% insured's glue solution.
B, the former paint preparation in basis
First deionized water 400kg, thickening material A 10kg are placed in stirrer 350rpm and stir 3 minutes;
Drop into pH adjusting agent 10kg, dispersion agent 20kg, defoamer 10kg, sanitas 15kg, kaolin 500kg and water 35kg again, heighten stirring velocity and stir 30 minutes to 700rpm.
C, base paint are mixed colours
Adjust red base paint: by the basis former paint 150kg, the water-based redness slurry 20kg and emulsion 528kg that obtain, stir 3 minutes in 350rpm; Drop into thickening material A 250kg, defoamer 5kg again, film coalescence aid 10kg, antifreezing agent 25kg stir 10 minutes in 650rpm; Finally add sanitas 2kg and water 10kg, stir 10 minutes in 650rpm, obtain adjusting red base paint.
Adjust yellow base paint: the same, just mill base color is yellow.
Adjust black base paint: the same, just mill base color is black.
D, external phase emulsion are prepared
First by emulsion 400kg and water 230kg, stir 3 minutes in 250rpm;
Then add film coalescence aid 8kg, antifreezing agent 12kg, defoamer 7kg, sanitas 3kg, linking agent 120kg and water 220kg, 700rpm and stir 30 minutes, obtained described external phase emulsion.
The preparation of E, colorful imitative stone soft look grain coating
First by 8% insured's glue solution 250kg, adjust black base paint 90kg, adjust yellow base paint 100kg, adjust red base paint 100kg, stir 10 minutes under 50rpm; Sieve and become the particle of desired shape size;
Then add external phase emulsion 350kg, thickening material B 10kg, 150rpm stirs 10 minutes.Obtain the colorful imitative stone of final finished soft look grain coating.
Embodiment 3
A, 8% insured's glue solution preparation
By 920kg deionized water and 80kg protecting glue, 550rpm in stirrer stirs 5 minutes, obtains described 8% insured's glue solution.
B, the former paint preparation in basis
First deionized water 500kg, thickening material A 5kg are placed in stirrer 350rpm and stir 8 minutes;
Drop into pH adjusting agent 1kg, dispersion agent 10kg, defoamer 5kg, sanitas 10kg, kaolin 400kg and water 69kg again, heighten stirring velocity and stir 20 minutes to 1000rpm.
C, base paint are mixed colours
Adjust red base paint: by the basis former paint 200kg, the water-based redness slurry 10kg and emulsion 613.5kg that obtain, stir 8 minutes in 250rpm; Drop into thickening material A 150kg, defoamer 1kg again, film coalescence aid 5kg, antifreezing agent 15kg stir 20 minutes in 550rpm; Finally add sanitas 0.5kg and water 5kg, stir 20 minutes in 550rpm, obtain adjusting red base paint.
Adjust yellow base paint: the same, just mill base color is yellow.
Adjust black base paint: the same, just mill base color is black.
D, external phase emulsion are prepared
First by emulsion 450kg and water 200kg, stir 8 minutes in 350rpm;
Then add film coalescence aid 5kg, antifreezing agent 10kg, defoamer 3kg, sanitas 1kg, linking agent 100kg and water 231kg, 850rpm and stir 20 minutes, obtained described external phase emulsion.
The preparation of E, colorful imitative stone soft look grain coating
First by 8% insured's glue solution 300kg, adjust black base paint 70kg, adjust yellow base paint 50kg, adjust red base paint 150kg, stir 15 minutes under 50rpm; Sieve and become the particle of desired shape size;
Then add external phase emulsion 400kg, thickening material B 30kg, 50rpm stirs 15 minutes.Obtain the colorful imitative stone of final finished soft look grain coating.
Embodiment 4
A, 8% insured's glue solution preparation
By 920kg deionized water and 80kg protecting glue, 500rpm in stirrer stirs 10 minutes, obtains described 8% insured's glue solution.
B, the former paint preparation in basis
First deionized water 460kg, thickening material A 7kg are placed in stirrer 300rpm and stir 5 minutes;
Drop into pH adjusting agent 8kg, dispersion agent 15kg, defoamer 8kg, sanitas 12kg, kaolin 420kg and water 70kg again, heighten stirring velocity and stir 25 minutes to 800rpm.
C, base paint are mixed colours
Adjust red base paint: by the basis former paint 170kg, the water-based redness slurry 12kg and emulsion 569kg that obtain, stir 5 minutes in 300rpm; Drop into thickening material A 210kg, defoamer 2kg again, film coalescence aid 6kg, antifreezing agent 23kg stir 15 minutes in 600rpm; Finally add sanitas 1.5kg and water 6.5kg, stir 150 minutes in 600rpm, obtain adjusting red base paint.
Adjust yellow base paint: the same, just mill base color is yellow.
Adjust black base paint: the same, just mill base color is black.
D, external phase emulsion are prepared
First by emulsion 350kg and water 250kg, stir 5 minutes in 300rpm;
Then add film coalescence aid 10kg, antifreezing agent 20kg, defoamer 8kg, sanitas 5kg, linking agent 150kg and water 207kg, 800rpm and stir 25 minutes, obtained described external phase emulsion.
The preparation of E, colorful imitative stone soft look grain coating
First by 8% insured's glue solution 300kg, adjust black base paint 1500kg, adjust yellow base paint 100kg, adjust red base paint 50kg, stir 5 minutes under 100rpm; Sieve and become the particle of desired shape size;
Then add external phase emulsion 380kg, thickening material B 20kg, 100rpm stirs 5 minutes.Obtain the colorful imitative stone of final finished soft look grain coating.
Above-described embodiment, just preferred embodiment of the present invention, is not used for limiting the scope of the present invention, therefore all equivalences done with the feature described in the claims in the present invention and principle change or modify, and all should be included within the claims in the present invention scope.
Product of the present invention is when using supporting finish paint, and wherein several main physical property is as shown in the table:
As seen from the above table, the present invention not only has appearance and the texture of natural granite, and adherence, water tolerance, alkali resistance are identical with natural granite, and QUV test and cold cycling test in all show the performance identical with natural granite.
Claims (10)
1. a colorful imitative stone soft look grain coating, is characterized in that, comprises the following raw material according to listed as parts by weight:
Described colored paint is at least two kinds of color toner base paint mixtures, and described thickening material B is hydrophobically-modified alkali swelling type thickening material.
2. colorful imitative stone soft look grain coating as claimed in claim 1; it is characterized in that; described 8% insured's glue solution stirs modulation in 8 ~ 15 minutes by the protecting glue of the water of 920 parts calculated by total amount part and 80 parts and forms under 450 ~ 550rpm, and described protecting glue is the wilkinite of organic carboxyl acid modification.
3. colorful imitative stone soft look grain coating as claimed in claim 1, it is characterized in that, described external phase emulsion comprises the following raw material according to listed as parts by weight:
Wherein linking agent is Xylo-Mucine.
4. colorful imitative stone soft look grain coating as claimed in claim 3, it is characterized in that, the preparation method of described external phase emulsion is:
First by described emulsion and 46.2% water, stir 3 ~ 8 minutes under 250 ~ 350rpm, adding the water of the film coalescence aid of described amount, antifreezing agent, defoamer, sanitas, linking agent and remainder, stirring 20 ~ 30 minutes under 700 ~ 900rpm, obtained described external phase emulsion.
5. colorful imitative stone soft look grain coating as claimed in claim 1, it is characterized in that, described color-mixed base paint comprises the following raw material according to listed as parts by weight:
Described thickening material A is Natvosol.
6. colorful imitative stone soft look grain coating as claimed in claim 5, is characterized in that, the preparation method of described color-mixed base paint:
First former for the basis of described amount paint, aqueous color paste, emulsion are stirred 8 ~ 15 minutes under 450 ~ 550rpm;
Add thickening material A, defoamer, film coalescence aid and antifreezing agent again, adjusting rotary speed stirs 10 ~ 20 minutes under 550 ~ 650rpm;
Finally add sanitas and the water of described amount, stir 10 ~ 20 minutes under 550 ~ 650rpm, obtained described color-mixed base paint.
7. colorful imitative stone soft look grain coating as described in claim 5 or 6, it is characterized in that, the following raw material according to listed as parts by weight drawn together by the former enamel-cover in described basis:
8. colorful imitative stone soft look grain coating as claimed in claim 7, it is characterized in that, the preparation method of the former paint in described basis is:
First by the water of the thickening material A and 87.3% of described amount, stir 3 ~ 8 minutes under 350 ~ 450rpm;
Add the water of the pH adjusting agent of described amount, dispersion agent, defoamer, sanitas, kaolin and remainder again, stir 20 ~ 30 minutes under 700 ~ 1000rpm, the former paint in obtained described basis.
9. prepare the method for the soft look grain of colorful imitative stone described in any one coating in claim 1-7, it is characterized in that:
First 8% insured's glue solution of described amount and colored paint are stirred 3 ~ 8 minutes under 50 ~ 150rpm, sieve;
Add the external phase emulsion of described amount, thickening material B again, stir 3 ~ 8 minutes under 50 ~ 150rpm, obtained described colorful imitative stone soft look grain coating; Wherein external phase emulsion, thickening material B need slowly to add.
10. the method for application of the soft look grain of colorful imitative stone described in any one coating in claim 1-9, is characterized in that, be specially:
Step one, batch scrape exterior wall putty one time, dry 5 ~ 8 days;
Step 2, roller coating or spraying exterior wall seal coat one time, dry 5 ~ 8 hours;
Step 3, roller coating or the real color bottom paint twice of spraying water-based, dry 5 ~ 8 hours;
Step 4, spray described colorful imitative stone soft look grain coating twice, dry 10 ~ 15 hours;
Step 5, spraying water-based finishing varnish one time, dry 5 ~ 8 hours; Apply complete.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510124185.1A CN104745027A (en) | 2015-03-19 | 2015-03-19 | Multicolor stone-like paint with soft color particles as well as preparation method and applying method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510124185.1A CN104745027A (en) | 2015-03-19 | 2015-03-19 | Multicolor stone-like paint with soft color particles as well as preparation method and applying method thereof |
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| CN104745027A true CN104745027A (en) | 2015-07-01 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945996A (en) * | 2015-07-13 | 2015-09-30 | 汇彩涂料（上海）股份有限公司 | Aqueous colorful wall paint |
| CN107722774A (en) * | 2017-10-23 | 2018-02-23 | 河北晨阳工贸集团有限公司 | A kind of flame-retardant water burnt-in sand coating and preparation method thereof |
| CN108864872A (en) * | 2018-08-07 | 2018-11-23 | 广州立邦涂料有限公司 | Aqueous pottery stone coating and preparation method thereof |
| CN109233511A (en) * | 2017-06-13 | 2019-01-18 | 上海三银涂料科技股份有限公司 | Imitative yellow rust stone grain, preparation method and the imitative yellow rust stone multicolor finish of corresponding water-water |
| CN110819156A (en) * | 2019-11-26 | 2020-02-21 | 上海岩首新材料科技有限公司 | Three-in-one type sand-in-water preparation process and construction process thereof |
-
2015
- 2015-03-19 CN CN201510124185.1A patent/CN104745027A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945996A (en) * | 2015-07-13 | 2015-09-30 | 汇彩涂料（上海）股份有限公司 | Aqueous colorful wall paint |
| CN109233511A (en) * | 2017-06-13 | 2019-01-18 | 上海三银涂料科技股份有限公司 | Imitative yellow rust stone grain, preparation method and the imitative yellow rust stone multicolor finish of corresponding water-water |
| CN109233511B (en) * | 2017-06-13 | 2020-10-16 | 上海三银涂料科技股份有限公司 | Yellow rust stone-imitated color particles, preparation method and corresponding water-in-water yellow rust stone-imitated multicolor paint |
| CN107722774A (en) * | 2017-10-23 | 2018-02-23 | 河北晨阳工贸集团有限公司 | A kind of flame-retardant water burnt-in sand coating and preparation method thereof |
| CN108864872A (en) * | 2018-08-07 | 2018-11-23 | 广州立邦涂料有限公司 | Aqueous pottery stone coating and preparation method thereof |
| CN110819156A (en) * | 2019-11-26 | 2020-02-21 | 上海岩首新材料科技有限公司 | Three-in-one type sand-in-water preparation process and construction process thereof |
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Application publication date: 20150701 |