CN106118553B - A kind of cracking reinforcing agent for wicker products - Google Patents
A kind of cracking reinforcing agent for wicker products Download PDFInfo
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- CN106118553B CN106118553B CN201610551269.8A CN201610551269A CN106118553B CN 106118553 B CN106118553 B CN 106118553B CN 201610551269 A CN201610551269 A CN 201610551269A CN 106118553 B CN106118553 B CN 106118553B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicines Containing Plant Substances (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a kind of cracking reinforcing agent for wicker products, including A liquid and B liquid, the A liquid is made of following substance：Wood vinegar, Mancozeb, konjac glucomannan, odium stearate, nonylphenol polyoxyethylene ether, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, dimethyl silicone polymer, ammonium polyacrylate, boric acid, water；The B liquid is made of following substance：Calgon, tartaric acid, sodium carboxymethylcellulose, active carbon nanoparticles, nano silicon dioxide, propylene glycol methyl ether acetate, acrylic emulsion, phellodendron extract, Camphora extract, water.The cracking reinforcing agent that the present invention prepares is under the collective effect of A liquid and B liquid, it is filled with gap well, avoid erosion of the exogenous impurity ingredient to it, the intensity and wearability of its Vermins-proof mildew-proof performance and entirety are improved again, the surface strength of final wicker products can be improved 40% or so, flexural strength can be improved 50% or so, and service life can extend 1 ~ 2 times, and use value is higher.
Description
Technical field
The invention belongs to wicker plaiting article manufacture fields, and in particular to a kind of cracking reinforcing agent for wicker products.
Background technology
Wicker plaiting article is a kind of traditional technology in China, and present wicker products are popular on the market, and the type of wicker products is numerous
It is more, there are the multiple types such as seat, basket, basket, dustpan, round-bottomed basket, crate, shallow basket made of wicker or thin bamboo strips, the gaily decorated basket, bamboo strainer, food dish at domestic aspect.Export trade side
Face, by opening up and designing, to have formed buck basket, flower pot coat, picnic tableware basket, hanging basket, lampshade, kennel, cat litter, Bird's Nest etc. more
Kind, the appreciation effect that low-grade goods become high-grade is formed in foreign trade, it is very popular.However wicker products preserve or
When improper use, it is susceptible to tiny crack, the deeper breach of bigger can be if things go on like this evolved into, can not only influence wicker plaiting article system
The antiseptic insect-repelling performance of product, and the intensity of wicker plaiting article can be reduced, it is deformed, that is, influences beautiful influence practicability again.People at present
Problems are not yet paid attention to, processing quality when usual wicker plaiting article finished product makes determines the length of service life, and is trying
The problem of not repaired maintenance to it with period, caused shorter service life and the wasting of resources.Groups of people use wooden use
Glue is bonded, although can play certain effect in the short time, can not solve question of substance.
Invention content
To solve the above-mentioned problems, the present invention provides a kind of cracking reinforcing agents for wicker products.
The present invention is achieved through the following technical solutions：
A kind of cracking reinforcing agent for wicker products, including A liquid and B liquid, the A liquid by following parts by weight substance system
At：2 parts of wood vinegar, 1 part of Mancozeb, 5 parts of konjac glucomannans, 6 parts of odium stearate, 3 parts of nonylphenol polyoxyethylene ether, 2 parts of high-carbon fat
Fat alcohol polyoxyethylene ether, 4 parts of positive silicic acid propyl esters, 8 parts of dimethyl silicone polymers, 5 parts of ammonium polyacrylates, 2 parts of boric acid, 100 parts of water；
The B liquid is made of the substance of following parts by weight：4 parts of calgons, 3 parts of tartaric acid, 6 parts of sodium carboxymethylcelluloses, 5 parts receive
Rice activated carbon, 5 parts of nano silicon dioxides, 4 parts of propylene glycol methyl ether acetates, 15 parts of acrylic emulsions, 7 parts of phellodendron extracts, 6 parts
Camphora extract, 50 parts of water.
Further, the preparation method of the A liquid includes the following steps：
（1）By water temperature heating to 55 ~ 58 DEG C, then konjac glucomannan and stearic acid sodium are added jointly, with 600 ~ 800 revs/min
The rotating speed of clock is stirred continuously 15min, then maintains 55 ~ 58 DEG C of condition heat preservation 30min spare again；
（2）By nonylphenol polyoxyethylene ether, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, dimethyl silicone polymer
Jointly and step with ammonium polyacrylate（1）The liquid of gained mixes, and it is 38 ~ 42 DEG C that heating, which keeps fluid temperature, with 1000 ~ 1200
Rev/min rotating speed be stirred continuously 20min, then cooled to room temperature is spare；
（3）Wood vinegar, Mancozeb and boric acid are added to step jointly（2）In the liquid of gained, with 350 ~ 400 turns/
The rotating speed of minute is stirred continuously after 10min, then homogeneous 1h up to A liquid.
Further, the preparation method of the B liquid includes the following steps：
（1）Calgon, tartaric acid, sodium carboxymethylcellulose, phellodendron extract and Camphora extract are added jointly
Into water, and it is 45 ~ 48 DEG C to heat holding aqueous temperature, is stirred continuously to uniformly rear spare；
（2）Active carbon nanoparticles, nano silicon dioxide and propylene glycol methyl ether acetate are added in acrylic emulsion jointly,
It is spare after stir process 15min in the ultrasonication instrument that frequency is 38KHz；
（3）By step（2）Acquired solution is mixed into step with the speed of 15 ~ 20ml/s（1）In the solution of gained, while with
500 revs/min of rotating speed stirs evenly up to B liquid.
A kind of application method of the cracking reinforcing agent of wicker products, includes the following steps：
（1）Impurity elimination first is rinsed to the pending position of wicker products with clear water；
（2）To step（1）Position after flushing is dried, and it is 20 ~ 30% to be dried to its surface moisture；
（3）A liquid is sprayed at step（2）On wicker products after drying, then wait for that its naturally dry is tack-free to surface
Until；
（4）B liquid is uniformly sprayed at step（3）On treated wicker products, it is 35 ~ 38 to put it into temperature after the completion
5 ~ 7min is dried under conditions of DEG C.
The present invention has the advantages that：
（1）It is miscellaneous that the A liquid that the present invention prepares can kill remaining bacterium, fungi, worm's ovum etc. at wicker products cracking well
Matter prevents it further to the erosion inside wicker plaiting article, at the same again have preferable mobility, with cellulosic structure compatibility compared with
By force, and tiny wooden burr can be softened to a certain extent, coats a hypoglyph on the surface thereof, established for subsequent operation
Excellent basis.
（2）Adhesiveness is stronger between the counterdie that the present invention B liquid prepared and A liquid are formed, active carbon nanoparticles, nano silicon dioxide
It is filled with the gap of wicker products well with acrylic emulsion, and enhances its wear resistence and intensity, phellodendron extract and camphor tree
The addition of brain extract enhances the Vermins-proof mildew-proof performance of wicker products again.
（3）The cracking reinforcing agent that the present invention prepares is filled with gap, avoids well under the collective effect of A liquid and B liquid
Erosion of the exogenous impurity ingredient to it, and improve the intensity and wearability of its Vermins-proof mildew-proof performance and entirety, A liquid and B
The mixture that liquid is collectively formed not only has good cohesive force, and has certain elasticity, its shock resistance can be improved, compared with
Pure glue, which bonds, has more practicability.The surface strength of final wicker products can be improved 40% or so, and 50% left side can be improved in flexural strength
The right side, less yielding, service life can extend 1 ~ 2 times, and use value is higher.
Specific implementation mode
Embodiment 1
A kind of cracking reinforcing agent for wicker products, including A liquid and B liquid, the A liquid by following parts by weight substance system
At：2 parts of wood vinegar, 1 part of Mancozeb, 5 parts of konjac glucomannans, 6 parts of odium stearate, 3 parts of nonylphenol polyoxyethylene ether, 2 parts of high-carbon fat
Fat alcohol polyoxyethylene ether, 4 parts of positive silicic acid propyl esters, 8 parts of dimethyl silicone polymers, 5 parts of ammonium polyacrylates, 2 parts of boric acid, 100 parts of water；
The B liquid is made of the substance of following parts by weight：4 parts of calgons, 3 parts of tartaric acid, 6 parts of sodium carboxymethylcelluloses, 5 parts receive
Rice activated carbon, 5 parts of nano silicon dioxides, 4 parts of propylene glycol methyl ether acetates, 15 parts of acrylic emulsions, 7 parts of phellodendron extracts, 6 parts
Camphora extract, 50 parts of water.
Further, the preparation method of the A liquid includes the following steps：
（1）By water temperature heating to 58 DEG C, then konjac glucomannan and stearic acid sodium are added jointly, with 700 revs/min of rotating speed
It is stirred continuously 15min, then maintains 56 DEG C of condition heat preservation 30min spare again；
（2）By nonylphenol polyoxyethylene ether, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, dimethyl silicone polymer
Jointly and step with ammonium polyacrylate（1）The liquid of gained mixes, and it is 39 DEG C that heating, which keeps fluid temperature, with 1100 revs/min
Rotating speed be stirred continuously 20min, then cooled to room temperature is spare；
（3）Wood vinegar, Mancozeb and boric acid are added to step jointly（2）In the liquid of gained, with 390 revs/min
Rotating speed be stirred continuously after 10min, then homogeneous 1h up to A liquid.
Further, the preparation method of the B liquid includes the following steps：
（1）Calgon, tartaric acid, sodium carboxymethylcellulose, phellodendron extract and Camphora extract are added jointly
Into water, and it is 48 DEG C to heat holding aqueous temperature, is stirred continuously to uniformly rear spare；
（2）Active carbon nanoparticles, nano silicon dioxide and propylene glycol methyl ether acetate are added in acrylic emulsion jointly,
It is spare after stir process 15min in the ultrasonication instrument that frequency is 38KHz；
（3）By step（2）Acquired solution is mixed into step with the speed of 18ml/s（1）In the solution of gained, while with 500
Rev/min rotating speed stir evenly up to B liquid.
A kind of application method of the cracking reinforcing agent of wicker products, includes the following steps：
（1）Impurity elimination first is rinsed to the pending position of wicker products with clear water；
（2）To step（1）Position after flushing is dried, and it is 27 ~ 30% to be dried to its surface moisture；
（3）A liquid is sprayed at step（2）On wicker products after drying, then wait for that its naturally dry is tack-free to surface
Until；
（4）B liquid is uniformly sprayed at step（3）On treated wicker products, it is 37 DEG C to put it into temperature after the completion
Under conditions of be dried 5min.
Comparative example 1
This comparative example 1 compared with Example 1, each composition proportion all same in the A liquid and B liquid, but preparing
When directly A liquid and B liquid ingredient be mixed integrated mixed liquor, the weight ratio of the two is 1:1.5, be also when in use
Directly spray mixed liquor.
Control group
Plank class adhesive.
In order to compare effect of the present invention, with the corresponding solvent of above-mentioned three kinds of modes respectively to same batch, cracking degree phase
As wicker products handled, and test statistics its performance finds that the flexural strength of 1 corresponding wicker products of embodiment is pair
It is 1.1 times of control group than 1.2 times of embodiment 1；Its service life is 1.3 times of comparative example 1, is the 1.7 of control group
Times, it is 2.5 times of unprocessed wicker products service life.
Claims (4)
1. a kind of cracking reinforcing agent for wicker products, which is characterized in that including A liquid and B liquid, the A liquid is by following weight
The substance of part is made：2 parts of wood vinegar, 1 part of Mancozeb, 5 parts of konjac glucomannans, 6 parts of odium stearate, 3 parts of nonylphenol polyoxyethylene ether,
2 parts of high-carbon fatty alcohol polyoxyethylene ethers, 4 parts of positive silicic acid propyl esters, 8 parts of dimethyl silicone polymers, 5 parts of ammonium polyacrylates, 2 parts of boron
Acid, 100 parts of water；The B liquid is made of the substance of following parts by weight：4 parts of calgons, 3 parts of tartaric acid, 6 parts of carboxymethyl fibres
The plain sodium of dimension, 5 parts of active carbon nanoparticles, 5 parts of nano silicon dioxides, 4 parts of propylene glycol methyl ether acetates, 15 parts of acrylic emulsions, 7 parts of Huangs
Cypress extract, 6 parts of Camphora extracts, 50 parts of water.
2. a kind of cracking reinforcing agent for wicker products according to claim 1, which is characterized in that the system of the A liquid
Preparation Method includes the following steps：
（1）By water temperature heating to 55 ~ 58 DEG C, then konjac glucomannan and stearic acid sodium are added jointly, with 600 ~ 800 revs/min
Rotating speed is stirred continuously 15min, then maintains 55 ~ 58 DEG C of condition heat preservation 30min spare again；
（2）By nonylphenol polyoxyethylene ether, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, dimethyl silicone polymer and gather
Ammonium acrylate is jointly and step（1）The liquid of gained mixes, and it is 38 ~ 42 DEG C that heating, which keeps fluid temperature, with 1000 ~ 1200 turns/
The rotating speed of minute is stirred continuously 20min, and then cooled to room temperature is spare；
（3）Wood vinegar, Mancozeb and boric acid are added to step jointly（2）In the liquid of gained, with 350 ~ 400 revs/min
Rotating speed be stirred continuously after 10min, then homogeneous 1h up to A liquid.
3. a kind of cracking reinforcing agent for wicker products according to claim 1, which is characterized in that the system of the B liquid
Preparation Method includes the following steps：
（1）Calgon, tartaric acid, sodium carboxymethylcellulose, phellodendron extract and Camphora extract are added to water jointly
In, and it is 45 ~ 48 DEG C to heat holding aqueous temperature, is stirred continuously to uniformly rear spare；
（2）Active carbon nanoparticles, nano silicon dioxide and propylene glycol methyl ether acetate are added in acrylic emulsion jointly, in frequency
It is spare after stir process 15min in the ultrasonication instrument that rate is 38KHz；
（3）By step（2）Acquired solution is mixed into step with the speed of 15 ~ 20ml/s（1）In the solution of gained, while with 500
Rev/min rotating speed stir evenly up to B liquid.
4. a kind of application method of the cracking reinforcing agent of wicker products as described in claim 1 ~ 3 any one, feature exist
In including the following steps：
（1）Impurity elimination first is rinsed to the pending position of wicker products with clear water；
（2）To step（1）Position after flushing is dried, and it is 20 ~ 30% to be dried to its surface moisture；
（3）A liquid is sprayed at step（2）On wicker products after drying, then wait for its naturally dry until surface is tack-free；
（4）B liquid is uniformly sprayed at step（3）On treated wicker products, it is 35 ~ 38 DEG C to put it into temperature after the completion
Under the conditions of be dried 5 ~ 7min.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610551269.8A CN106118553B (en) | 2016-07-13 | 2016-07-13 | A kind of cracking reinforcing agent for wicker products |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610551269.8A CN106118553B (en) | 2016-07-13 | 2016-07-13 | A kind of cracking reinforcing agent for wicker products |
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| CN106118553A CN106118553A (en) | 2016-11-16 |
| CN106118553B true CN106118553B (en) | 2018-08-24 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107574710A (en) * | 2017-09-26 | 2018-01-12 | 阜南县腾祥工艺品有限公司 | A kind of processing method for improving paper establishment product and using characteristic |
| CN107653739A (en) * | 2017-09-26 | 2018-02-02 | 阜南县腾祥工艺品有限公司 | A kind of coating of braiding paper |
| CN108867166A (en) * | 2018-08-06 | 2018-11-23 | 安徽三和工艺品有限公司 | A kind of braiding high-quality waterproofing agent of paper |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1580144A (en) * | 2003-08-04 | 2005-02-16 | 深圳市海川实业股份有限公司 | Environmenttally friendly water-based transparent putty for woodenware |
| CN103265837A (en) * | 2013-05-28 | 2013-08-28 | 南京工程学院 | Preparation method of painted real-wood furniture crack repairing paste and crack repairing method |
| CN104927516A (en) * | 2015-05-29 | 2015-09-23 | 阜南县猛发工艺品有限公司 | Willow weaving paint |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1580144A (en) * | 2003-08-04 | 2005-02-16 | 深圳市海川实业股份有限公司 | Environmenttally friendly water-based transparent putty for woodenware |
| CN103265837A (en) * | 2013-05-28 | 2013-08-28 | 南京工程学院 | Preparation method of painted real-wood furniture crack repairing paste and crack repairing method |
| CN104927516A (en) * | 2015-05-29 | 2015-09-23 | 阜南县猛发工艺品有限公司 | Willow weaving paint |
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