CN108867166A - A kind of braiding high-quality waterproofing agent of paper - Google Patents

A kind of braiding high-quality waterproofing agent of paper Download PDF

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Publication number
CN108867166A
CN108867166A CN201810883356.2A CN201810883356A CN108867166A CN 108867166 A CN108867166 A CN 108867166A CN 201810883356 A CN201810883356 A CN 201810883356A CN 108867166 A CN108867166 A CN 108867166A
Authority
CN
China
Prior art keywords
parts
paper
sodium
braiding
waterproofing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810883356.2A
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Chinese (zh)
Inventor
徐治合
徐蓝天
徐艳云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Three Arts & Crafts Co Ltd
Original Assignee
Anhui Three Arts & Crafts Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Three Arts & Crafts Co Ltd filed Critical Anhui Three Arts & Crafts Co Ltd
Priority to CN201810883356.2A priority Critical patent/CN108867166A/en
Publication of CN108867166A publication Critical patent/CN108867166A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/34Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of high-quality waterproofing agents of braiding paper, are made of following substance:Corn fiber gum, zeins, sodium alginate, stearate, nonylphenol polyoxyethylene ether, terpene resin, urea, sodium tetraborate, sodium carboxymethylcellulose, glycerine, deionized water.The present invention provides a kind of waterproofing agents, the collocation of its raw material components is reasonable, ingredient is safe and harmless, it is environmentally protective, on human health almost without influence, it is coated on paper, the water repellent waterproof ability of paper can be obviously improved, and the flexibility of paper can be improved, improve printing, machinability, the great market competitiveness and popularizing value.

Description

A kind of braiding high-quality waterproofing agent of paper
Technical field
The invention belongs to weave processing technique field, and in particular to a kind of braiding high-quality waterproofing agent of paper.
Background technique
Paper is seen everywhere, and can be used for industry, office, culture and life, therefore the waste and old paper generated is also very much, greatly It is thrown away after being mostly all crushed, only fraction will do it recycling, and for the utility value for improving waste and old paper, it is dirty to reduce environment Dye, is woven into life appliance or the art work for waste and old paper, has very high use and enjoying value, and being capable of protection ring Income is improved in border.
Paper is easy to absorb water, and knitting in use can be mouldy because absorbing water, or even rots, and influences use value, Therefore braiding is needed to carry out water-proofing treatment with paper.Water-proofing treatment directly is carried out to knitting currently, having in existing method, still Waterproof is uneven, and waterproofing agent for paper available on the market is many kinds of, but waterproof effect validity period is short, and using effect is bad.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of high-quality waterproofing agent of braiding paper is provided.
The present invention is achieved by the following technical solutions:
A kind of braiding high-quality waterproofing agent of paper, is made of the substance of following parts by weight:
20 ~ 25 parts of corn fiber gums, 5 ~ 10 parts of zeins, 3 ~ 5 parts of sodium alginates, 10 ~ 15 parts of stearate, 6 ~ 9 parts Nonylphenol polyoxyethylene ether, 10 ~ 14 parts of terpene resins, 2 ~ 5 parts of urea, 3 ~ 6 parts of sodium tetraborates, 7 ~ 11 parts of carboxymethyl celluloses Sodium, 4 ~ 8 parts of glycerine, 100 ~ 120 parts of deionized waters.
Preferably, it is made of the substance of following parts by weight:
23 parts of corn fiber gums, 9 parts of zeins, 4 parts of sodium alginates, 13 parts of stearate, 8 parts of Nonyl phenos Ether, 12 parts of terpene resins, 4 parts of urea, 5 parts of sodium tetraborates, 9 parts of sodium carboxymethylcelluloses, 6 parts of glycerine, 110 parts of deionizations Water.
Further, the stearate is odium stearate, magnesium stearate, any one in zinc stearate.
A kind of preparation method of the high-quality waterproofing agent of braiding paper, includes the following steps:
(1)First corn fiber gum, zeins, sodium alginate, terpene resin, urea, deionized water are put into jointly In reaction kettle, it is 55 ~ 60 DEG C that heating, which keeps the temperature in reaction kettle, spare after 1 ~ 1.5h of ultrasonic treatment;
(2)Remaining all substances are put into step jointly(1)In treated reaction kettle, heating keeps the temperature in reaction kettle Degree is 62 ~ 66 DEG C, is taken out after being ultrasonically treated 40 ~ 50min.
Further, step(1)Described in ultrasonic treatment when ultrasonic wave frequency be 360 ~ 400kHz.
Further, step(2)Described in ultrasonic treatment when ultrasonic wave frequency be 450 ~ 480kHz.
The present invention has the following advantages that compared with prior art:
The present invention provides a kind of waterproofing agent, rationally, ingredient is safe and harmless for raw material components collocation, environmentally protective, strong to human body Health is coated on paper almost without influence, can be obviously improved the water repellent waterproof ability of paper, and can improve the flexible of paper Property, improve printing, machinability, the great market competitiveness and popularizing value.
Specific embodiment
Embodiment 1
A kind of braiding high-quality waterproofing agent of paper, is made of the substance of following parts by weight:
20 parts of corn fiber gums, 5 parts of zeins, 3 parts of sodium alginates, 10 parts of stearate, 6 parts of Nonyl phenos Ether, 10 parts of terpene resins, 2 parts of urea, 3 parts of sodium tetraborates, 7 parts of sodium carboxymethylcelluloses, 4 parts of glycerine, 100 parts of deionizations Water.
Further, the stearate is odium stearate.
A kind of preparation method of the high-quality waterproofing agent of braiding paper, includes the following steps:
(1)First corn fiber gum, zeins, sodium alginate, terpene resin, urea, deionized water are put into jointly In reaction kettle, it is 55 DEG C that heating, which keeps the temperature in reaction kettle, spare after ultrasonic treatment 1h;
(2)Remaining all substances are put into step jointly(1)In treated reaction kettle, heating keeps the temperature in reaction kettle Degree is 62 DEG C, is taken out after being ultrasonically treated 40min.
Further, step(1)Described in ultrasonic treatment when ultrasonic wave frequency be 360kHz.
Further, step(2)Described in ultrasonic treatment when ultrasonic wave frequency be 450kHz.
Embodiment 2
A kind of braiding high-quality waterproofing agent of paper, is made of the substance of following parts by weight:
23 parts of corn fiber gums, 9 parts of zeins, 4 parts of sodium alginates, 13 parts of stearate, 8 parts of Nonyl phenos Ether, 12 parts of terpene resins, 4 parts of urea, 5 parts of sodium tetraborates, 9 parts of sodium carboxymethylcelluloses, 6 parts of glycerine, 110 parts of deionizations Water.
Further, the stearate is magnesium stearate.
A kind of preparation method of the high-quality waterproofing agent of braiding paper, includes the following steps:
(1)First corn fiber gum, zeins, sodium alginate, terpene resin, urea, deionized water are put into jointly In reaction kettle, it is 58 DEG C that heating, which keeps the temperature in reaction kettle, spare after ultrasonic treatment 1.3h;
(2)Remaining all substances are put into step jointly(1)In treated reaction kettle, heating keeps the temperature in reaction kettle Degree is 65 DEG C, is taken out after being ultrasonically treated 45min.
Further, step(1)Described in ultrasonic treatment when ultrasonic wave frequency be 380kHz.
Further, step(2)Described in ultrasonic treatment when ultrasonic wave frequency be 470kHz.
Embodiment 3
A kind of braiding high-quality waterproofing agent of paper, is made of the substance of following parts by weight:
25 parts of corn fiber gums, 10 parts of zeins, 5 parts of sodium alginates, 15 parts of stearate, 9 parts of polyoxyethylene nonyl phenyl second Alkene ether, 14 parts of terpene resins, 5 parts of urea, 6 parts of sodium tetraborates, 11 parts of sodium carboxymethylcelluloses, 8 parts of glycerine, 120 parts go from Sub- water.
Further, the stearate is zinc stearate.
A kind of preparation method of the high-quality waterproofing agent of braiding paper, includes the following steps:
(1)First corn fiber gum, zeins, sodium alginate, terpene resin, urea, deionized water are put into jointly In reaction kettle, it is 60 DEG C that heating, which keeps the temperature in reaction kettle, spare after ultrasonic treatment 1.5h;
(2)Remaining all substances are put into step jointly(1)In treated reaction kettle, heating keeps the temperature in reaction kettle Degree is 66 DEG C, is taken out after being ultrasonically treated 50min.
Further, step(1)Described in ultrasonic treatment when ultrasonic wave frequency be 400kHz.
Further, step(2)Described in ultrasonic treatment when ultrasonic wave frequency be 480kHz.
Paper after waterproofing agent treatment of the present invention, which is dipped in 120h in water, disrepair phenomenon will not occurs, and can be by the soft of paper Toughness improves 15% or so, and folding rate improves 10% or more, weaves breakage rate reduction by 20% or so, the great market competitiveness and popularization Use value.

Claims (6)

1. the high-quality waterproofing agent that paper is used in a kind of braiding, which is characterized in that be made of the substance of following parts by weight:
20 ~ 25 parts of corn fiber gums, 5 ~ 10 parts of zeins, 3 ~ 5 parts of sodium alginates, 10 ~ 15 parts of stearate, 6 ~ 9 parts Nonylphenol polyoxyethylene ether, 10 ~ 14 parts of terpene resins, 2 ~ 5 parts of urea, 3 ~ 6 parts of sodium tetraborates, 7 ~ 11 parts of carboxymethyl celluloses Sodium, 4 ~ 8 parts of glycerine, 100 ~ 120 parts of deionized waters.
2. the high-quality waterproofing agent that paper is used in a kind of braiding according to claim 1, which is characterized in that by following parts by weight Substance be made:
23 parts of corn fiber gums, 9 parts of zeins, 4 parts of sodium alginates, 13 parts of stearate, 8 parts of Nonyl phenos Ether, 12 parts of terpene resins, 4 parts of urea, 5 parts of sodium tetraborates, 9 parts of sodium carboxymethylcelluloses, 6 parts of glycerine, 110 parts of deionizations Water.
3. the high-quality waterproofing agent that paper is used in a kind of braiding according to claim 1 or 2, which is characterized in that described is hard Resin acid salt is odium stearate, magnesium stearate, any one in zinc stearate.
4. a kind of preparation method of the high-quality waterproofing agent of braiding paper as claimed in claim 1 or 2, which is characterized in that Include the following steps:
(1)First corn fiber gum, zeins, sodium alginate, terpene resin, urea, deionized water are put into jointly In reaction kettle, it is 55 ~ 60 DEG C that heating, which keeps the temperature in reaction kettle, spare after 1 ~ 1.5h of ultrasonic treatment;
(2)Remaining all substances are put into step jointly(1)In treated reaction kettle, heating keeps the temperature in reaction kettle Degree is 62 ~ 66 DEG C, is taken out after being ultrasonically treated 40 ~ 50min.
5. a kind of preparation method of the high-quality waterproofing agent of braiding paper according to claim 4, which is characterized in that step Suddenly(1)Described in ultrasonic treatment when ultrasonic wave frequency be 360 ~ 400kHz.
6. a kind of preparation method of the high-quality waterproofing agent of braiding paper according to claim 4, which is characterized in that step Suddenly(2)Described in ultrasonic treatment when ultrasonic wave frequency be 450 ~ 480kHz.
CN201810883356.2A 2018-08-06 2018-08-06 A kind of braiding high-quality waterproofing agent of paper Pending CN108867166A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810883356.2A CN108867166A (en) 2018-08-06 2018-08-06 A kind of braiding high-quality waterproofing agent of paper

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Application Number Priority Date Filing Date Title
CN201810883356.2A CN108867166A (en) 2018-08-06 2018-08-06 A kind of braiding high-quality waterproofing agent of paper

Publications (1)

Publication Number Publication Date
CN108867166A true CN108867166A (en) 2018-11-23

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ID=64307981

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Country Status (1)

Country Link
CN (1) CN108867166A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103057170A (en) * 2013-01-04 2013-04-24 宁波开诚工艺品有限公司 Production process of straw mat Japanese paper
CN103405083A (en) * 2013-08-09 2013-11-27 宁波市鄞州黎明工艺品有限公司 Processing technology and product of imitation vine and bamboo composite dual-purpose mat
CN104207560A (en) * 2014-08-14 2014-12-17 宁波市鄞州黎明工艺品有限公司 Mat capable of being washed by water and machine and processing process of mat
CN106118553A (en) * 2016-07-13 2016-11-16 阜南县猛发工艺品有限公司 A kind of cracking reinforcing agent for wicker products
CN106192564A (en) * 2016-07-22 2016-12-07 阜南县金威工艺品有限公司 A kind of braiding waterproofing agent for paper

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103057170A (en) * 2013-01-04 2013-04-24 宁波开诚工艺品有限公司 Production process of straw mat Japanese paper
CN103405083A (en) * 2013-08-09 2013-11-27 宁波市鄞州黎明工艺品有限公司 Processing technology and product of imitation vine and bamboo composite dual-purpose mat
CN104207560A (en) * 2014-08-14 2014-12-17 宁波市鄞州黎明工艺品有限公司 Mat capable of being washed by water and machine and processing process of mat
CN106118553A (en) * 2016-07-13 2016-11-16 阜南县猛发工艺品有限公司 A kind of cracking reinforcing agent for wicker products
CN106192564A (en) * 2016-07-22 2016-12-07 阜南县金威工艺品有限公司 A kind of braiding waterproofing agent for paper

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Application publication date: 20181123