CN103173299A - Novel water-saving and environment-friendly bio-cleaning material and preparation method thereof - Google Patents
Novel water-saving and environment-friendly bio-cleaning material and preparation method thereof Download PDFInfo
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- CN103173299A CN103173299A CN 201110431933 CN201110431933A CN103173299A CN 103173299 A CN103173299 A CN 103173299A CN 201110431933 CN201110431933 CN 201110431933 CN 201110431933 A CN201110431933 A CN 201110431933A CN 103173299 A CN103173299 A CN 103173299A
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Abstract
The invention discloses a novel water-saving and environment-friendly bio-cleaning material and a preparation method of the novel water-saving and environment-friendly bio-cleaning material. The preparation method of the bio-cleaning material comprises the following steps of: (a), calcining shells; (b), crushing and grinding the shells into shell powder; (c), adding the shell powder into an acid and alkali resistant high-temperature container, adding water and organic acid to the acid and alkali resistant high-temperature container, heating up and concentrating the mixture to obtain a thick product of containing Ca(OH)2; (d), introducing a gas mixture of CO2 and air to the thick product for carrying out carbonization reaction to obtain CaCO3 mud; (e), drying the CaCO3 mud to obtain the powder; and (f), sufficiently mixing the powder with an enzyme preparation in a mixer to obtain the bio-cleaning material. The bio-cleaning material provided by the invention can be used for simply treating the washed domestic sewage and using the treated domestic sewage for agricultural irrigation, so that harms are not caused to the human during the washing process while the water resources are saved, and therefore, immeasurable social value and economic benefits are achieved.
Description
Technical field
The present invention relates to the biological washing of a kind of water-saving environmental-protection novel material and preparation method thereof, the raw material sources of this biology detergent are extensive, more easily obtain, and should the biology detergent be environmentally friendly detergents.
Background technology
Washing the most usually, is flooded with various washings in life for the common people's family, have a dinner and will wash the dishes later, and clothes is dirty needs laundry, and in family, all kinds of textiless, furniture, floor, electrical equipment all need regular cleaning.Washing is the part of life, so can touch a large amount of washing composition in life.The performance of washing composition, effect so, quality, security with regard to substantial connection to national quality of life and health.There is a lot of drawbacks in the cleaning product of present stage, such as for the waste of existing water resources, to the harm of ecotope, threat and the waste water after washing of human health is difficult to process, also has the starting material major part to derive from oil or caused the raising of product cost by synthetic.
The open CN1533846 of Chinese patent application discloses a kind of detergent and has adopted the washing methods of its detergent.The detergent of this patent application document is the surface that the method for utilization collision is washed washings, it can be made nucleome (1) have tackiness and elastic water and can be prevented between each nucleome because clinging power causes adhesion by what most nucleomes, nucleomes adopting gelatin or glue system contained, and can keep the form of each nucleome and form at most anti discrete particles of nucleome surface attachment; In this state, if it is sprayed to washings, rely on so the clinging power of nucleome just can catch the foreign matter on washings surface.
Yet this detergent needs repeatedly rinse after cleaning process, be unfavorable for environmental protection and water saving.
China is the big producing country of fishery products, and according to statistics, the output of national shellfish fishery products in 2009 is about 1,172 ten thousand tons, and the subsidiary discarded shell that produces 3,000,000 tons of left and right will be large source of pollution of environment if can not effectively utilize.
So whether the inventor considers if discarded shell can be used for the manufacture of cleaning product, can turn waste into wealth, and obtain good technique effect.
Summary of the invention
Technical problem to be solved by this invention is, the biological washing of a kind of water-saving environmental-protection novel material and preparation method thereof is provided, and biological detergent preparation method of the present invention can take full advantage of discarded shell, obtains biological detergent.Through evidence, the inventor is surprised to find, utilize biological detergent preparation method of the present invention to prepare resulting biological detergent, washing effect is good, the few rinsing of foam volume is simple, can be used in agricultural irrigation after can and making sanitary sewage after washing through simple the processing, can not work the mischief to the mankind in washing process in the time of saving water resource, thereby bring immeasurable social value and economic benefit.
In order to solve the problems of the technologies described above, the invention provides following technical scheme:
Technical scheme 1.
A kind of preparation method of biological washing novel material comprises following step:
(a) with shell calcining 1 hour～5 hours, calcining temperature was 800 ℃～1200 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent.
In step (a), by controlling the calcination condition of shell, that is, control calcination time and the calcining temperature of shell, main purpose is in order to remove the organism in shell.Because time and the temperature of calcining are all scopes, determining of so concrete calcination time and calcining temperature is as the criterion with the organic volatilization fully in shell.After organism volatilizees fully, remaining inorganics only, perhaps trace, trace is organic residual, but considered the reason of calcining cost, be as the criterion not affect technique effect of the present invention, for example, the organic content after calcining wherein is below 5ppm (1,000,000/).
In step (b), for the cooling shell that obtains, carry out fragmentation and grinding.About the method that grinds and grind, generally adopt the mechanical mill mode.As for using the not restriction of which kind of machinery, as long as oyster shell whiting can be ground to 4 microns～6 microns.Through evidence, oyster shell whiting in this scope is suitable, because the particle diameter that grinds is too little, namely less than 4 microns, so need to drop into the mechanical energy that more strengthens, and on the other hand, if the particle diameter that grinds is too large, namely greater than 6 microns, the amount of the detergent that consumes in the washing so can enlarge markedly, nor is beneficial to next step heating concentration operation.
In step (c), water and organic acid dissolving shell, after the oyster shell whiting dissolving, the concentrated hydrolysis reaction that occurs of heating can generate Ca (OH)
2Thick product.
In step (d), this Ca (OH)
2Thick product and carbon dioxide reaction just can generate the carbonic acid calcium mud.Although can pass into pure carbon dioxide, to consider from the angle of cost, the mixed gas that still uses carbon dioxide and oxygen is good.
In step (e), both can obtain powder to calcium carbonate mud dry heat.For drying conditions wherein, such as drying temperature, time, pressure etc. all less than restriction, is as the criterion can access powder.Concrete operational condition, those skilled in the art can determine and change according to the actual production conditions of oneself.
(f) powder with step (e) fully mixes in mixing tank with zymin, finally obtains biomaterial.About not restriction of hybrid mode, the mode of preferably using mechanical stirring to mix.Well-mixed degree is looked evenly with feeling the pulse with the finger-tip and is got final product, and other mixes might not to require molecular level.Consider from the technique effect angle, yes, and the more even of mixing is good, but considers that in washing process, meeting produces solvency action, so as long as visual even.
Technical scheme 2.
Preparation method according to technical scheme 1 described biological detergent is characterized in that, described shell comprises one or more in scallop, freshwater mussel and spiral shell.
The kind of shell is a lot, and scallop, freshwater mussel and spiral shell are the shell kinds that extensively exists, and from the complexity angle that obtains, preferably use one or more in scallop, freshwater mussel and spiral shell.That is to say, can preferably use separately their three kinds a kind of, the perhaps combination of any two kinds in them, perhaps their all combinations of three kinds.As for using which kind of array mode, not restriction.
Technical scheme 3.
Preparation method according to technical scheme 1 or 2 described biological detergent is characterized in that, in step (c), the quality of the water that adds is 10 times to 50 times of oyster shell whiting quality.
In this technical scheme, the angle of test proves, if the amount of moisture add too much, for example surpass 50 times of oyster shell whiting quality, need so larger heat energy in follow-up reacting by heating, yet add very little not too easily with fully reaction of acid.
Technical scheme 4.
Preparation method according to the described biological detergent of any one in technical scheme 1～3 is characterized in that, in step (c), adding the organic acid amount is 1%～20% of oyster shell whiting quality.
Technical scheme 5.
Preparation method according to the described biological detergent of any one in technical scheme 1～4 is characterized in that, in step (c), described organic acid comprises one or more in citric acid, acetic acid, oxalic acid, tartrate, Whitfield's ointment, xitix.
Technical scheme 6.
Preparation method according to technical scheme 5 described biological detergents is characterized in that, in step (c), described organic acid comprises citric acid.
Technical scheme 7.
Preparation method according to the described biological detergent of any one in technical scheme 1～6 is characterized in that, in step (d), and Ca (OH)
2The mass concentration of suspension be 5%～15%.
Technical scheme 8.
Preparation method according to the described biological detergent of any one in technical scheme 1～7 is characterized in that, in step (d), and described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 15%～60%.
Technical scheme 9.
Preparation method according to the described biological detergent of any one in technical scheme 1～8 is characterized in that, in step (d), and described CO
2Linearity to be blown into speed be 10～200L/mincm
2(liter/min clock square metre).
Technical scheme 10.
Preparation method according to the described biological detergent of any one in technical scheme 1～9, it is characterized in that, in step (d), the reaction times of described carburizing reagent is 80～500min, the medial temperature of reaction is 20～60 ℃, stir in described carbonation reaction, stir speed (S.S.) is 60～100rpm.
Technical scheme 11.
Preparation method according to the described biological detergent of any one in technical scheme 1～10 is characterized in that, in step (f), described zymin is one or more in Sumizyme MP, alkali cellulose enzyme, amylase, lipase.
Technical scheme 12.
Preparation method according to the described biological detergent of any one in technical scheme 1～11, it is characterized in that, in step (f), described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 2.5～3.5: 2.5～3.5: 3.5～4.5.
Technical scheme 13.
Preparation method according to technical scheme 12 described biological detergents is characterized in that, in step (f), described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 3: 3: 4.
Technical scheme 14.
A kind of biological detergent is characterized in that, this biomaterial is the biological detergent for preparing by the described preparation method of any one in technical scheme 1～13.
The present invention has developed the biological washing of a kind of water-saving environmental-protection novel material.At first this ep-type material is take shell as main raw material, and raw material comes from the Nature, is the derived product of Aquatic Product Process Industry.The starting material wide material sources, not only natural environmental-protective but also realized utilization of waste material, and cheap is conducive to reduce the cost of cleaning product.Auxiliary material can use the enzyme classes preparation, comprises proteolytic enzyme, lipase, amylase and cellulase, and these zymins are easy and fully biodegradable.The hazardous and noxious substances that does not comprise any contaminate environment in the waste water that washing stays later is easy to process, and the growth owing to containing a large amount of calcium carbonate irrigated farmlands in shell and also help farm crop has really realized zero release.This product can not produce abundant foam, and rinsing one can make washings clean to twice, has reached the purpose of water saving.
Embodiment
For those skilled in the art can understand technical scheme of the present invention better, provide following specific embodiment.But these embodiment do not limit protection scope of the present invention.
The raw material sources that use in following embodiment are respectively:
Shell Shenzhen sea cowry think of handicraft company limited
Letter (China) Investment Co., Ltd of Sumizyme MP Novi
Letter (China) Investment Co., Ltd of alkali cellulose enzyme Novi
Letter (China) Investment Co., Ltd of amylase Novi
Letter (China) Investment Co., Ltd of lipase Novi
Embodiment 1
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 1 hour, calcining temperature was 1200 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is scallop;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 10 times of oyster shell whiting quality, and adding the organic acid amount is 20% of oyster shell whiting quality, and described organic acid is acetic acid, Ca (OH)
2The mass concentration of suspension be 15%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 60%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 80min, and the medial temperature of reaction is 60 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 100rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and the mass ratio of described Sumizyme MP, alkali cellulose enzyme, amylase, lipase is 2.5: 2.5: 3.5: 1.
Utilize the prepared biological detergent of embodiment 1 to wash experiment, the results show, the sanitary sewage after washing can be used in agricultural irrigation after simply processing.
Embodiment 2
The present embodiment is the preparation method about the biological washing of a kind of water-saving environmental-protection novel material, is with the difference of embodiment 1, and in step (c), described organic acid is citric acid.
Experiment showed, that the sanitary sewage after not only washing can be used in agricultural irrigation after simply processing, and effect is better than embodiment 1.
Embodiment 3
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 5 hours, calcining temperature was 800 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is freshwater mussel;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 50 times of oyster shell whiting quality, and adding the organic acid amount is 1% of oyster shell whiting quality, and described organic acid is citric acid, Ca (OH)
2The mass concentration of suspension be 15%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 15%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 500min, and the medial temperature of reaction is 60 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 80rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 3.5: 3.5: 4.5.
Utilize the prepared biological detergent of embodiment 3 to wash experiment, the results show, the sanitary sewage after washing can be used in agricultural irrigation after simply processing.
Embodiment 4
The present embodiment is the preparation method about the biological washing of a kind of water-saving environmental-protection novel material, is with the difference of embodiment 3, and in step (c), described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 3: 3: 4.
Experiment showed, that the sanitary sewage after not only washing can be used in agricultural irrigation after simply processing, and soil removability is better than embodiment 3.
Embodiment 5
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 3 hours, calcining temperature was 1000 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is spiral shell;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 30 times of oyster shell whiting quality, and adding the organic acid amount is 10% of oyster shell whiting quality, and described organic acid is oxalic acid, Ca (OH)
2The mass concentration of suspension be 10%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 40%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 200min, and the medial temperature of reaction is 40 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 80rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 2.5: 3.5: 4.5.
Utilize the prepared biological detergent of embodiment 5 to wash experiment, the results show, the sanitary sewage after washing can be used in agricultural irrigation after simply processing.
Biological detergent of the present invention can not produce abundant foam, and rinsing one can make washings clean to twice, has reached the purpose of water saving.
Embodiment 6
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 4, calcining temperature is 900 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is scallop;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 10 times of oyster shell whiting quality, and adding the organic acid amount is 20% of oyster shell whiting quality, and described organic acid is tartrate, Ca (OH)
2The mass concentration of suspension be 8%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 35%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 300min, and the medial temperature of reaction is 38 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 90rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 3: 2.5: 4.5.
Embodiment 7
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 2 hours, calcining temperature was 850 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is spiral shell;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 10 times to 50 times of oyster shell whiting quality, and adding the organic acid amount is 20% of oyster shell whiting quality, and described organic acid is Whitfield's ointment, Ca (OH)
2The mass concentration of suspension be 8%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 50%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 450min, and the medial temperature of reaction is 50 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 60rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 3: 3: 4.
Embodiment 8
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 5 hours, calcining temperature was 1200 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is freshwater mussel;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 50 times of oyster shell whiting quality, and adding the organic acid amount is 1% of oyster shell whiting quality, and described organic acid is xitix, Ca (OH)
2The mass concentration of suspension be 15%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 60%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 500min, and the medial temperature of reaction is 20 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 100rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 3.5: 2.5: 4.5.
Embodiment 9
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 5 hours, calcining temperature was 900 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is freshwater mussel;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 10 times to 50 times of oyster shell whiting quality, and adding the organic acid amount is 16% of oyster shell whiting quality, and described organic acid is citric acid, Ca (OH)
2The mass concentration of suspension be 15%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 60%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 80min, and the medial temperature of reaction is 60 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 100rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 2.5: 3.5: 3.5.
Embodiment 10
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 5 hours, calcining temperature was 1200 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is scallop, freshwater mussel and spiral shell, and mass ratio is 1: 1: 1;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 10 times to 50 times of oyster shell whiting quality, adding the organic acid amount is 1%～20% of oyster shell whiting quality, described organic acid is the mixture of citric acid, acetic acid, oxalic acid, tartrate, Whitfield's ointment, xitix, and the quality of various acid equates, Ca (OH)
2The mass concentration of suspension be 5%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 60%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 500min, and the medial temperature of reaction is 60 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 60rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 3: 3: 4.
Embodiment 11
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 2 hours, calcining temperature was 1050 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is scallop and freshwater mussel, and the mass ratio of scallop and freshwater mussel is 1: 1;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 10 times to 50 times of oyster shell whiting quality, adding the organic acid amount is 20% of oyster shell whiting quality, described organic acid is the mixture of citric acid, acetic acid, oxalic acid, tartrate, Whitfield's ointment, xitix, and the quality of various acid equates, Ca (OH)
2The mass concentration of suspension be 11%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 38%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 260min, and the medial temperature of reaction is 50 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 95rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 2.5: 3.5: 4.5.
Embodiment 12
The present embodiment is about the preparation method of the biological washing of a kind of water-saving environmental-protection novel material, comprises the steps:
(a) with shell calcining 5 hours, calcining temperature was 800 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing, and described shell is scallop, freshwater mussel and spiral shell, and the mass ratio of scallop, freshwater mussel and spiral shell is 1: 1: 1;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product; The quality of the water that adds is 30 times of oyster shell whiting quality, and adding the organic acid amount is 10.5% of oyster shell whiting quality, and described organic acid is citric acid, Ca (OH)
2The mass concentration of suspension be 10%, described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 32.5%;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud, the reaction times of described carburizing reagent is 290min, and the medial temperature of reaction is 40 ℃, stirs in described carbonation reaction, and stir speed (S.S.) is 80rpm;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent; Described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, lipase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 2.5: 2.5: 4.5.
The invention has the advantages that:
1. product involved in the present invention can effectively be removed the spot of clothing and vessel surface, and can injury to clothing and vessel.
2. not only natural environmental-protective but also realized utilization of waste material, and cheap.
3. foam volume is little, is easy to rinse, saving water resource.
4. the waste water that produces after the washing does not contain objectionable impurities, can not work the mischief to environment and animals and plants, can reuse after simple process.
Abovely utilize embodiment to be illustrated to technical scheme of the present invention; the detailed description of these embodiment is all in order to make those skilled in the art to technical scheme of the present invention, comparatively distinct understanding be arranged, can not to be used for limiting protection scope of the present invention.For a person skilled in the art, they can make retouching and improve technical scheme of the present invention according to the general knowledge of oneself, within will be understood that these retouchings and improvement are contained in protection scope of the present invention.
Claims (14)
1. the preparation method of the biological washing of water-saving environmental-protection novel material comprises following step:
(a) with shell calcining 1 hour～5 hours, calcining temperature was 800 ℃～1200 ℃, makes the organism in shell volatilize fully, and calcining naturally cools to room temperature after finishing;
(b) the cooling shell that obtains of step (a) is carried out crushing grinding, make shell become oyster shell whiting, the particle diameter of described oyster shell whiting is 4 microns～6 microns;
(c) described oyster shell whiting is joined in the acid-fast alkali-proof elevated temperature vessel, then adds entry and organic acid, stir and fully mix after heat concentratedly, the heating enriched mixture obtains Ca (OH)
2Thick product;
(d) pass into CO in described thick product
2Carry out carburizing reagent with the mixed gas of air, obtain CaCO
3Mud;
(e) dry described CaCO
3Mud obtains powder;
(f) powder with step (e) fully mixes in mixing tank with zymin, obtains biological detergent.
2. the preparation method of biological detergent according to claim 1, is characterized in that, described shell comprises one or more in scallop, freshwater mussel and spiral shell.
3. the preparation method of biological detergent according to claim 1 and 2, is characterized in that, in step (c), the quality of the water that adds is 10 times to 50 times of oyster shell whiting quality.
4. the preparation method of the described biological detergent of any one according to claim 1～3, is characterized in that, in step (c), adding the organic acid amount is 1%～20% of oyster shell whiting quality.
5. the preparation method of the described biological detergent of any one according to claim 1～4, is characterized in that, in step (c), described organic acid comprises one or more in citric acid, acetic acid, oxalic acid, tartrate, Whitfield's ointment, xitix.
6. the preparation method of biological detergent according to claim 5, is characterized in that, in step (c), described organic acid comprises citric acid.
7. the preparation method of the described biological detergent of any one according to claim 1～6, is characterized in that, in step (d), and Ca (OH)
2The mass concentration of suspension be 5%～15%.
8. the preparation method of the described biological detergent of any one according to claim 1～7, is characterized in that, in step (d), and described CO
2With the CO in the mixed gas of air
2Volumetric concentration be 15%～60%.
9. the preparation method of the described biological detergent of any one according to claim 1～8, is characterized in that, in step (d), and described CO
2Linearity to be blown into speed be 10～200L/mincm
2
10. the preparation method of the described biological detergent of any one according to claim 1～9, it is characterized in that, in step (d), the reaction times of described carburizing reagent is 80～500min, the medial temperature of reaction is 20～60 ℃, stir in described carbonation reaction, stir speed (S.S.) is 60～100rpm.
11. according to claim 1～10, the preparation method of the described biological detergent of any one, is characterized in that, in step (f), described zymin is one or more in Sumizyme MP, alkali cellulose enzyme, amylase, lipase.
12. the preparation method of the described biological detergent of any one according to claim 1～11, it is characterized in that, in step (f), described zymin is Sumizyme MP, alkali cellulose enzyme, amylase, and described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 2.5～3.5: 2.5～3.5: 3.5～4.5.
13. the preparation method of biological detergent according to claim 12 is characterized in that, in step (f), described Sumizyme MP, alkali cellulose enzyme, diastatic mass ratio are 3: 3: 4.
14. a biological detergent is characterized in that, this biomaterial is the biological detergent for preparing by the described preparation method of any one in claim 1～13.
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| CN 201110431933 CN103173299A (en) | 2011-12-21 | 2011-12-21 | Novel water-saving and environment-friendly bio-cleaning material and preparation method thereof |
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|---|---|---|---|
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046520A (en) * | 2014-05-19 | 2014-09-17 | 梁晓 | Non-phosphate detergent composition |
| CN104351253A (en) * | 2014-09-23 | 2015-02-18 | 江阴宝易德医疗科技有限公司 | Natural antibacterial adsorption ultrafine powder and preparation method thereof |
| CN111517351A (en) * | 2020-04-20 | 2020-08-11 | 池州市贵兴非矿新材料有限公司 | Method for preparing active calcium oxide |
-
2011
- 2011-12-21 CN CN 201110431933 patent/CN103173299A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046520A (en) * | 2014-05-19 | 2014-09-17 | 梁晓 | Non-phosphate detergent composition |
| CN104351253A (en) * | 2014-09-23 | 2015-02-18 | 江阴宝易德医疗科技有限公司 | Natural antibacterial adsorption ultrafine powder and preparation method thereof |
| CN111517351A (en) * | 2020-04-20 | 2020-08-11 | 池州市贵兴非矿新材料有限公司 | Method for preparing active calcium oxide |
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Application publication date: 20130626 |