CN106118553A - A kind of cracking reinforcing agent for wicker products - Google Patents

A kind of cracking reinforcing agent for wicker products Download PDF

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Publication number
CN106118553A
CN106118553A CN201610551269.8A CN201610551269A CN106118553A CN 106118553 A CN106118553 A CN 106118553A CN 201610551269 A CN201610551269 A CN 201610551269A CN 106118553 A CN106118553 A CN 106118553A
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parts
liquid
wicker products
reinforcing agent
sodium
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CN201610551269.8A
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CN106118553B (en
Inventor
李明
李东猛
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FUNAN COUNTY MENGFA ARTS & CRAFTS Co Ltd
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FUNAN COUNTY MENGFA ARTS & CRAFTS Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention discloses a kind of cracking reinforcing agent for wicker products, including A liquid and B liquid, described A liquid is made up of following material: wood vinegar, Mancozeb, Konjac glucomannan, sodium stearate, NPE, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, polydimethylsiloxane, ammonium polyacrylate, boric acid, water;Described B liquid is made up of following material: sodium hexameta phosphate, tartaric acid, sodium carboxymethyl cellulose, active carbon nanoparticles, nano silicon, propylene glycol methyl ether acetate, acrylic emulsion, Cortex Phellodendri extract, Camphora extract, water.The cracking reinforcing agent of present invention preparation is under the common effect of A liquid and B liquid, well it is filled with gap, avoid the erosion to it of the exogenous impurity composition, improve again its Vermins-proof mildew-proof performance and the intensity of entirety and wearability, the surface strength of final wicker products can improve about 40%, rupture strength can improve about 50%, and service life can extend 1 ~ 2 times, and use value is higher.

Description

A kind of cracking reinforcing agent for wicker products
Technical field
The invention belongs to wicker plaiting article manufacture field, be specifically related to a kind of cracking reinforcing agent for wicker products.
Background technology
Wicker plaiting article is China's one traditional technology, and present wicker products is commercially popular, and the kind of wicker products is numerous Many, the polytypes such as seat, basket, basket, dustpan, round-bottomed basket, crate, shallow basket made of wicker or thin bamboo strips, the gaily decorated basket, bamboo strainer, food dish are had at domestic aspect.Export trade side Face, has formed buck basket, flower pot coat, picnic tableware basket, hanging basket, lampshade, kennel, cat litter, Bird's Nest etc. through developing and design many Kind, foreign trade is formed the appreciation effect that low-grade goods become high-grade, very popular.But wicker products preserve or During improper use, tiny crack easily occurs, if things go on like this can develop into bigger deeper breach, not only can affect wicker plaiting article system The antiseptic insect-repelling performance of product, can reduce again the intensity of wicker plaiting article, be deformed, and i.e. affecting attractive in appearance affects again practicality.People at present Not yet paying attention to for problems, the quality that processes when usual wicker plaiting article finished product makes determines the length in service life, and in examination It is not carried out maintenance maintenance with period, cause the shorter problem with the wasting of resources in service life.Groups of people use wooden use Glue bonds, although can play certain effect in the short time, but can not solve question of substance.
Summary of the invention
In order to solve the problems referred to above, the invention provides a kind of cracking reinforcing agent for wicker products.
The present invention is achieved through the following technical solutions:
A kind of cracking reinforcing agent for wicker products, including A liquid and B liquid, described A liquid is made up of the material of following weight portion: 2 Part wood vinegar, 1 part of Mancozeb, 5 parts of Konjac glucomannan, 6 parts of sodium stearates, 3 parts of NPEs, 2 parts of high-carbon fatty alcohols Polyoxyethylene ether, 4 parts of positive silicic acid propyl ester, 8 parts of polydimethylsiloxane, 5 parts of ammonium polyacrylates, 2 parts of boric acid, 100 parts of water;Described B liquid is made up of the material of following weight portion: 4 parts of sodium hexameta phosphate, 3 parts of tartaric acid, 6 parts of sodium carboxymethyl cellulose, 5 parts of nanometers are lived Property charcoal, 5 parts of nano silicons, 4 parts of propylene glycol methyl ether acetates, 15 parts of acrylic emulsions, 7 parts of Cortex Phellodendri extracts, 6 parts of Camphoras Extract, 50 parts of water.
Further, the preparation method of described A liquid comprises the steps:
(1) by water temp. heating to 55 ~ 58 DEG C, then Konjac glucomannan and stearic acid sodium are added jointly, with 600 ~ 800 revs/min Rotating speed is stirred continuously 15min, maintains 55 ~ 58 DEG C of condition insulation 30min standby the most again;
(2) by NPE, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, polydimethylsiloxane and poly- Ammonium acrylate is common with the liquid mixing of step (1) gained, and heating holding temperature of liquid is 38 ~ 42 DEG C, with 1000 ~ 1200 turns/ Minute rotating speed be stirred continuously 20min, then naturally cool to room temperature standby;
(3) wood vinegar, Mancozeb and boric acid are joined jointly in the liquid of step (2) gained, with 350 ~ 400 revs/min Rotating speed be stirred continuously 10min, then homogenizing 1h after i.e. obtain A liquid.
Further, the preparation method of described B liquid comprises the steps:
(1) sodium hexameta phosphate, tartaric acid, sodium carboxymethyl cellulose, Cortex Phellodendri extract and Camphora extract are joined water jointly In, and to heat holding aqueous temperature be 45 ~ 48 DEG C, is stirred continuously to the most standby after uniformly;
(2) active carbon nanoparticles, nano silicon and propylene glycol methyl ether acetate are joined in acrylic emulsion jointly, at frequency Rate be 38KHz ultrasonic Treatment instrument in standby after stir process 15min;
(3) step (2) gained solution is mixed in the solution of step (1) gained with the speed of 15 ~ 20ml/s, simultaneously with 500 Rev/min rotating speed stir and i.e. obtain B liquid.
The using method of the cracking reinforcing agent of a kind of wicker products, comprises the steps:
(1) first it is rinsed roguing with clear water position pending to wicker products;
(2) position after rinsing step (1) is dried, and drying to its surface moisture is 20 ~ 30%;
(3) A liquid is sprayed at step (2) dry after wicker products on, then treat its naturally dry to surface tack-free;
(4) being uniformly sprayed at by B liquid on the wicker products after step (3) processes, putting it into temperature after completing is 35 ~ 38 DEG C Under the conditions of dried 5 ~ 7min.
There is advantages that
(1) the A liquid of present invention preparation can well kill at wicker products cracking the impurity such as the antibacterial of residual, fungus, worm's ovum, anti- Only it is further to the erosion within wicker plaiting article, has again preferable mobility simultaneously, relatively strong with cellulosic structure affinity, and Tiny wooden burr can be softened to a certain extent, coat a hypoglyph in its surface, establish very well for follow-up operation Basis.
(2) between the B liquid of present invention preparation and the counterdie of A liquid formation, adhesiveness is relatively strong, active carbon nanoparticles, nano silicon Well it is filled with the gap of wicker products with acrylic emulsion, and enhances its wear resistence and intensity, Cortex Phellodendri extract and Camphor tree The interpolation of brain extract enhances again the Vermins-proof mildew-proof performance of wicker products.
(3) the cracking reinforcing agent of present invention preparation is under the common effect of A liquid and B liquid, is well filled with gap, it is to avoid The erosion to it of the exogenous impurity composition, improves again its Vermins-proof mildew-proof performance and the intensity of entirety and wearability, A liquid and B The mixture that liquid is collectively forming not only has good cohesive force, has again certain elasticity, can improve its shock resistance, relatively Pure glue bonds more practicality.The surface strength of final wicker products can improve about 40%, and it is left that rupture strength can improve 50% The right side, is less susceptible to deformation, can extend 1 ~ 2 times service life, and use value is higher.
Detailed description of the invention
Embodiment 1
A kind of cracking reinforcing agent for wicker products, including A liquid and B liquid, described A liquid is made up of the material of following weight portion: 2 Part wood vinegar, 1 part of Mancozeb, 5 parts of Konjac glucomannan, 6 parts of sodium stearates, 3 parts of NPEs, 2 parts of high-carbon fatty alcohols Polyoxyethylene ether, 4 parts of positive silicic acid propyl ester, 8 parts of polydimethylsiloxane, 5 parts of ammonium polyacrylates, 2 parts of boric acid, 100 parts of water;Described B liquid is made up of the material of following weight portion: 4 parts of sodium hexameta phosphate, 3 parts of tartaric acid, 6 parts of sodium carboxymethyl cellulose, 5 parts of nanometers are lived Property charcoal, 5 parts of nano silicons, 4 parts of propylene glycol methyl ether acetates, 15 parts of acrylic emulsions, 7 parts of Cortex Phellodendri extracts, 6 parts of Camphoras Extract, 50 parts of water.
Further, the preparation method of described A liquid comprises the steps:
(1) by water temp. heating to 58 DEG C, then Konjac glucomannan and stearic acid sodium jointly being added, the rotating speed with 700 revs/min is continuous Stirring 15min, maintains 56 DEG C of condition insulation 30min standby the most again;
(2) by NPE, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, polydimethylsiloxane and poly- Ammonium acrylate is common with the liquid mixing of step (1) gained, and heating keeps temperature of liquid to be 39 DEG C, with 1100 revs/min turn Speed is stirred continuously 20min, then naturally cools to room temperature standby;
(3) wood vinegar, Mancozeb and boric acid are joined jointly in the liquid of step (2) gained, with 390 revs/min turn Speed i.e. obtains A liquid after being stirred continuously 10min, then homogenizing 1h.
Further, the preparation method of described B liquid comprises the steps:
(1) sodium hexameta phosphate, tartaric acid, sodium carboxymethyl cellulose, Cortex Phellodendri extract and Camphora extract are joined water jointly In, and to heat holding aqueous temperature be 48 DEG C, is stirred continuously to the most standby after uniformly;
(2) active carbon nanoparticles, nano silicon and propylene glycol methyl ether acetate are joined in acrylic emulsion jointly, at frequency Rate be 38KHz ultrasonic Treatment instrument in standby after stir process 15min;
(3) step (2) gained solution is mixed in the solution of step (1) gained with the speed of 18ml/s, simultaneously with 500 turns/ Minute rotating speed stir and i.e. obtain B liquid.
The using method of the cracking reinforcing agent of a kind of wicker products, comprises the steps:
(1) first it is rinsed roguing with clear water position pending to wicker products;
(2) position after rinsing step (1) is dried, and drying to its surface moisture is 27 ~ 30%;
(3) A liquid is sprayed at step (2) dry after wicker products on, then treat its naturally dry to surface tack-free;
(4) B liquid is uniformly sprayed on the wicker products after step (3) processes, after completing, puts it into the bar that temperature is 37 DEG C Dried 5min under part.
Comparative example 1
Compared with Example 1, described A liquid is the most identical with each composition proportion in B liquid, but the most straight for this comparative example 1 Connecing the mixed liquor that A liquid and B liquid composition carry out be mixed and made into one, both weight ratios are 1:1.5, are the most also direct Spray mixed liquor.
Matched group
Plank class adhesive.
In order to contrast effect of the present invention, with solvent corresponding to above-mentioned three kinds of modes respectively to same batch, cracking degree phase As wicker products process, and its performance of test statistics, find that the rupture strength of the wicker products of embodiment 1 correspondence is right Ratio 1.2 times of embodiment 1, is 1.1 times of matched group;Its service life is 1.3 times of comparative example 1, is the 1.7 of matched group Times, it is 2.5 times of the unprocessed wicker products life-span.

Claims (4)

1. the cracking reinforcing agent for wicker products, it is characterised in that including A liquid and B liquid, described A liquid is by following weight Part material make: 2 parts of wood vinegar, 1 part of Mancozeb, 5 parts of Konjac glucomannan, 6 parts of sodium stearates, 3 parts of NPEs, 2 parts of high-carbon fatty alcohol polyoxyethylene ethers, 4 parts of positive silicic acid propyl ester, 8 parts of polydimethylsiloxane, 5 parts of ammonium polyacrylates, 2 parts of boron Acid, 100 parts of water;Described B liquid is made up of the material of following weight portion: 4 parts of sodium hexameta phosphate, 3 parts of tartaric acid, 6 parts of carboxymethyl fibres Dimension element sodium, 5 parts of active carbon nanoparticles, 5 parts of nano silicons, 4 parts of propylene glycol methyl ether acetates, 15 parts of acrylic emulsions, 7 parts of Huangs Cypress extract, 6 parts of Camphora extracts, 50 parts of water.
A kind of cracking reinforcing agent for wicker products the most according to claim 1, it is characterised in that the system of described A liquid Preparation Method comprises the steps:
(1) by water temp. heating to 55 ~ 58 DEG C, then Konjac glucomannan and stearic acid sodium are added jointly, with 600 ~ 800 revs/min Rotating speed is stirred continuously 15min, maintains 55 ~ 58 DEG C of condition insulation 30min standby the most again;
(2) by NPE, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, polydimethylsiloxane and poly- Ammonium acrylate is common with the liquid mixing of step (1) gained, and heating holding temperature of liquid is 38 ~ 42 DEG C, with 1000 ~ 1200 turns/ Minute rotating speed be stirred continuously 20min, then naturally cool to room temperature standby;
(3) wood vinegar, Mancozeb and boric acid are joined jointly in the liquid of step (2) gained, with 350 ~ 400 revs/min Rotating speed be stirred continuously 10min, then homogenizing 1h after i.e. obtain A liquid.
A kind of cracking reinforcing agent for wicker products the most according to claim 1, it is characterised in that the system of described B liquid Preparation Method comprises the steps:
(1) sodium hexameta phosphate, tartaric acid, sodium carboxymethyl cellulose, Cortex Phellodendri extract and Camphora extract are joined water jointly In, and to heat holding aqueous temperature be 45 ~ 48 DEG C, is stirred continuously to the most standby after uniformly;
(2) active carbon nanoparticles, nano silicon and propylene glycol methyl ether acetate are joined in acrylic emulsion jointly, at frequency Rate be 38KHz ultrasonic Treatment instrument in standby after stir process 15min;
(3) step (2) gained solution is mixed in the solution of step (1) gained with the speed of 15 ~ 20ml/s, simultaneously with 500 Rev/min rotating speed stir and i.e. obtain B liquid.
4. the wicker products as described in claim 1 ~ 3 cracking reinforcing agent using method, it is characterised in that include as Lower step:
(1) first it is rinsed roguing with clear water position pending to wicker products;
(2) position after rinsing step (1) is dried, and drying to its surface moisture is 20 ~ 30%;
(3) A liquid is sprayed at step (2) dry after wicker products on, then treat its naturally dry to surface tack-free;
(4) being uniformly sprayed at by B liquid on the wicker products after step (3) processes, putting it into temperature after completing is 35 ~ 38 DEG C Under the conditions of dried 5 ~ 7min.
CN201610551269.8A 2016-07-13 2016-07-13 A kind of cracking reinforcing agent for wicker products Active CN106118553B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107574710A (en) * 2017-09-26 2018-01-12 阜南县腾祥工艺品有限公司 A kind of processing method for improving paper establishment product and using characteristic
CN107653739A (en) * 2017-09-26 2018-02-02 阜南县腾祥工艺品有限公司 A kind of coating of braiding paper
CN108867166A (en) * 2018-08-06 2018-11-23 安徽三和工艺品有限公司 A kind of braiding high-quality waterproofing agent of paper

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1580144A (en) * 2003-08-04 2005-02-16 深圳市海川实业股份有限公司 Environmenttally friendly water-based transparent putty for woodenware
CN103265837A (en) * 2013-05-28 2013-08-28 南京工程学院 Preparation method of painted real-wood furniture crack repairing paste and crack repairing method
CN104927516A (en) * 2015-05-29 2015-09-23 阜南县猛发工艺品有限公司 Willow weaving paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1580144A (en) * 2003-08-04 2005-02-16 深圳市海川实业股份有限公司 Environmenttally friendly water-based transparent putty for woodenware
CN103265837A (en) * 2013-05-28 2013-08-28 南京工程学院 Preparation method of painted real-wood furniture crack repairing paste and crack repairing method
CN104927516A (en) * 2015-05-29 2015-09-23 阜南县猛发工艺品有限公司 Willow weaving paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107574710A (en) * 2017-09-26 2018-01-12 阜南县腾祥工艺品有限公司 A kind of processing method for improving paper establishment product and using characteristic
CN107653739A (en) * 2017-09-26 2018-02-02 阜南县腾祥工艺品有限公司 A kind of coating of braiding paper
CN108867166A (en) * 2018-08-06 2018-11-23 安徽三和工艺品有限公司 A kind of braiding high-quality waterproofing agent of paper

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