CN106118462A - A kind of wicker products damaged face protective agent - Google Patents

A kind of wicker products damaged face protective agent Download PDF

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Publication number
CN106118462A
CN106118462A CN201610551282.3A CN201610551282A CN106118462A CN 106118462 A CN106118462 A CN 106118462A CN 201610551282 A CN201610551282 A CN 201610551282A CN 106118462 A CN106118462 A CN 106118462A
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parts
liquid
wicker products
water
calcium
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CN201610551282.3A
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Inventor
李明
李东猛
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FUNAN COUNTY MENGFA ARTS & CRAFTS Co Ltd
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FUNAN COUNTY MENGFA ARTS & CRAFTS Co Ltd
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Priority to CN201610551282.3A priority Critical patent/CN106118462A/en
Publication of CN106118462A publication Critical patent/CN106118462A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of wicker products damaged face protective agent; including A liquid and B liquid, described A liquid is made up of following material: Bamboo vinegar solution, carbendazim, guar gum, calcium stearate, NPE, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, polydimethylsiloxane, ammonium polyacrylate, boric acid, water;Described B liquid is made up of following material: calcium pyrophosphate, daucic acid, paraffin oil, dodecyl sodium sulfate, xylitol, carbamide, sodium polyacrylate, magnesium stearate, Ammonium persulfate., propandiol butyl ether, dibutyl tin laurate, nano-calcium carbonate, nano titanium oxide, nanofiber, water-based polyurethane adhesive, butyl acetate, water.The damaged face protective agent of present invention preparation is under A liquid and B liquid act on jointly; avoid the erosion to its inside of the exogenous impurity composition; the mixture that A liquid and B liquid are collectively forming has good cohesive force, and its wear-resisting intensity improves about 60%, extends 1.5 ~ 2 times service life.

Description

A kind of wicker products damaged face protective agent
Technical field
The invention belongs to wicker plaiting article manufacture field, be specifically related to a kind of wicker products damaged face protective agent.
Background technology
Wicker plaiting article is China's one traditional technology, and present wicker products is commercially popular, and the kind of wicker products is numerous Many, the polytypes such as seat, basket, basket, dustpan, round-bottomed basket, crate, shallow basket made of wicker or thin bamboo strips, the gaily decorated basket, bamboo strainer, food dish are had at domestic aspect.Export trade side Face, has formed buck basket, flower pot coat, picnic tableware basket, hanging basket, lampshade, kennel, cat litter, Bird's Nest etc. through developing and design many Kind, foreign trade is formed the appreciation effect that low-grade goods become high-grade, very popular.But, making at wicker products During with, inevitably causing its surface abrasion or fracture, its interior tissue exposes in atmosphere, if not locating Reason, under outside erosion, its performance can constantly decline with the life-span, and the mode that someone uses secondary to spray paint processes, although It can be kept not weather within a period of time, but because of the structure out-of-flatness in damaged face, easily cause coming off of secondary paint, and nothing Method strengthens its surface abrasion resistance, the most easily exposes damaged face, and action effect is the best.
Summary of the invention
In order to solve the problems referred to above, the invention provides a kind of wicker products damaged face protective agent.
The present invention is achieved through the following technical solutions:
A kind of wicker products damaged face protective agent, including A liquid and B liquid, described A liquid is made up of the material of following weight portion: 2 parts Bamboo vinegar solution, 2 parts of carbendazim, 4 parts of guar gums, 5 parts of calcium stearates, 3 parts of NPEs, 2 parts of high-carbon fatty alcohol polyoxies Vinyl Ether, 5 parts of positive silicic acid propyl ester, 8 parts of polydimethylsiloxane, 6 parts of ammonium polyacrylates, 2 parts of boric acid, 120 parts of water;Described B liquid Be made up of the material of following weight portion: 4 parts of calcium pyrophosphates, 3 parts of daucic acid, 7 parts of paraffin oil, 5 parts of dodecyl sodium sulfates, 2 parts Xylitol, 2 parts of carbamide, 4 parts of sodium polyacrylate, 3 parts of magnesium stearate, 3 parts of Ammonium persulfate .s, 6 parts of propandiol butyl ethers, 4 part of two Laurel Acid dibutyl tin, 3 parts of nano-calcium carbonates, 3 parts of nano titanium oxides, 4 parts of nanofibers, 12 parts of water-based polyurethane adhesives, 8 parts Butyl acetate, 60 parts of water.
Further, the length of described nanofiber is not more than 5 microns.
Further, the preparation method of described A liquid comprises the steps:
(1) by water temp. heating to 55 ~ 58 DEG C, then guar gum and calcium stearate are added jointly, with 500 ~ 700 revs/min Rotating speed is stirred continuously 15min, maintains 55 ~ 58 DEG C of condition insulation 30min standby the most again;
(2) by NPE, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, polydimethylsiloxane and poly- Ammonium acrylate is common with the liquid mixing of step (1) gained, and heating holding temperature of liquid is 38 ~ 42 DEG C, with 1300 ~ 1500 turns/ Minute rotating speed be stirred continuously 20min, then naturally cool to room temperature standby;
(3) Bamboo vinegar solution, carbendazim and boric acid are joined jointly in the liquid of step (2) gained, with 400 ~ 500 revs/min Rotating speed i.e. obtains A liquid after being stirred continuously 10min, then homogenizing 1h.
Further, the preparation method of described B liquid comprises the steps:
(1) by calcium pyrophosphate, daucic acid, paraffin oil, dodecyl sodium sulfate, xylitol, carbamide, sodium polyacrylate, stearic acid Magnesium, Ammonium persulfate. and nanofiber are added to the water jointly, and keeping solution temperature is 55 ~ 60 DEG C, is stirred continuously to the most standby;
(2) propandiol butyl ether, dibutyl tin laurate, nano-calcium carbonate, nano titanium oxide and butyl acetate are added jointly Entering in water-based polyurethane adhesive, keeping solution temperature is 37 ~ 42 DEG C, stirs with the rotating speed of 1000 ~ 1200 revs/min Standby;
(3) solution of step (2) gained is mixed in the solution of step (1) gained with the speed of 8 ~ 12ml/s, applies simultaneously Frequency is that the ultrasound wave of 42KHz carries out aid in treatment, naturally cools to room temperature and i.e. obtain B liquid after puddling uniformly.By step (2) gained Solution join in mode slow, anisothermal in the solution of step (1) gained, liquidating of utilizing that temperature do not waits acts on into one Step enhances the intersolubility between material molecule, carries out Sonication assisted treatment simultaneously, improves the compactness of B liquid.
The protectant using method in a kind of damaged face of wicker products, comprises the steps:
(1) first it is rinsed roguing with clear water position pending to wicker products;
(2) position after rinsing step (1) is dried, and drying to its surface moisture is 18 ~ 23%;
(3) A liquid is sprayed at step (2) dry after wicker products on, then treat its naturally dry to surface tack-free;
(4) being uniformly sprayed at by B liquid on the wicker products after step (3) processes, putting it into temperature after completing is 40 ~ 42 DEG C Under the conditions of dried 3 ~ 4min, put it in the freezer that temperature is 2 ~ 4 DEG C freezing 4 ~ 5min the most again, finally take out nature Recover to room temperature.
There is advantages that
(1) the A liquid of present invention preparation can well kill the impurity such as the antibacterial of wicker products breakage face place residual, fungus, worm's ovum, Prevent it further to the erosion within wicker plaiting article, there is again preferable mobility simultaneously, relatively strong with cellulosic structure affinity, And tiny wooden burr can be softened to a certain extent, coat a hypoglyph in its surface, established very for follow-up operation Good basis.
(2) between the B liquid of present invention preparation and the counterdie of A liquid formation, adhesiveness is relatively strong, nano-calcium carbonate, nanometer titanium dioxide Titanium, nanofiber and water-based polyurethane adhesive etc. have well covered damaged face, together form a network structure, strengthen The wear-resisting intensity on surface.
(3) the damaged face protective agent of present invention preparation is under the common effect of A liquid and B liquid, well covers damaged face, Avoid the erosion to its inside of the exogenous impurity composition, improve the mixing that its Vermins-proof mildew-proof performance, A liquid and B liquid are collectively forming Thing has good cohesive force, preferable with wicker plaiting article interior tissue associativity, imparts again the anti-wear performance that damaged face is stronger, wear-resisting Intensity improves about 60%, reduces its probability again damaged, and can extend 1.5 ~ 2 times service life, and using effect is preferable.
Detailed description of the invention
Embodiment 1
A kind of wicker products damaged face protective agent, including A liquid and B liquid, described A liquid is made up of the material of following weight portion: 2 parts Bamboo vinegar solution, 2 parts of carbendazim, 4 parts of guar gums, 5 parts of calcium stearates, 3 parts of NPEs, 2 parts of high-carbon fatty alcohol polyoxies Vinyl Ether, 5 parts of positive silicic acid propyl ester, 8 parts of polydimethylsiloxane, 6 parts of ammonium polyacrylates, 2 parts of boric acid, 120 parts of water;Described B liquid Be made up of the material of following weight portion: 4 parts of calcium pyrophosphates, 3 parts of daucic acid, 7 parts of paraffin oil, 5 parts of dodecyl sodium sulfates, 2 parts Xylitol, 2 parts of carbamide, 4 parts of sodium polyacrylate, 3 parts of magnesium stearate, 3 parts of Ammonium persulfate .s, 6 parts of propandiol butyl ethers, 4 part of two Laurel Acid dibutyl tin, 3 parts of nano-calcium carbonates, 3 parts of nano titanium oxides, 4 parts of nanofibers, 12 parts of water-based polyurethane adhesives, 8 parts Butyl acetate, 60 parts of water.
Further, the length of described nanofiber is not more than 5 microns.
Further, the preparation method of described A liquid comprises the steps:
(1) by water temp. heating to 56 DEG C, then guar gum and calcium stearate jointly being added, the rotating speed with 570 revs/min is continuous Stirring 15min, maintains 55 DEG C of condition insulation 30min standby the most again;
(2) by NPE, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, polydimethylsiloxane and poly- Ammonium acrylate is common with the liquid mixing of step (1) gained, and heating keeps temperature of liquid to be 40 DEG C, with 1200 revs/min turn Speed is stirred continuously 20min, then naturally cools to room temperature standby;
(3) Bamboo vinegar solution, carbendazim and boric acid are joined jointly in the liquid of step (2) gained, with the rotating speed of 440 revs/min A liquid is i.e. obtained after being stirred continuously 10min, then homogenizing 1h.
Further, the preparation method of described B liquid comprises the steps:
(1) by calcium pyrophosphate, daucic acid, paraffin oil, dodecyl sodium sulfate, xylitol, carbamide, sodium polyacrylate, stearic acid Magnesium, Ammonium persulfate. and nanofiber are added to the water jointly, and keeping solution temperature is 55 DEG C, is stirred continuously to the most standby;
(2) propandiol butyl ether, dibutyl tin laurate, nano-calcium carbonate, nano titanium oxide and butyl acetate are added jointly Entering in water-based polyurethane adhesive, keeping solution temperature is 38 DEG C, stirs standby with the rotating speed of 1200 revs/min;
(3) solution of step (2) gained is mixed in the solution of step (1) gained with the speed of 10ml/s, applies frequency simultaneously Rate is that the ultrasound wave of 42KHz carries out aid in treatment, naturally cools to room temperature and i.e. obtain B liquid after puddling uniformly.
The protectant using method in a kind of damaged face of wicker products, comprises the steps:
(1) first it is rinsed roguing with clear water position pending to wicker products;
(2) position after rinsing step (1) is dried, and drying to its surface moisture is 20 ~ 23%;
(3) A liquid is sprayed at step (2) dry after wicker products on, then treat its naturally dry to surface tack-free;
(4) B liquid is uniformly sprayed on the wicker products after step (3) processes, after completing, puts it into the bar that temperature is 40 DEG C Dried 3min under part, puts it into freezing 5min in the freezer that temperature is 4 DEG C the most again, finally takes out clear-cutting forestland to often Temperature.
Comparative example 1
Compared with Example 1, described A liquid is the most identical with each composition proportion in B liquid, but the most straight for this comparative example 1 Connecing the mixed liquor that A liquid and B liquid composition carry out be mixed and made into one, both weight ratios are 1:2, are the most also directly sprays Spill mixed liquor.
Matched group
The most common plank water paint.
In order to contrast effect of the present invention, with solvent corresponding to above-mentioned three kinds of modes respectively to same batch, surface fracture journey Spend similar wicker products to process, and its performance of test statistics, find the surface abrasion resistance of the wicker products of embodiment 1 correspondence Intensity is 1.2 times of comparative example 1, is 1.4 times of matched group;Its service life is 1.4 times of comparative example 1, is right According to 1.8 times of group, it it is 2.7 times of the unprocessed wicker products life-span.

Claims (5)

1. a wicker products damaged face protective agent, it is characterised in that including A liquid and B liquid, described A liquid is by following weight portion Material make: 2 parts of Bamboo vinegar solution, 2 parts of carbendazim, 4 parts of guar gums, 5 parts of calcium stearates, 3 parts of NPEs, 2 parts High-carbon fatty alcohol polyoxyethylene ether, 5 parts of positive silicic acid propyl ester, 8 parts of polydimethylsiloxane, 6 parts of ammonium polyacrylates, 2 parts of boric acid, 120 parts of water;Described B liquid is made up of the material of following weight portion: 4 parts of calcium pyrophosphates, 3 parts of daucic acid, 7 parts of paraffin oil, 5 part ten Dialkyl sulfonates, 2 parts of xylitol, 2 parts of carbamide, 4 parts of sodium polyacrylate, 3 parts of magnesium stearate, 3 parts of Ammonium persulfate .s, 6 parts the third two Alcohol butyl ether, 4 parts of dibutyl tin laurates, 3 parts of nano-calcium carbonates, 3 parts of nano titanium oxides, 4 parts of nanofibers, 12 parts of aqueouss Polyurethane adhesive, 8 parts of butyl acetates, 60 parts of water.
A kind of damaged face of wicker products the most according to claim 1 protective agent, it is characterised in that described nanofiber Length is not more than 5 microns.
A kind of damaged face of wicker products the most according to claim 1 protective agent, it is characterised in that the preparation of described A liquid Method comprises the steps:
(1) by water temp. heating to 55 ~ 58 DEG C, then guar gum and calcium stearate are added jointly, with 500 ~ 700 revs/min Rotating speed is stirred continuously 15min, maintains 55 ~ 58 DEG C of condition insulation 30min standby the most again;
(2) by NPE, high-carbon fatty alcohol polyoxyethylene ether, positive silicic acid propyl ester, polydimethylsiloxane and poly- Ammonium acrylate is common with the liquid mixing of step (1) gained, and heating holding temperature of liquid is 38 ~ 42 DEG C, with 1300 ~ 1500 turns/ Minute rotating speed be stirred continuously 20min, then naturally cool to room temperature standby;
(3) Bamboo vinegar solution, carbendazim and boric acid are joined jointly in the liquid of step (2) gained, with 400 ~ 500 revs/min Rotating speed i.e. obtains A liquid after being stirred continuously 10min, then homogenizing 1h.
A kind of damaged face of wicker products the most according to claim 1 protective agent, it is characterised in that the preparation of described B liquid Method comprises the steps:
(1) by calcium pyrophosphate, daucic acid, paraffin oil, dodecyl sodium sulfate, xylitol, carbamide, sodium polyacrylate, stearic acid Magnesium, Ammonium persulfate. and nanofiber are added to the water jointly, and keeping solution temperature is 55 ~ 60 DEG C, is stirred continuously to the most standby;
(2) propandiol butyl ether, dibutyl tin laurate, nano-calcium carbonate, nano titanium oxide and butyl acetate are added jointly Entering in water-based polyurethane adhesive, keeping solution temperature is 37 ~ 42 DEG C, stirs with the rotating speed of 1000 ~ 1200 revs/min Standby;
(3) solution of step (2) gained is mixed in the solution of step (1) gained with the speed of 8 ~ 12ml/s, applies simultaneously Frequency is that the ultrasound wave of 42KHz carries out aid in treatment, naturally cools to room temperature and i.e. obtain B liquid after puddling uniformly.
5. the protectant using method in the damaged face of the wicker products as described in claim 1 ~ 4, it is characterised in that include Following steps:
(1) first it is rinsed roguing with clear water position pending to wicker products;
(2) position after rinsing step (1) is dried, and drying to its surface moisture is 18 ~ 23%;
(3) A liquid is sprayed at step (2) dry after wicker products on, then treat its naturally dry to surface tack-free;
(4) being uniformly sprayed at by B liquid on the wicker products after step (3) processes, putting it into temperature after completing is 40 ~ 42 DEG C Under the conditions of dried 3 ~ 4min, put it in the freezer that temperature is 2 ~ 4 DEG C freezing 4 ~ 5min the most again, finally take out nature Recover to room temperature.
CN201610551282.3A 2016-07-13 2016-07-13 A kind of wicker products damaged face protective agent Pending CN106118462A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4280944A (en) * 1979-05-17 1981-07-28 Mitsui-Nisso Corporation Thermosetting polyurethane resin and coating agent thereof prepared from at least two polyoxyalkylene polyols, blocking agent, chain-elongating agent, cross-linking agent and a mixture of diisocyanates
CN101457118A (en) * 2007-12-12 2009-06-17 比亚迪股份有限公司 Nano paint and preparation method thereof
CN104497663A (en) * 2014-12-30 2015-04-08 青岛佳尚创意文化有限公司 Antibacterial latex paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4280944A (en) * 1979-05-17 1981-07-28 Mitsui-Nisso Corporation Thermosetting polyurethane resin and coating agent thereof prepared from at least two polyoxyalkylene polyols, blocking agent, chain-elongating agent, cross-linking agent and a mixture of diisocyanates
CN101457118A (en) * 2007-12-12 2009-06-17 比亚迪股份有限公司 Nano paint and preparation method thereof
CN104497663A (en) * 2014-12-30 2015-04-08 青岛佳尚创意文化有限公司 Antibacterial latex paint

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Application publication date: 20161116