CN105331229A - Coating for cement fence and preparation method thereof - Google Patents

Coating for cement fence and preparation method thereof Download PDF

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CN105331229A
CN105331229A CN201410389879.3A CN201410389879A CN105331229A CN 105331229 A CN105331229 A CN 105331229A CN 201410389879 A CN201410389879 A CN 201410389879A CN 105331229 A CN105331229 A CN 105331229A
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agent
coating
weight part
color stuffing
parts
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邢军
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Abstract

The invention provides a coating for a cement fence and a preparation method thereof to overcome the problems of poor ultraviolet resistance and proneness to ageing of conventional cement fence coatings, belonging to the technical field of constructional materials. The coating comprises the following raw materials by weight: 35 to 50 parts of acrylic acid emulsion, 1 to 5 parts of a film forming auxiliary agent, 1 to 2 parts of a dispersing and wetting agent, 20 to 40 parts of a pigment filling material, 10 to 20 parts of deionized water, 3 to 5 parts of an aging-resistant auxiliary agent, 1 to 2 parts of a leveling agent and 1 to 2 parts of a thickening agent. The preparation method comprises the following steps: mixing the acrylic acid emulsion, the film forming auxiliary agent and the thickening agent so as to obtain a base material; preparing color paste from deionized water, the dispersing and wetting agent and the pigment filling material; mixing the base material with the color paste; adding the aging-resistant auxiliary agent and the leveling agent; and carrying out filtering so as to obtain the coating. Under synergism of the acrylic acid emulsion, the pigment filling material and the aging-resistant auxiliary agent, ultraviolet resistance and aging resistance of the coating are substantially improved, brightness of the surface of the cement fence is improved, and the integral aesthetic properties of a building are improved.

Description

A kind of enclosure coating and preparation method thereof
Technical field
The present invention relates to the technical field of material of construction, refer to a kind of enclosure coating and preparation method thereof especially.
Background technology
The many merits such as cement works thing is low with its cost, fire resistance good, it is simple to make and practical, suddenly become the primary product of current building trade, greatly meet modern people and produce and growing demand of living.From cement wall surface, cement post to enclosure etc., cement building product miscellaneous constantly emerges in large numbers in face of us.Enclosure is also known as cement artistic fence, Cement guard bar, cement railing, and along with the continuous propelling of new rural village and new town construction process, enclosure makes our production and the change of living environment generation essence with the speed of making rapid progress.Various places government in succession put into effect demolish walls reveal the green, the environmental reconstruction policies such as scape of ventilating, prohibite and build solid enclosure wall by laying bricks or stones, traditional enclosure wall must replace by enclosure.
Existing enclosure is generally fitted up at its surface spraying coating for wall surface, thus reach handsome in appearance, the lines flow smoothly and coloury object.Because enclosure is subject to solar radiation for a long time, particularly in summer, temperature obviously raises; In addition, Sometimes When It Rains, often endure again the impact of rainwater to the fullest extent; Existing coating for wall surface anti-uv-ray is poor, not ageing-resistant, makes existing enclosure occur the phenomenon such as decortication after exposing to the weather, and has a strong impact on its result of use and attractive in appearance.
Summary of the invention
The present invention proposes a kind of enclosure coating and preparation method thereof, solves enclosure coating anti-uv-ray difference and easily aging problem in prior art.
A kind of enclosure coating of the present invention, its technical scheme is achieved in that the raw material comprising following weight part: ACRYLIC EMULSION 35-50 part, film coalescence aid 1-5 part, dispersion agent and wetting agent 1-2 part, color stuffing 20-40 part, deionized water 10-20 part, anti-aging auxiliary agent 3-5 part, flow agent 1-2 part, thickening material 1-2 part.
The present invention forms base-material with ACRYLIC EMULSION under the effect of film coalescence aid and thickening material, by color stuffing, it is carried out to the adjustment of color and granularity, and make color stuffing, oil phase and aqueous phase fully disperse and mix under the effect of dispersion agent and wetting agent, deionized water and flow agent, thus form homogeneous coating.Under the synergy of ACRYLIC EMULSION and anti-aging auxiliary agent, make coating have excellent outdoor weatherability, after a procedure, ageing-resistant performance and the anti-ultraviolet property on its surface increase substantially this coating, coatingsurface brightness increases, and improves the overall appearance performance of cement works thing.
As the preferred embodiment of one, the raw material that described ACRYLIC EMULSION comprises following weight percent is made: vinylformic acid 40-45%, butyl acrylate 40-45%, deionized water 5-10%, emulsifying agent 3-5%, acrylamide 1-3%, organosilane monomer 1-3%.ACRYLIC EMULSION of the present invention is on the basis of traditional pure acrylic latex, add acrylamide and organosilane monomer, the weather resistance of ACRYLIC EMULSION is further enhanced, and improve its waterproof, contaminated resistance, the glossiness of coating is improved, protect look gloss retention strong, can the growth of mould fungus inhibition.
As the preferred embodiment of one, described anti-aging auxiliary agent is substituted acrylate.Substituted acrylate antiaging agent is cheap and easy to get, and this antiaging agent is also acrylic acid derivative, and it can act synergistically better with ACRYLIC EMULSION, fully increases the ageing resistance of coating.
As the preferred embodiment of one, in described color stuffing, pigment is inorganic oxide iron pigment, and described inorganic oxide iron pigment is the one in red iron oxide, iron oxide yellow and iron oxide black.Inorganic oxide iron pigment has very high chemical stability, and fast light alkali resistance is good, energy strong absorption ultraviolet, and effectively protective cover base-material and capped article are from ultraviolet destruction; And its solvent resistant, water-fast, chemical resistance good.
As the preferred embodiment of one, in described color stuffing, filler is the one in coarse whiting, talcum powder or kaolin.The particle shape of different fillers is not identical, and the talcum powder with platy particle can improve the globality of film, thus also favourable to water tolerance, alkali resistance etc.; There is the coarse whiting of round particle, when thickness collocation uses, its filling effect can be given full play to; Kaolin also has the effect to film delustring.
As the preferred embodiment of one, described color stuffing granularity is less than 50 μm, and the weight ratio of described pigment and described filler is 1:3 ~ 1:2.The granularity of color stuffing is thinner, its with base-material and anti-aging auxiliary agent mix easier, the dispersiveness of gained coating is better, and more evenly, meanwhile, the color of coating is more stable.Filler is mainly used in adjusting the gloss of coating, quality, suspension and viscosity, can also reduce the cost of coating; Pigment is the important component part of coating, is the coloured subparticle shape material of a class, gives coating with color, and plays the effect of decoration and protection.
As the preferred embodiment of one, described film coalescence aid is Lauryl Alcohol ester, and described dispersion agent and wetting agent are anion surfactant, and described flow agent is association type flow agent, and described thickening material is alkaline swelling type thickening material.Film coalescence aid is alkoxide, mainly Lauryl Alcohol ester, Lauryl Alcohol ester has the advantages such as strong adaptability, consumption is few, density good, stability is strong, it is incompatible with water, thus the original gloss of coating can be kept, Lauryl Alcohol ester also can give the performances such as the better weathering resistance of coating, scrub resistance and color developing.Adopt anion surfactant as dispersion agent and wetting agent, the surface energy of effective reduction color stuffing, improve its surfactivity, can promote dispersion, soak and prevent cohesion, anion surfactant is attracted to the surface of color stuffing particle, by electrostatic repulsion or space bit resistance, prevent them from combining, reduce production energy consumption, shorten the production time, improve production efficiency.Flow agent can impel coating in drying and forming-film process, form smooth, smooth, a uniform film, and association type flow agent can provide splendid mobility, levelling property, stable viscosity, also has good color developing, brushing good hand touch.Alkali swollen thickener has good water retention property, and consistency is good, stable viscosity, and toning property is good, and glossiness is high, can significantly improve the viscosity under system low shearing speed.
As the preferred embodiment of one, also comprise the raw material of following weight part: defoamer 0.1-0.5 part, antimildew disinfectant 0.1-0.5 part.Defoamer and antimildew disinfectant can also be added in coating of the present invention, defoamer can remove the unwanted bubbles produced in coating process, improves the performance of coating, the defoamers such as this silicon ether Copolymer, organo-siloxane, polyethers, there is antifoaming speed faster, but the feature that the bubble time is longer.Antimildew disinfectant for kill or mould fungus inhibition, bacterium growth, can prevent coating and film from going mouldy, effectively extend the quality guaranteed period of coating.
The preparation method of a kind of enclosure coating of the present invention, its technical scheme is achieved in that and comprises the following steps: 1) get ACRYLIC EMULSION, film coalescence aid and thickening material, be uniformly mixed, and forms base-material, for subsequent use; 2) get pigment and filler mixing, grinding, screening after, formed color stuffing, for subsequent use; 3) remove ionized water, dispersion agent and wetting agent, be uniformly mixed, form the aqueous solution, and by step 2) gained color stuffing adds in the aqueous solution, forms mill base; 4) by step 1) gained base-material and step 3) gained mill base mixes, and adding anti-aging auxiliary agent and flow agent in it, filtering, obtaining product.
The present invention forms base-material by ACRYLIC EMULSION, film coalescence aid and thickening material, and make color stuffing form mill base under the effect of dispersion agent and wetting agent, base-material and mill base mixing, and under the effect of antiaging agent and flow agent, form the coating with uvioresistant and ageing-resistant performance, this coating manufacture craft is simple, raw material is cheap and easy to get, reaction conditions is gentle, environment friendly and pollution-free, is easy to realize industrialization.
As the preferred embodiment of one, in step 3) in the described aqueous solution, also add defoamer 0.1-0.5 weight part, antimildew disinfectant 0.1-0.5 weight part.Defoamer can also be added, in order to eliminate the deleterious bubbles produced in coating process in mill base; Certainly, in base-material, also appropriate defoamer can be added.Also add antimildew disinfectant in mill base to be used for preventing coating and film from going mouldy, effectively extend the quality guaranteed period of coating.
Beneficial effect of the present invention: the present invention to be polymerized ACRYLIC EMULSION by vinylformic acid, butyl acrylate, acrylamide and organosilane monomer, with this ACRYLIC EMULSION for base-material, under the effect of antiaging agent, thickening material and film coalescence aid etc., form a kind of new enclosure tailor-(made) coating; The preparation method of this coating is simple, mild condition, cost is low, is convenient to realize industrialization, this coating has excellent uvioresistant and ageing-resistant performance, its glossiness is high, and water resistant, high temperature resistant performance is strong, substantially increases the brightness on enclosure surface, add the overall aesthetics of cement works thing, the effect of artificial granite, artificial white marble, antique copper etc. can be reached, improve the decoration grade of enclosure, the market competitiveness of enclosure is strengthened greatly.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is process flow diagram of the present invention.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
A kind of enclosure coating, comprises the raw material of following weight part: ACRYLIC EMULSION 35-50 part, film coalescence aid 1-5 part, dispersion agent and wetting agent 1-2 part, color stuffing 20-40 part, deionized water 10-20 part, anti-aging auxiliary agent 3-5 part, flow agent 1-2 part, thickening material 1-2 part.
Further, the raw material that described ACRYLIC EMULSION comprises following weight percent is made: vinylformic acid 40-45%, butyl acrylate 40-45%, deionized water 5-10%, emulsifying agent 3-5%, acrylamide 1-3%, organosilane monomer 1-3%.
Described anti-aging auxiliary agent is substituted acrylate.
In described color stuffing, pigment is inorganic oxide iron pigment, and described inorganic oxide iron pigment is the one in red iron oxide, iron oxide yellow and iron oxide black.
In described color stuffing, filler is the one in coarse whiting, talcum powder or kaolin.
Described color stuffing granularity is less than 50 μm, and the weight ratio of described pigment and described filler is 1:3 ~ 1:2.
Described film coalescence aid is Lauryl Alcohol ester, and described dispersion agent and wetting agent are anion surfactant, and described flow agent is association type flow agent, and described thickening material is alkaline swelling type thickening material.
Further, also comprise the raw material of following weight part: defoamer 0.1-0.5 part, antimildew disinfectant 0.1-0.5 part.
Accompanying drawings 1, a kind of preparation method of enclosure coating, comprises the following steps:
1) get ACRYLIC EMULSION, film coalescence aid and thickening material, be uniformly mixed, form base-material, for subsequent use;
2) get pigment and filler mixing, grinding, screening after, formed color stuffing, for subsequent use;
3) remove ionized water, dispersion agent and wetting agent, be uniformly mixed, form the aqueous solution, and by step 2) gained color stuffing adds in the aqueous solution, forms mill base;
4) by step 1) gained base-material and step 3) gained mill base mixes, and adds anti-aging auxiliary agent and flow agent within it, filter, obtain product.
Further, in step 3) in the described aqueous solution, also add defoamer 0.1-0.5 weight part, antimildew disinfectant 0.1-0.5 weight part.
Embodiment one
1) get ACRYLIC EMULSION 35 weight part, film coalescence aid 5 weight part and thickening material 2 weight part, be uniformly mixed, form base-material, for subsequent use; Wherein, thickening material is alkaline swelling type thickening material, and ACRYLIC EMULSION is polymerized by vinylformic acid 40wt%, butyl acrylate 45wt%, deionized water 6wt%, emulsifying agent 5wt%, acrylamide 2wt% and organosilane monomer 2wt%.
2) get color stuffing, wherein the weight ratio of pigment and filler is 1:2, and after mixing, grinding, screening, its particle of less than 50 μm, forms color stuffing, for subsequent use; Wherein, pigment is inorganic oxide iron pigment, and filler is kaolin.
3) remove ionized water 20 weight part, dispersion agent and wetting agent 2 weight part, defoamer 0.5 weight part, be uniformly mixed, form the aqueous solution, and by step 2) gained color stuffing 20 weight part adds in the aqueous solution, forms mill base; Wherein, dispersion agent and wetting agent are anion surfactant.
4) by step 1) gained base-material and step 3) gained mill base mixes, and adds anti-aging auxiliary agent 5 weight part and flow agent 1 weight part within it, filter, obtain product.
Gained enclosure coating is made up of the defoamer of the anti-aging auxiliary agent of the deionized water of the color stuffing of the ACRYLIC EMULSION of 35 weight parts, the film coalescence aid of 5 weight parts, the dispersion agent of 2 weight parts and wetting agent, 20 weight parts, 20 weight parts, 5 weight parts, the flow agent of 1 weight part, the thickening material of 2 weight parts and 0.5 weight part, it brushes convenient, coatingsurface brightness is high, has very high weathering resistance, alkali resistance, water tolerance, abrasion resistance and the sex change of resistance to coating temperature.
Embodiment two
1) get ACRYLIC EMULSION 50 weight part, film coalescence aid 3 weight part and thickening material 1 weight part, be uniformly mixed, form base-material, for subsequent use; Wherein, ACRYLIC EMULSION is polymerized by vinylformic acid 40wt%, butyl acrylate 40wt%, deionized water 10wt%, emulsifying agent 3.5wt%, acrylamide 3wt%, organosilane monomer 3wt% and ammonium persulphate 0.5wt%.
2) get color stuffing, after mixing, grinding, screening, form color stuffing, for subsequent use.
3) ionized water 10 weight part, dispersion agent and wetting agent 1 weight part, defoamer 0.3 weight part, anticorrosion and bactericidal agent 0.1 weight part is removed, be uniformly mixed, form the aqueous solution, and by step 2) gained color stuffing 30 weight part adds in the aqueous solution, forms mill base.
4) by step 1) gained base-material and step 3) gained mill base mixes, and adds anti-aging auxiliary agent 3 weight part and flow agent 2 weight part within it, and flow agent is association type flow agent, filters, obtains product.
Gained enclosure coating is made up of the anticorrosion and bactericidal agent of the flow agent of the anti-aging auxiliary agent of the deionized water of the color stuffing of the ACRYLIC EMULSION of 50 weight parts, the film coalescence aid of 3 weight parts, the dispersion agent of 1 weight part and wetting agent, 30 weight parts, 10 weight parts, 3 weight parts, 2 weight parts, the thickening material of 1 weight part, the defoamer of 0.3 weight part and 0.1 weight part, it brushes convenient, coatingsurface brightness is high, has very high weathering resistance, alkali resistance, water tolerance, abrasion resistance and the sex change of resistance to coating temperature.
Embodiment three
1) get ACRYLIC EMULSION 40 weight part, film coalescence aid 1 weight part and thickening material 1.5 weight part, be uniformly mixed, form base-material, for subsequent use; Film coalescence aid is phenolic ester class, can be Lauryl Alcohol ester.
2) get color stuffing, wherein the weight ratio of pigment and filler is 1:3, and after mixing, grinding, screening, its particle of less than 40 μm, forms color stuffing, for subsequent use; Wherein, pigment is the iron oxide black in inorganic oxide iron pigment, and filler is coarse whiting.
3) remove ionized water 15 weight part, dispersion agent and wetting agent 1.5 weight part, be uniformly mixed, form the aqueous solution, and by step 2) gained color stuffing 40 weight part adds in the aqueous solution, forms mill base; Wherein, dispersion agent and wetting agent are anion surfactant.
4) by step 1) gained base-material and step 3) gained mill base mixes, and adds anti-aging auxiliary agent 4 weight part and flow agent 1.5 weight part within it, filter, obtain product.
Gained enclosure coating is made up of the thickening material of the deionized water of the color stuffing of the ACRYLIC EMULSION of 40 weight parts, the film coalescence aid of 1 weight part, the dispersion agent of 1.5 weight parts and wetting agent, 40 weight parts, 15 weight parts, the anti-aging auxiliary agent of 4 weight parts, the flow agent of 1.5 weight parts and 1.5 weight parts, it brushes convenient, coatingsurface brightness is high, has very high weathering resistance, alkali resistance, water tolerance, abrasion resistance and the sex change of resistance to coating temperature.
Embodiment four
1) get ACRYLIC EMULSION 45 weight part, film coalescence aid 4 weight part and thickening material 1 weight part, be uniformly mixed, form base-material, for subsequent use; Wherein, ACRYLIC EMULSION is by vinylformic acid 45wt%, butyl acrylate 42wt%, deionized water 5wt%, methacrylic acid 2%, emulsifying agent 3wt%, and acrylamide 1wt%, organosilane monomer 1wt%, buffer reagent 0.5wt% and ammonium persulphate 0.5wt% are polymerized.
2) get color stuffing, wherein the weight ratio of pigment and filler is 2:5, and after mixing, grinding, screening, its particle of less than 20 μm, forms color stuffing, for subsequent use; Wherein, pigment is the iron oxide yellow in inorganic oxide iron pigment, and filler is talcum powder.
3) ionized water 20 weight part, dispersion agent and wetting agent 2 weight part, defoamer 0.1 weight part, anticorrosion and bactericidal agent 0.5 weight part is removed, be uniformly mixed, form the aqueous solution, and by step 2) gained color stuffing 30 weight part adds in the aqueous solution, forms mill base; Wherein, dispersion agent and wetting agent are anion surfactant.
4) by step 1) gained base-material and step 3) gained mill base mixes, and adds anti-aging auxiliary agent 3 weight part and flow agent 2 weight part within it, and antiaging agent is substituted acrylate, filters, obtains product.
Gained enclosure coating is made up of the anticorrosion and bactericidal agent of the flow agent of the anti-aging auxiliary agent of the deionized water of the color stuffing of the ACRYLIC EMULSION of 45 weight parts, the film coalescence aid of 4 weight parts, the dispersion agent of 2 weight parts and wetting agent, 30 weight parts, 20 weight parts, 3 weight parts, 2 weight parts, the thickening material of 1 weight part, the defoamer of 0.1 weight part and 0.5 weight part, it brushes convenient, coatingsurface brightness is high, has very high weathering resistance, alkali resistance, water tolerance, abrasion resistance and the sex change of resistance to coating temperature.
Embodiment five
1) get ACRYLIC EMULSION 45 weight part, film coalescence aid 2 weight part and thickening material 2 weight part, be uniformly mixed, form base-material, for subsequent use; Wherein, ACRYLIC EMULSION is polymerized by vinylformic acid 42wt%, butyl acrylate 43wt%, deionized water 7wt%, emulsifying agent 4wt%, acrylamide 3wt% and organosilane monomer 1wt%.
2) get color stuffing, wherein the weight ratio of pigment and filler is 1:2, and after mixing, grinding, screening, its particle of less than 10 μm, forms color stuffing, for subsequent use; Wherein, pigment is the red iron oxide in inorganic oxide iron pigment, and filler is kaolin.
3) ionized water 15 weight part, dispersion agent and wetting agent 2 weight part, defoamer 0.2 weight part, anticorrosion and bactericidal agent 0.3 weight part is removed, be uniformly mixed, form the aqueous solution, and by step 2) gained color stuffing 20 weight part adds in the aqueous solution, forms mill base.
4) by step 1) gained base-material and step 3) gained mill base mixes, and adds anti-aging auxiliary agent 4 weight part and flow agent 2 weight part within it, filter, obtain product.
Gained enclosure coating is made up of the anticorrosion and bactericidal agent of the flow agent of the anti-aging auxiliary agent of the deionized water of the color stuffing of the ACRYLIC EMULSION of 45 weight parts, the film coalescence aid of 2 weight parts, the dispersion agent of 2 weight parts and wetting agent, 20 weight parts, 15 weight parts, 4 weight parts, 2 weight parts, the thickening material of 2 weight parts, the defoamer of 0.2 weight part and 0.3 weight part, it brushes convenient, coatingsurface brightness is high, has very high weathering resistance, alkali resistance, water tolerance, abrasion resistance and the sex change of resistance to coating temperature.
The five kinds of coating embodiment of the present invention one to embodiment five prepared and certain commercially available exterior coating carry out performance test according to the national standard of " GB/T9755-2001 exterior wall coating material of synthetic resin emulsion ", in addition, also it is carried out glossiness test on glossiness tester; Table 1 lists the water tolerance of gained coating of the present invention and certain commercial coating, alkali resistance, abrasion resistance, temperature-change resistance and glossiness five kinds of the performance test results.
Table 1 coating property test result contrast table
As can be seen from Table 1, the glossiness of enclosure coating of the present invention reaches as high as 85 degree, and this cannot reach in commercial coating; It is all without exception that coating of the present invention floods 96h in water, and namely commercial coating occurs metachromatism after immersion 24h; In strong alkali solution, coating dipping 48h of the present invention is all without exception, and namely commercial coating occurs obvious metachromatism less than 12h in strong alkali solution; Abrasion resistance test-results shows, the washability ability of coating of the present invention can reach 6000 times, and the washability ability of commercial coating only has 2000 times; The temperature-change resistance test result of coating of the present invention shows, it forwards refrigerator to from baking box and to circulate 5 times so back and forth and above all without any exception, and commercial coating is circulated after 3 times back and forth, and its performance then significantly declines.
Therefore, coating of the present invention meets the national standard of GB/T9755-2001 exterior wall coating material of synthetic resin emulsion far away, and, its water tolerance, alkali resistance, abrasion resistance and temperature-change resistance all have raising in various degree, in addition, its glossiness have also been obtained and significantly improves, possess excellent ultraviolet-resistent property and ageing-resistant performance, substantially increase the brightness on enclosure surface, add the overall aesthetics of cement works thing, artificial granite can be reached, artificial white marble, the effect of antique copper etc., improve the decoration grade of enclosure, the market competitiveness of enclosure is strengthened greatly.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (10)

1. an enclosure coating, is characterized in that, comprises the raw material of following weight part:
ACRYLIC EMULSION 35-50 part, film coalescence aid 1-5 part, dispersion agent and wetting agent 1-2 part, color stuffing 20-40 part, deionized water 10-20 part, anti-aging auxiliary agent 3-5 part, flow agent 1-2 part, thickening material 1-2 part.
2. enclosure coating according to claim 1, is characterized in that: the raw material that described ACRYLIC EMULSION comprises following weight percent is made:
Vinylformic acid 40-45%, butyl acrylate 40-45%, deionized water 5-10%, emulsifying agent 3-5%, acrylamide 1-3%, organosilane monomer 1-3%.
3. enclosure coating according to claim 2, is characterized in that: described anti-aging auxiliary agent is substituted acrylate.
4. enclosure coating according to claim 1, is characterized in that: in described color stuffing, and pigment is inorganic oxide iron pigment, and described inorganic oxide iron pigment is the one in red iron oxide, iron oxide yellow and iron oxide black.
5. enclosure coating according to claim 4, is characterized in that: in described color stuffing, filler is the one in coarse whiting, talcum powder or kaolin.
6. enclosure coating according to claim 5, is characterized in that: described color stuffing granularity is less than 50 μm, and the weight ratio of described pigment and described filler is 1:3 ~ 1:2.
7. enclosure coating according to claim 1, is characterized in that:
Described film coalescence aid is Lauryl Alcohol ester, and described dispersion agent and wetting agent are anion surfactant, and described flow agent is association type flow agent, and described thickening material is alkaline swelling type thickening material.
8. enclosure coating according to claim 7, is characterized in that, also comprises the raw material of following weight part: defoamer 0.1-0.5 part, antimildew disinfectant 0.1-0.5 part.
9. a preparation method for the enclosure coating according to claim 1-7 any one, is characterized in that, comprise the following steps:
1) get ACRYLIC EMULSION, film coalescence aid and thickening material, be uniformly mixed, form base-material, for subsequent use;
2) get pigment and filler mixing, grinding, screening after, formed color stuffing, for subsequent use;
3) remove ionized water, dispersion agent and wetting agent, be uniformly mixed, form the aqueous solution, and by step 2) gained color stuffing adds in the aqueous solution, forms mill base;
4) by step 1) gained base-material and step 3) gained mill base mixes, and adds anti-aging auxiliary agent and flow agent within it, filter, obtain product.
10. the preparation method of enclosure coating according to claim 9, is characterized in that: in step 3) in the described aqueous solution, also add defoamer 0.1-0.5 weight part, antimildew disinfectant 0.1-0.5 weight part.
CN201410389879.3A 2014-08-08 2014-08-08 Coating for cement fence and preparation method thereof Pending CN105331229A (en)

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CN111393921A (en) * 2020-04-01 2020-07-10 郑州熙虎科技有限公司 Special paint for antique building art antiquing
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CN103342782A (en) * 2013-07-02 2013-10-09 广东海顺新材料科技有限公司 Organosilicone modified acrylate emulsion, preparation method thereof and water-based artificial stone prepared from organosilicone modified acrylate emulsion

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CN106987185A (en) * 2017-04-01 2017-07-28 浙江绿果新材料有限公司 A kind of acrylic emulsion coatings
CN107099199A (en) * 2017-04-01 2017-08-29 浙江绿果新材料有限公司 A kind of cardanol polyoxyethylene ether coating
CN106987185B (en) * 2017-04-01 2020-05-01 浙江绿果新材料有限公司 Acrylic latex paint
CN111393921A (en) * 2020-04-01 2020-07-10 郑州熙虎科技有限公司 Special paint for antique building art antiquing
CN113899885A (en) * 2021-09-16 2022-01-07 中铁十五局集团有限公司 Laboratory detection method for shield slurry film-forming performance
CN113899885B (en) * 2021-09-16 2023-04-25 中铁十五局集团有限公司 Laboratory detection method for shield mud film forming performance

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