CN107099199A - A kind of cardanol polyoxyethylene ether coating - Google Patents
A kind of cardanol polyoxyethylene ether coating Download PDFInfo
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- CN107099199A CN107099199A CN201710214133.2A CN201710214133A CN107099199A CN 107099199 A CN107099199 A CN 107099199A CN 201710214133 A CN201710214133 A CN 201710214133A CN 107099199 A CN107099199 A CN 107099199A
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- polyoxyethylene ether
- cardanol polyoxyethylene
- levelling agent
- coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of cardanol polyoxyethylene ether coating, it is made up of the component of following parts by weight：45~70 parts of filming emulsion；2~10 parts of color stuffing；1~5 part of dispersant；2~8 parts of levelling agent；8~20 parts of cardanol polyoxyethylene ether；2~6 parts of defoamer；1~5 part of coalescents；20~30 parts of water.Abrasion resistance of the present invention is good, alkali resistance is good, strong covering power, can be washed with water and smear, and drying time of the invention is shorter, it is very easy to use, free formaldehyde content is relatively low simultaneously, meets environmental requirement, therefore combination property of the present invention is preferable, for a kind of high-performance environmentally-friendly emulsion paint, its scope of application is wider.
Description
Technical field
The invention belongs to chemical production technical field, and in particular to a kind of cardanol polyoxyethylene ether coating.
Background technology
Coating, in the entitled paint of Chinese tradition, so-called coating is to be coated in the body surface protected or decorated, and
The continuous film of firm attachment can be formed with coated article, is typically based on resin or oil or emulsion, to add or without face
Material, filler, add corresponding additive, the thick liquid being formulated with organic solvent or water.
Emulsion paint is water-dispersible paint, and it is that, using synthetic resin emulsion as base-material, filler is added after grinding distribution
The refined coating of various auxiliary agents.Emulsion paint possesses many merits different from traditional metope coating, is such as easy to brush, does
It is dry it is rapid, paint film is water-fast, scrub resistance is good etc..In China, people are traditionally base-material synthetic resin emulsion, are scattered using water
Medium, adds pigment, filler (also known as extender pigment) and auxiliary agent, the coating being made through certain technical process.
With the progress of science and technology, the raising of human living standard, requirement of the people to indoor environment, air quality is got over
Come higher；Modern industry proposes more stringent requirement to terrace simultaneously, and such as food, medicine industrial requirements terrace does not rise
Ash, no unwanted volatile is clean dustless；Mechanical industry requires resistance to strong mechanical shock, wear-resistant, and fork truck etc. can be subjected to for a long time
The roll off of vehicle, is also easily repaired even if local damage；The industrial plant such as lathe, instrument and meter ground is subjected to various oils and invaded
Lose seepage, it is difficult to thoroughly remove, it is desirable to which terrace oil resistivity is good, chemical industry then requires that terrace is resistant to the corruption of various chemical mediators
Erosion；Therefore with the very fast development of coating technology, in order to adapt to different occasions, environment, coating needs to meet corresponding characteristic.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of cardanol polyoxyethylene ether coating, combination property is strong, is applicable
Property is extensive.
In order to solve the above-mentioned technical problem, the technical scheme is that：A kind of cardanol polyoxyethylene ether coating, by with
The component composition of lower parts by weight：
Preferably, being made up of the component of following parts by weight：
Preferably, the color stuffing be titanium dioxide, kaolin, diatomite, mica powder and cuprous oxide at least
It is a kind of.
Preferably, the dispersant is triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose spread out
At least one of biological, polyacrylamide and fatty acid polyethylene glycol ester.
Preferably, described levelling agent is organosilicon levelling agent, esters of acrylic acid levelling agent, fluorine richness organosilicon levelling
At least one of agent, wax modified organic silicon levelling agent.
Preferably, the levelling agent is made up of organosilicon levelling agent and esters of acrylic acid levelling agent, the organosilicon
The weight ratio of levelling agent and esters of acrylic acid levelling agent is 1~3:2~3.
Preferably, the defoamer is tributyl phosphate, diisopropanolamine (DIPA) polyoxyethylene polyoxypropylene ether and polyoxy
At least one of propylene polyoxyethylene glycerol ether.
Preferably, the coalescents are propylene glycol methyl ether acetate, phenmethylol, Lauryl Alcohol ester and hexylene glycol fourth
At least one of ether acetate.
Preferably, the filming emulsion is at least one of styrene-acrylic emulsion and acrylic emulsion.
Preferably, the filming emulsion is made up of styrene-acrylic emulsion and acrylic emulsion, the styrene-acrylic emulsion and acrylic acid
The weight ratio of emulsion is 1~3:3~5.
Compared with prior art, beneficial effects of the present invention are embodied in：
(1) abrasion resistance of the present invention is good, and alkali resistance is good, strong covering power, can be washed with water and smear, and drying time of the invention compared with
It is short, it is very easy to use, while free formaldehyde content is relatively low, meet environmental requirement, therefore combination property of the present invention is preferably,
For a kind of high-performance environmentally-friendly emulsion paint, its scope of application is wider.
(2) cardanol polyoxyethylene ether can replace NPE in the present invention, and OPEO is secondary
The petroleum chemicals such as the phenols APEO such as OPEO, because petroleum chemicals biological degradability is poor, the present invention can
To improve biological degradability, the pollution to environment is reduced.
Embodiment
The embodiment to the present invention is described further below.Herein it should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but does not constitute limitation of the invention.In addition, invention described below
As long as involved technical characteristic does not constitute conflict and can be just mutually combined each other in each embodiment.
Embodiment 1
A kind of cardanol polyoxyethylene ether coating, is made up of the component of following parts by weight：45 parts of styrene-acrylic emulsion；Titanium dioxide
5 parts；5 parts of kaolin；1 part of lauryl sodium sulfate；8 parts of esters of acrylic acid levelling agent；8 parts of cardanol polyoxyethylene ether；Two is different
6 parts of Propanolamine polyoxyethylene polyoxypropylene ether；1 part of propylene glycol methyl ether acetate；20 parts of water.
The preparation method of above-mentioned cardanol polyoxyethylene ether coating, comprises the following steps：
Various materials are weighed according to formula, in the case of stirring, are added each material in water, high-speed stirred is disperseed,
Obtain the cardanol polyoxyethylene ether coating.
Embodiment 2
A kind of cardanol polyoxyethylene ether coating, is made up of the component of following parts by weight：35 parts of styrene-acrylic emulsion；Acrylic acid
35 parts of emulsion；1 part of diatomite；0.5 part of mica powder；0.5 part of cuprous oxide；3 parts of triethyl group hexyl phosphoric acid；2 parts of methyl anyl alcohol；Third
1 part of olefin(e) acid esters levelling agent；1 part of fluorine richness organosilicon levelling agent；20 parts of cardanol polyoxyethylene ether；Diisopropanolamine (DIPA) polyoxy third
1 part of alkene APEO；1 part of polyoxyethylene polyoxypropylene glycerin ether；3 parts of phenmethylol；2 parts of Lauryl Alcohol ester；30 parts of water.
The preparation method of above-mentioned cardanol polyoxyethylene ether coating, comprises the following steps：
Various materials are weighed according to formula, in the case of stirring, are added each material in water, high-speed stirred is disperseed,
Obtain the cardanol polyoxyethylene ether coating.
Embodiment 3
A kind of cardanol polyoxyethylene ether coating, is made up of the component of following parts by weight：65 parts of acrylic emulsion；Diatom
3 parts of soil；3 parts of cuprous oxide；1 part of polyacrylamide；2 parts of fatty acid polyethylene glycol ester；3 parts of organosilicon levelling agent；Acrylate
3 parts of class levelling agent；16 parts of cardanol polyoxyethylene ether；4 parts of polyoxyethylene polyoxypropylene glycerin ether；1 part of phenmethylol；Lauryl Alcohol
3 parts of ester；25 parts of water
The preparation method of above-mentioned cardanol polyoxyethylene ether coating, comprises the following steps：
Various materials are weighed according to formula, in the case of stirring, are added each material in water, high-speed stirred is disperseed,
Obtain the cardanol polyoxyethylene ether coating.
Embodiment 4
A kind of cardanol polyoxyethylene ether coating, is made up of the component of following parts by weight：65 parts of styrene-acrylic emulsion；Diatomite
3 parts；3 parts of cuprous oxide；1 part of polyacrylamide；2 parts of fatty acid polyethylene glycol ester；3 parts of organosilicon levelling agent；Esters of acrylic acid
3 parts of levelling agent；16 parts of cardanol polyoxyethylene ether；4 parts of polyoxyethylene polyoxypropylene glycerin ether；1 part of phenmethylol；Lauryl Alcohol ester
3 parts；30 parts of water.
The preparation method of above-mentioned cardanol polyoxyethylene ether coating, comprises the following steps：
Various materials are weighed according to formula, in the case of stirring, are added each material in water, high-speed stirred is disperseed,
Obtain the cardanol polyoxyethylene ether coating.
Embodiment 5
A kind of cardanol polyoxyethylene ether coating, is made up of the component of following parts by weight：30 parts of styrene-acrylic emulsion；Acrylic acid
35 parts of emulsion；3 parts of diatomite；3 parts of cuprous oxide；1 part of polyacrylamide；2 parts of fatty acid polyethylene glycol ester；Organosilicon levelling agent
3 parts；3 parts of esters of acrylic acid levelling agent；16 parts of cardanol polyoxyethylene ether；4 parts of polyoxyethylene polyoxypropylene glycerin ether；Phenmethylol
1 part；3 parts of Lauryl Alcohol ester；25 parts of water.
The preparation method of above-mentioned cardanol polyoxyethylene ether coating, comprises the following steps：
Various materials are weighed according to formula, in the case of stirring, are added each material in water, high-speed stirred is disperseed,
Obtain the cardanol polyoxyethylene ether coating.
Comparative example 1
A kind of cardanol polyoxyethylene ether coating, is made up of the component of following parts by weight：30 parts of styrene-acrylic emulsion；Acrylic acid
35 parts of emulsion；3 parts of diatomite；3 parts of cuprous oxide；1 part of polyacrylamide；2 parts of fatty acid polyethylene glycol ester；Organosilicon levelling agent
3 parts；3 parts of esters of acrylic acid levelling agent；4 parts of polyoxyethylene polyoxypropylene glycerin ether；1 part of phenmethylol；3 parts of Lauryl Alcohol ester；Water
25 parts.
The preparation method of above-mentioned cardanol polyoxyethylene ether coating, comprises the following steps：
Various materials are weighed according to formula, in the case of stirring, are added each material in water, high-speed stirred is disperseed,
Obtain the cardanol polyoxyethylene ether coating.
Comparative example 2
A kind of cardanol polyoxyethylene ether coating, is made up of the component of following parts by weight：30 parts of styrene-acrylic emulsion；Acrylic acid
35 parts of emulsion；3 parts of diatomite；3 parts of cuprous oxide；1 part of polyacrylamide；2 parts of fatty acid polyethylene glycol ester；Polyoxypropylene polyoxy
4 parts of Ethylene Glycol ether；1 part of phenmethylol；3 parts of Lauryl Alcohol ester；25 parts of water.
The preparation method of above-mentioned cardanol polyoxyethylene ether coating, comprises the following steps：
Various materials are weighed according to formula, in the case of stirring, are added each material in water, high-speed stirred is disperseed,
Obtain the cardanol polyoxyethylene ether coating.
The cardanol polyoxyethylene ether coating that embodiment 1~5 and comparative example 1~2 are prepared carries out properties
The measure of index, the specific project that determines is referring to table 1, and testing result is shown in Table 2.
Table 1
Table 2
Embodiments of the present invention are explained in detail above, but the invention is not restricted to described embodiment.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out many
Change, modification, replacement and modification are planted, are still fallen within protection scope of the present invention.
Claims (10)
1. a kind of cardanol polyoxyethylene ether coating, it is characterised in that be made up of the component of following parts by weight：
2. cardanol polyoxyethylene ether coating as claimed in claim 1, it is characterised in that by the component group of following parts by weight
Into：
3. cardanol polyoxyethylene ether coating as claimed in claim 1 or 2, it is characterised in that the color stuffing be titanium dioxide,
At least one of kaolin, diatomite, mica powder and cuprous oxide.
4. cardanol polyoxyethylene ether coating as claimed in claim 1 or 2, it is characterised in that the dispersant is triethyl group
Hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose derivative, polyacrylamide and fatty acid polyethylene glycol ester
At least one of.
5. cardanol polyoxyethylene ether coating as claimed in claim 1 or 2, it is characterised in that described levelling agent is organic
At least one of silicon levelling agent, esters of acrylic acid levelling agent, fluorine richness organosilicon levelling agent, wax modified organic silicon levelling agent.
6. cardanol polyoxyethylene ether coating as claimed in claim 5, it is characterised in that the levelling agent is by organosilicon levelling
The weight ratio of agent and esters of acrylic acid levelling agent composition, the organosilicon levelling agent and esters of acrylic acid levelling agent is 1~3:2
~3.
7. cardanol polyoxyethylene ether coating as claimed in claim 1 or 2, it is characterised in that the defoamer is tricresyl phosphate
At least one of butyl ester, diisopropanolamine (DIPA) polyoxyethylene polyoxypropylene ether and polyoxyethylene polyoxypropylene glycerin ether.
8. cardanol polyoxyethylene ether coating as claimed in claim 1 or 2, it is characterised in that the coalescents are the third two
At least one of alcohol methyl ether acetate, phenmethylol, Lauryl Alcohol ester and hexylene glycol monobutyl ether acetate.
9. cardanol polyoxyethylene ether coating as claimed in claim 1 or 2, it is characterised in that the filming emulsion is phenylpropyl alcohol
At least one of emulsion and acrylic emulsion.
10. cardanol polyoxyethylene ether coating as claimed in claim 9, it is characterised in that the filming emulsion is by phenylpropyl alcohol breast
Liquid and acrylic emulsion composition, the weight ratio of the styrene-acrylic emulsion and acrylic emulsion is 1~3:3~5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710214133.2A CN107099199A (en) | 2017-04-01 | 2017-04-01 | A kind of cardanol polyoxyethylene ether coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710214133.2A CN107099199A (en) | 2017-04-01 | 2017-04-01 | A kind of cardanol polyoxyethylene ether coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107099199A true CN107099199A (en) | 2017-08-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710214133.2A Pending CN107099199A (en) | 2017-04-01 | 2017-04-01 | A kind of cardanol polyoxyethylene ether coating |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044628A (en) * | 2012-12-25 | 2013-04-17 | 中盈长江国际新能源投资有限公司 | Preparation method of biomass-based polymer emulsion |
| WO2015090444A1 (en) * | 2013-12-20 | 2015-06-25 | Basf Coatings Gmbh | Formulations containing pigment and filler |
| CN105013391A (en) * | 2015-08-05 | 2015-11-04 | 吴俊宏 | Preparation method of surface active agent |
| CN105331229A (en) * | 2014-08-08 | 2016-02-17 | 邢军 | Coating for cement fence and preparation method thereof |
-
2017
- 2017-04-01 CN CN201710214133.2A patent/CN107099199A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044628A (en) * | 2012-12-25 | 2013-04-17 | 中盈长江国际新能源投资有限公司 | Preparation method of biomass-based polymer emulsion |
| WO2015090444A1 (en) * | 2013-12-20 | 2015-06-25 | Basf Coatings Gmbh | Formulations containing pigment and filler |
| CN105331229A (en) * | 2014-08-08 | 2016-02-17 | 邢军 | Coating for cement fence and preparation method thereof |
| CN105013391A (en) * | 2015-08-05 | 2015-11-04 | 吴俊宏 | Preparation method of surface active agent |
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Application publication date: 20170829 |
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