CN103756562B - A kind of fluorine-containing organic silicon stone anti-fouling agent and preparation method thereof - Google Patents
A kind of fluorine-containing organic silicon stone anti-fouling agent and preparation method thereof Download PDFInfo
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- CN103756562B CN103756562B CN201410031729.5A CN201410031729A CN103756562B CN 103756562 B CN103756562 B CN 103756562B CN 201410031729 A CN201410031729 A CN 201410031729A CN 103756562 B CN103756562 B CN 103756562B
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Abstract
The invention discloses a kind of fluorine-containing organic silicon stone anti-fouling agent and preparation method thereof, its anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 90 130 weight portion, fluorine silicon resin 20 35 weight portion, fluorosilicon oil 10 30 weight portion, dispersion wetting agent 5 10 weight portion, defoamer 3 10 weight portion, preservative 15 weight portion, silane coupler 15 weight portion, coalescents 10 25 weight portion, color stuffing 15 weight portion and thickening agent 27 weight portion.The invention has the beneficial effects as follows: compared with conventional antifouling agents, the anti-fouling agent of the present invention has the advantage of Water-proof and oil-proof and good penetrability, improves the resistance to soiling of stone material, and makes simple, directly uses without dilution, easy to use.
Description
Technical field
The present invention relates to a kind of anti-fouling agent, particularly to a kind of fluorine-containing organic silicon stone anti-fouling agent and preparation method thereof.
Background technology
Stone material has beautiful attractive in appearance, the advantage such as firm and durable, material are easy to get of color as a kind of building and ornament materials.Therefore, carve from the rock cave in ancient times, stone bridge, pinnacle to modern various devices and various cliff painting, statue, wall, monument and the exterior wall of building and ground etc. all extensively commonly use stone material.But, after these construction materials use several years, there will be pathological changes and stone material itself at stone surface can be polluted by various invasives, and thus stone surface there will be water spots, greasy dirt, tells the phenomenons such as Huang.The generation of these phenomenons is owing to this type of material has micropore, easily absorbs corrosive gas, moisture and pollutant in air.And these phenomenons can cause its decorative effect, and it is used for the life-span and causes significant impact.In order to prevent the pathological changes of stone material, at home and abroad occur that stone surface is antifouling and maintenance technology.At present, the surface soiling agent Water-proof and oil-proof on market and antifouling property are poor.
Summary of the invention
It is an object of the invention to provide a kind of fluorine-containing organic silicon stone anti-fouling agent for stone protector, there is Water-proof and oil-proof and the advantage improving stone material ruggedness.
In order to realize foregoing invention purpose, the invention provides a kind of fluorine-containing organic silicon stone anti-fouling agent, described anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 90-130 weight portion, fluorine silicon resin 20-35 weight portion, fluorosilicon oil 10-30 weight portion, dispersion wetting agent 5-10 weight portion, defoamer 3-10 weight portion, preservative 1-5 weight portion, silane coupler 1-5 weight portion, coalescents 10-25 weight portion, color stuffing 1-5 weight portion and thickening agent 2-7 weight portion.
Described anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 90-115 weight portion, fluorine silicon resin 25-35 weight portion, fluorosilicon oil 10-21 weight portion, dispersion wetting agent 5-8 weight portion, defoamer 3-7 weight portion, preservative 1-3 weight portion, silane coupler 1-3 weight portion, coalescents 10-17 weight portion, color stuffing 1-3 weight portion and thickening agent 2-5 weight portion.
Described anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 106-130 weight portion, fluorine silicon resin 20-31 weight portion, fluorosilicon oil 17-30 weight portion, dispersion wetting agent 7-10 weight portion, defoamer 5-10 weight portion, preservative 2-5 weight portion, silane coupler 2-5 weight portion, coalescents 15-25 weight portion, color stuffing 2-5 weight portion and thickening agent 3-7 weight portion.
Described anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 105-125 weight portion, fluorine silicon resin 23-31 weight portion, fluorosilicon oil 15-25 weight portion, dispersion wetting agent 6-9 weight portion, defoamer 4-8 weight portion, preservative 2-4 weight portion, silane coupler 2-4 weight portion, coalescents 13-21 weight portion, color stuffing 2-4 weight portion and thickening agent 3-6 weight portion.
Described anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 116 weight portion, fluorine silicon resin 27 weight portion, fluorosilicon oil 21 weight portion, dispersion wetting agent 8 weight portion, defoamer 6 weight portion, preservative 3 weight portion, silane coupler 3 weight portion, coalescents 17 weight portion, color stuffing 3 weight portion and thickening agent 4 weight portion.
Described anti-fouling agent the most also includes malic acid and Cera Flava；Described anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 90-130 weight portion, fluorine silicon resin 20-35 weight portion, malic acid 5-12 weight portion, fluorosilicon oil 10-30 weight portion, Cera Flava 3-7 weight portion, dispersion wetting agent 5-10 weight portion, defoamer 3-10 weight portion, preservative 1-5 weight portion, silane coupler 1-5 weight portion, coalescents 10-25 weight portion, color stuffing 1-5 weight portion and thickening agent 2-7 weight portion.
Described anti-fouling agent is preferably made up of the raw material of following ratio of weight and number: petroleum ether 112 weight portion, fluorine silicon resin 27 weight portion, malic acid 8 weight portion, fluorosilicon oil 23 weight portion, Cera Flava 5 weight portion, dispersion wetting agent 7 weight portion, defoamer 5 weight portion, preservative 3 weight portion, silane coupler 3 weight portion, coalescents 16 weight portion, color stuffing 3 weight portion and thickening agent 5 weight portion.
Described fluorosilicon oil be with alkyl acrylic 12 heptyl ester and alkyl acyloxy propyl trimethoxy silicane for primary raw material synthesize fluorosilicon oil, wherein, alkyl is methyl, ethyl or propyl group；The boiling point of described petroleum ether is 60-90 DEG C.
Described dispersion wetting agent be phosphoric acid, silicate, the most in join one or more in polyhydric alcohol-many aziridines block copolymer, enuatrol and sulfonate；Wherein, the percentage by weight of described phosphoric acid is 0% ~ 10%, 10% ~ 30% or 40% ~ 100%, and the percentage by weight of described silicate is 0% ~ 35%, 40% ~ 65%, 70% ~ 100%；Described many most in join the percentage by weight of polyhydric alcohol-many aziridines block copolymer be 0% ~ 10%, 20% ~ 35% or 40% ~ 100%；The percentage by weight of described enuatrol is 0% ~ 10%, 10% ~ 30% or 40% ~ 100%；The percentage by weight of described sulfonate is 0% ~ 20%, 20% ~ 35% or 45% ~ 100%, and the percentage by weight summation of five kinds of described compositions is 100%；Be preferably: described dispersion wetting agent by 10% ~ 30% phosphoric acid, 0% ~ 35% silicate, more than 20% ~ 35% in join polyhydric alcohol-many aziridines block copolymer, 10% ~ 30% enuatrol and 0% ~ 20% sulfonate and form, the percentage by weight summation of five kinds of described compositions is 100%；Most preferably, described dispersion wetting agent by 15% phosphoric acid, 15% silicate, more than 32% in join polyhydric alcohol-many aziridines block copolymer, 21% enuatrol and 17% sulfonate and form,
Described defoamer is one or more in HT-606, HT-610 and NXZ；Wherein, the percentage by weight of described HT-606 is 0% ~ 10%, 15% ~ 35% or 40% ~ 100%, the percentage by weight of described HT-610 is 0% ~ 10%, 10% ~ 30% or 35% ~ 100%, the percentage by weight of described NXZ is 0% ~ 30%, 35% ~ 60% or 60% ~ 100%, and the percentage by weight summation of three kinds of described compositions is 100%；It is preferably: described defoamer is made up of 15% ~ 35%HT-606,10% ~ 30%HT-610 and 35% ~ 60%NXZ, and the percentage by weight summation of three kinds of described compositions is 100%；Most preferably: described defoamer is made up of 30%HT-606,10%HT-610 and 60%NXZ.
Described preservative is one or more in sodium rice silver, zinc oxide and magnesium oxide；Wherein, the percentage by weight of described nanometer silver is 0% ~ 20%, 25% ~ 65% or 70% ~ 100%, the percentage by weight of described zinc oxide is 0% ~ 10%, 10% ~ 30% or 40% ~ 100%, the percentage by weight of described magnesium oxide is 0% ~ 20%, 20% ~ 35% or 45% ~ 100%, and the percentage by weight summation of three kinds of described compositions is 100%；It is preferably: described preservative is made up of 25% ~ 65% sodium rice silver, 10% ~ 30% zinc oxide and 20% ~ 45% magnesium oxide, and the percentage by weight summation of three kinds of described compositions is 100%；Most preferably: described preservative is made up of the zinc oxide that the sodium rice silver that percentage by weight is 52%, percentage by weight are 19% and the magnesium oxide that percentage by weight is 29%.
Described silane coupler is one or more in methacryloxy trimethoxy silane, γ-isocyanates propyl-triethoxysilicane and γ-mercaptopropyl trimethoxysilane；Wherein, the percentage by weight of described methacryloxy trimethoxy silane is 0%-20%, 20%-45% or 50%-100%；The percentage by weight of described γ-isocyanates propyl-triethoxysilicane is 0%-10%, 10%-25% or 40%-100%；The percentage by weight of described γ-mercaptopropyl trimethoxysilane is 0%-30%, 35%-45% or 50%-100%, and the percentage by weight summation of three kinds of described compositions is 100%；It is preferably: described silane coupler is made up of 20%-45% methacryloxy trimethoxy silane, 10%-25% γ-isocyanates propyl-triethoxysilicane and 35%-45% γ-mercaptopropyl trimethoxysilane, and the percentage by weight summation of three kinds of described compositions is 100%；Most preferably: described silane coupler is made up of 41% methacryloxy trimethoxy silane, 21% γ-isocyanates propyl-triethoxysilicane and 38 γ-mercaptopropyl trimethoxysilane.
Described coalescents is one or more in epoxy soybean oil, chlorinated paraffin, adjacent benzene dicaprylate and adjacent benzene dibutyrate；Wherein, the percentage by weight of described epoxy soybean oil is 0%-15%, 15%-35% or 40%-100%, the percentage by weight of described chlorinated paraffin is 0%-10%, 10%-40% or 45%-100%, the percentage by weight of described adjacent benzene dicaprylate is 0%-10%, 15%-30%, 30%-50% or 55%-100% and adjacent benzene dibutyrate 0%-20%, 25%-45% or 50%-100%, and the percentage by weight summation of four kinds of described compositions is 100%；It is preferably: described coalescents is made up of 10%-40% epoxy soybean oil, 10%-40% chlorinated paraffin, 15%-30% neighbour's benzene dicaprylate and 25%-45% neighbour's benzene dibutyrate, and the percentage by weight summation of four kinds of described compositions is 100%；Most preferably: described coalescents is made up of 35% epoxy soybean oil, 12% chlorinated paraffin, 18% adjacent benzene dicaprylate and 35% adjacent benzene dibutyrate.
Described thickening agent is sodium chloride and carboxylic hydroxyl fiber receive in one or both；The percentage by weight of described sodium chloride is 0%-30%, 35%-55% or 60%-100%, and the percentage by weight that described carboxylic hydroxyl fiber is received is 0-40,40-65 or 70%-100%, and the percentage by weight summation of two kinds of described compositions is 100%；It is preferably: described thickening agent is received formed by 35%-55% sodium chloride and 40%-65% carboxylic hydroxyl fiber, and the percentage by weight summation of two kinds of described compositions is 100%；Most preferably: described thickening agent is received formed by 51% sodium chloride and 49% carboxylic hydroxyl fiber
Described color stuffing is nano titanium oxide.
In order to preferably realize foregoing invention purpose, the invention provides the preparation method of a kind of fluorine-containing organic silicon stone anti-fouling agent, described preparation method is: at room temperature, weighs all raw materials according to ratio of weight and number, is sufficiently mixed and uniformly i.e. can get anti-fouling agent.
The technical scheme that the embodiment of the present invention provides has the benefit that compared with conventional antifouling agents, the anti-fouling agent of the present invention has the advantage of Water-proof and oil-proof and good penetrability, improves the resistance to soiling of stone material, and makes simple, directly use without dilution, easy to use.
Detailed description of the invention
Embodiment 1
Embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent, anti-fouling agent is made up of the raw material of following parts by weight: petroleum ether 112 weight portion, fluorine silicon resin 27 weight portion, malic acid 8 weight portion, fluorosilicon oil 23 weight portion, Cera Flava 5 weight portion, dispersion wetting agent 7 weight portion, defoamer 5 weight portion, preservative 3 weight portion, silane coupler 3 weight portion, coalescents 16 weight portion, color stuffing 3 weight portion and thickening agent 5 weight portion.
Wherein, fluorosilicon oil is the fluorosilicon oil synthesized for primary raw material with methacrylic acid 12 heptyl ester and methacryloxypropyl trimethoxy silane；The boiling point of petroleum ether is 80 DEG C.
Dispersion wetting agent be grouped into by the one-tenth of following percentage by weight: phosphatase 11 5%, silicate 15%, the most in join polyhydric alcohol-many aziridines block copolymer 32%, enuatrol 21% and sulfonate 17%；Defoamer is grouped into by the one-tenth of following percentage by weight: 30%HT-606,10%HT-610 and 60%NXZ.
Preservative is grouped into by the one-tenth of following percentage by weight: sodium rice silver 52%, zinc oxide 19% and magnesium oxide 29%.
Silane coupler is grouped into by the one-tenth of following percentage by weight: methacryloxy trimethoxy silane 41%, γ-isocyanates propyl-triethoxysilicane 21% and γ-mercaptopropyl trimethoxysilane 38%.
Coalescents is grouped into by the one-tenth of following percentage by weight: epoxy soybean oil 35%, chlorinated paraffin 12%, adjacent benzene dicaprylate 18% and adjacent benzene dibutyrate 35%.
Thickening agent is grouped into by the one-tenth of following percentage by weight: sodium chloride 51% and carboxylic hydroxyl fiber receive 49%.
Color stuffing is nano titanium oxide.
The preparation method embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent is: at room temperature, weigh all raw materials according to ratio of weight and number, is sufficiently mixed and uniformly i.e. can get anti-fouling agent.
Embodiment 2
Embodiments provide a kind of fluorine-containing organic silicon stone anti-fouling agent, the raw material composition of the ratio of weight and number of described anti-fouling agent: petroleum ether 116 weight portion, fluorine silicon resin 27 weight portion, fluorosilicon oil 21 weight portion, dispersion wetting agent 8 weight portion, defoamer 6 weight portion, preservative 3 weight portion, silane coupler 3 weight portion, coalescents 17 weight portion, color stuffing 3 weight portion and thickening agent 4 weight portion.
Wherein, fluorosilicon oil is the fluorosilicon oil synthesized for primary raw material with methacrylic acid 12 heptyl ester and methacryloxypropyl trimethoxy silane；The boiling point of petroleum ether is 70 DEG C.
Dispersion wetting agent be grouped into by the one-tenth of following percentage by weight: phosphatase 11 1%, silicate 18%, the most in join polyhydric alcohol-many aziridines block copolymer 21%, enuatrol 27% and sulfonate 23%；Defoamer is grouped into by the one-tenth of following percentage by weight: 20%HT-606,50%HT-610 and 20%NXZ.
Preservative is grouped into by the one-tenth of following percentage by weight: sodium rice silver 27%, zinc oxide 59% and magnesium oxide 14%.
Silane coupler is grouped into by the one-tenth of following percentage by weight: methacryloxy trimethoxy silane 35%, γ-isocyanates propyl-triethoxysilicane 15% and γ-mercaptopropyl trimethoxysilane 50%.
Coalescents is grouped into by the one-tenth of following percentage by weight: epoxy soybean oil 15%, chlorinated paraffin 29%, adjacent benzene dicaprylate 26% and adjacent benzene dibutyrate 30%.
Thickening agent is grouped into by the one-tenth of following percentage by weight: sodium chloride 39% and carboxylic hydroxyl fiber receive 61%.
Color stuffing is nano titanium oxide.
The preparation method embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent is: at room temperature, weigh all raw materials according to ratio of weight and number, is sufficiently mixed and uniformly i.e. can get anti-fouling agent.
Embodiment 3
Embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent, anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 102 weight portion, fluorine silicon resin 30 weight portion, fluorosilicon oil 16 weight portion, dispersion wetting agent 6 weight portion, defoamer 5 weight portion, preservative 2 weight portion, silane coupler 2 weight portion, coalescents 13 weight portion, color stuffing 2 weight portion and thickening agent 3 weight portion.
Wherein, fluorosilicon oil is the fluorosilicon oil synthesized for primary raw material with methacrylic acid 12 heptyl ester and methacryloxypropyl trimethoxy silane；The boiling point of petroleum ether is 90 DEG C.
Dispersion wetting agent is grouped into by the one-tenth of following percentage by weight: phosphoric acid 21%, silicate 19%, enuatrol 34% and sulfonate 26%.
Defoamer is grouped into by the one-tenth of following percentage by weight: 20%HT-606 and 80%NXZ.
Preservative is grouped into by the one-tenth of following percentage by weight: sodium rice silver 51% and zinc oxide 49%.
Silane coupler is grouped into by the one-tenth of following percentage by weight: methacryloxy trimethoxy silane 35%, γ-isocyanates propyl-triethoxysilicane 15% and γ-mercaptopropyl trimethoxysilane 50%.
Coalescents is grouped into by the one-tenth of following percentage by weight: epoxy soybean oil 24%, adjacent benzene dicaprylate 41% and adjacent benzene dibutyrate 35%.
Thickening agent is grouped into by the one-tenth of following percentage by weight: sodium chloride 49% and carboxylic hydroxyl fiber receive 51%.
Color stuffing is nano titanium oxide.
The preparation method embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent is: at room temperature, weigh all raw materials according to ratio of weight and number, is sufficiently mixed and uniformly i.e. can get anti-fouling agent.
Embodiment 4
Embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent, anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 118 weight portion, fluorine silicon resin 26 weight portion, fluorosilicon oil 23 weight portion, dispersion wetting agent 8 weight portion, defoamer 7 weight portion, preservative 4 weight portion, silane coupler 4 weight portion, coalescents 19 weight portion, color stuffing 4 weight portion and thickening agent 5 weight portion.
Wherein, fluorosilicon oil is the fluorosilicon oil synthesized for primary raw material with methacrylic acid 12 heptyl ester and methacryloxypropyl trimethoxy silane；The boiling point of petroleum ether is 85 DEG C.
Dispersion wetting agent be grouped into by the one-tenth of following percentage by weight: silicate 22%, the most in join polyhydric alcohol-many aziridines block copolymer 26% and enuatrol 52%；Defoamer is grouped into by the one-tenth of following percentage by weight: 64%HT-606 and 36%HT-610.
Preservative is grouped into by the one-tenth of following percentage by weight: zinc oxide 53% and magnesium oxide 47%.
Silane coupler is grouped into by the one-tenth of following percentage by weight: methacryloxy trimethoxy silane 25% and γ-mercaptopropyl trimethoxysilane 75%.
Coalescents is grouped into by the one-tenth of following percentage by weight: epoxy soybean oil 27%, chlorinated paraffin 34% and adjacent benzene dicaprylate 39%.
Thickening agent is that carboxylic hydroxyl fiber is received.
Color stuffing is nano titanium oxide.
The preparation method embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent is: at room temperature, weigh all raw materials according to ratio of weight and number, is sufficiently mixed and uniformly i.e. can get anti-fouling agent.
Embodiment 5
Embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent, anti-fouling agent is made up of the raw material of following ratio of weight and number: petroleum ether 90 weight portion, fluorine silicon resin 35 weight portion, malic acid 12 weight portion, fluorosilicon oil 30 weight portion, Cera Flava 7 weight portion, dispersion wetting agent 10 weight portion, defoamer 9 weight portion, preservative 4 weight portion, silane coupler 4 weight portion, coalescents 19 weight portion, color stuffing 3 weight portion and thickening agent 4 weight portion.
Wherein, fluorosilicon oil is the fluorosilicon oil synthesized for primary raw material with methacrylic acid 12 heptyl ester and methacryloxypropyl trimethoxy silane；The boiling point of petroleum ether is 90 DEG C.
Dispersion wetting agent is grouped into by the one-tenth of following percentage by weight: silicate 34%, enuatrol 39% and sulfonate 27%.
Defoamer is grouped into by the one-tenth of following percentage by weight: 43%HT-610 and 57%NXZ.
Preservative is grouped into by the one-tenth of following percentage by weight: sodium rice silver 44% and magnesium oxide 56%.
Silane coupler is grouped into by the one-tenth of following percentage by weight: methacryloxy trimethoxy silane 35% and γ-isocyanates propyl-triethoxysilicane 65%.
Coalescents is grouped into by the one-tenth of following percentage by weight: epoxy soybean oil 21%, chlorinated paraffin 37% and adjacent benzene dibutyrate 42%.
Thickening agent is grouped into by the one-tenth of following percentage by weight: sodium chloride 47% and carboxylic hydroxyl fiber receive 53%.
Color stuffing is nano titanium oxide.
The preparation method embodiments providing a kind of fluorine-containing organic silicon stone anti-fouling agent is: at room temperature, weigh all raw materials according to ratio of weight and number, is sufficiently mixed and uniformly i.e. can get anti-fouling agent.
Contrast test
1, test material
For examination anti-fouling agent: the anti-fouling agent (embodiment group 1-5) of embodiment of the present invention 1-5；Fluorine-containing organic silicon siloxane compound (matched group 1)；Conventional antifouling agents (matched group 2).Wherein, the fluorine-containing organic silicon siloxane compound of matched group 1 is according to Application No. 201110001005.2, and application publication number is the anti-fouling agent of the content production of description embodiment 2 in CN 102585232 A patent documentation.
For examination stone material: select artificial stone as examination stone material；The test that often group anti-fouling agent is identical selects identical artificial stone to test.
2, test method
By being respectively coated on artificial stone surface after the anti-fouling agent of embodiment of the present invention 1-5, the dilution of fluorine-containing organic silicon siloxane compound and after conventional antifouling agents dilution, after placing 7-10 days after being coated with twice, stone surface is tested.Wherein, water contact angle OCA video optics contact angle instrument is tested, and tests contact angle with 0.5ml water droplet on sample；Permeability Quanta200 type scanning electron microscope test, first cuts the stone material sample after coating, then section is carried out testing permeability；Soil resistance soy sauce and coffee drop in stone surface respectively, treat that soy sauce and coffee are placed one day after drying, wash with clear water, then observe with microscope, according to dirt revolution mark, antipollution standard are divided into Three Estate: fine, good, poor.All using identical stone material before test, test result is as shown in table 1 every time.
Table 1: the antifouling property detection synopsis of the stone material of use product of the present invention and conventional products respectively:
| Group | Water contact angle | Anti-coffee pollutes | Anti-soy sauce pollutes | Grease proofness | Permeability |
| Embodiment group 1 | 142 | Very well | Very well | Very well | 2.4 mm |
| Embodiment group 2 | 141 | Very well | Very well | Very well | 2.3 mm |
| Embodiment group 3 | 139 | Very well | Very well | Very well | 2.3 mm |
| Embodiment group 4 | 139 | Very well | Very well | Very well | 2.1 mm |
| Embodiment group 5 | 141 | Very well | Very well | Very well | 2.3 mm |
| Matched group 1 | 120 | Good | Good | Very well | 1.8mm |
| Matched group 2 | 100 | Difference | Difference | Difference | 1mm |
Data from table 1: use the anti-fouling agent of embodiment of the present invention 1-5 to be coated on artificial slabstone, each test parameter is superior to conventional products assay, the stone protectant of embodiment of the present invention 1-5 has good anti-fouling effect to stone material, improves the ruggedness of stone material；Compared with the anti-fouling agent of matched group 1, the anti-fouling agent of the present invention is superior to the anti-fouling agent of matched group 1 at water contact angle, the pollution of anti-coffee, the pollution of anti-soy sauce and permeability, and the preparation of the anti-fouling agent of the present invention is simple, easy to use, need not before using dilute directly use.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (3)
1. a fluorine-containing organic silicon stone anti-fouling agent, it is characterized in that, described anti-fouling agent is made up of the raw material of following parts by weight: petroleum ether 90-130 weight portion, fluorine silicon resin 20-35 weight portion, malic acid 5-12 weight portion, fluorosilicon oil 10-30 weight portion, Cera Flava 3-7 weight portion, dispersion wetting agent 5-10 weight portion, defoamer 3-10 weight portion, preservative 1-5 weight portion, silane coupler 1-5 weight portion, coalescents 10-25 weight portion, color stuffing 1-5 weight portion and thickening agent 2-7 weight portion；
Described fluorosilicon oil be with alkyl acrylic 12 heptyl ester and alkyl acyloxy propyl trimethoxy silicane for primary raw material synthesize fluorosilicon oil, wherein, alkyl is methyl, ethyl or propyl group；The boiling point of described petroleum ether is 60-90 DEG C；Described dispersion wetting agent be phosphoric acid, silicate, the most in join one or more in polyhydric alcohol-many aziridines block copolymer, enuatrol and sulfonate；Described defoamer is one or more in HT-606, HT-610 and NXZ；Described preservative is sodium rice silver, zinc oxide and magnesium oxide；Described silane coupler is one or more in methacryloxy trimethoxy silane, γ-isocyanates propyl-triethoxysilicane and γ-mercaptopropyl trimethoxysilane；Described coalescents is one or more in epoxy soybean oil, chlorinated paraffin, adjacent benzene dicaprylate and adjacent benzene dibutyrate；Described thickening agent is sodium chloride and carboxylic hydroxyl fiber receive in one or both；Described color stuffing is nano titanium oxide.
Fluorine-containing organic silicon stone anti-fouling agent the most according to claim 1, it is characterized in that, described anti-fouling agent is made up of the raw material of following parts by weight: petroleum ether 112 weight portion, fluorine silicon resin 27 weight portion, malic acid 8 weight portion, fluorosilicon oil 23 weight portion, Cera Flava 5 weight portion, dispersion wetting agent 7 weight portion, defoamer 5 weight portion, preservative 3 weight portion, silane coupler 3 weight portion, coalescents 16 weight portion, color stuffing 3 weight portion and thickening agent 5 weight portion.
3. the preparation method of a fluorine-containing organic silicon stone anti-fouling agent as claimed in claim 1 or 2, it is characterised in that described preparation method is: at room temperature, weighs all raw materials according to ratio of weight and number, is sufficiently mixed and uniformly i.e. can get anti-fouling agent.
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| CN108300284A (en) * | 2017-08-23 | 2018-07-20 | 宁波千玉琉璃制品股份有限公司 | A kind of waterproof and oilproof coating |
| CN107502281A (en) * | 2017-08-29 | 2017-12-22 | 无为县鑫品石业有限公司 | A kind of marble marine glue and its manufacture method, use technique |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008513231A (en) * | 2004-10-06 | 2008-05-01 | ダイキン工業株式会社 | Laminated body excellent in antifouling property and interlayer adhesion and method for producing the same |
| CN101186766A (en) * | 2006-11-16 | 2008-05-28 | 国家纳米技术与工程研究院 | Masking liquid for protecting stone cultural artifact and using method thereof |
| CN101544868A (en) * | 2009-05-08 | 2009-09-30 | 厦门大学 | Fluoro-silicone self-cleaning paint and preparation method thereof |
| CN101775144A (en) * | 2009-01-09 | 2010-07-14 | 比亚迪股份有限公司 | Fluorine silicon resin, preparation method thereof and antifouling paint |
| CN102108256A (en) * | 2010-12-31 | 2011-06-29 | 哈尔滨工业大学深圳研究生院 | Inorganic-organic superhydrophobic nanocomposite for stone historical relics and preparation method thereof |
| CN102174290A (en) * | 2011-02-14 | 2011-09-07 | 成都理工大学 | Method for preparing ceramic tile antifouling agent |
-
2014
- 2014-01-23 CN CN201410031729.5A patent/CN103756562B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008513231A (en) * | 2004-10-06 | 2008-05-01 | ダイキン工業株式会社 | Laminated body excellent in antifouling property and interlayer adhesion and method for producing the same |
| CN101186766A (en) * | 2006-11-16 | 2008-05-28 | 国家纳米技术与工程研究院 | Masking liquid for protecting stone cultural artifact and using method thereof |
| CN101775144A (en) * | 2009-01-09 | 2010-07-14 | 比亚迪股份有限公司 | Fluorine silicon resin, preparation method thereof and antifouling paint |
| CN101544868A (en) * | 2009-05-08 | 2009-09-30 | 厦门大学 | Fluoro-silicone self-cleaning paint and preparation method thereof |
| CN102108256A (en) * | 2010-12-31 | 2011-06-29 | 哈尔滨工业大学深圳研究生院 | Inorganic-organic superhydrophobic nanocomposite for stone historical relics and preparation method thereof |
| CN102174290A (en) * | 2011-02-14 | 2011-09-07 | 成都理工大学 | Method for preparing ceramic tile antifouling agent |
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