CN106987185B - Acrylic latex paint - Google Patents
Acrylic latex paint Download PDFInfo
- Publication number
- CN106987185B CN106987185B CN201710213806.2A CN201710213806A CN106987185B CN 106987185 B CN106987185 B CN 106987185B CN 201710213806 A CN201710213806 A CN 201710213806A CN 106987185 B CN106987185 B CN 106987185B
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- CN
- China
- Prior art keywords
- parts
- cardanol
- latex paint
- leveling agent
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an acrylic latex paint which is composed of the following components in parts by weight: 30-75 parts of acrylic emulsion; 1-12 parts of pigment and filler; 1-4 parts of a dispersing agent; 3-9 parts of a leveling agent; 10-22 parts of an emulsifier; 3-6 parts of a defoaming agent; 2-5 parts of a film forming auxiliary agent; 20-40 parts of water; the emulsifier is prepared by mixing cardanol polyoxyethylene ether, cardanol sulfonate and cardanol glycidyl ether. The components of the invention have good compatibility, and the components complement each other, so the invention has synergistic effect, the invention has good washing resistance, good alkali resistance, strong covering power, can be washed and smeared by water, and the invention has short drying time, very convenient use, and lower content of free formaldehyde, and meets the requirement of environmental protection, therefore, the invention has better comprehensive performance, is a high-performance environment-friendly latex paint, and has wider application range.
Description
Technical Field
The invention belongs to the technical field of chemical production, and particularly relates to an acrylic latex paint.
Background
The coating is a viscous liquid prepared by coating on the surface of a protected or decorated object and forming a firmly attached continuous film with the coated object, generally by taking resin, oil or emulsion as a main material, adding or not adding pigments and fillers, adding corresponding auxiliary agents and using an organic solvent or water.
The emulsion paint is water dispersive paint, which is prepared with synthetic resin emulsion as base material, stuffing, and assistants. The emulsion paint has the advantages different from the traditional wall paint, such as easy brushing, quick drying, water resistance of paint film, good scrubbing resistance and the like. In China, people are used to prepare the paint by taking synthetic resin emulsion as a base material, taking water as a dispersion medium, adding pigment, filler (also called as bulk pigment) and an auxiliary agent and carrying out certain technological processes.
With the improvement of scientific technology and the improvement of the living standard of human beings, the requirements of people on the indoor environment and the air quality are higher and higher; meanwhile, the modern industry puts forward more and more strict requirements on the terrace, and the terrace does not have dust, harmful volatile matters and is clean and dustless as required by industries such as food, medicine and the like; the mechanical industry requires resistance to strong mechanical impact, resistance to abrasion, ability to withstand rolling of forklift and other vehicles for a long time, and ease of maintenance even if locally damaged; the ground of industrial workshops such as machine tools, instruments and meters and the like is often corroded and leaked by various oils, is difficult to completely remove, and requires the terrace to have good oil resistance, and the chemical industry requires the terrace to be resistant to corrosion of various chemical media; therefore, with the rapid development of coating technology, the coating needs to meet corresponding characteristics in order to adapt to different occasions and environments.
Disclosure of Invention
The invention aims to provide the acrylic latex paint which has strong comprehensive performance and wide applicability.
In order to solve the technical problems, the technical scheme of the invention is as follows: the acrylic latex paint is characterized by comprising the following components in parts by weight:
30-75 parts of acrylic emulsion; 1-12 parts of pigment and filler; 1-4 parts of a dispersing agent; 3-9 parts of a leveling agent; 10-22 parts of an emulsifier; 3-6 parts of a defoaming agent; 2-5 parts of a film forming auxiliary agent; 20-40 parts of water;
the emulsifier is prepared by mixing cardanol polyoxyethylene ether, cardanol sulfonate and cardanol glycidyl ether.
Preferably, the mass ratio of the cardanol polyoxyethylene ether to the cardanol sulfonate to the cardanol glycidyl ether is 1-3: 3-5: 2 to 4.
Preferably, the mass ratio of the cardanol polyoxyethylene ether to the cardanol sulfonate to the cardanol glycidyl ether is 2: 4: 3.
preferably, the pigment and filler is at least one of titanium dioxide, kaolin, diatomite, mica powder and cuprous oxide.
Preferably, the dispersant is at least one of triethylhexyl phosphoric acid, sodium dodecyl sulfate, methylpentanol, cellulose derivatives, polyacrylamide and fatty acid polyglycol ester.
Preferably, the leveling agent is at least one of an organic silicon leveling agent, an acrylate leveling agent, a fluorine modified organic silicon leveling agent and a wax modified organic silicon leveling agent.
Preferably, the leveling agent consists of an organic silicon leveling agent and an acrylate leveling agent, and the weight ratio of the organic silicon leveling agent to the acrylate leveling agent is 1-3: 2-3.
Preferably, the defoaming agent is at least one of tributyl phosphate, diisopropanolamine polyoxypropylene polyoxyethylene ether and polyoxypropylene polyoxyethylene glycerol ether.
Preferably, the film-forming aid is at least one of propylene glycol methyl ether acetate, benzyl alcohol, lauryl alcohol ester and hexylene glycol butyl ether acetate.
Compared with the prior art, the invention has the beneficial effects that:
(1) the components of the invention have good compatibility, and the components complement each other, so the invention has synergistic effect, the invention has good washing resistance, good alkali resistance, strong covering power, can be washed and smeared by water, and the invention has short drying time, very convenient use, and lower content of free formaldehyde, and meets the requirement of environmental protection, therefore, the invention has better comprehensive performance, is a high-performance environment-friendly latex paint, and has wider application range.
(2) The cardanol polyoxyethylene ether can replace nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, sec-octylphenol polyoxyethylene ether and other phenol polyoxyethylene ethers and other petrochemical products, and the biodegradability of the petrochemical products is poor, so that the cardanol polyoxyethylene ether can improve the biodegradability and reduce the pollution to the environment.
Detailed Description
The following further describes the embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Example 1
The acrylic latex paint consists of the following components in parts by weight: 45 parts of acrylic emulsion; 5 parts of titanium dioxide; 5 parts of kaolin; 1 part of sodium dodecyl sulfate; 8 parts of acrylate leveling agent; 8 parts of an emulsifier; 6 parts of diisopropanolamine polyoxypropylene polyoxyethylene ether; 1 part of propylene glycol methyl ether acetate; 20 parts of water;
the emulsifier is prepared by mixing cardanol polyoxyethylene ether, cardanol sulfonate and cardanol glycidyl ether, wherein the mass ratio of the cardanol polyoxyethylene ether to the cardanol sulfonate to the cardanol glycidyl ether is 1: 5: 4.
the preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
Example 2
The acrylic latex paint consists of the following components in parts by weight: 35 parts of acrylic emulsion; 1 part of diatomite; 0.5 part of mica powder; 0.5 part of cuprous oxide; 3 parts of triethylhexyl phosphoric acid; 2 parts of methyl amyl alcohol; 1 part of acrylate leveling agent; 1 part of fluorine modified organic silicon flatting agent; 20 parts of an emulsifier; 1 part of diisopropanolamine polyoxypropylene polyoxyethylene ether; 1 part of polyoxypropylene polyoxyethylene glycerol ether; 3 parts of benzyl alcohol; 2 parts of dodecyl alcohol ester; 40 parts of water;
the emulsifier is prepared by mixing cardanol polyoxyethylene ether, cardanol sulfonate and cardanol glycidyl ether, wherein the mass ratio of the cardanol polyoxyethylene ether to the cardanol sulfonate to the cardanol glycidyl ether is 2: 3: 3.
the preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
Example 3
The acrylic latex paint consists of the following components in parts by weight: 65 parts of acrylic emulsion; 3 parts of diatomite; 3 parts of cuprous oxide; 1 part of polyacrylamide; 2 parts of fatty acid polyglycol ester; 3 parts of an organic silicon flatting agent; 3 parts of an acrylate leveling agent; 16 parts of an emulsifier; 4 parts of polyoxypropylene polyoxyethylene glycerol ether; 1 part of benzyl alcohol; 3 parts of dodecyl alcohol ester; and 30 parts of water.
The emulsifier is prepared by mixing cardanol polyoxyethylene ether, cardanol sulfonate and cardanol glycidyl ether, wherein the mass ratio of the cardanol polyoxyethylene ether to the cardanol sulfonate to the cardanol glycidyl ether is 3: 3: 2.
the preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
Example 4
The acrylic latex paint consists of the following components in parts by weight: 65 parts of acrylic emulsion; 3 parts of diatomite; 3 parts of cuprous oxide; 1 part of polyacrylamide; 2 parts of fatty acid polyglycol ester; 3 parts of an organic silicon flatting agent; 3 parts of an acrylate leveling agent; 16 parts of an emulsifier; 4 parts of polyoxypropylene polyoxyethylene glycerol ether; 1 part of benzyl alcohol; 3 parts of dodecyl alcohol ester; and 30 parts of water.
The emulsifier is prepared by mixing cardanol polyoxyethylene ether, cardanol sulfonate and cardanol glycidyl ether, wherein the mass ratio of the cardanol polyoxyethylene ether to the cardanol sulfonate to the cardanol glycidyl ether is 1: 3: 2.
the preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
Example 5
The acrylic latex paint consists of the following components in parts by weight: 65 parts of acrylic emulsion; 3 parts of diatomite; 3 parts of cuprous oxide; 1 part of polyacrylamide; 2 parts of fatty acid polyglycol ester; 3 parts of an organic silicon flatting agent; 3 parts of an acrylate leveling agent; 16 parts of an emulsifier; 4 parts of polyoxypropylene polyoxyethylene glycerol ether; 1 part of benzyl alcohol; 3 parts of dodecyl alcohol ester; and 30 parts of water.
The emulsifier is prepared by mixing cardanol polyoxyethylene ether, cardanol sulfonate and cardanol glycidyl ether, wherein the mass ratio of the cardanol polyoxyethylene ether to the cardanol sulfonate to the cardanol glycidyl ether is 2: 4: 3.
the preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
Comparative example 1
The acrylic latex paint consists of the following components in parts by weight: 65 parts of acrylic emulsion; 3 parts of diatomite; 3 parts of cuprous oxide; 1 part of polyacrylamide; 2 parts of fatty acid polyglycol ester; 3 parts of an organic silicon flatting agent; 3 parts of an acrylate leveling agent; 4 parts of polyoxypropylene polyoxyethylene glycerol ether; 1 part of benzyl alcohol; 3 parts of dodecyl alcohol ester; and 30 parts of water.
The preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
Comparative example 2
The acrylic latex paint consists of the following components in parts by weight: 65 parts of acrylic emulsion; 3 parts of diatomite; 3 parts of cuprous oxide; 1 part of polyacrylamide; 2 parts of fatty acid polyglycol ester; 4 parts of polyoxypropylene polyoxyethylene glycerol ether; 1 part of benzyl alcohol; 3 parts of dodecyl alcohol ester; and 30 parts of water.
The preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
Comparative example 3
The acrylic latex paint consists of the following components in parts by weight: 65 parts of acrylic emulsion; 3 parts of diatomite; 3 parts of cuprous oxide; 1 part of polyacrylamide; 2 parts of fatty acid polyglycol ester; 3 parts of an organic silicon flatting agent; 3 parts of an acrylate leveling agent; 4 parts of polyoxypropylene polyoxyethylene glycerol ether; 1 part of benzyl alcohol; 3 parts of dodecyl alcohol ester; 16 parts of cardanol polyoxyethylene ether; and 30 parts of water.
The preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
Comparative example 4
The acrylic latex paint consists of the following components in parts by weight: 65 parts of acrylic emulsion; 3 parts of diatomite; 3 parts of cuprous oxide; 1 part of polyacrylamide; 2 parts of fatty acid polyglycol ester; 3 parts of an organic silicon flatting agent; 3 parts of an acrylate leveling agent; 4 parts of polyoxypropylene polyoxyethylene glycerol ether; 1 part of benzyl alcohol; 3 parts of dodecyl alcohol ester; 7 parts of cardanol sulfonate; 9 parts of cardanol glycidyl ether; and 30 parts of water.
The preparation method of the latex paint comprises the following steps:
weighing various materials according to the formula, adding the materials in water under the condition of stirring, and stirring at a high speed for dispersing to obtain the latex paint.
The latex paints prepared in examples 1-5 and comparative examples 1-4 were subjected to measurement of various performance indexes, the specific measurement items are shown in table 1, and the detection results are shown in table 2.
TABLE 1
TABLE 2
The embodiments of the present invention have been described in detail, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.
Claims (8)
1. The acrylic latex paint is characterized by comprising the following components in parts by weight:
30-75 parts of acrylic emulsion; 1-12 parts of pigment and filler; 1-4 parts of a dispersing agent; 3-9 parts of a leveling agent; 10-22 parts of an emulsifier; 3-6 parts of a defoaming agent; 2-5 parts of a film forming auxiliary agent; 20-40 parts of water;
the emulsifier is prepared by mixing cardanol polyoxyethylene ether, cardanol sulfonate and cardanol glycidyl ether; the mass ratio of the cardanol polyoxyethylene ether to the cardanol sulfonate to the cardanol glycidyl ether is 1-3: 3-5: 2 to 4.
2. The acrylic latex paint as claimed in claim 1, wherein the mass ratio of the cardanol polyoxyethylene ether, the cardanol sulfonate and the cardanol glycidyl ether is 2: 4: 3.
3. the acrylic latex paint as claimed in claim 1, wherein said pigment and filler is at least one of titanium dioxide, kaolin, diatomaceous earth, mica powder and cuprous oxide.
4. The acrylic latex paint according to claim 1, wherein said dispersant is at least one of triethylhexylphosphoric acid, sodium dodecylsulfate, methylpentanol, cellulose derivative, polyacrylamide, and fatty acid polyglycol ester.
5. The acrylic latex paint according to claim 1, wherein said leveling agent is at least one of silicone leveling agent, acrylate leveling agent, fluorine modified silicone leveling agent, and wax modified silicone leveling agent.
6. The acrylic latex paint as claimed in claim 5, wherein the leveling agent is composed of an organosilicon leveling agent and an acrylate leveling agent, and the weight ratio of the organosilicon leveling agent to the acrylate leveling agent is 1-3: 2-3.
7. The acrylic latex coating according to claim 1, wherein said defoaming agent is at least one of tributyl phosphate, diisopropanolamine polyoxypropylene polyoxyethylene ether, and polyoxypropylene polyoxyethylene glyceryl ether.
8. The acrylic latex paint according to claim 1, wherein said film-forming aid is at least one of propylene glycol methyl ether acetate, benzyl alcohol, lauryl alcohol ester and hexylene glycol butyl ether acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710213806.2A CN106987185B (en) | 2017-04-01 | 2017-04-01 | Acrylic latex paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710213806.2A CN106987185B (en) | 2017-04-01 | 2017-04-01 | Acrylic latex paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106987185A CN106987185A (en) | 2017-07-28 |
| CN106987185B true CN106987185B (en) | 2020-05-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710213806.2A Expired - Fee Related CN106987185B (en) | 2017-04-01 | 2017-04-01 | Acrylic latex paint |
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| Country | Link |
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| CN (1) | CN106987185B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044628A (en) * | 2012-12-25 | 2013-04-17 | 中盈长江国际新能源投资有限公司 | Preparation method of biomass-based polymer emulsion |
| CN103962052A (en) * | 2014-05-09 | 2014-08-06 | 中国科学院理化技术研究所 | Saturated cardanol ether sulfonate surfactant and preparation method and application thereof |
| WO2015090444A1 (en) * | 2013-12-20 | 2015-06-25 | Basf Coatings Gmbh | Formulations containing pigment and filler |
| CN105013391A (en) * | 2015-08-05 | 2015-11-04 | 吴俊宏 | Preparation method of surface active agent |
| CN105331229A (en) * | 2014-08-08 | 2016-02-17 | 邢军 | Coating for cement fence and preparation method thereof |
| CN105602403A (en) * | 2016-01-27 | 2016-05-25 | 四川彭山星源特种涂料有限公司 | Solvent-free epoxy anticorrosive paint for drinking water transport and distribution equipment and preparing method of solvent-free epoxy anticorrosive paint |
-
2017
- 2017-04-01 CN CN201710213806.2A patent/CN106987185B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044628A (en) * | 2012-12-25 | 2013-04-17 | 中盈长江国际新能源投资有限公司 | Preparation method of biomass-based polymer emulsion |
| WO2015090444A1 (en) * | 2013-12-20 | 2015-06-25 | Basf Coatings Gmbh | Formulations containing pigment and filler |
| CN103962052A (en) * | 2014-05-09 | 2014-08-06 | 中国科学院理化技术研究所 | Saturated cardanol ether sulfonate surfactant and preparation method and application thereof |
| CN105331229A (en) * | 2014-08-08 | 2016-02-17 | 邢军 | Coating for cement fence and preparation method thereof |
| CN105013391A (en) * | 2015-08-05 | 2015-11-04 | 吴俊宏 | Preparation method of surface active agent |
| CN105602403A (en) * | 2016-01-27 | 2016-05-25 | 四川彭山星源特种涂料有限公司 | Solvent-free epoxy anticorrosive paint for drinking water transport and distribution equipment and preparing method of solvent-free epoxy anticorrosive paint |
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| CN106987185A (en) | 2017-07-28 |
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