CN104086117A - Waterborne colorful lacquer composite exterior wall construction paint - Google Patents

Waterborne colorful lacquer composite exterior wall construction paint Download PDF

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Publication number
CN104086117A
CN104086117A CN201410330691.1A CN201410330691A CN104086117A CN 104086117 A CN104086117 A CN 104086117A CN 201410330691 A CN201410330691 A CN 201410330691A CN 104086117 A CN104086117 A CN 104086117A
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reactor
colorful
paint
color
minute
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CN104086117B (en
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陈凯
吴勇
胡娟
陈萍
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Zhejiang Transfar Paint Co Ltd
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Zhejiang Transfar Paint Co Ltd
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Abstract

The invention discloses waterborne colorful lacquer composite exterior wall construction paint. The preparation method of the existing environment-friendly waterborne colorful paint has the defects of more spraying track numbers for achieving a relatively good effect, labor and time waste and high construction difficulty. The waterborne colorful lacquer composite exterior wall construction paint comprises the following raw material components in percentage by mass: 20-30% of lacquer slurry, 35-45% of colorful points and 30-35% of colorful color sand. According to the invention, the colorful paint is compounded by using two tracks of lacquer, the construction can be finished by adding two tracks of nanometer antifouling self-cleaning finish-coat paint, and the excellent ageing resistance of lacquer and an authentic granite material simulated effect of the colorful paint are achieved.

Description

A kind of waterborne multicolor true stone paint complex building exterior coating
Technical field
The present invention relates to technical field of coatings, especially a kind of waterborne multicolor true stone paint complex building exterior coating.
Background technology
Aqueous colorful stone-like coating is along with development in recent years, rely on artificial granite stone effect true to nature, with stone material compare the outward appearance of building own requirement, construct simple and convenient, without the advantage such as dangerous that drops, use and had widespread use as building external paint.And the extensive water-soluble colorful coating construction technology using is mainly the true mineral varnish of twice (or twice emulsion paint) and twice multicolor finish now, then add twice finishing paint.Workman's the labour intensity of not only constructing is large, and cost of labor is high, the cracking or the peeling that also exist the matching difference existing between true mineral varnish (or emulsion paint) and multicolor finish to cause.Water bag water paint uses true mineral varnish bottoming, and hair side of a light face can produce the effect of light and shade inequality, makes to incorporate entirety.And aqueous colorful stone-like coating has just solved this class problem well, spraying consistence, light and shade consistence.Aqueous colorful stone-like coating has better incorporating property than single water bag water paint, and idea and background colour are more unified, imitate verisimilitude more as.
Application number is the preparation method that 201210156035.5 Chinese invention patent provides a kind of environment-friendly type aqueous multicolor finish: 1. granulating colloidal solution preparation; 2. color grain preparation, white basis paint, Color mode paint, the preparation of color grain; 3. finished product paint: the preparation of emulsion C component, lacquering obtains water-soluble colorful coating.Its preparation is simple, steady quality, and superior performance, cost is low, good weatherability, naturalness is high, and decoration and protectiveness are good.How just can reach reasonable effect but the method need to spray number, work consuming is consuming time, and difficulty of construction is large.
Summary of the invention
For existing market main product (priming paint, middlely be coated with that color some paint is separately made, construction) in construction technology numerous and diverse, the weak point such as should not operate, the object of this invention is to provide a kind of convenient construction, technique is simple, waterborne multicolor true stone paint complex building exterior coating that can one moulding.
A kind of waterborne multicolor true stone paint complex building exterior coating, comprises following component raw material and mass percent:
True mineral varnish slurry 20-30%,
Colorful color some 35-45%,
Each color sand 30-35%,
The preparation process of the colorful complex building exterior coating of the true mineral varnish of described water-based is:
A: the true mineral varnish slurry of formula ratio is dropped in reactor, open 80-120 rev/min and drop into colorful color some grain, disperse 1-3 minute, reach even look grain;
B: add successively each color sand, note interpolation speed, be controlled at 10-30 minute and add, prevent from becoming broken because of metal to-metal contact between colorful color point and each color sand, after adding, stir and can adopt same rotating speed to stir 2-8 minute, make the colorful complex building exterior coating of the true mineral varnish of water-based.
Described true mineral varnish slurry comprises following component raw material and mass percent:
Wherein said Mierocrystalline cellulose is non-ionic type Mierocrystalline cellulose; Described film coalescence aid is the one or more combination among ethylene glycol, propylene glycol monobutyl ether (BCS), Lauryl Alcohol ester, and the preparation process of true mineral varnish slurry is:
A: the soft water of formula ratio is added to reactor, add the Mierocrystalline cellulose of 30-50% formula ratio, with disperseing 3-5 minute under rotating speed 700-900 rev/min;
B: continue to add remaining Mierocrystalline cellulose, under same rotational speed, disperse 3-5 minute, Mierocrystalline cellulose adds film coalescence aid, propylene glycol, biocide mildewcide successively after breaing up completely, and stirring velocity 700-900 rev/min is disperseed 2-5 minute, finally add organosilicon crylic acid latex, make true mineral varnish slurry.
Described colorful color point comprises following component raw material and mass percent:
Protection glue solution 50-60%,
Base paint 40-50% of all kinds,
Base paint of all kinds is the base paint of the different colours color dot of allotment, and the preparation process of described colorful color point is:
A: first described protection glue solution is joined in reactor, use three leaf dispersion impellers of cutting type to stir, control speed is under 100-200 rev/min, by web plate, base paint of all kinds is joined in reactor successively, stir 3-10 minute, reach required color dot size, make mixture;
B: then gained mixture is crossed to screen cloth, reach final required color dot size, soak 10-24 hour, make color dot reach required hardness.
In described base paint, the weight percent of each component is as follows:
Wherein, described response type protection glue is that weight ratio is the protection glue solution of 6-10%, and described Mierocrystalline cellulose is non-ionic type Mierocrystalline cellulose; Described defoamer adopts aqueous medium versatility mineral oil defoaming agent;
The preparation process of base paint of all kinds is:
A: soft water is poured in reactor, controlled rotating speed at 400-600 rev/min, add Mierocrystalline cellulose, dispersion agent, defoamer to stir 3-5 minute;
B: titanium dioxide, calcined kaolin, pH adjusting agent are dropped into reactor successively, control rotating speed and stir 20-30 minute under 1000-1200 rev/min;
C: by 100-200 order quartz sand, 200 order quartz sands and mildew-resistant algaecide, flexible silicon acrylic emulsion drop into reactor, control rotating speed and stir 3-5 minute under 700-900 rev/min;
D: under 700-900 rev/min of rotating speed, add response type protection glue, wetting agent to reactor, stir 5-10 minute, make base paint;
E: according to the color of marble grouan, add required aqueous color paste in above-mentioned base paint, be deployed into needed color, make base paint of all kinds.
Described protection glue solution comprises the following raw material that is calculated in mass percent calculation:
Wherein, sequestrant is the chelated dispersants TF-510 that Zhejiang Province Chuanhua Co., Ltd produces;
The preparation process of described protection glue solution is:
A: soft water is dropped into reactor, control rotating speed at 400-600 rev/min, drop into sequestrant and disperse 3-5 minute;
B: drop into trisodium phosphate to reactor, stir 3-5 minute under same rotational speed;
C: drop into protection rubber powder to reactor, stir 20-30 minute under same rotational speed; According to the addition of the soft or hard extent control protection rubber powder of color dot, addition is more, and the hardness of look grain is harder.
The beneficial effect that the present invention has:
The present invention is with respect to prior art, this product construction only needs the true mineral varnish compound multi-colour paint of twice, add the self-cleaning finishing paint of twice nanometer resistant and just can complete construction, and form the ageing-resistant performance of existing true mineral varnish excellence, possesses again multicolor finish artificial granite stone effect true to nature simultaneously, add nanometer finishing paint stain resistant, self-cleaning function, is conducive to reduce labour intensity, reduces trimming cost.
Embodiment
In order further to understand summary of the invention of the present invention, Characteristic, following case study on implementation for example, and be described in detail as follows:
Embodiment 1
The colorful complex building exterior coating of a kind of true mineral varnish of water-based, the weight percent between the true mineral varnish slurry of composition of raw materials, colorful color point, each color sand is: 20: 45: 35.
The preparation process of the colorful complex building exterior coating of the true mineral varnish of described water-based is:
A: true mineral varnish slurry is dropped in reactor, open 100 revs/min and drop into colorful color point, disperse 1 minute, reach even look grain;
B: add successively each color sand, notice that adding procedure speed wants slowly, prevent between colorful color point and the color sand of high density because metal to-metal contact becomes broken, stirring after adding can same rotating speed stirring 3 minutes, makes the colorful complex building exterior coating of the true mineral varnish of water-based;
Component and the weight percent of true mineral varnish slurry are as follows: soft water 35.4, Mierocrystalline cellulose (HBR250) 0.4, film coalescence aid propylene glycol monobutyl ether (BCS) 2, film coalescence aid (TEXANOL) 2, biocide mildewcide (WL-3) 0.2, organosilicon crylic acid latex (RS-991) 60.Its preparation process is:
A: soft water is added to reactor, add the Mierocrystalline cellulose of 30% formula ratio, disperse 5 minutes under 800 revs/min of rotating speeds;
B: continue to add remaining Mierocrystalline cellulose, under same rotational speed, disperse 5 minutes, Mierocrystalline cellulose adds film coalescence aid BCS, film coalescence aid TEXANOL, propylene glycol, biocide mildewcide successively after opening completely, 800 revs/min of dispersions of stirring velocity 5 minutes, finally add organosilicon crylic acid latex, make true mineral varnish slurry.
The weight percent of base paint is as follows: soft water 35, Mierocrystalline cellulose (HBR250) 1, dispersion agent (1124) 0.5; defoamer (NXZ) 0.3; titanium dioxide (R996) 1, calcined kaolin (4000 order kaolin) 15, pH adjusting agent (AMP95) 0.3; 100-200 order quartz sand 10; 200 order quartz sands 10, mildew-resistant algaecide 0.4, flexible silicon acrylic emulsion 31.2; response type protection glue 15, wetting agent 0.3.
The preparation process of base paint of all kinds is:
A: soft water is poured in reactor, controlled rotating speed at 400 revs/min, add Mierocrystalline cellulose, dispersion agent, defoamer to stir 5 minutes;
B: titanium dioxide, calcined kaolin, pH adjusting agent are dropped into reactor successively, control rotating speed and stir under 1200 revs/min 30 minutes;
C: 100-200 order quartz sand and 200 order quartz sands, mildew-resistant algaecide, flexible silicon acrylic emulsion are dropped into reactor, control rotating speed and stir under 700 revs/min 3 minutes;
D: under 700 revs/min of rotating speeds, add 9% protection glue solution, wetting agent to reactor, stir 5 minutes, make base paint;
E: according to the color of marble grouan, add required aqueous color paste in above-mentioned base paint, be deployed into needed color, make base paint of all kinds.
Protection glue solution weight percent: soft water 90.4, sequestrant 0.3, trisodium phosphate 0.3, protection rubber powder 9.
A: soft water is dropped into reactor, control rotating speed at 600 revs/min, drop into sequestrant and disperse 3 minutes;
B: drop into trisodium phosphate to reactor, stir under same rotational speed 3 minutes;
C: drop into protection rubber powder to reactor, stir under same rotational speed 30 minutes; According to the addition of the soft or hard extent control protection rubber powder of color dot, addition is more, and the hardness of look grain is harder.
Colorful color point comprises calculates following raw material by weight percentage:
Protection glue solution 50,
Base paint 50 of all kinds,
Base paint of all kinds is the base paint of the different colours color dot of allotment.
The preparation process of described colorful color point is:
A: first described protection glue solution is joined in reactor, use three leaf dispersion impellers of cutting type to stir, control speed is under 100 revs/min, by web plate, base paint of all kinds is joined in reactor successively, stir 3 minutes, reach required color dot size, make mixture;
B: then gained mixture is crossed to screen cloth, reach final required color dot size, soak 10 hours, make color dot reach required hardness.
The Performance Detection of the colorful complex building exterior coating of the true mineral varnish of water-based of the present invention is as follows:
Embodiment 2
The colorful complex building exterior coating of a kind of true mineral varnish of water-based, the weight percent between the true mineral varnish slurry of composition of raw materials, colorful color point, each color sand is: 30: 35: 35.
The preparation process of the colorful complex building exterior coating of the true mineral varnish of water-based is as follows:
A: true mineral varnish slurry is dropped in reactor, open 100 revs/min and drop into colorful color some grain, disperse 1 minute, reach even look grain;
B: add successively each color sand, notice that adding procedure speed is slow, stir after adding and can stir 2 minutes by same rotating speed, make the colorful complex building exterior coating of the true mineral varnish of water-based.
Component and the weight percent of true mineral varnish slurry are as follows: soft water 45, Mierocrystalline cellulose (HBR250) 0.4, film coalescence aid propylene glycol monobutyl ether (BCS) 2, film coalescence aid (TEXANOL) 2, biocide mildewcide (WL-3) 0.2, organosilicon crylic acid latex (RS-991) 50.4.
A: soft water is added to reactor, add the Mierocrystalline cellulose of 50% formula ratio, disperse 3 minutes under 800 revs/min of rotating speeds;
B: continue to add remaining Mierocrystalline cellulose, under same rotational speed, disperse 3 minutes, Mierocrystalline cellulose adds BCS, film coalescence aid, propylene glycol, biocide mildewcide successively after opening completely, 800 revs/min of dispersions of stirring velocity 2 minutes, finally add organosilicon crylic acid latex, make true mineral varnish slurry.
The weight percent of base paint component is as follows: soft water 35; Mierocrystalline cellulose (HBR250) 1; dispersion agent (1124) 0.5, defoamer (NXZ) 0.3, titanium dioxide (R996) 1; calcined kaolin (4000 order kaolin) 15; pH adjusting agent (AMP95) 0.3, mildew-resistant algaecide 0.4, flexible silicon acrylic emulsion 31.2; response type protection glue 15, wetting agent 0.3.
The preparation process of base paint of all kinds is:
A: soft water is poured in reactor, controlled rotating speed at 600 revs/min, add Mierocrystalline cellulose, dispersion agent, defoamer to stir 3 minutes;
B: titanium dioxide, calcined kaolin, pH adjusting agent are dropped into reactor successively, control rotating speed and stir under 1000-1200 rev/min 20 minutes;
C: again 100-200 order quartz sand, 200 order quartz sands, mildew-resistant algaecide, flexible silicon acrylic emulsion are dropped into reactor, control rotating speed and stir under 900 revs/min 3 minutes;
D: under 900 revs/min of rotating speeds, add 7% protection glue solution, wetting agent to reactor, stir 10 minutes, make base paint;
E: according to the color of marble grouan, add required aqueous color paste in above-mentioned base paint, be deployed into needed color, make base paint of all kinds.
Protection glue solution weight percent: soft water 92.4, sequestrant 0.3, trisodium phosphate 0.3, protection rubber powder 7.
Colorful color point comprises calculates following raw material by weight percentage:
Protection glue solution 60,
Base paint 40 of all kinds,
The preparation process of described colorful color point is:
A: first described protection glue solution is joined in reactor, use three leaf dispersion impellers of cutting type to stir, control speed is under 200 revs/min, by web plate, base paint of all kinds is joined in reactor successively, stir 10 minutes, reach required color dot size, make mixture;
B: then gained mixture is crossed to screen cloth, reach final required color dot size, soak 24 hours, make color dot reach required hardness.
The Performance Detection of the colorful complex building exterior coating of the true mineral varnish of water-based of the present invention is as follows:
The above, only, for the true mineral varnish construction of the present invention embodiment, be not used for limiting scope of the invention process.Making a formal request according to the present invention that shape, structure, feature and spirit described in scope does so all is all equivalent variations or modification, all should be included in of the present invention make a formal request the scope of the claims within.

Claims (5)

1. a waterborne multicolor true stone paint complex building exterior coating, is characterized in that, comprises following component raw material and mass percent:
True mineral varnish slurry 20-30%,
Colorful color some 35-45%,
Each color sand 30-35%,
The preparation process of described waterborne multicolor true stone paint complex building exterior coating is:
A: the true mineral varnish slurry of formula ratio is dropped in reactor, open 80-120 rev/min and drop into colorful color point, disperse 1-3 minute, reach even look grain;
B: add successively each color sand, note interpolation speed, be controlled at 10-30 minute and add, prevent from becoming broken because of metal to-metal contact between colorful color point and each color sand, after adding, stir and can adopt same rotating speed to stir 2-8 minute, make the colorful complex building exterior coating of the true mineral varnish of water-based;
Described true mineral varnish slurry comprises following component raw material and mass percent:
2. waterborne multicolor true stone paint complex building exterior coating according to claim 1, is characterized in that, described Mierocrystalline cellulose is non-ionic type Mierocrystalline cellulose; Described film coalescence aid is the one or more combination among ethylene glycol, propylene glycol monobutyl ether, Lauryl Alcohol ester, and the preparation process of described true mineral varnish slurry is:
A: the soft water of formula ratio is added to reactor, add the Mierocrystalline cellulose of 30-50% formula ratio, disperse 3-5 minute under rotating speed 700-900 rev/min;
B: continue to add remaining Mierocrystalline cellulose, under same rotational speed, disperse 3-5 minute, Mierocrystalline cellulose adds film coalescence aid, propylene glycol, biocide mildewcide successively after breaing up completely, and stirring velocity 700-900 rev/min is disperseed 2-5 minute, finally add organosilicon crylic acid latex, make true mineral varnish slurry.
3. waterborne multicolor true stone paint complex building exterior coating according to claim 1, is characterized in that, described colorful color point comprises following component raw material and mass percent:
Protection glue solution 50-60%,
Base paint 40-50% of all kinds,
Base paint of all kinds is the base paint of the different colours color dot of allotment, and the preparation process of described colorful color point is:
A: first described protection glue solution is joined in reactor, use three leaf dispersion impellers of cutting type to stir, control speed is under 100-200 rev/min, by web plate, base paint of all kinds is joined in reactor successively, stir 3-10 minute, reach required color dot size, make mixture;
B: then gained mixture is crossed to screen cloth, reach final required color dot size, soak 10-24 hour, make color dot reach required hardness.
4. waterborne multicolor true stone paint complex building exterior coating according to claim 3, is characterized in that, in base paint, the mass percent of each component is as follows:
Wherein, described response type protection glue is that weight ratio is the protection glue solution of 6-10%; Described Mierocrystalline cellulose is non-ionic type Mierocrystalline cellulose; Described defoamer adopts aqueous medium versatility mineral oil defoaming agent;
The preparation process of base paint of all kinds is:
A: soft water is poured in reactor, controlled rotating speed at 400-600 rev/min, add Mierocrystalline cellulose, dispersion agent, defoamer to stir 3-5 minute;
B: titanium dioxide, calcined kaolin, pH adjusting agent are dropped into reactor successively, control rotating speed and stir 20-30 minute under 1000-1200 rev/min;
C: 100-200 order quartz sand and 200 order quartz sands and mildew-resistant algaecide, flexible silicon acrylic emulsion are dropped into reactor, control rotating speed and stir 3-5 minute under 700-900 rev/min;
D: under 700-900 rev/min of rotating speed, add response type protection glue, wetting agent to reactor, stir 5-10 minute, make base paint;
E: according to the color of marble grouan, add required aqueous color paste in above-mentioned base paint, be deployed into needed color, make base paint of all kinds.
5. waterborne multicolor true stone paint complex building exterior coating according to claim 4, is characterized in that: described protection glue solution comprises the following raw material that is calculated in mass percent calculation:
The preparation process of described protection glue solution is:
A: soft water is dropped into reactor, control rotating speed at 400-600 rev/min, drop into sequestrant and disperse 3-5 minute;
B: drop into trisodium phosphate to reactor, stir 3-5 minute under same rotational speed;
C: drop into protection rubber powder to reactor, stir 20-30 minute under same rotational speed, according to the addition of the soft or hard extent control protection rubber powder of color dot, addition is more, and the hardness of color dot is harder.
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Cited By (10)

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Publication number Priority date Publication date Assignee Title
CN104910737A (en) * 2015-06-23 2015-09-16 陈良伢 Water-based composite multicolor natural stone external wall paint
CN106699007A (en) * 2017-01-05 2017-05-24 辽阳意邦新型建材集团有限公司 Preparation method of real mineral varnish and real mineral varnish prepared thereby
CN107236459A (en) * 2017-06-05 2017-10-10 山东华德隆建材科技有限公司 Colorful former stone stone-like coating
CN109988472A (en) * 2019-03-04 2019-07-09 江西赛宝莉实业有限公司 A kind of hilllock mineral varnish of 5D and preparation method thereof
CN109988474A (en) * 2019-04-03 2019-07-09 福建菲特普环保科技有限公司 A kind of early stage excellent water resistance water burnt-in sand multicolor finish
CN110756100A (en) * 2019-11-07 2020-02-07 杭小洁 Real stone paint preparation system, preparation process and components thereof
CN111410885A (en) * 2020-05-12 2020-07-14 安徽绿梦佳涂料有限公司 Water-based colorful real stone paint
CN111807759A (en) * 2019-04-10 2020-10-23 广东顺德派齐新材料有限公司 Novel sand-containing multicolor paint and preparation method thereof
CN115926559A (en) * 2022-11-10 2023-04-07 浙江添艺新材料有限公司 Anti-aging batch-scraping type colorful stone-like paint and preparation method thereof
CN116239902A (en) * 2022-12-30 2023-06-09 成都富思特新材料有限公司 High-coverage stone-like paint and preparation method thereof

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CN102617071A (en) * 2012-03-23 2012-08-01 尚怀兴 High-gloss real stone lacquer and marble simulation lacquer
CN102634257A (en) * 2012-05-18 2012-08-15 天津市荣新建筑装饰涂料有限公司 Environment-friendly aqueous multicolor paint and preparation method thereof

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CN102617071A (en) * 2012-03-23 2012-08-01 尚怀兴 High-gloss real stone lacquer and marble simulation lacquer
CN102634257A (en) * 2012-05-18 2012-08-15 天津市荣新建筑装饰涂料有限公司 Environment-friendly aqueous multicolor paint and preparation method thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104910737A (en) * 2015-06-23 2015-09-16 陈良伢 Water-based composite multicolor natural stone external wall paint
CN106699007A (en) * 2017-01-05 2017-05-24 辽阳意邦新型建材集团有限公司 Preparation method of real mineral varnish and real mineral varnish prepared thereby
CN106699007B (en) * 2017-01-05 2019-01-29 辽宁意邦新型材料科技集团有限公司 A kind of preparation method and lacquer obtained by this method of lacquer
CN107236459A (en) * 2017-06-05 2017-10-10 山东华德隆建材科技有限公司 Colorful former stone stone-like coating
CN109988472A (en) * 2019-03-04 2019-07-09 江西赛宝莉实业有限公司 A kind of hilllock mineral varnish of 5D and preparation method thereof
CN109988474A (en) * 2019-04-03 2019-07-09 福建菲特普环保科技有限公司 A kind of early stage excellent water resistance water burnt-in sand multicolor finish
CN111807759A (en) * 2019-04-10 2020-10-23 广东顺德派齐新材料有限公司 Novel sand-containing multicolor paint and preparation method thereof
CN110756100A (en) * 2019-11-07 2020-02-07 杭小洁 Real stone paint preparation system, preparation process and components thereof
CN110756100B (en) * 2019-11-07 2022-07-22 河南七彩异涂新材料科技有限公司 Real stone paint coating preparation system, preparation process and components thereof
CN111410885A (en) * 2020-05-12 2020-07-14 安徽绿梦佳涂料有限公司 Water-based colorful real stone paint
CN115926559A (en) * 2022-11-10 2023-04-07 浙江添艺新材料有限公司 Anti-aging batch-scraping type colorful stone-like paint and preparation method thereof
CN116239902A (en) * 2022-12-30 2023-06-09 成都富思特新材料有限公司 High-coverage stone-like paint and preparation method thereof

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