CN104087103A - Liquid aqueous multi-color granite coating and preparation method thereof - Google Patents
Liquid aqueous multi-color granite coating and preparation method thereof Download PDFInfo
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- CN104087103A CN104087103A CN201410334190.0A CN201410334190A CN104087103A CN 104087103 A CN104087103 A CN 104087103A CN 201410334190 A CN201410334190 A CN 201410334190A CN 104087103 A CN104087103 A CN 104087103A
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Abstract
The invention discloses a liquid aqueous multi-color granite coating and a preparation method thereof, for solving the problems that a conventional aqueous granite coating is severely thickened after a multi-color coating is stored, and is large in viscosity and has easily damaged constructed multi-color particles. The liquid aqueous multi-color granite coating is prepared from the following raw materials in parts by weight: 23.0-27.0 parts of silicone acrylic emulsion, 1.0-2.0 parts of propylene glycol, 1.0-2.0 parts of filming agent, 0.1-0.3 part of defoaming agent, 8.0-14.8 parts of water, 0.1-0.3 part of preservative, 0.1-0.3 part of thickening agent and 58.0-62.0 parts of multi-color particles. According to the coating, multi-color paint protecting glue is used together with special resins, elastic emulsion and silicone acrylic emulsion special for multi-color paint, the reaction gel degrees of different components are controlled to achieve relative balance of a system, the coating is free of color bleeding phenomenon after being stored for a long time and is clear and definite in color particle after being sprayed, the later thickening phenomenon of the stored liquid aqueous multi-color granite coating is effectively solved, and the storage and construction stability is improved.
Description
Technical field
The invention belongs to building coating technical field, relate in particular to a kind of liquid aqueous seven color granite coatings and preparation method thereof.
Background technology
Mostly most of water granite paints in the market, be to be made with one protection glue, store the bleeding of color grain, multicolor finish after thickening serious, viscosity is large, the color grain of construction cracky.Meanwhile, water granite paint self poor water resistance, stain resistance deficiency, while being used to outdoor body of wall, surface becomes easily infected by dust earth, artificial clean more difficult.
Summary of the invention
The object of the present invention is to provide a kind of good stability, liquid aqueous seven color granite coatings that fidelity is high and preparation method thereof, serious with thickening after solving the storage multicolor finish that existing water granite paint exists, viscosity is large, the problem of the color grain of construction cracky.
Another object of the present invention is to provide a kind of preparation method of liquid aqueous seven color granite coatings.
For achieving the above object, the technical scheme that the present invention takes is: a kind of liquid aqueous seven color granite coatings, be prepared from by following raw materials according: 23.0～27.0 parts of organosilicon crylic acid latexs, 1.0～2.0 parts of propylene glycol, 1.0～2.0 parts of film coalescence aid, 0.1～0.3 part of defoamer, 8.0～14.8 parts, water, 0.1～0.3 part of sanitas, 0.1～0.3 part of thickening material, 58.0～62.0 parts, colorful particle
Described colorful particle is prepared from by following raw materials according: 53.0～57.0 parts, water, 0.2～0.4 part of defoamer, 0.1～0.3 part of sanitas, 0.3～0.5 part of wetting dispersing agent, 1.0～2.0 parts of titanium dioxides, 15.0～19.0 parts of calcined kaolins, 2.0～3.0 parts of Special Resins, 0.1～0.3 part of pH adjusting agent; 18.0～22.0 parts of elastic emulsions, 2.0～3.8 parts of G-30 protection glues.
Preferably, described defoamer is the one in the SN-NXZ of Nuo Pu section defoamer, Bi Ke BYK-024 defoamer or Bi Ke BYK-033 defoamer.
Preferably, described sanitas is the one in ROHM AND HAAS LXE sanitas, the modest MB-11 sanitas of moral or the modest MB-16 sanitas of moral.
Preferably, described wetting dispersing agent is the one in A-4 wetting agent, EML-7383 wetting agent or X-405 wetting agent.
The preparation method of above-mentioned a kind of liquid aqueous seven color granite coatings, comprises the following steps:
Steps A, preparation G-30 protection glue: in equipment, adding weight ratio is 93% water, starts stirring, slowly adding weight ratio is 7% G-30 protection glue, stirs 30 minutes;
Step B, prepare base paint: in equipment, add successively water, defoamer, sanitas and wetting dispersing agent, start stirring, disperse 5-15 minute with turn/min of 700-900, then slowly add successively titanium dioxide and kaolin, disperse 15-25min with turn/min of 1100-1300, add successively Q-25 Special Resin, pH adjusting agent, disperse 25-35min, the G-30 protection glue that finally adds elastic emulsion and steps A to prepare, disperses 5-10min;
Step C, prepares colorful particle: in the obtained base paint of step B, add mill base, then add 7%G-30 protection glue, start dispersion impeller, cut into turn/min of 200-400 the particle that requires specification;
Step D, the preparation of water-soluble colorful coating: add successively organosilicon crylic acid latex, propylene glycol in equipment, start stirring, by turn/min of velocity modulation 400-600, add film coalescence aid, dispersed with stirring 5-15 minute, add successively defoamer, water, sanitas, thickening material, stir 5-15min, finally add the prepared colorful particle of step C, obtain liquid aqueous seven color grouan coating products.
Liquid aqueous seven color granite coatings are that liquid water-base resin wraps up jellied hydrate colour particle, and be suspended in equably in specific water based emulsion liquid, finally form the liquid gluey multipolymer of polymer colourful, that granular size is random, pass through disposable spray finishing, can present the decorative pattern of multicolour simultaneously, a lot of colored particle are interlaced, are described as " seamless wallpaper ", particularly in high-grade internal wall finishing, are used widely in internal wall finishing field.
Liquid aqueous seven color granite coatings due to lightweight, unit construction area consumption is few, can not increase the load pressure of buildings, the danger that more tool does not come off, there is the outward appearance of lithotome, have splendid weathering resistance, general case can not faded, and keeps long-term cleaning with ornamental.
The preparation method of liquid aqueous seven color granite coatings provided by the invention, the multi-color lacquer protection glue adopting is anionic colloid, it is white powder, nonpoisonous and tasteless, water insoluble, be insoluble in the organic solvents such as ethanol, become the colloid of suspension but can expand in water, the aquation dispersion liquid shape that is translucent; Itself and Special Resin and Ahmedabad emulsion full of elasticity and organosilicon crylic acid latex collocation are used, have better viscosity and stability, the long time stored bleeding phenomenon that there will not be of products obtained therefrom, compared with traditional aqueous colorful granite coating, the natural and tripping completely blending of the paint film that these liquid aqueous seven color granite coatings form through construction grouan texture after construction, clear between look grain, clearly demarcated, any surface finish, soft, film is tough and tensile, height adheres to, do not chap, high weather-proof temperature resistance becomes, high resistant easy cleaning, self-cleaning function is strong.Efficiently solve the rear thickening phenomenon that liquid aqueous seven color granite coatings occur in storage, improved storage, construction stability.
Liquid aqueous seven color granite coatings prepared by the inventive method, have following beneficial effect:
Liquid aqueous seven color granite coatings through construction become paint film water tolerance: carry out performance test according to chemical industry standard HG/T4343-2012, compound coating is after soak test, coating does not occur bubbling, ftractures, peels off, dry linting, obviously variable color, the obvious defects of film coating phenomenon such as loss of gloss, compared with before test, color is unchanged.These liquid aqueous seven color grouan coating applications, after building surface film forming, can not peel off because of rain drop erosion variable color.
2. artificial ageing resistance: carry out performance test according to chemical industry standard HG/T4343-2012, made paint film 1000h is non-foaming, do not peel off, flawless, without efflorescence, without obviously variable color, without obvious loss of gloss.These liquid aqueous seven color grouan coating products through construction film forming after, can not drench with rain because exposing to the weather fade, efflorescence.
By the liquid aqueous seven color grouan coating products that prepare according to method provided by the invention, carry out performance test according to chemical industry standard HG/T4343-2012, result is as table 1:
Embodiment
In order further to understand the present invention, below in conjunction with example, the preferred embodiment of the invention is described, still, it is in order further to show advantages and features of the invention that these examples are described, instead of limits claim of the present invention.
In following embodiment, unspecified material is and is purchased.Wherein protecting glue is the firm G-30 of the having protection in Shanghai glue; elastic emulsion is rich BATF 2788 elastic emulsions of Ahmedabad; wetting dispersing agent is that the firm A-4 of the having wetting agent in Shanghai, Shanghai become EML-7383 wetting agent or Tao Shi X-405 wetting agent; titanium dioxide is the general R-2196 Rutile type Titanium Dioxide of Wuxi person of outstanding talent; kaolin is interior drizzly western superfine calcined kaolin; pH adjusting agent is the multi-functional auxiliary agent of camine328, Tao Shi AMP-95pH conditioning agent or the modest DMAE water-based of moral amine neutralizing agent, and thickening material selects the firm Q-25 of the having Special Resin of Tao Shi AP-10 thickening material or Shanghai thickening material.Mill base is that iron oxide or phthalocyanine are mill base of all kinds.
Embodiment 1
1. preparation 7%G-30 protection glue: add water 279.0kg in equipment, start stirring, slowly add G-30 protection glue 21.0kg, stir 30 minutes with 1200 turn/min;
2. prepare base paint: in equipment, add successively water 165.0kg, Nuo Puke SN-NXZ defoamer 1.2kg, ROHM AND HAAS LXE sanitas 0.9kg and Shanghai is firm A-4 wetting dispersing agent 0.9kg, start stirring, disperse 10 minutes with 800 turn/min, then slowly add successively the Wuxi general R-2196 Rutile type Titanium Dioxide 4.5kg of person of outstanding talent and interior drizzly western superfine calcined kaolin 57.0kg, disperse 20min with 1200 turn/min, add successively the multi-functional pH adjusting agent 0.3kg of the Shanghai firm Q-25 of having Special Resin thickening material 7.5kg and camine328, disperse 30min, finally add the rich BATF 2788 elastic emulsion 54.0kg of Ahmedabad and 7%G-30 protection glue 8.7kg, disperse 5min,
3. the colorful particle of preparation: iron oxide mill base in the obtained base paint of step 2 as required, be modulated into base paint of all kinds, in base paint of all kinds, add 7%G-30 protection glue by weight 1:1 again, start dispersion impeller, cut into 300 turn/min that to require each colored particle of specification to amount to 580.0kg for subsequent use;
4. the preparation of water-soluble colorful coating: add successively the rich BATF 4937A organosilicon crylic acid latex 230.0kg of Ahmedabad and propylene glycol 20.0kg in equipment, start stirring, by turn/min of velocity modulation 500, add film coalescence aid 15.0kg, dispersed with stirring 10 minutes, add successively the SN-NXZ of Nuo Pu section defoamer 3.0kg, water 148.0kg, ROHM AND HAAS LXE sanitas 1.0kg and Tao Shi AP-10 thickening material 3.0kg, stir 10min, finally add the prepared of all kinds colorful particle 580.0kg of step 3, obtain liquid aqueous seven color grouan coating products.
Embodiment 2
1. preparation 7%G-30 protection glue: add water 297.6kg in equipment, start stirring, slowly add G-30 protection glue 22.4kg, stir 30 minutes with 1200 turn/min;
2. prepare base paint: in equipment, add successively water 159.0kg, Bi Ke BYK-024 defoamer 0.9kg, the modest MB-11 sanitas of moral 0.6kg becomes EML-7383 wetting agent 1.5kg with Shanghai, start stirring, disperse 5 minutes with 700 turn/min, then slowly add successively the Wuxi general R-2196 Rutile type Titanium Dioxide 3.0kg of person of outstanding talent and interior drizzly western superfine calcined kaolin 51.0kg, disperse 15min with 1100 turn/min, add successively the Shanghai firm Q-25 of having Special Resin thickening material 6.0kg and Tao Shi AMP-95pH conditioning agent 0.6kg, disperse 25min, finally add the rich BATF 2788 elastic emulsion 66.0kg of Ahmedabad and 7%G-30 protection glue 11.4kg, disperse 5min,
3. the colorful particle of preparation: adding phthalocyanine as required in the obtained base paint of step 2 is mill base, be modulated into base paint, in base paint of all kinds, add 7%G-30 protection glue by weight 1:1 again, start dispersion impeller, cut into 200 turn/min that to require each colored particle of specification to amount to 600.0kg for subsequent use;
4. the preparation of water-soluble colorful coating: add successively the rich BATF 4937A organosilicon crylic acid latex 250.0kg of Ahmedabad and propylene glycol 10.0kg in equipment, start stirring, by turn/min of velocity modulation 400, add film coalescence aid 20.0kg, dispersed with stirring 5 minutes, add successively Bi Ke BYK-024 defoamer 1.0kg, water 114kg, moral modest MB-11 sanitas 3.0kg and Tao Shi AP-10 thickening material 2.0kg, stir 10min, finally add the prepared of all kinds colorful particle 600.0kg of step 3, obtain liquid aqueous seven color grouan coating products.
Embodiment 3
1. preparation 7%G-30 protection glue: add water 372.0kg in equipment, start stirring, slowly add G-30 protection glue 28.0kg, stir 30 minutes with 1200 turn/min;
2. prepare base paint: in equipment, add successively water 228.0kg, Bi Ke BYK-033 defoamer 0.8kg, moral modest MB-16 sanitas 0.4kg and Tao Shi X-405 wetting agent 1.6kg, start stirring, disperse 15 minutes with 900 turn/min, then slowly add successively the Wuxi general R-2196 Rutile type Titanium Dioxide 8.0kg of person of outstanding talent and interior drizzly western superfine calcined kaolin 60.0kg, disperse 25min with 1300 turn/min, add successively the Shanghai firm Q-25 of having Special Resin thickening material 12.0kg and the modest DMAE water-based of moral amine neutralizing agent 1.2kg, disperse 35min, finally add the rich BATF 2788 elastic emulsion 80.0kg of Ahmedabad and 7%G-30 protection glue 8.0kg, disperse 10min,
3. the colorful particle of preparation: add iron oxide mill base as required in the obtained base paint of step 2, be modulated into base paint of all kinds, in base paint of all kinds, add 7%G-30 protection glue by weight 1:1 again, start dispersion impeller, cut into 600 turn/min that to require each colored particle of specification to amount to 620.0kg for subsequent use;
4. the preparation of water-soluble colorful coating: add successively the rich BATF 4937A organosilicon crylic acid latex 270.0kg of Ahmedabad and propylene glycol 15.0kg in equipment, start stirring, by turn/min of velocity modulation 600, add film coalescence aid 10.0kg, dispersed with stirring 10 minutes, add successively Bi Ke BYK-033 defoamer 2.0kg, water 80.0kg, moral modest MB-16 sanitas 2.0kg and Tao Shi AP-10 thickening material 1.0kg, stir 15min, finally add the prepared of all kinds colorful particle 620.0kg of step 3, obtain liquid aqueous seven color grouan coating products.
Claims (5)
1. liquid aqueous seven color granite coatings, it is characterized in that it is prepared from by following raw materials according: 23.0～27.0 parts of organosilicon crylic acid latexs, 1.0～2.0 parts of propylene glycol, 1.0～2.0 parts of film coalescence aid, 0.1～0.3 part of defoamer, 8.0～14.8 parts, water, 0.1～0.3 part of sanitas, 0.1～0.3 part of thickening material, 58.0～62.0 parts, colorful particle
Described colorful particle is prepared from by following raw materials according: 53.0～57.0 parts, water, 0.2～0.4 part of defoamer, 0.1～0.3 part of sanitas, 0.3～0.5 part of wetting dispersing agent, 1.0～2.0 parts of titanium dioxides, 15.0～19.0 parts of calcined kaolins, 2.0～3.0 parts of Special Resins, 0.1～0.3 part of pH adjusting agent; 18.0～22.0 parts of elastic emulsions, 2.0～3.8 parts of G-30 protection glues.
2. the liquid aqueous seven color granite coatings of one according to claim 1, is characterized in that: described defoamer is the one in the SN-NXZ of Nuo Pu section defoamer, Bi Ke BYK-024 defoamer or Bi Ke BYK-033 defoamer.
3. the liquid aqueous seven color granite coatings of one according to claim 1, is characterized in that: described sanitas is the one in ROHM AND HAAS LXE sanitas, the modest MB-11 sanitas of moral or the modest MB-16 sanitas of moral.
4. the liquid aqueous seven color granite coatings of one according to claim 1, is characterized in that: described wetting dispersing agent is the one in A-4 wetting agent, EML-7383 wetting agent or X-405 wetting agent.
5. the preparation method of a kind of liquid aqueous seven color granite coatings claimed in claim 1, is characterized in that it comprises the following steps:
Steps A, preparation G-30 protection glue: in equipment, adding weight ratio is 93% water, starts stirring, slowly adding weight ratio is 7% G-30 protection glue, stirs 30 minutes;
Step B, prepare base paint: in equipment, add successively water, defoamer, sanitas and wetting dispersing agent, start stirring, disperse 5-15 minute with turn/min of 700-900, then slowly add successively titanium dioxide and kaolin, disperse 15-25min with turn/min of 1100-1300, add successively Q-25 Special Resin, pH adjusting agent, disperse 25-35min, the G-30 protection glue that finally adds elastic emulsion and steps A to prepare, disperses 5-10min;
Step C, prepares colorful particle: in the obtained base paint of step B, add mill base, then add 7%G-30 protection glue, start dispersion impeller, cut into turn/min of 200-400 the particle that requires specification;
Step D, the preparation of water-soluble colorful coating: add successively organosilicon crylic acid latex, propylene glycol in equipment, start stirring, by turn/min of velocity modulation 400-600, add film coalescence aid, dispersed with stirring 5-15 minute, add successively defoamer, water, sanitas, thickening material, stir 5-15min, finally add the prepared colorful particle of step C, obtain liquid aqueous seven color grouan coating products.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106047177A (en) * | 2016-06-26 | 2016-10-26 | 余林岚 | Waterborne multi-colored diagonal-stone-imitated coating and production and spraying methods thereof |
| CN106634323A (en) * | 2016-09-23 | 2017-05-10 | 甘肃连心涂料有限责任公司 | Preparation method of multi-colour |
| CN108192448A (en) * | 2018-01-05 | 2018-06-22 | 吕跃文 | Aqueous forest negative oxygen ion artificial granite paint and preparation method thereof |
| CN108373700A (en) * | 2016-10-28 | 2018-08-07 | 贵州省漆彩金州涂料有限公司 | A kind of exterior wall paint and preparation method thereof |
| CN109504207A (en) * | 2017-09-15 | 2019-03-22 | 万华化学（宁波）有限公司 | A kind of water-soluble colorful coating and preparation method thereof |
| CN114395330A (en) * | 2021-12-01 | 2022-04-26 | 河北三棵树涂料有限公司 | Preparation method of high-humidity-adhesion liquid granite coating |
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| CN101525506A (en) * | 2009-04-03 | 2009-09-09 | 富思特制漆（北京）有限公司 | Liquid granite paint and preparing method thereof |
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2014
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| CN103254709A (en) * | 2013-04-11 | 2013-08-21 | 三棵树涂料股份有限公司 | Two-component emulsion water-in-water multi-color paint and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106047177A (en) * | 2016-06-26 | 2016-10-26 | 余林岚 | Waterborne multi-colored diagonal-stone-imitated coating and production and spraying methods thereof |
| CN106634323A (en) * | 2016-09-23 | 2017-05-10 | 甘肃连心涂料有限责任公司 | Preparation method of multi-colour |
| CN108373700A (en) * | 2016-10-28 | 2018-08-07 | 贵州省漆彩金州涂料有限公司 | A kind of exterior wall paint and preparation method thereof |
| CN109504207A (en) * | 2017-09-15 | 2019-03-22 | 万华化学（宁波）有限公司 | A kind of water-soluble colorful coating and preparation method thereof |
| CN108192448A (en) * | 2018-01-05 | 2018-06-22 | 吕跃文 | Aqueous forest negative oxygen ion artificial granite paint and preparation method thereof |
| CN114395330A (en) * | 2021-12-01 | 2022-04-26 | 河北三棵树涂料有限公司 | Preparation method of high-humidity-adhesion liquid granite coating |
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Application publication date: 20141008 |