CN106366814B - One kind is containing colorful environmental protection coating material of sand mold and preparation method thereof - Google Patents
One kind is containing colorful environmental protection coating material of sand mold and preparation method thereof Download PDFInfo
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- CN106366814B CN106366814B CN201610726195.7A CN201610726195A CN106366814B CN 106366814 B CN106366814 B CN 106366814B CN 201610726195 A CN201610726195 A CN 201610726195A CN 106366814 B CN106366814 B CN 106366814B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to one kind containing colorful environmental protection coating material of sand mold and preparation method thereof; it is made of pigment component, decentralized medium and varnish, pigment component includes RO water, cellulose, dispersing agent, pigments and fillers, defoaming agent, coalescing agent, lotion, antifreezing agent, inorganic protection sol solution, PH regulator, fungicide, the first thickener and natural colour sand；Decentralized medium includes RO water, coalescing agent, rheological agent, lotion, organic protection sol solution, defoaming agent and coupling agent；Varnish includes RO water, lotion, PH regulator, fungicide, defoaming agent, coalescing agent, antifreezing agent and the second thickener.Compared with prior art, the storage of the colorful environmental protection coating material produced by the present invention containing sand mold and construction stability are good, the adhesive force and water resistance excellent performance of dry film, product use process, rough to feel, multicolor finish is well arranged, can preferably show the grain effect of lithotome.
Description
Technical field
The present invention relates to a kind of coating, more particularly, to one kind containing colorful environmental protection coating material of sand mold and preparation method thereof.
Background technique
Natural granite is used just gradually to be eliminated as Discussion on architecture decoration for vertical face material, due to opening for lithotome
It adopts tired, destruction of the exploitation to natural environment and the pollution to environment, the natural color difference of stone material source mine and steel hangs the peace of stone material
The factors such as full property difference, with paint pattern replace the pattern effect of natural granite by however it is raw.
Water-soluble colorful coating is the hot spot product for applying to architecture inside and outside decoration paint field in recent years, and decorative effect is prominent
Out, multicolour decorative pattern can be presented after dry by disposable spray finishing in emulsion paint or quartzy color sand paint surface in product simultaneously,
Vivid effect is true to nature, has similar to the exterior decorative effect as granite.Compared to natural granite, there is very big price
Advantage can save trimming cost, while the dope layer is thin light, and construction technology is simple, safety and the feature of environmental protection and natural cladding
Stone material is highly suitable to be applied for top-grade building object such as office building, hotel, household, hospital and not compared to all greatly improving
The decoration of alien invasion in villa etc. helps to promote building figure image and class.
Water-soluble colorful coating product is good in existing market lures uneven, and prior art material is only played without flexibility, product
Decorative performance and ignore whole weather resistance, the rough sense of product is insufficient, and multicolor finish stereovision fuzzy can not really embody
Stone texture effect, product stable storing degree is inadequate, is easy between color spot because being gelatinized after thickening.
Summary of the invention
It is an object of the present invention to overcome the above-mentioned drawbacks of the prior art and provide a kind of color layerings point
Bright, adhesive force it is strong containing colorful environmental protection coating material of sand mold and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of colorful environmental protection coating material containing sand mold, is made of, the pigment component packet pigment component, decentralized medium and varnish
Following component and parts by weight content: RO water 23-40, cellulose 0.7-2.0, dispersing agent 0.1-0.3, pigments and fillers 5-15 are included, is defoamed
Agent 0.05-0.3, coalescing agent 0.5-2, lotion 15-30, antifreezing agent 0.5-1.5, inorganic protection sol solution 3-10, PH regulator
0.15-0.4, fungicide 0.15-0.4, the first thickener 1-5, natural colour sand 20-50；
The decentralized medium includes following component and parts by weight content: RO water 20-85, coalescing agent 0.3-0.8, rheology
Agent 0.2-0.5, lotion 5-10, organic protection sol solution 10-30, defoaming agent 0.1-0.3, inorganic protection sol solution 5-50, coupling
Agent 0.5-1.0；
The varnish includes following component and parts by weight content: RO water 13-40, lotion 60-80, PH regulator 0.1-
0.3, fungicide 0.1-0.3, defoaming agent 0.1-0.2, coalescing agent 0.6-3, antifreezing agent 0.8-1.5, the second thickener 0.8-2.
Organic protection sol solution is organic cellulose ether compound, fine selected from hydroxyethyl cellulose, carboxymethyl
One or more mixtures of dimension element or polyanion cellulose, the inorganic protection sol solution are lithium magnesium silicate aqueous solution.
The cellulose Wei Kong cellulose ether, the dispersing agent are hydrophobic copolymer sodium salt dispersing agent.
The pigments and fillers be selected from calcined kaolin, coarse whiting, mica powder, talcum powder or rutile type titanium white one kind or
A variety of mixtures.
The defoaming agent is one or two kinds of mixtures of modified polyorganosiloxane or organic-silicon-modified mineral oil, described
Coalescing agent is Lauryl Alcohol ester, and the fungicide is the nitrogen thia cyclics without organic volatile.
The lotion is waterborne acrylic, organosilicon waterborne acrylic or waterborne polyurethane resin
One or more mixtures, the coupling agent are titanate coupling agent.
The antifreezing agent is propylene glycol, and the PH regulator is 2-amino-2-methyl-1-propanol, the rheology
Agent is silica.
First thickener is hydroxypropyl-trimethyl ammonium chloride, and second thickener is hydrophobically modified alkali solubility
One or more mixtures of emulsion-type thickening agent or association type polyurethane thickener.
The preparation method of the colorful environmental protection coating material containing sand mold, specifically includes the following steps:
(1) pigment component is prepared
It stocks up by formula, cellulose is added in RO water, stir 10-20min, control stirring rate is 1000-
1200rpm after sequentially adding dispersing agent, pigments and fillers, defoaming agent, stirs 25-35min；Sequentially add coalescing agent, antifreeze
Agent, lotion, inorganic protection sol solution, PH regulator, fungicide, natural colour sand and the first thickener, control stirring rate are
800-1000rpm stirs 5-15min to get pigment component；
(2) decentralized medium is prepared
It stocks up by formula, rheological agent and coalescing agent is sequentially added in RO water, control stirring rate is 1000-
1200rpm stirs 5-15min；Sequentially add lotion, organic protection sol solution, defoaming agent, inorganic protection sol solution and coupling
Agent, control stirring rate are 800-1000rpm, stir 5-15min to get decentralized medium；
(3) varnish is prepared
It stocks up by formula, lotion is added in RO water, control mixing speed is 500-800rpm, stirs 5-15min；Again according to
Secondary addition PH regulator, fungicide, defoaming agent, antifreezing agent and coalescing agent are eventually adding the second thickener, mixing speed control
For 900-1200rpm, 5-15min is stirred to get varnish；
(4) preparation of the colorful environmental protection coating material containing sand mold
A variety of different pigment components made from step (1) are added separately in decentralized medium made from step (2), point
Dispersion media coats pigment component, is then granulated, stands, finally adds varnish made from step (3), stir evenly to obtain the final product
It containing the colorful environmental protection coating material of sand mold, is granulated using sieve, time of repose 4-8h.
Compared with prior art, the colorful environmental protection coating material prepared by the present invention containing sand mold, using decentralized medium to pigment component
It is coated, in addition to adding the inorganic protection sol solution of lithium magnesium silicate class in a dispersion medium, is imitated using the steric hindrance that it has
Should come protect the base paint particle of different color mix can storage-stable, be unlikely to colour mixture even different color particle melt
It is combined into except single color material, also adds organic protective glue and carry out coordinated, organic protective glue auxiliary increases inorganic protection
The space steric effect of glue, while certain lubricant effect being provided, better space steric effect is provided for pigment component, is made more
The pigment component of kind color will not generate showing for colour contamination during production and storage because of contact between color spot and color spot
As, ensure that the storage stability of the colorful environmental protection coating material containing sand mold and construction stability are more preferable in this way, and the adhesive force of dry film with
The performances such as water resistance are more excellent, and product use process, rough to feel, multicolor finish is well arranged, show natural stone well
The grain effect of material.
Existing coating is added to too many inorganic gel class material, often due to realizing stability requirement in formula
Lead to the disadvantages of water penetration is higher, anti-accumulation of salt in the surface soil ability is poor and paint film is partially crisp, while colorful color spot is smaller, fidelity and moulding are certainly
It is greatly lowered by degree, colorful environmental protection coating material individual packages prepared by the present invention, in specific spraying before use, again and emulsion components
It is mixed into a set of finished product, is sprayed after mixing, this mode enhances storage stability, while reaching the excellent property of paint film after construction
Can, avoid the above problem；The present invention also by adding thickener hydroxypropyl-trimethyl ammonium chloride in pigment component, utilizes crosslinking
Reaction principle makes the surface of pigment component form reticular structure, enhance the stability of the colorful environmental protection coating material containing sand mold, appearance and
Dry film performance keeps the formula of the colorful environmental protection coating material containing sand mold and technique more accurate, rigorous, reliable.
Specific embodiment
The present invention is described in detail combined with specific embodiments below.
Embodiment 1-3 and comparative example 1
The ingredient of embodiment 1-3 and comparative example 1 is as shown in table 1, table 2, wherein cellulose Cai Yong Kong cellulose ether；
Dispersing agent is hydrophobic copolymer sodium salt dispersing agent；Pigments and fillers are calcined kaolin, coarse whiting, mica powder, talcum powder or rutile-type
Titanium dioxide；Defoaming agent is modified polyorganosiloxane；Coalescing agent is Lauryl Alcohol ester；Lotion is waterborne acrylic；It is antifreeze
Agent is propylene glycol；PH regulator is 2-amino-2-methyl-1-propanol；Fungicide is the nitrogen sulphur heterocyclic without organic volatile
Compound；Rheological agent is silica；Coupling agent is titanate coupling agent；Inorganic protection sol solution is lithium magnesium silicate aqueous solution；
First thickener is hydroxypropyl-trimethyl ammonium chloride；Second thickener is hydrophobically modified alkali-soluble emulsion type thickener；Organic guarantor
Shield sol solution is hydroxyethyl cellulose.
1 embodiment 1-3 of table, 1 pigment component of comparative example and varnish ingredient
2 decentralized medium ingredient of table
| Component | Comparative example 1 | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| RO water | 85 | 75 | 65 | 20 |
| Coalescing agent | 0.5 | 0.5 | 0.5 | 0.5 |
| Rheological agent | 0.5 | 0.5 | 0.5 | 0.5 |
| Lotion | 10 | 10 | 10 | 10 |
| Organic protection sol solution | 0 | 10 | 20 | 30 |
| Defoaming agent | 0.2 | 0.2 | 0.2 | 0.2 |
| Inorganic protection sol solution | 5 | 5 | 5 | 40 |
| Coupling agent | 1 | 1 | 1 | 1 |
Specifically prepared using following steps:
(1) pigment component is prepared
It is added cellulose in RO water, stirs 10-20min, control stirring rate is 1000-1200rpm, is sequentially added point
After powder, pigments and fillers, defoaming agent, 25-35min is stirred；Sequentially add coalescing agent, antifreezing agent, lotion, inorganic protection peptization
Liquid, PH regulator, fungicide, natural colour sand and the first thickener, control stirring rate are 800-1000rpm, stir 5-
15min is to get pigment component；
(2) decentralized medium is prepared
Rheological agent and coalescing agent are sequentially added in RO water, control stirring rate is 1000-1200rpm, stirs 5-
15min；Sequentially add lotion, organic protection sol solution, defoaming agent, inorganic protection sol solution and coupling agent, control stirring speed
Rate is 800-1000rpm, stirs 5-15min to get decentralized medium；
(3) varnish is prepared
Lotion is added in RO water, control mixing speed is 500-800rpm, stirs 5-15min；Sequentially add PH tune
Agent, fungicide, defoaming agent, antifreezing agent and coalescing agent are saved, the second thickener is eventually adding, mixing speed control is 900-
1200rpm stirs 5-15min to get varnish；
(4) preparation of the colorful environmental protection coating material containing sand mold
A variety of different pigment components made from step (1) are added separately in decentralized medium made from step (2), point
Dispersion media coats pigment component, is granulated using sieve, stands 4-8h, finally adds varnish made from step (3), stirring
Uniformly up to the colorful environmental protection coating material containing sand mold.
It to above-mentioned finished product, is sprayed through spraying equipment, observe the influence to material and carries out grading evaluation, Storage period is half
Year, storage stability rating result is as shown in table 3,
3 stability rating result of table
| Embodiment title | Spraying effect is commented | Storage stability |
| Comparative example 1 | Difference | Difference |
| Embodiment 1 | It is excellent | It is excellent |
| Embodiment 2 | It is excellent | It is excellent |
| Embodiment 3 | In | In |
National testing agency is sent to detect product made from embodiment 1, performance report is as shown in table 4.
4 survey report of table
By organic protection sol solution of addition different proportion in decentralized medium, to the molding effect and stable storing of color spot
Property have significant impact, when not adding organic protective glue, material can not be formed, color spot paste, organic protection glue amount 10-20 weight
When measuring part, effect is best, and when reaching 30 parts by weight, color spot is partially hard, and overall effect starts to be deteriorated；For storage stability, have
When machine protective glue is not added, material can not be formed, and paste is presented in color spot；With the raising of organic protection glue amount, color spot is stored
There is significant help, after storage 6 months, takes out material to even application, the clear simultaneously ungelatinized of color spot；But with adding for additive amount
When greatly, more than 30 parts by weight, color spot is complete but slightly less than normal, and partially firmly, overall effect is bad.
Embodiment 4-6
Embodiment 4-6 is identical as 1 preparation method of embodiment, specific formula as illustrated in tables 5-7:
5 embodiment 4-6 pigment component formula of table
6 embodiment 4-6 decentralized medium formula of table
7 embodiment 4-6 lacquer formulation of table
It is above-mentioned, cellulose Wei Kong cellulose ether；Dispersing agent is hydrophobic copolymer sodium salt dispersing agent；Pigments and fillers are calcination
Kaolin, coarse whiting, mica powder, talcum powder or rutile type titanium white；Defoaming agent is organic-silicon-modified mineral oil；Coalescing agent is
Lauryl Alcohol ester；Lotion is organosilicon waterborne acrylic；Antifreezing agent is propylene glycol；PH regulator is 2- amino -2- first
Base -1- propyl alcohol；Fungicide is the nitrogen thia cyclics without organic volatile；Rheological agent is silica；Coupling agent is
Titanate coupling agent；First thickener is hydroxypropyl-trimethyl ammonium chloride；Second thickener is association type polyurethane thickener；Nothing
It is lithium magnesium silicate aqueous solution that machine, which protects sol solution, and it is carboxymethyl cellulose that organic polymer, which protects sol solution,.
Claims (8)
1. a kind of colorful environmental protection coating material containing sand mold, which is characterized in that it is made of pigment component, decentralized medium and varnish,
The pigment component includes following component and parts by weight content: RO water 23-40, cellulose 0.7-2.0, dispersing agent 0.1-
0.3, pigments and fillers 5-15, defoaming agent 0.05-0.3, coalescing agent 0.5-2, lotion 15-30, antifreezing agent 0.5-1.5, inorganic protection
Sol solution 3-10, pH adjusting agent 0.15-0.4, fungicide 0.15-0.4, the first thickener 1-5, natural colour sand 20-50；
The decentralized medium includes following component and parts by weight content: RO water 20-85, coalescing agent 0.3-0.8, rheological agent
0.2-0.5, lotion 5-10, organic protection sol solution 10-30, defoaming agent 0.1-0.3, inorganic protection sol solution 5-50, coupling agent
0.5-1.0；
The varnish includes following component and parts by weight content: RO water 13-40, lotion 60-80, pH adjusting agent 0.1-0.3 are killed
Microbial inoculum 0.1-0.3, defoaming agent 0.1-0.2, coalescing agent 0.6-3, antifreezing agent 0.8-1.5, the second thickener 0.8-2；
Organic protection sol solution is organic cellulose ether compound, is selected from hydroxyethyl cellulose, carboxymethyl cellulose
Or one or more mixtures of polyanion cellulose, the inorganic protection sol solution are lithium magnesium silicate aqueous solution；
First thickener is hydroxypropyl-trimethyl ammonium chloride, and second thickener is hydrophobically modified alkali-soluble emulsion
One or two kinds of mixtures of type thickener or association type polyurethane thickener.
2. one kind colorful environmental protection coating material containing sand mold according to claim 1, which is characterized in that the cellulose is hydroxyl second
Base cellulose ether, the dispersing agent are hydrophobic copolymer sodium salt dispersing agent.
3. one kind colorful environmental protection coating material containing sand mold according to claim 1, which is characterized in that the pigments and fillers are selected from forging
Burn one or more mixtures of kaolin, coarse whiting, mica powder, talcum powder or rutile type titanium white.
4. one kind colorful environmental protection coating material containing sand mold according to claim 1, which is characterized in that the defoaming agent is to be modified
One or two kinds of mixtures of polysiloxanes or organic-silicon-modified mineral oil, the coalescing agent is Lauryl Alcohol ester, described
Fungicide be the nitrogen thia cyclics without organic volatile.
5. one kind colorful environmental protection coating material containing sand mold according to claim 1, which is characterized in that the lotion is aqueous third
One or more mixtures of olefin(e) acid system resin, organosilicon waterborne acrylic or waterborne polyurethane resin, the idol
Connection agent is titanate coupling agent.
6. one kind colorful environmental protection coating material containing sand mold according to claim 1, which is characterized in that the antifreezing agent is the third two
Alcohol, the pH adjusting agent are 2-amino-2-methyl-1-propanol, and the rheological agent is silica.
7. a kind of preparation method of the colorful environmental protection coating material containing sand mold as described in claim 1, which is characterized in that specifically include with
Lower step:
(1) pigment component is prepared
It stocks up by formula, cellulose is added in RO water, stir 10-20min, control stirring rate is 1000-1200rpm, according to
After secondary addition dispersing agent, pigments and fillers, defoaming agent, 25-35min is stirred；Sequentially add coalescing agent, antifreezing agent, lotion, inorganic
Sol solution, pH adjusting agent, fungicide, natural colour sand and the first thickener are protected, control stirring rate is 800-1000rpm, is stirred
5-15min is mixed to get pigment component；
(2) decentralized medium is prepared
It stocks up by formula, rheological agent and coalescing agent is sequentially added in RO water, control stirring rate is 1000-1200rpm, is stirred
Mix 5-15min；Lotion, organic protection sol solution, defoaming agent, inorganic protection sol solution and coupling agent, control is sequentially added to stir
Mixing rate is 800-1000rpm, stirs 5-15min to get decentralized medium；
(3) varnish is prepared
It stocks up by formula, lotion is added in RO water, control mixing speed is 500-800rpm, stirs 5-15min；Successively add again
Enter pH adjusting agent, fungicide, defoaming agent, antifreezing agent and coalescing agent, be eventually adding the second thickener, mixing speed control is
900-1200rpm stirs 5-15min to get varnish；
(4) preparation of the colorful environmental protection coating material containing sand mold
A variety of different pigment components made from step (1) are added separately in decentralized medium made from step (2), dispersion is situated between
Confrontation pigment component is coated, and is then granulated, is stood, finally add varnish made from step (3), stirs evenly up to containing sand
The colorful environmental protection coating material of type.
8. the preparation method of the colorful environmental protection coating material according to claim 7 containing sand mold, which is characterized in that step (4) is described
Granulation be granulated using sieve, time of the standing is 4-8h.
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