CN102391767A - High-solid-content interior and exterior crosslinked type water-in-water colorful granite paint and preparation method thereof - Google Patents
High-solid-content interior and exterior crosslinked type water-in-water colorful granite paint and preparation method thereof Download PDFInfo
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Abstract
The invention discloses high-solid-content interior and exterior crosslinked type water-in-water colorful granite paint. The paint comprises a dispersing phase, a dispersing medium and a suspension emulsion, wherein the weight ratio of the dispersing phase to the dispersing medium to the suspension emulsion is (50-60): (20-25): (20-25); the dispersing phase comprises deionized water, bentonite, alkali-tackified aqueous polyurethane resin, a wetting agent, a dispersing agent, a defoaming agent, a filling material, ceramic pigment, a mould proof and antiseptic agent, a film-forming aid and an aqueous isocyanate and an association type rheological agent; the dispersing medium comprises a bentonite solution and alkaline inorganic sol; and the suspension emulsion comprises a PUA (polyurethane acrylate) polyurethane water dispersion or aqueous silicon resin, an association type rheological agent, a mould proof and antiseptic agent and deionized water. The high-solid-content interior and exterior crosslinked type water-in-water colorful granite paint disclosed by the invention is a high-solid-content full-aqueous product obtained by adopting an interior and exterior crosslinking technique and is an environmentally-friendly decoration material having extremely good stability and high coating rate, has the service life more than 10 years and is an idea substitute of marble, granite, rock true mineral varnish and the like.
Description
Technical field
The present invention relates to a kind of high inside and outside colorful granite coating of cross-linking type water bag water that contains admittedly, the invention still further relates to the preparation method of this colorful granite coating.
Background technology
Natural granite is good because of weather resistance, and quality is hard, rich texture, and good endurance, as bright as a sixpence after the wearable optical processing, the decorative effect of magnificent noble quality is arranged and protect effect, in high-grade decoration of exterior wall engineering, use wider.But lithotome is as a kind of hard brittle material, and its material homogeneity is relatively poor, and the flexural strength discreteness is big, in generation, exploitation, the course of processing, can produce some slight and don't detectable internal injuries unavoidably.And excessive exploitation can cause soil erosion, is unfavorable for the protection of ecotope.Though stone material is not born the load of three-dimensional arrangement in the curtain wall process, must bear the influence of load such as deadweight, wind, earthquake and temperature and effect, and seam crossing hides dirt and immersion easily, thereby influence attractive in appearance.Even the stone material that therefore uses meets the regulation of national product standard, but still after the several years, has potential safety hazard unavoidably, and involves great expense, certain radiativity is arranged again, consider from the environmental protection and energy saving aspect, should be downtrending gradually.
People are studying artificial granite coating always and are substituting natural granite, and common artificial granite coating variety mainly contains at present: natural real stone paint, the true mineral varnish of artificial granite, oiliness multicolor finish, color sheet coating.Some is approaching on decorative effect though as the true mineral varnish of one of substitute and the true mineral varnish of artificial granite; Product performance also have performance preferably; But because its main raw material is a natural colour sand, on color is selected, can not follow one's bent, and product itself still exists splitting resistance difference contamination resistance not enough; Shortcomings such as emulation property difference can only be lacked the application of the alternative grouan of part.The oiliness multicolor finish contains organic solvent, and is harmful, is eliminated.
The water-thinned color granite coating that exterior wall in being applied to is also arranged in the market; But adopt simple physics to coat because it is produced, or adopt the outer gel technique of the outer gel technique of zwitterion or colloidal polar material and base paint gelifying agent (the different in nature metals ion on look grain surface), gel reaction time long (needing 2-3 hours) product look grain is stable inadequately; Store easy bleeding, colour contamination; Because what all influence the power of look grain for ionic concentration height and dosage, concentration of metal ions is low more, and color grains is just tiny partially; The coating film of gel formation is just soft partially, is easy to generate the look grain to external phase bleeding and the muddy phenomenon of external phase; Simultaneously the concentration or the addition of gelifying agent metals ion can not be higher, and gel to occur excessive otherwise cross, and particle is hard partially, behind the spraying application between the monochrome particles amalgamation poor, there is similar little skinning on the surface, outward appearance does not resemble the natural granite effect.Finally cause stone material texture poor, and the coating of processing contain low, reasons such as glue spread is low, construction cost height, inreal formation commercialization and industrialization admittedly.
Summary of the invention
Goal of the invention: the objective of the invention is to the deficiency to prior art, provide that a kind of controllability is strong, look grain controlled amount, stability is high, stone material texture is strong height contain the inside and outside colorful granite coating of cross-linking type water bag water admittedly.
Another object of the present invention is to provide this height to contain the preparation method of the inside and outside colorful granite coating of cross-linking type water bag water admittedly.
Technical scheme: height of the present invention contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, comprises disperse phase, dispersion medium and suspension emulsion, and the weight ratio between said disperse phase, dispersion medium and the suspension emulsion is 50～60:20～25:20～25; Wherein, said disperse phase comprises: 5～15 parts of deionized waters, 1～2 part of wilkinite, 40～60 parts of alkali tackify waterborne polyurethane resins; Wetting agent 0.1--～0.2 part, 0.3～0.5 part of dispersion agent, 0.1～0.3 part of skimmer, 15～30 parts of fillers; 1～5 part of beramic color, 0.1～0.3 part of fungusproof anti-corrosion agent, 2～5 parts of film coalescence aid; 0.6～1.0 part of water-based isocyanate, 1～2 part of association type rheological agent is in weight part; Said dispersion medium comprises: 40～50 parts of wilkinite solution, and 50～60 parts of alkaline inorganic sols are in weight part; Said suspension emulsion comprises: 70～80 parts in any one in PUA polyurethane aqueous dispersion body or the water-based silicone resin or two kinds of mixtures, and 1～2 part of association type rheological agent, 0.1～0.2 part of fungusproof anti-corrosion agent, 15～30 parts of deionized waters are in weight part.More than each component be the commercially available prod.
Said wilkinite is preferably any one or a few the mixture in lithium magnesium silicate (being commonly called as the synthetic clay), neusilin, the hydrophilic organobentonite.
Said alkali tackify waterborne polyurethane resin is preferably the aliphatic polyurethane water dispersion.
Said wetting agent is preferably the APEOfree alkyl polyoxyethylene ether, and said dispersion agent is preferably APEOfree ammonium acrylate salt copolymer.
Said filler is generally selected mineral fillers such as process white or coarse whiting for use.
Said beramic color is the mineral dye of high-temperature calcination.
Said water-based isocyanate is preferably aliphatic polymeric isocyanate, its NCO content (%) >=13, solid content >=75%; Certain other water-based isocyanates; Also can use such as aromatic poly-isocyanate, but only can use, can not use as outdoor coating as indoor paint.
Said association type rheological agent is preferably any one or the two kinds of mixtures in acrylic association type rheological agent, the PU association type rheological agent.
Said alkaline inorganic sol is preferably a kind of or its mixture in water glass colloidal sol, potassium silicate colloidal sol, the silicic acid sol.
Height of the present invention contains the preparation method of the inside and outside colorful granite coating of cross-linking type water bag water admittedly, it is characterized in that comprising the steps:
(1) each composition with disperse phase mixes; The microgel reaction takes place in (alkali tackify waterborne polyurethane resin and water-based isocyanate) between the inner different high molecular polymers of disperse phase; Accomplished in about 30 minutes, promptly interior crosslinking technological generates stable flexible gelinite;
(2) the gelinite cutting or the suction filtration that disperse phase are generated are processed soft gel grain, and size can be confirmed as requested;
(3) said soft gel grain is mixed with dispersion medium; Soft gel grain and dispersion medium are immiscible, and behind soft gel grain contact dispersion medium, the alkali tackify waterborne polyurethane resin generation gel reaction on alkaline inorganic sol in the dispersion medium and soft gel grain surface generates the transparency protected gel coat of pliable and tough thin layer; Accomplished in about 15 minutes; Be the external crosslinking technology, stably be coated on soft gel grain surface, outside the phase mutual diffusion of the dispersion medium component that coating component in the block film and film are outer; Can also prevent to assemble between the coating particles, condense, stablize gluey protection system thereby form one;
(4) the glue protection system with step (3) gained is dispersed in the suspension emulsion, obtains product height of the present invention and contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly.
The concrete production technique of the inventive method is following:
1, the preparation of disperse phase
Part deionized water, wilkinite, wetting agent, dispersion agent, skimmer, fungusproof anti-corrosion agent are mixed, be stirred to uniform state, slowly add filler and monochromatic beramic color again, high speed dispersion gets final product to fineness＜50um.Add alkali tackify waterborne polyurethane resin, balance of deionized water, film coalescence aid mixing again, again with association type rheological agent adjustment viscosity to 110 ± 5ku (20 ℃), adding the water-based isocyanate crosslinking reaction at last, to be soft gelinite half a hour subsequent use.
2, the preparation of dispersion medium
Wilkinite is added to the solution (weight percent) that is made in the water about 5%, and middling speed is dispersed to fully dissolving, adds alkaline inorganic sol middling speed again and is uniformly dispersed and gets final product.
3, the configuration of suspension emulsion
PUA polyurethane aqueous dispersion body or water-based silicone resin, the association type rheological agent, fungusproof anti-corrosion agent, deionized water low speed mixing gets final product.
4, the preparation of look grain
Respectively the soft gelinite of disperse phase is cut into the particle of finger size, join in the special-purpose granulating equipment again, can make particle by setting size of particles and join in the dispersion medium, stirring at low speed mixes, and the reaction of look seed lac got final product about 15 minutes.
5, the high preparation that contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly
By colour table requirement or requirement of client look grain not of the same race and ratio is mixed, add suspension emulsion and stirring at low speed even stable granite coating.
It is full aqueous product that height of the present invention contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, and performance is according to the unit elongation in JG/T24-2000 sand textured building coating standard and the JG/T172 one 2005 elastic coating standards.Elasticity is preferably arranged, can cover the slight crack of body of wall.
Product of the present invention is through detecting, and performance is as shown in table 1.
Table 1 product performance of the present invention
The present invention compared with prior art, its beneficial effect is: 1, product of the present invention is the full aqueous product of high solids content that adopts inside and outside crosslinking technological, excellent stability; The environment friendly decorative material that spreading rate is high, its product can reach more than 10 years work-ing life, is ideal substitutes such as marble, grouan, the true mineral varnish of sliver; Product each item excellent performance; Both having met the environmental protection and energy saving requirement, and can reach high-grade wall decoration requirement again, is a kind of environment protecting building paint that has potentiality; 2, product of the present invention is able to (also to claim a colored paint material surface) on the surface of dispersive look grain through the gel property that utilizes macromolecular material and forms flexible protective membrane with inner, thus the prevention secondary aggregation; The principle of the invention is with the theory of colloid chemistry in the physical chemistry system and the surface chemistry main theoretical basis of the reform of Chinese economic structure as the formula for a product design; The physical change of material and the multinomial conversion of chemical reaction have been incorporated; Comprise water bag emulsifying water technology, inside and outside crosslinking technological, and Ceramic Composite technology; The aqueous base tackify urethane resin of liquid state is refined into the pliable and tough particle of hydrate colour of colloidal; And be suspended in equably in the specific aqueous medium, finally having formed the liquid gelationus multipolymer of polymer colourful, that particle size is controlled, it not only has all characteristics of top-grade building coating; Have more extremely strong weathering resistance, antiacid rain, resistance to cracking and characteristics such as the feature of environmental protection and artificial grantie, particularly it imitates granitic effect and has reached high degree, stage hard to tell whether it is true or false.
Embodiment
Be elaborated in the face of technical scheme of the present invention down, but protection scope of the present invention is not limited to said embodiment.
Embodiment 1:The height of present embodiment contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, comprises that the weight ratio between disperse phase, dispersion medium and the suspension emulsion is 55:20:25.
The component and the weight part of disperse phase are following:
10 parts of deionized waters, 2 parts of hydrophilic organobentonites, 55 parts of alkali tackify waterborne polyurethane resins; Wetting agent 0.1--part, 0.3 part of dispersion agent, 0.3 part of skimmer; 22 parts of fillers, 3 parts of beramic colors, 0.2 part of fungusproof anti-corrosion agent; 4 parts of film coalescence aid, 1 part of water-based isocyanate, 2 parts of association type rheological agents.
The component of dispersion medium and weight part are:
Wilkinite solution (hydrophilic organobentonite 5% solution) (weight percent) 40 parts, 60 parts of alkaline inorganic sols (water glass colloidal sol).
The component of suspension emulsion and weight part are:
70 parts of PUA polyurethane aqueous dispersion bodies, 1 part of association type rheological agent, 0.2 part of fungusproof anti-corrosion agent, 28.8 parts of deionized waters.
The production technique that the height of present embodiment contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly is following:
1, the preparation of disperse phase
The deionized water of 50% volume is mixed with hydrophilic organobentonite, wetting agent, dispersion agent, skimmer, fungusproof anti-corrosion agent, be stirred to uniform state, slowly add filler and monochromatic beramic color again, high speed dispersion 30 minutes gets final product to fineness＜50um.Add alkali tackify waterborne polyurethane resin, surplus deionized water, film coalescence aid mixing again, again with association type rheological agent adjustment viscosity to 110 ± 5ku (20 ℃), adding the water-based isocyanate crosslinking reaction at last, to be soft gelinite half a hour subsequent use.
2, the preparation of dispersion medium
Wilkinite is added to is made into 5% solution (weight percent) in the water, high speed dispersion 20 minutes is to dissolving fully, adds alkaline inorganic sol middling speed again and is uniformly dispersed and gets final product.
3, the configuration of suspension emulsion
The PUA polyurethane aqueous dispersion body, the association type rheological agent, fungusproof anti-corrosion agent, deionized water low speed mixing gets final product.
4, the preparation of look grain
Respectively the soft gelinite of disperse phase is cut into the particle of finger size, join in the special-purpose granulating equipment again, can make particle by setting size of particles and join in the dispersion medium, stirring at low speed mixes, and the reaction of look seed lac got final product about 15 minutes.
5, the high preparation that contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly
By colour table requirement or requirement of client look grain not of the same race and ratio is mixed, add suspension emulsion and stirring at low speed even stable granite coating.
Height of the present invention contains the Performance Detection such as the table 2 of the inside and outside colorful granite coating of cross-linking type water bag water admittedly:
Table 2 present embodiment makes consolidates the performance that contains the inside and outside colorful granite coating of cross-linking type water bag water
Embodiment 2:Present embodiment primary process is with embodiment 1, and different is, height contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, comprises disperse phase, dispersion medium and suspension emulsion, between weight ratio be 50:25:25.
The component and the weight part of disperse phase are following:
10 parts of deionized waters, 2 parts of wilkinites (neusilin and hydrophilic organobentonite half and half), 60 parts of alkali tackify waterborne polyurethane resins; Wetting agent 0.1--part, 0.5 part of dispersion agent, 0.3 part of skimmer; 16 parts of fillers, 3 parts of beramic colors, 0.3 part of fungusproof anti-corrosion agent; 5 parts of film coalescence aid, 0.8 part of water-based isocyanate, 2 parts of association type rheological agents.
The component of dispersion medium and weight part are:
Wilkinite solution (5% solution of neusilin and hydrophilic organobentonite half and half) (weight percent) 45 parts, 55 parts of alkaline inorganic sols (potassium silicate colloidal sol).
The component of suspension emulsion and weight part are:
75 parts of water-based silicone resin, 2 parts of association type rheological agents, 0.2 part of fungusproof anti-corrosion agent, 22.8 parts of deionized waters.
Embodiment 3:Present embodiment primary process is with embodiment 1, and different is, height contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, comprises disperse phase, dispersion medium and suspension emulsion, between weight ratio be 60:20:20.
The component and the weight part of disperse phase are following:
10 parts of deionized waters, 2 parts of wilkinites (lithium magnesium silicate and hydrophilic organobentonite half and half), 54 parts of alkali tackify waterborne polyurethane resins; 0.2 part of wetting agent, 0.5 part of dispersion agent, 0.3 part of skimmer; 20 parts of fillers, 5 parts of beramic colors, 0.2 part of fungusproof anti-corrosion agent; 5 parts of film coalescence aid, 0.8 part of water-based isocyanate, 2 parts of association type rheological agents.
The component and the weight part of dispersion medium are following:
Special wilkinite solution (5% solution of lithium magnesium silicate and hydrophilic organobentonite half and half) (weight percent) 50 parts,
Alkalescence inorganic sol (silicic acid sol) 50 parts.
The component and the weight part of suspension emulsion are following:
Half and half 80 parts of PUA polyurethane aqueous dispersion body and water-based silicone resin, 1 part of association type rheological agent, 0.1 part of fungusproof anti-corrosion agent, 18.9 parts of deionized waters.
Embodiment 4～7:Primary process is with embodiment 1, and wherein related component and content are seen table 3～4.
Weight ratio among table 3 embodiment 4～7 between disperse phase, dispersion medium and the suspension emulsion
| ? | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| Weight ratio | 50：20：20 | 60：20：20 | 60：25：25 | 55：25：20 |
Each component and content among table 4 embodiment 4～7 are in weight part
Embodiment 8:The height that is made into according to embodiment 1-7 is contained the inside and outside colorful granite coating of cross-linking type water bag water admittedly constructs, comprise following steps:
1, the japanning basal plane must dry, smooth, clean, firm, weakly alkaline.Construction temperature>=5 ℃, construction humidity≤80%.
2, even coating penetrating priming paint 1-2 roads in the basic unit that handles well.
3, colored paint 2 roads of constructing midway, construction at interval can more than 4 hours.
4, jointing: the jointing adhesive tape is fitted; Pattern according to planning is demarcated with the line of ink marker. be affixed on the position of demarcation with the jointing adhesive tape of required specification. should note tightness in order to avoid come off when taping; The afterbody that the jointing adhesive tape sticks, should plan up and down, so that tear up operation.
5, be coated with in treating colored paint uses after dry 6 hours bore contain admittedly as general this height of trade sales coating spray gun spraying of 2-3mm inside and outside the colorful granite coating of cross-linking type water bag water 2 roads.Coating needs to test with regard to conditions such as spray gun bore, blast to the apperance of filming earlier in advance, a large amount of sprayings of row again.The operation of spray gun need keep certain speed, certain distance, nozzle and spraying face to need keeping parallelism during spraying.The ending of spraying is sentenced in jointing place and is advisable.
6, jointing: the jointing adhesive tape removes, in be coated with the coating of main material after, the planning initial, up and down of fitting according to the jointing adhesive tape is given order and is torn up, and notes not destroying the integrity of ditch seam.
7, treat that this granite coating evenly is coated with aqueous polyurethane finishing paint 1-2 road after dry 24 hours.
8, cleaning arrangement: should the material of maintenance be removed after spraying finishes, and contaminated position is cleaned out.
As stated, although represented and explained the present invention that with reference to specific preferred embodiment it shall not be construed as the restriction to the present invention self.Under the spirit and scope of the present invention prerequisite that does not break away from the accompanying claims definition, can make various variations in form with on the details to it.
Claims (10)
1. one kind high contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, and it is characterized in that: comprise disperse phase, dispersion medium and suspension emulsion, the weight ratio between said disperse phase, dispersion medium and the suspension emulsion is 50～60:20～25:20～25; Wherein,
Said disperse phase comprises: 5～15 parts of deionized waters, 1～2 part of wilkinite, 40～60 parts of alkali tackify waterborne polyurethane resins, wetting agent 0.1--～0.2 part; 0.3～0.5 part of dispersion agent, 0.1～0.3 part of skimmer, 15～30 parts of fillers; 1～5 part of beramic color, 0.1～0.3 part of fungusproof anti-corrosion agent, 2～5 parts of film coalescence aid; 0.6～1.0 part of water-based isocyanate, 1～2 part of association type rheological agent is in weight part;
Said dispersion medium comprises: 40～50 parts of wilkinite solution, and 50～60 parts of alkaline inorganic sols are in weight part;
Said suspension emulsion comprises: 70～80 parts in any one in PUA polyurethane aqueous dispersion body or the water-based silicone resin or two kinds of mixtures, and 1～2 part of association type rheological agent, 0.1～0.2 part of fungusproof anti-corrosion agent, 15～30 parts of deionized waters are in weight part.
2. height according to claim 1 contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, it is characterized in that: said wilkinite is any one or a few the mixture in lithium magnesium silicate, neusilin, the hydrophilic organobentonite.
3.
.Height according to claim 1 contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, and it is characterized in that: said alkali tackify waterborne polyurethane resin is the aliphatic polyurethane water dispersion.
4.
.Height according to claim 1 contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, and it is characterized in that: said wetting agent is the APEOfree alkyl polyoxyethylene ether.
5.
.Height according to claim 1 contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, and it is characterized in that: said dispersion agent is an APEOfree ammonium acrylate salt copolymer.
6. height according to claim 1 contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, and it is characterized in that: said water-based isocyanate is an aliphatic polymeric isocyanate.
7. height according to claim 1 contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, it is characterized in that: said association type rheological agent is any one or the two kinds of mixtures in acrylic association type rheological agent, the PU association type rheological agent.
8. height according to claim 1 contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly, and it is characterized in that: said alkaline inorganic sol is a kind of or its mixture in water glass colloidal sol, potassium silicate colloidal sol, the silicic acid sol.
9. contain the preparation method of the inside and outside colorful granite coating of cross-linking type water bag water according to the described height of arbitrary claim in the claim 1～8 admittedly, it is characterized in that comprising the steps:
(1) each composition with disperse phase mixes, and between the inner different high molecular polymers of disperse phase the microgel reaction takes place, and generates flexible gelinite;
(2) the gelinite cutting or the suction filtration that disperse phase are generated are processed soft gel grain;
(3) said soft gel grain is mixed with dispersion medium; The alkali tackify waterborne polyurethane resin generation gel reaction on alkaline inorganic sol in the dispersion medium and soft gel grain surface generates the transparency protected gel coat of pliable and tough thin layer; Stably be coated on soft gel grain surface, form one and stablize gluey protection system;
(4) the glue protection system with step (3) gained is dispersed in the suspension emulsion, obtains product height of the present invention and contains the inside and outside colorful granite coating of cross-linking type water bag water admittedly.
10. contain the preparation method of the inside and outside colorful granite coating of cross-linking type water bag water according to the height shown in the claim 9 admittedly, it is characterized in that:
The method of mixing of disperse phase is in the step (1): part deionized water, wilkinite, wetting agent, dispersion agent, skimmer, fungusproof anti-corrosion agent are mixed; Be stirred to uniform state; Slowly add filler and monochromatic beramic color again, high speed dispersion adds alkali tackify waterborne polyurethane resin, balance of deionized water, film coalescence aid mixing again to fineness＜50um; With association type rheological agent adjustment viscosity to 110 ± 5ku, add the water-based isocyanate crosslinking reaction at last and be soft gelinite again.
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| CN 201110188800 CN102391767B (en) | 2011-07-07 | 2011-07-07 | High-solid-content interior and exterior crosslinked type water-in-water colorful granite paint and preparation method thereof |
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| CN 201110188800 CN102391767B (en) | 2011-07-07 | 2011-07-07 | High-solid-content interior and exterior crosslinked type water-in-water colorful granite paint and preparation method thereof |
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| CN101693800A (en) * | 2009-10-20 | 2010-04-14 | 鳄鱼制漆(上海)有限公司 | Preparation method and construction process of waterborne marble-imitated multicolor paint |
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