CN108913008A - One kind aqueous ground color coating material and preparation method thereof - Google Patents

One kind aqueous ground color coating material and preparation method thereof Download PDF

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Publication number
CN108913008A
CN108913008A CN201810608748.8A CN201810608748A CN108913008A CN 108913008 A CN108913008 A CN 108913008A CN 201810608748 A CN201810608748 A CN 201810608748A CN 108913008 A CN108913008 A CN 108913008A
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China
Prior art keywords
agent
coating material
color coating
ground
slurries
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CN201810608748.8A
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Inventor
仝其超
郑毅
胡中源
董立志
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Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201810608748.8A priority Critical patent/CN108913008A/en
Publication of CN108913008A publication Critical patent/CN108913008A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of aqueous ground color coating material and preparation method thereof, the aqueous ground color coating material includes that according to the mass fraction following group is grouped as:No soap closes silicone acrylic emulsion, PU resin, deionized water, pH adjusting agent, dispersing agent, fungicide, antifreezing agent, protective glue, kaolin, wetting agent, thickener, ground wetting agent, defoaming agent, coalescing agent, isocyanate curing agent, levelling agent.Coating of the present invention has marbling effect, has the non-skid property that VOC content is low, hardness is high, wearability is good, excellent, can be suitable for the decoration of apartment for elderly people and some non-slip floors very well.

Description

One kind aqueous ground color coating material and preparation method thereof
Technical field
The present invention relates to functional environment-friendly paint fields, and in particular to one kind aqueous ground color coating material and preparation method thereof.
Background technique
Color coating material coating in aqueous ground refers to that coating has marbling effect, and has hardness height, wearability good.Excellent Non-skid property.It can be suitable for the decoration of apartment for elderly people and some non-slip floors very well.And requirement of the people to coating at this stage It is higher and higher, it is also more and more diversified, it is therefore desirable to a kind of aqueous ground color coating material be provided, can make up for it this vacancy, solved Ground floor brick does not have the problem of anti-skidding problem and some wood floors inferior long-term release formaldehyde, and ground environment is made also With good decorative performance and non-skid property, to reach the personalization and art up requirement of people's finishing.
Summary of the invention
The purpose of the present invention is to provide deionization aqueous ground color coating material of a kind of new-type antiskid and preparation method thereof.
In order to achieve the above objectives, present invention employs following technical proposals:A kind of aqueous ground color coating material of the invention, it is described Aqueous ground color coating material include that according to the mass fraction following group is grouped as:
Further, the silicone acrylic emulsion closes silicone acrylic emulsion for no soap.
Further, the dispersing agent is one of sodium salt dispersing agent P30 and high-molecular copolymer BYK-190 or two Kind combination;The silicone acrylic emulsion is rich 6733 of Ahmedabad.
Further, the protective glue is the S482 of Lockwood;The levelling agent is in the 346 and 331 of Bi Ke One or two combination;The PU resin is Bayer 2470;The isocyanate curing agent is the 2655 of Bayer.
Further, the pH adjusting agent is one or both of AMP-95 and S-150 combination;The thickener is One or both of TT-935 and HS30000YP2 combination;The wetting agent is one or both of X-405 and LCN407 Combination;The fungicide is one or both of sterilization K9N of BIT class fungicide LXE and Kathon CG class combination;The antifreezing agent For the combination of one or both of ethylene glycol and propylene glycol;The coalescing agent is one of COASOL and TEXANOL or two Kind combination.
Further, the concentration of the protective glue is 5-8%.
Further, the concentration of the isocyanate curing agent is 80%.
Further, the kaolinic fineness is not more than 50um.
Further, the ratio of the PU resin and isocyanates is 5:1.
The preparation method of color coating material in aqueous ground of the present invention, includes the following steps:
(1) deionized water, thickener, coalescing agent, defoaming agent, dispersing agent and wetting agent are uniformly mixed and obtain slurries A;
(2) kaolin, antifreezing agent, fungicide and pH adjusting agent are added into slurries A, is uniformly mixed and obtains slurries B;
(3) silicone acrylic emulsion is added into slurries B and levelling agent, uniformly mixed slurries C (deploys different colors);
(4) protection latex solution is added into slurries C, is granulated to get the color component A in ground is arrived;
(5) deionized water, PU resin, defoaming agent, ground wetting agent, levelling agent are uniformly mixed and obtain the color B component in ground;
(6) isocyanate curing agent is opened in clean container with PGDA (being opened dilute with PGDA is common sense) dilute, mixing is It is even to obtain the color component C in ground.
Beneficial effect:Coating of the present invention have marbling effect, have VOC content is low, hardness is high, wearability is good, it is excellent Non-skid property, the decoration of apartment for elderly people and some non-slip floors can be suitable for very well.
Compared with prior art, the invention has the advantages that:
(1) present invention have the function of absorption harmful organic substance, VOC content is low, good skid resistance, formation paint film Adhesive force is strong, has excellent water resistance and solvent resistance, therefore the environmentally friendly and individual character for having reached people's promotion is art up It is required that.
Specific embodiment
By following embodiment, present invention be described in more detail, but should be noted that the scope of the present invention is not implemented by these Any restrictions of example.
In addition, in order to better illustrate the present invention, being given in specific embodiment below numerous specific Details.It will be appreciated by those skilled in the art that without certain details, the present invention equally be can be implemented.In other reality It applies in example, method well known to those skilled in the art, means is not described in detail, in order to highlight purport of the invention. In the present invention, indicate that the unit of material content is based on weight in terms of part, unless otherwise stated.In addition, about skill of the invention The measuring method of art index is in the art using standard method, and for details, reference can be made to newest national standards, unless in addition saying It is bright.In an embodiment of the present invention, the adhesive force of paint film is preferably according to GB/T1720-1979 standard testing, the water resistance of paint film It is preferred that according to GB/T1733-1993 standard testing, VOC content is preferably according to GB18582-2008 standard testing, in the present invention, name Word term both includes singular, also includes plural form, unless context separately explicitly points out.It is heretofore described " extremely Few one kind " refers not only to the case where including "one" or "an", prior the case where also including " multiple " or " a variety of ".
Color coating material in aqueous ground of the present invention, due to containing function monomer and acrylic ester monomer polymerization by PU resin It forms, amido therein can reduce or eliminate the organic pollutant in air, therefore can reduce VOC content.The present invention Described in PU resin and isocyanate curing agent blend proportion be it is optimal, there is good hardness and solvent resistance.
Heretofore described various auxiliary agents, the auxiliary agent that can be used using any this field, can directly be bought It obtains, it can also oneself preparation.In section Example of the invention, the pH adjusting agent is AMP-95 or S-150, institute The dispersing agent stated is P30 or BYK190, and the thickener is TT-935 HS30000YP2 thickener, and the wetting agent is X- 405 or LCN407, the fungicide are the sterilization K9N of BIT class fungicide LXE or Kathon CG class, and the antifreezing agent is di-alcohols, Such as perhaps the propylene glycol coalescing agent is COASOL or TEXANOL to ethylene glycol.
Embodiment 1
A kind of aqueous ground color coating material of the invention, the aqueous ground color coating material includes following component according to the mass fraction Composition:
The preparation method of color coating material in aqueous ground of the present invention, includes the following steps:
(1) by 25 parts of deionized waters, 0.5 part of TT-935 thickener, 8 parts of COASOL coalescing agents, 4 parts of 731A dispersing agents and 1.5 parts of X-405 wetting agents are uniformly mixed, and are slowly added to 10 parts of kaolin, fineness≤50um obtains slurries A;
(2) 40 parts of lotions, 0.3 part of ethylene glycol antifreeze, 0.3 part of BIT class fungicide LXE and 1 part of pH are added into slurries A Regulator AMP-95 is uniformly mixed and obtains slurries B.(spare toning)
(3) the S482 protective glue that 7% concentration is added into slurries B, which is uniformly mixed, to be granulated;
(4) by 15 parts of deionized water, 80 parts of PU resin, 0.5 part of defoaming agent, 1.5 parts of ground wetting agent, 3 parts of levelling agent, mixed It closes and uniformly obtains the color B component in ground;
(5) XP-2655 is opened in clean container with PGDA dilute.(wherein 2655 concentration is 80%) is uniformly mixed To ground coloured silk component C.(B:C=6:1)
Embodiment 2
Embodiment 2 the difference from embodiment 1 is that:
A kind of aqueous ground color coating material of the invention, the aqueous ground color coating material includes following component according to the mass fraction Composition:
The preparation method of color coating material in aqueous ground of the present invention, includes the following steps:
In step (1), by 25 parts of deionized waters, 0.5 part of TT-935 thickener, 8 parts of COASOL coalescing agents, 4 parts 731A dispersing agent and 1.5 parts of X-405 wetting agents are uniformly mixed, and are slowly added to 10 parts of kaolin, fineness≤50um obtains slurries A;
In step (2), 40 parts of lotions, 0.3 part of ethylene glycol antifreeze, 0.3 part of BIT class fungicide are added into slurries A LXE and 1 part of pH adjusting agent AMP-95 is uniformly mixed and obtains slurries B.(spare toning)
In step (3), the S482 protective glue that 7% concentration is added into slurries B, which is uniformly mixed, to be granulated;
In step (4), by 15 parts of deionized water, 80 parts of PU resin, 0.5 part of defoaming agent, 1.5 parts of ground wetting agent, stream 3 parts of flat agent is uniformly mixed and obtains the color B component in ground
In step (5), XP-2655 is opened in clean container with PGDA dilute.(wherein 2655 concentration is 80%) It is uniformly mixed and obtains the color component C in ground.(5:1)
Embodiment 3
Embodiment 3 the difference from embodiment 1 is that:
A kind of aqueous ground color coating material of the invention, the aqueous ground color coating material includes following component according to the mass fraction Composition:
The preparation method of color coating material in aqueous ground of the present invention, includes the following steps:
In step (1), by 25 parts of deionized waters, 0.5 part of TT-935 thickener, 8 parts of COASOL coalescing agents, 4 parts 731A dispersing agent and 1.5 parts of X-405 wetting agents are uniformly mixed, and are slowly added to 10 parts of kaolin, fineness≤50um obtains slurries A;
In step (2), 40 parts of lotions, 0.3 part of ethylene glycol antifreeze, 0.3 part of BIT class fungicide are added into slurries A LXE and 1 part of pH adjusting agent AMP-95 is uniformly mixed and obtains slurries B.(spare toning)
In step (3), the S482 protective glue that 7% concentration is added into slurries B, which is uniformly mixed, to be granulated;
In step (4), by 15 parts of deionized water, 80 parts of PU resin, 0.5 part of defoaming agent, 1.5 parts of ground wetting agent, stream 3 parts of flat agent is uniformly mixed and obtains the color B component in ground
In step (5), XP-2655 is opened in the container of anhydrous cleaning with PGDA dilute.(wherein 2655 concentration is 80%) it is uniformly mixed and obtains the color component C in ground.(B:C=4:1)
Embodiment 4
Embodiment 4 the difference from embodiment 1 is that:
A kind of aqueous ground color coating material of the invention, the aqueous ground color coating material includes following component according to the mass fraction Composition:
The preparation method of color coating material in aqueous ground of the present invention, includes the following steps:
In step (1), by 25 parts of deionized waters, 0.5 part of TT-935 thickener, 8 parts of COASOL coalescing agents, 4 parts 731A dispersing agent and 1.5 parts of X-405 wetting agents are uniformly mixed, and are slowly added to 10 parts of kaolin, fineness≤50um obtains slurries A;
In step (2), 40 parts of lotions, 0.3 part of ethylene glycol antifreeze, 0.3 part of BIT class fungicide are added into slurries A LXE and 1 part of pH adjusting agent AMP-95 is uniformly mixed and obtains slurries B.(spare toning)
In step (3), the S482 protective glue that 7% concentration is added into slurries B, which is uniformly mixed, to be granulated;
In step (4), by 15 parts of deionized water, 80 parts of PU resin, 0.5 part of defoaming agent, 1.5 parts of ground wetting agent, stream 3 parts of flat agent is uniformly mixed and obtains the color B component in ground
In step (5), XP-2655 is opened in clean container with PGDA dilute.(wherein 2655 concentration is 80%) It is uniformly mixed and obtains the color component C in ground.(B:C=3:1)
Embodiment 5
Embodiment 5 the difference from embodiment 1 is that:The preparation method of color coating material in aqueous ground of the present invention, including such as Lower step:
In step (1), by 25 parts of deionized waters, 0.5 part of TT-935 thickener, 8 parts of COASOL coalescing agents, 4 parts 731A dispersing agent and 1.5 parts of X-405 wetting agents are uniformly mixed, and are slowly added to 10 parts of kaolin, fineness≤50um obtains slurries A;
In step (2), 40 parts of lotions, 0.3 part of ethylene glycol antifreeze, 0.3 part of BIT class fungicide are added into slurries A LXE and 1 part of pH adjusting agent AMP-95 is uniformly mixed and obtains slurries B.(spare toning)
In step (3), the S482 protective glue that 5% concentration is added into slurries B, which is uniformly mixed, to be granulated;
In step (4), by 15 parts of deionized water, 80 parts of PU resin, 0.5 part of defoaming agent, 1.5 parts of ground wetting agent, stream 3 parts of flat agent is uniformly mixed and obtains the color B component in ground
In step (5), XP-2655 is opened in clean container with PGDA dilute.(wherein 2655 concentration is 80%) It is uniformly mixed and obtains ground coloured silk component C (B:C=5:1)
Embodiment 6
Embodiment 6 the difference from embodiment 1 is that:The preparation method of color coating material in aqueous ground of the present invention, including such as Lower step:
In step (1), by 25 parts of deionized waters, 0.5 part of TT-935 thickener, 8 parts of COASOL coalescing agents, 4 parts 731A dispersing agent and 1.5 parts of X-405 wetting agents are uniformly mixed, and are slowly added to 10 parts of kaolin, fineness≤50um obtains slurries A;
In step (2), 40 parts of lotions, 0.3 part of ethylene glycol antifreeze, 0.3 part of BIT class fungicide are added into slurries A LXE and 1 part of pH adjusting agent AMP-95 is uniformly mixed and obtains slurries B.(spare toning)
In step (3), the S482 protective glue that 9% concentration is added into slurries B, which is uniformly mixed, to be granulated;
In step (4), by 15 parts of deionized water, 80 parts of PU resin, 0.5 part of defoaming agent, 1.5 parts of ground wetting agent, stream 3 parts of flat agent is uniformly mixed and obtains the color B component in ground
In step (5), XP-2655 is opened in clean container with PGDA dilute.(wherein 2655 concentration is 80%) It is uniformly mixed and obtains the color component C in ground.(B:C=5:1)
Embodiment 7
A kind of aqueous ground color coating material of the invention, the aqueous ground color coating material includes following component according to the mass fraction Composition:
The dispersing agent is 731A dispersing agent;The silicone acrylic emulsion is rich 6733 of Ahmedabad;The protective glue is Lip river gram The S482 of Wood;The levelling agent is the 346 of Bi Ke;The PU resin is Bayer 2470;The isocyanate curing agent is to visit The 2655 of ear;The pH adjusting agent is AMP-95;The thickener is TT-935;The wetting agent is X-405;The sterilization Agent is BIT class fungicide LXE;The antifreezing agent is ethylene glycol;The coalescing agent is COASOL.
The concentration of the protective glue is 7%.
The concentration of the isocyanate curing agent is 80%.
The kaolinic fineness is not more than 50um.
The ratio of the PU resin and isocyanates is 5:1.
The preparation method of color coating material in aqueous ground of the present invention, includes the following steps:
In step (1), deionized water, thickener, coalescing agent, defoaming agent, dispersing agent and wetting agent are uniformly mixed Obtain slurries A;
In step (2), kaolin, antifreezing agent, fungicide and pH adjusting agent are added into slurries A, is uniformly mixed and obtains Slurries B;
In step (3), silicone acrylic emulsion is added into slurries B and levelling agent, uniformly mixed slurries C (are deployed different Color);
In step (4), protection latex solution is added into slurries C, is granulated to get the color component A in ground is arrived;
In step (5), deionized water, PU resin, defoaming agent, ground wetting agent, levelling agent are uniformly mixed and obtained Ground coloured silk B component;
In step (6), isocyanate curing agent is opened in clean container with PGDA dilute, is uniformly mixed that obtain ground color Component C.
Embodiment 8
Embodiment 8 and the difference of embodiment 7 are:A kind of aqueous ground color coating material of the invention, the aqueous ground color coating Material is grouped as including following group according to the mass fraction:
The dispersing agent is high-molecular copolymer BYK-190;The protective glue is the S482 of Lockwood;The levelling Agent is 331;The pH adjusting agent is S-150;The thickener is HS30000YP2;The wetting agent is LCN407;It is described Fungicide is the sterilization K9N of Kathon CG class;The antifreezing agent is propylene glycol;The coalescing agent is TEXANOL.
The concentration of the protective glue is 5%.
Embodiment 9
Embodiment 9 and the difference of embodiment 7 are:A kind of aqueous ground color coating material of the invention, the aqueous ground color coating Material is grouped as including following group according to the mass fraction:
The dispersing agent is the combination of sodium salt dispersing agent P30 and high-molecular copolymer BYK-190;The levelling agent is complete Gram 346 and 331 combination;The pH adjusting agent is the combination of AMP-95 and S-150;The thickener be TT-935 and The combination of HS30000YP2;The wetting agent is the combination of X-405 and LCN407;The fungicide be BIT class fungicide LXE and The combination of the sterilization K9N of Kathon CG class;The antifreezing agent is the combination of ethylene glycol and propylene glycol;The coalescing agent be COASOL and The combination of TEXANOL.
The concentration of the protective glue is 7%.
Comparative example 1
By the ratio change of B, component C in embodiment 1, other conditions are constant, and aqueous ground color coating material is prepared.
Comparative example 2
By the ratio change of B, component C in embodiment 1, other conditions are constant, and aqueous ground color coating material is prepared.
Comparative example 3
By the ratio change of B, component C in embodiment 1, other conditions are constant, and aqueous ground color coating material is prepared.
Comparative example 4
By the ratio change of B, component C in embodiment 1, other conditions are constant, and aqueous ground color coating material is prepared.
Comparative example 5
Gum concentration will be protected to reduce in embodiment 1, other conditions are constant, and aqueous ground color coating material is prepared.
Comparative example 6
Gum concentration will be protected to increase in embodiment 1, other conditions are constant, and aqueous ground color coating material is prepared to above-mentioned implementation The aqueous ground color coating material being prepared in example and comparative example carries out analysis detection, and concrete outcome is as shown in table 1.
Table 1
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, the present invention Claimed range is delineated by the appended claims, the specification and equivalents thereof from the appended claims.

Claims (10)

1. a kind of aqueous ground color coating material, it is characterised in that:The aqueous ground color coating material includes according to the mass fraction such as the following group It is grouped as:
2. color coating material in aqueous ground according to claim 1, it is characterised in that:The silicone acrylic emulsion closes the third cream of silicon for no soap Liquid.
3. color coating material in aqueous ground according to claim 1, it is characterised in that:The dispersing agent is sodium salt dispersing agent P30 With one or both of high-molecular copolymer BYK-190 combination;The silicone acrylic emulsion is rich 6733 of Ahmedabad.
4. color coating material in aqueous ground according to claim 1, it is characterised in that:The protective glue is the S482 of Lockwood; One or both of 346 and 331 combinations that the levelling agent is Bi Ke;The PU resin is Bayer 2470;The isocyanic acid Ester curing agent is the 2655 of Bayer.
5. color coating material in aqueous ground according to claim 1, it is characterised in that:The pH adjusting agent is AMP-95 and S- One or both of 150 combinations;The thickener is one or both of TT-935 and HS30000YP2 combination;The profit Humectant is one or both of X-405 and LCN407 combination;The fungicide is killing for BIT class fungicide LXE and Kathon CG class One or both of bacterium K9N combination;The antifreezing agent is the combination of one or both of ethylene glycol and propylene glycol;The film forming Auxiliary agent is one or both of COASOL and TEXANOL combination.
6. color coating material in aqueous ground according to claim 1, it is characterised in that:The concentration of the protective glue is 5-8%.
7. color coating material in aqueous ground according to claim 1, it is characterised in that:The concentration of the isocyanate curing agent is 80%.
8. color coating material in aqueous ground according to claim 1, it is characterised in that:The kaolinic fineness is not more than 50um; The ratio of the PU resin and isocyanates is 5:1.
9. the preparation method of the described in any item aqueous ground color coating material of claim 1 to 8, it is characterised in that include the following steps:
(1) deionized water, thickener, coalescing agent, defoaming agent, dispersing agent and wetting agent are uniformly mixed and obtain slurries A;
(2) kaolin, antifreezing agent, fungicide and pH adjusting agent are added into slurries A, is uniformly mixed and obtains slurries B;
(3) silicone acrylic emulsion is added into slurries B and levelling agent, uniformly mixed slurries C (deploys different colors);
(4) protection latex solution is added into slurries C, is granulated to get the color component A in ground is arrived;
(5) deionized water, PU resin, defoaming agent, ground wetting agent, levelling agent are uniformly mixed and obtain the color B component in ground;
(6) isocyanate curing agent is opened in clean container with PGDA dilute, is uniformly mixed and obtains the color component C in ground.
10. the preparation method of color coating material in aqueous ground according to claim 9, it is characterised in that including:The B component and C The mass ratio of component is 3-6:1.
CN201810608748.8A 2018-06-13 2018-06-13 One kind aqueous ground color coating material and preparation method thereof Pending CN108913008A (en)

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CN106752495A (en) * 2016-11-25 2017-05-31 厦门富思特新材料科技有限公司 One kind exempts from Lacquer finish automatically cleaning aqueous colorful exterior coating and preparation method thereof
CN106634511A (en) * 2016-12-07 2017-05-10 亚士漆(上海)有限公司 Water white resistant particle crosslinking type water-in-water multicolor paint
CN107163818A (en) * 2017-06-19 2017-09-15 无锡市赛易特化工有限公司 Colorful floor paint
CN107652810A (en) * 2017-08-03 2018-02-02 河北晨阳工贸集团有限公司 Aqueous, environmental protective discoloration art coatings and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113811287A (en) * 2019-04-05 2021-12-17 艾默罗德卡拉玛化学品公司 Low VOC multifunctional additives for improving aqueous polymer film properties
EP3946249A4 (en) * 2019-04-05 2023-01-18 Emerald Kalama Chemical, LLC Low voc multifunctional additives to improve waterborne polymer film properties
CN113811287B (en) * 2019-04-05 2023-11-17 朗盛公司 Low VOC multi-functional additives for improving waterborne polymer film properties

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