CN107987632A - A kind of aqueous double-component matte varnish and its production technology - Google Patents
A kind of aqueous double-component matte varnish and its production technology Download PDFInfo
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- CN107987632A CN107987632A CN201711182371.6A CN201711182371A CN107987632A CN 107987632 A CN107987632 A CN 107987632A CN 201711182371 A CN201711182371 A CN 201711182371A CN 107987632 A CN107987632 A CN 107987632A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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Abstract
The invention discloses a kind of aqueous double-component matte varnish, it is made of component A and B component, wherein component A is matte varnish resin combination, and B component is isocyanate curing agent, and the matte varnish resin combination, the mass ratio of isocyanate curing agent between the two are 1:0.09;The matte varnish resin combination is made of the raw material of following mass percent:Water-based acrylic resin 70%;Aqueous polyurethane dispersion 15%;Coalescents 7%;Wetting aid 0.5%;Surface slip auxiliary agent 0.5%;Leveling auxiliary agent 0.5%;Thickening aids 0.5%;Antifoam additives 0.5%, graphene 0.3%;Traditional Chinese medicine ingredients 0.3%, delustring auxiliary agent 5%;Further include the production technology of the aqueous double-component matte varnish.The dull finishing coat of the present invention has low production cost, and widely used, excellent performance, is worth of widely use.
Description
Technical field
The present invention relates to dumb light paint, is specifically a kind of aqueous double-component dull finishing coat and its production technology.
Background technology
With the lifting of people's life grade and the highest attention to health, following home decoration and coatings for furniture market
It must be the world of water paint.Reasonable improvement using with environmental sanitation of the popularization of water-borne wood coating for resource, all ten
Divide favourable.
Dumb light paint is called " sub-gloss varnish ", is one kind of paint.For dumb light paint and semigloss paint are mainly the gloss of paint film.One
As for the glossiness of semigloss paint should be between 40-60 (60 degree of angles).Dumb light paint gloss should be below 20 (60 degree of angles).Brush
Semigloss paint paint film is more plain afterwards, and dumb light paint paint film more has texture.But:" sub-gloss varnish " should be more commonly used, the spy of " sub-gloss varnish "
Point be lacquer painting than milder, it is somewhat vaporific.Another is exactly polish lacquer.
At present, it is to obtain matte effect by adding flatting silica that the preparation method of water-based matte varnish, which is mainly divided,.But by
In the limitation of delustring powder material self character, flatting efficiency, surface appearance effects, feel etc. can be affected and show endless
Such as people's will.
The content of the invention
It is an object of the invention to provide a kind of aqueous double-component dull finishing coat and its production technology, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical solution:
A kind of aqueous double-component matte varnish, is made of component A and B component, and wherein component A is matte varnish resin
Composition, B component are isocyanate curing agent, and the matte varnish resin combination, isocyanate curing agent are between the two
Mass ratio be 1:0.09;The matte varnish resin combination is made of the raw material of following mass percent:Aqueous acrylamide
Acid resin 65%~75%;Aqueous polyurethane dispersion 10%~20%;Coalescents 5%~10%;Wetting aid 0.1%~
1%;Surface slip auxiliary agent 0.1%~1%;Leveling auxiliary agent 0.1%~1%;Thickening aids 0.1%~1%;Antifoam additives
0.1%~1%, graphene 0.1%~0.5%;Traditional Chinese medicine ingredients 0.1%~0.5%, delustring auxiliary agent 3-8%.
As the further scheme of the present invention:The matte varnish resin combination by following mass percent raw material
Composition:Water-based acrylic resin 68%~73%;Aqueous polyurethane dispersion 13%~17%;Coalescents 6%~8%;Profit
Wet auxiliary agent 0.3%~0.7%;Surface slip auxiliary agent 0.3%~0.7%;Leveling auxiliary agent 0.3%~0.7%;Thickening aids
0.3%~0.7%;Antifoam additives 0.3%~0.7%, graphene 0.2%~0.4%;Traditional Chinese medicine ingredients 0.2%~0.4%, disappear
Light auxiliary agent 4-6%.
As further scheme of the invention:The matte varnish resin combination by following mass percent original
Material composition:Water-based acrylic resin 70%;Aqueous polyurethane dispersion 15%;Coalescents 7%;Wetting aid 0.5%;Table
Face slip aid 0.5%;Leveling auxiliary agent 0.5%;Thickening aids 0.5%;Antifoam additives 0.5%, graphene 0.3%;Chinese medicine into
Divide 0.3%, delustring auxiliary agent 5%.
As further scheme of the invention:The nco value of the isocyanate curing agent is 8.5~9.5.
As further scheme of the invention:The nco value of the isocyanate curing agent is 9.2.
As further scheme of the invention:The traditional Chinese medicine ingredients select Chinese gall, honeysuckle, dandelion, eucalyptus,
Honey, ganoderma lucidum, cordate houttuynia, one kind of aloe or its combination.
As further scheme of the invention:The antifoam additives select modified siloxane defoamer.
As further scheme of the invention:The leveling auxiliary agent selection titanate esters modified organic silicon chelating levelling agent,
Titanate esters modified polyacrylate chelating levelling agent, one kind of organosilicon-modified acrylic copolymer levelling agent or its combination.
As further scheme of the invention:The production technology of the aqueous double-component matte varnish, by following
Step forms:
S1. the dispersion cylinder of standard clean and up to specification is selected;
S2. component A is prepared:Water-based acrylic resin, aqueous polyurethane point are firstly added into dispersion cylinder by measuring requirement
Granular media, then starts dispersion machine, and rotating speed is maintained at 1500~2200r/min, is then slowly added into deionized water in formula rate
Liquid is uniformly mixed with coalescents, 5~10min is stirred for after adding, decelerates to 1000~1200r/min, stirring
Under sequentially add defoamer, wetting aid, graphene, after adding, stir 5~10min, rotating speed brings up to 1800~2200r/
Min, and 15~30min is kept, 600~800r/min is decelerated to, leveling auxiliary agent, surface slip are sequentially added under stirring
Auxiliary agent, Chinese medicinal ingredients and delustring auxiliary agent, after stirring 5~10min, add thickening aids, and carry out viscosity test, and viscosity reaches
To -4 glasss of 70~120s are applied, finally, filtering, packaging, are made component A;
S3. B component is prepared:Isocyanates is weighed by measuring requirement, and into the dispersion cylinder for having nitrogen protection (inflated with nitrogen)
By the mixture of metering addition PMA propylene glycol methyl ether acetates, PGDA propylene-glycol diacetates or both, add while stirring,
5 minutes are stirred under 350~450r/min rotating speeds to being uniformly dispersed, filters, pack, B component is made;
S4. obtained B component in obtained component A in step S2 and step S3 is pressed 1:0.09,800~1100r/min
Censorship after being dispersed to uniformly, obtained matte varnish is filtered and packaged after qualified respectively.
Compared with prior art, the beneficial effects of the invention are as follows:
The aqueous double-component matte varnish particle diameter of the present invention is smaller, and the transparency of wet film and dry film is fine, while can be with
Fill the gap of other materials generation so that whole coating system is fine and close, fillibility is good, anti-pollution and medium-resistance are good;By
There is higher hardness in aqueous double-component matte varnish, the hardness of whole coating system is got a promotion;The water of the present invention
Property the addition of two-component matte varnish grapheme material improve painting layer scratch resistance, it is anti-be adhered, anti-cracking ability.This hair
Bright dull finishing coat has low production cost, and widely used, excellent performance, is worth of widely use.
Embodiment
Technical scheme will be clearly and completely described below, it is clear that described embodiment is this hair
Bright part of the embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art exist
All other embodiments obtained under the premise of creative work are not made, belong to the scope of protection of the invention.
Embodiment 1
A kind of aqueous double-component matte varnish, is made of component A and B component, and wherein component A is matte varnish resin
Composition, B component are isocyanate curing agent, and the matte varnish resin combination, isocyanate curing agent are between the two
Mass ratio be 1:0.09;The matte varnish resin combination is made of the raw material of following mass percent:Aqueous acrylamide
Acid resin 75%;Aqueous polyurethane dispersion 20%;Coalescents 10%;Wetting aid 1%;Surface slip auxiliary agent 1%;Stream
Flat auxiliary agent 1%;Thickening aids 1%;Antifoam additives 1%, graphene 0.5%;Traditional Chinese medicine ingredients 0.5%, delustring auxiliary agent 5%.
The nco value of isocyanate curing agent is 9.5.
Traditional Chinese medicine ingredients select Chinese gall, honeysuckle, dandelion, eucalyptus, honey, ganoderma lucidum, cordate houttuynia, one kind of aloe
Or its combination.
The antifoam additives select modified siloxane defoamer.
The leveling auxiliary agent selects titanate esters modified organic silicon chelating levelling agent, titanate esters modified polyacrylate chelating stream
Flat agent, one kind of organosilicon-modified acrylic copolymer levelling agent or its combination.
The production technology of the aqueous double-component matte varnish, comprises the steps of:
S1. the dispersion cylinder of standard clean and up to specification is selected;
S2. component A is prepared:Water-based acrylic resin, aqueous polyurethane point are firstly added into dispersion cylinder by measuring requirement
Granular media, then starts dispersion machine, and rotating speed is maintained at 1500~2200r/min, is then slowly added into deionized water in formula rate
Liquid is uniformly mixed with coalescents, 5~10min is stirred for after adding, decelerates to 1000~1200r/min, stirring
Under sequentially add defoamer, wetting aid, graphene, after adding, stir 5~10min, rotating speed brings up to 1800~2200r/
Min, and 15~30min is kept, 600~800r/min is decelerated to, leveling auxiliary agent, surface slip are sequentially added under stirring
Auxiliary agent, Chinese medicinal ingredients and delustring auxiliary agent, after stirring 5~10min, add thickening aids, and carry out viscosity test, and viscosity reaches
To -4 glasss of 70~120s are applied, finally, filtering, packaging, are made component A;
S3. B component is prepared:Isocyanates is weighed by measuring requirement, and into the dispersion cylinder for having nitrogen protection (inflated with nitrogen)
By the mixture of metering addition PMA propylene glycol methyl ether acetates, PGDA propylene-glycol diacetates or both, add while stirring,
5 minutes are stirred under 350~450r/min rotating speeds to being uniformly dispersed, filters, pack, B component is made;
S4. obtained B component in obtained component A in step S2 and step S3 is pressed 1:0.09 be dispersed to uniformly after give
Inspection, obtained matte varnish is filtered and packaged after qualified respectively.
Testing result such as table 1:
Table 1
Survey report such as table 2
Table 2
Embodiment 2
A kind of aqueous double-component matte varnish, is made of component A and B component, and wherein component A is matte varnish resin
Composition, B component are isocyanate curing agent, and the matte varnish resin combination, isocyanate curing agent are between the two
Mass ratio be 1:0.09;The matte varnish resin combination is made of the raw material of following mass percent:Aqueous acrylamide
Acid resin 70%;Aqueous polyurethane dispersion 15%;Coalescents 7%;Wetting aid 0.5%;Surface slip auxiliary agent 0.5%;
Leveling auxiliary agent 0.5%;Thickening aids 0.5%;Antifoam additives 0.5%, graphene 0.3%;Traditional Chinese medicine ingredients 0.3%, delustring auxiliary agent
4.5%.
The nco value of isocyanate curing agent is 9.2.
Traditional Chinese medicine ingredients select Chinese gall, honeysuckle, dandelion, eucalyptus, honey, ganoderma lucidum, cordate houttuynia, one kind of aloe
Or its combination.
Antifoam additives select modified siloxane defoamer.
Leveling auxiliary agent selects titanate esters modified organic silicon chelating levelling agent, titanate esters modified polyacrylate chelating levelling
Agent, one kind of organosilicon-modified acrylic copolymer levelling agent or its combination.
The production technology of aqueous double-component matte varnish, comprises the steps of:
S1. the dispersion cylinder of standard clean and up to specification is selected;
S1. the dispersion cylinder of standard clean and up to specification is selected;
S2. component A is prepared:Water-based acrylic resin, aqueous polyurethane point are firstly added into dispersion cylinder by measuring requirement
Granular media, then starts dispersion machine, and rotating speed is maintained at 1500~2200r/min, is then slowly added into deionized water in formula rate
Liquid is uniformly mixed with coalescents, 5~10min is stirred for after adding, decelerates to 1000~1200r/min, stirring
Under sequentially add defoamer, wetting aid, graphene, after adding, stir 5~10min, rotating speed brings up to 1800~2200r/
Min, and 15~30min is kept, 600~800r/min is decelerated to, leveling auxiliary agent, surface slip are sequentially added under stirring
Auxiliary agent, Chinese medicinal ingredients and delustring auxiliary agent, after stirring 5~10min, add thickening aids, and carry out viscosity test, and viscosity reaches
To -4 glasss of 70~120s are applied, finally, filtering, packaging, are made component A;
S3. B component is prepared:Isocyanates is weighed by measuring requirement, and into the dispersion cylinder for having nitrogen protection (inflated with nitrogen)
By the mixture of metering addition PMA propylene glycol methyl ether acetates, PGDA propylene-glycol diacetates or both, add while stirring,
5 minutes are stirred under 350~450r/min rotating speeds to being uniformly dispersed, filters, pack, B component is made;
S4. obtained B component in obtained component A in step S2 and step S3 is pressed 1:0.09 be uniformly dispersed after censorship,
Obtained matte varnish is filtered and packaged after qualification respectively.
Embodiment 3
A kind of aqueous double-component matte varnish, is made of component A and B component, and wherein component A is matte varnish resin
Composition, B component are isocyanate curing agent, and the matte varnish resin combination, isocyanate curing agent are between the two
Mass ratio be 1:0.09;The matte varnish resin combination is made of the raw material of following mass percent:Aqueous acrylamide
Acid resin 65%;Aqueous polyurethane dispersion 10%;Coalescents 5%;Wetting aid 0.1%;Surface slip auxiliary agent 0.1%;
Leveling auxiliary agent 0.1%;Thickening aids 0.1%;Antifoam additives 0.1%, graphene 0.1%;Traditional Chinese medicine ingredients 0.1%, delustring auxiliary agent
5.5%.
The nco value of isocyanate curing agent is 8.5.
Traditional Chinese medicine ingredients select Chinese gall, honeysuckle, dandelion, eucalyptus, honey, ganoderma lucidum, cordate houttuynia, one kind of aloe
Or its combination.
Antifoam additives select modified siloxane defoamer.
Leveling auxiliary agent selects titanate esters modified organic silicon chelating levelling agent, titanate esters modified polyacrylate chelating levelling
Agent, one kind of organosilicon-modified acrylic copolymer levelling agent or its combination.
The production technology of aqueous double-component matte varnish, comprises the steps of:
S1. the dispersion cylinder of standard clean and up to specification is selected;
S1. the dispersion cylinder of standard clean and up to specification is selected;
S2. component A is prepared:Water-based acrylic resin, aqueous polyurethane point are firstly added into dispersion cylinder by measuring requirement
Granular media, then starts dispersion machine, and rotating speed is maintained at 1500~2200r/min, is then slowly added into deionized water in formula rate
Liquid is uniformly mixed with coalescents, 5~10min is stirred for after adding, decelerates to 1000~1200r/min, stirring
Under sequentially add defoamer, wetting aid, graphene, after adding, stir 5~10min, rotating speed brings up to 1800~2200r/
Min, and 15~30min is kept, 600~800r/min is decelerated to, leveling auxiliary agent, surface slip are sequentially added under stirring
Auxiliary agent, Chinese medicinal ingredients and delustring auxiliary agent, after stirring 5~10min, add thickening aids, and carry out viscosity test, and viscosity reaches
To -4 glasss of 70~120s are applied, finally, filtering, packaging, are made component A;
S3. B component is prepared:Isocyanates is weighed by measuring requirement, and into the dispersion cylinder for having nitrogen protection (inflated with nitrogen)
By the mixture of metering addition PMA propylene glycol methyl ether acetates, PGDA propylene-glycol diacetates or both, add while stirring,
5 minutes are stirred under 350~450r/min rotating speeds to being uniformly dispersed, filters, pack, B component is made;
S4. obtained B component in obtained component A in step S2 and step S3 is pressed 1:0.091:After 0.09 is uniformly dispersed
Censorship, obtained matte varnish is filtered and packaged after qualified respectively.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.
If not specified, conventional means of the technological means known to those skilled in the art employed in embodiment, institute
The reagent and product of use are also available commercial.The source of agents useful for same, trade name and its composition is listed if necessary
Component person, indicates on the first appearance.
Claims (9)
1. a kind of aqueous double-component matte varnish, it is characterised in that be made of component A and B component, wherein component A is dumb light
Clear finish resin combination, B component are isocyanate curing agent, the matte varnish resin combination, cured with isocyanates
The mass ratio of agent between the two is 1:0.09;The matte varnish resin combination by following mass percent raw material group
Into:Water-based acrylic resin 65%~75%;Aqueous polyurethane dispersion 10%~20%;Coalescents 5%~10%;Wetting
Auxiliary agent 0.1%~1%;Surface slip auxiliary agent 0.1%~1%;Leveling auxiliary agent 0.1%~1%;Thickening aids 0.1%~1%;
Antifoam additives 0.1%~1%, graphene 0.1%~0.5%;Traditional Chinese medicine ingredients 0.1%~0.5%, delustring auxiliary agent 3-8%.
2. aqueous double-component matte varnish according to claim 1, it is characterised in that the matte varnish resin group
Compound is made of the raw material of following mass percent:Water-based acrylic resin 68%~73%;Aqueous polyurethane dispersion 13%
~17%;Coalescents 6%~8%;Wetting aid 0.3%~0.7%;Surface slip auxiliary agent 0.3%~0.7%;Levelling helps
Agent 0.3%~0.7%;Thickening aids 0.3%~0.7%;Antifoam additives 0.3%~0.7%, graphene 0.2%~0.4%;
Traditional Chinese medicine ingredients 0.2%~0.4%, delustring auxiliary agent 4-6%.
3. aqueous double-component matte varnish according to claim 2, it is characterised in that the matte varnish resin group
Compound is made of the raw material of following mass percent:Water-based acrylic resin 70%;Aqueous polyurethane dispersion 15%;Film forming helps
Agent 7%;Wetting aid 0.5%;Surface slip auxiliary agent 0.5%;Leveling auxiliary agent 0.5%;Thickening aids 0.5%;Antifoam additives
0.5%, graphene 0.3%;Traditional Chinese medicine ingredients 0.3%, delustring auxiliary agent 5%.
4. aqueous double-component matte varnish according to claim 1, it is characterised in that the isocyanate curing agent
Nco value is 8.5~9.5.
5. according to the aqueous double-component matte varnish described in claim 4, it is characterised in that the isocyanate curing agent
Nco value is 9.2.
6. aqueous double-component matte varnish according to claim 1, it is characterised in that the traditional Chinese medicine ingredients select five times
Son, honeysuckle, dandelion, eucalyptus, honey, ganoderma lucidum, cordate houttuynia, one kind of aloe or its combination.
7. aqueous double-component matte varnish according to claim 1, it is characterised in that the antifoam additives, which are selected, to be modified
Silicone antifoam agent.
8. aqueous double-component matte varnish according to claim 1, it is characterised in that the leveling auxiliary agent selects metatitanic acid
Ester modified organosilicon chelating levelling agent, titanate esters modified polyacrylate chelating levelling agent, organosilicon-modified acrylic copolymer
One kind of levelling agent or its combination.
A kind of 9. production technology of aqueous double-component matte varnish as described in claim 1-5 is any, it is characterised in that by
Following steps form:
S1. the dispersion cylinder of standard clean and up to specification is selected;
S2. component A is prepared:Water-based acrylic resin, aqueous polyurethane dispersion are firstly added into dispersion cylinder by measuring requirement,
Then dispersion machine is started, rotating speed is maintained at 1500~2200r/min, is then slowly added into deionized water and film forming in formula rate
The uniformly mixed liquid of auxiliary agent, 5~10min is stirred for after adding, and decelerates to 1000~1200r/min, under stirring successively
Defoamer, wetting aid, graphene are added, after adding, stirs 5~10min, rotating speed brings up to 1800~2200r/min, and protects
15~30min is held, decelerates to 600~800r/min, leveling auxiliary agent, surface slip auxiliary agent, Chinese medicine are sequentially added under stirring
Composition and delustring auxiliary agent, after stirring 5~10min, add thickening aids, and carry out viscosity test, and viscosity reaches -4 glass 70 of painting
~120s, finally, filtering, packaging, are made component A;
S3. B component is prepared:Isocyanates is weighed by measuring requirement, and into the dispersion cylinder for having nitrogen protection (inflated with nitrogen) based on
The mixture of amount addition PMA propylene glycol methyl ether acetates, PGDA propylene-glycol diacetates or both, adds while stirring, 350~
5 minutes are stirred under 450r/min rotating speeds to being uniformly dispersed, filters, pack, B component is made;
S4. obtained B component in obtained component A in step S2 and step S3 is pressed 1:0.09,800~1100r/min disperses
To uniform rear censorship, obtained matte varnish is filtered and packaged respectively after qualified.
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CN109111838A (en) * | 2018-07-14 | 2019-01-01 | 广东富特化工有限公司 | A kind of polyurethane intaglio plate table print dumb paint and preparation method thereof |
CN109627888A (en) * | 2018-09-06 | 2019-04-16 | 国网浙江省电力有限公司宁波供电公司 | A kind of dedicated high durable matte varnish of ABS ground and preparation method thereof |
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Cited By (9)
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CN108793833A (en) * | 2018-05-28 | 2018-11-13 | 广东韩丽家居集团股份有限公司 | A kind of environment-friendly sheet and its production method |
CN109111838A (en) * | 2018-07-14 | 2019-01-01 | 广东富特化工有限公司 | A kind of polyurethane intaglio plate table print dumb paint and preparation method thereof |
CN109627888A (en) * | 2018-09-06 | 2019-04-16 | 国网浙江省电力有限公司宁波供电公司 | A kind of dedicated high durable matte varnish of ABS ground and preparation method thereof |
CN109627948A (en) * | 2018-12-13 | 2019-04-16 | 广东华兹卜新材料科技有限公司 | A kind of scratch resistant wood coating |
CN109666393A (en) * | 2018-12-17 | 2019-04-23 | 上海仰世实业有限公司 | Coating and preparation method thereof |
CN110028890A (en) * | 2019-04-28 | 2019-07-19 | 英德市雅家涂料有限公司 | A kind of aqueous double-component dumb light woodcare paint and preparation method thereof |
CN113480926A (en) * | 2019-05-21 | 2021-10-08 | 河北晨阳工贸集团有限公司 | High-resistance double-component environment-friendly water-based matte clear finish paint |
CN115160877A (en) * | 2022-08-11 | 2022-10-11 | 君子兰涂料(天津)有限公司 | UV (ultraviolet) film-coated finish paint and preparation method thereof |
CN115160877B (en) * | 2022-08-11 | 2023-04-07 | 君子兰涂料(天津)有限公司 | UV (ultraviolet) film-coated finish paint and preparation method thereof |
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