CN101591491A - A kind of fully water based granite multicolor paint and preparation method thereof - Google Patents
A kind of fully water based granite multicolor paint and preparation method thereof Download PDFInfo
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- CN101591491A CN101591491A CNA2008100380594A CN200810038059A CN101591491A CN 101591491 A CN101591491 A CN 101591491A CN A2008100380594 A CNA2008100380594 A CN A2008100380594A CN 200810038059 A CN200810038059 A CN 200810038059A CN 101591491 A CN101591491 A CN 101591491A
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Abstract
The invention provides a kind of fully water based granite multicolor paint, comprise base paint, colloid and synthetic emulsion, between weight ratio be: 30～40: 30～40: 20～40.Fully water based granite multicolor paint of the present invention is full aqueous product, Voc is low, environmental protection, solvent-free, be ideal substitutes such as marble, grouan, its product performance can be according to GB/T9755-2001, synthetic resins exterior coating standard, and good elasticity is arranged, can cover the slight crack of body of wall.
Description
Technical field
The present invention relates to a kind of inner, external wall coating, specifically, relate to a kind of fully water based granite multicolor paint and preparation method thereof.
Background technology
Coating is a kind of finishing material, comprise a variety of, as interior outer wall building coating, topcoat material, anticorrosion of steel structure material, water-borne wood coating, UV solidify and other functional coatings etc.Building coating is government's new industry of putting forth effort to help in recent years, also is development in recent years industry rapidly.But at present traditional building coating is mainly based on aqueous latex paint, solvent-borne type synthetic resin coating; Product sense organ effect is single, and color is based on single real look, and the decorative effect of product is not good.Along with the raising that people require decorative effect, adopt a large amount of granite building materials or glass curtain wall as finishing material now on the market, increased dependence and consumption greatly to natural resources; This material own wt is heavier simultaneously, and also there is bigger hidden danger in exterior wall safety.The raising that requires along with energy-saving and environmental protection and to the lifting of wall body decoration effect requirements, the multicolor finish market requirement with grouan texture is very big.
The granite multicolor paint that exterior wall in being applied to is also arranged in the market, but its product all is solvent type, or oil-in-water-type, contain a large amount of organic solvents in the product, have greater environmental impacts in the use.Stability, the durability of products of product look grain are also relatively poor simultaneously.
The production of full-aqueous multicolour paint is also arranged on the existing market, but because its production process complexity, technique controlling difficulty is very big, and the long and not enough causes for stable of product look grain of production cycle does not really form commercialization and industrialization.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art, a kind of fully water based granite multicolor paint is provided, its controllability is strong, and the big I of product look grain is arbitrarily controlled, and look grain stability is high.
Another object of the present invention is to provide a kind of preparation method of fully water based granite multicolor paint, its production technique is simple, controllability is strong.
In order to realize purpose of the present invention, a kind of fully water based granite multicolor paint of the present invention comprises base paint, colloid and synthetic emulsion, between weight ratio be: 30～40: 30～40: 20～40; The component and the weight part of described base paint are as follows:
40～50 parts of anionic emulsions,
1～3 part in hydrophilic protection glue,
0.1～0.5 part of wetting agent,
0.1～0.5 part of dispersion agent,
0.1～0.5 part of defoamer,
0.1～0.5 part in sterilant,
10～15 parts of pigment,
20～30 parts in water,
1～2 part of film coalescence aid,
0.1～0.5 part of thickening material.
Weight part of the present invention is this area weight unit commonly used, as gram, kilogram, two, ton etc.As follows.
Described base paint mainly provides the particle of producing color, and this particle is changeable, requires quite stable, can not be dissolved in the colloid,
Described anionic emulsion can be selected one or more mixtures of phenylpropyl alcohol, pure third, elasticity or modification organosilicon crylic acid latex for use.
Described wetting ability protection glue is selected from a kind of of polyvinyl alcohol, methyl or ethyl cellulose or its mixture.
Described wetting agent is selected nonionic block polyether type tensio-active agent for use, and such as block polyoxyethylene polyoxypropylene ether (X-405), it all has good wetting effect to all pigment.
Described dispersion agent is selected the nonionic surface active agent class for use, and such as nonionic polyurethane dispersion agent (TCP-8030N), it has good divergent function to the pigment class titanium dioxide.
It is major ingredient that described defoamer can be selected hydrophobically modified silicon-dioxide and mineral oil for use, and such as defoamer RF-202, defoaming effect is obvious, has no side effect.
Pigment can select for use proportion little, and the filler that contains the small-amount free metal ion is as weighting material, and it can obviously improve particulate fullness ratio and stability.Color can be selected monochrome or secondary color for use, generally being advisable with the mineral dye preparation.Be preferably titanium dioxide.
Described sterilant can be selected the benzisothiazole ketone for use, such as 2-benzisothiazole-3-ketone (BIT), good broad spectrum is arranged.
Described film coalescence aid is an alkoxide, such as HY-1800, good film-formation result is arranged.
Described thickening material is an alkali swelling associative thickener, such as TT-615.
Described colloidal major function is that base paint is wrapped up by colloid, and base paint acts on mutually with polar material in the colloid, forms a reticulated structure, firm the wrapping of base paint, forms stable one by one particle, and it comprises following component and weight proportion:
10～20 parts of cationic synthetic resins,
2～4 parts of retardant,
1～2 part of film coalescence aid,
80～90 parts in water.
Described cationic synthetic resin solution can be selected one or more mixtures of cationic polyacrylamide and fluorine modified copolymer emulsion for use.
Described retardant can be selected the salt of calcium, magnesium, aluminium or ammonium etc. for use.
A kind of or its mixture of the optional spent glycol butyl ether of described film coalescence aid, propylene glycol, 2-Butoxyethyl acetate.
Described synthetic emulsion can be selected one or more mixtures in phenylpropyl alcohol, pure third, elasticity or the fluorine modified emulsion for use.
The present invention is owing to the different in nature particle on colloidal polar material and base paint look grain surface absorbs mutually; colloid is attracted to the surface of look grain; the emulsion of polar component in the colloid and base paint particle surface and pigment reaction; form the hard layer of half gel state, stablize gluey protection system thereby form one.This system can not interpenetrate, and stably is suspended in the transparent emulsion, can not sink to the bottom.This gelatinization reaction generally needs 2-3 hour.
The preparation method of fully water based granite multicolor paint of the present invention, it comprises the steps:
1) elder generation mixes each composition of base paint, and viscosity controller is at 100-105ku;
2) will protect each composition of glue to mix then;
3) at last base paint is joined in the protection glue, stir, gelatinization reaction 1-2 hour, add synthetic emulsion again, and the continuation reaction formed in 1-2 hour.
Concrete production technique is as follows:
1, the preparation of base paint
Partly water, hydrophilic protection glue, wetting agent, dispersion agent, defoamer mix, and are stirred to uniform state, slowly add pigment again, and middling speed is dispersed to fineness≤50um and gets final product.Add anionic emulsion, water, film coalescence aid at last, adjust viscosity to 100 ± 5ku with thickening material.Standby.
2, the toning of base paint
The base paint for preparing is added in the paint cylinder, and middling speed stirs, and slowly adds aqueous color paste (can allocate by this area mill base commonly used), is mixed to uniform state, is adjusted to the color of design in advance, and is standby.
3, the preparation of protection glue
Retardant is added in the water, and middling speed is dispersed to dissolving fully, adds cationic synthetic resin again, and the middling speed dispersion extremely was dissolved to colourless transparent solution in about 30 minutes fully, and then added film coalescence aid, mixes to get final product.
4, the preparation of look grain lacquer
Base paint after will mixing colours by granulating equipment respectively adds in the granulating equipment; can make particle by setting size of particles joins in the protective colloid; stirring at low speed; mix; look seed lac reaction 1-2 hour; add the negatively charged ion synthetic emulsion, and continue to react the stable look grain lacquer of formation after 1-2 hour.
5, the preparation of fully water based granite multicolor paint
By colour table requirement or requirement of client look grain lacquer not of the same race and ratio is mixed, and stirring at low speed is even.
Fully water based granite multicolor paint of the present invention is full aqueous product, Voc is low, environmental protection, solvent-free, be ideal substitutes such as marble, grouan, its product performance can be according to GB/T9755-2001, synthetic resins exterior coating standard, and good elasticity is arranged, can cover the slight crack of body of wall.Specific performance is as follows:
| Interventions Requested | Technical requirements | Detection method |
| Condition in container | No lump stirs the back uniform state | Range estimation |
| Cryostatic stabilization matter | Never degenerate | GB/T9268-1988 |
| Time of drying (hour) | 2 | GB/T1728-1979 second method |
| Water tolerance (96h) | No abnormal | GB/T1733-1993 |
| Alkali resistance (48h) | No abnormal | GB/T9265-1988 |
| Contamination resistance | ≤15 | GB/T9780-2005 |
| Artificial ageing resistance | 800h is non-foaming, does not come off efflorescence≤1 grade, variable color≤1 grade | GB/T1865--1997 |
| Tension set (normal temperature) | ≥200 | JG/T172-2005 |
Embodiment
Cooperate appended graphic explanation in detail by specific embodiment below, so that the effect that is easier to understand purpose of the present invention, technology contents, characteristics and is reached.
Embodiment 1
The fully water based granite multicolor paint of present embodiment comprises base paint, colloid and benzene emulsion, between weight ratio be: 30: 40: 30.
The component and the weight part of base paint are as follows: 40 parts of anionic emulsions (benzene emulsion 296DS); 3 parts in hydrophilic protection glue (methylcellulose gum); 0.2 part of wetting agent (block polyoxyethylene polyoxypropylene ether X-405); 0.1 part of nonionic polyurethane dispersion agent TCP-8030N, 0.3 part of defoamer RF-202,0.5 part of sterilant BIT; 12 parts of pigment R-902 titanium whites; 30 parts in water, 2 parts of film coalescence aid HY-1800,0.1 part of thickening material TT-615.
Colloidal component and weight proportion: 15 parts of cationic synthetic resins (polyacrylamide), 4 parts in retardant lime carbonate, 1 part of film coalescence aid butyl glycol ether, 90 parts in water.
The production technique of the fully water based granite multicolor paint of present embodiment is as follows:
1, the preparation of base paint
Partly water, hydrophilic protection glue, wetting agent, dispersion agent, defoamer mix, and are stirred to uniform state, slowly add pigment again, and middling speed is dispersed to fineness≤50um and gets final product.Add anionic emulsion, water at last, film coalescence aid is adjusted viscosity to 100 ± 5ku with thickening material.Standby.
2, the toning of base paint
The base paint for preparing is added in the paint cylinder, and middling speed stirs, and slowly adds aqueous color paste, is mixed to uniform state, is adjusted to the color of design in advance, and is standby.
The consumption of aqueous color paste is the 0.1-20% of base paint amount, and the prescription of general mill base is: water 30-68%, Mierocrystalline cellulose 1-3%, sanitas 0.1-0.15%, pigment 30-68%.
The mill base preparation process is: earlier water and Mierocrystalline cellulose are stirred, Mierocrystalline cellulose is fully expanded, add sanitas and pigment, stir.The selection and the preparation process of each composition of mill base all are well known to those skilled in the art.
3, the preparation of protection glue
Retardant is added in the water, and middling speed is dispersed to dissolving fully, adds cationic synthetic resin again, and the middling speed dispersion extremely was dissolved to colourless transparent solution in about 30 minutes fully, and then added film coalescence aid, mixes to get final product.
4, the preparation of look grain lacquer
By granulating equipment each colored paint is added in the granulating equipment respectively, made particle by setting size of particles and joined in the protective colloid stirring at low speed; mix; look seed lac reaction 2 hours adds the negatively charged ion synthetic emulsion, and continues to react the stable look grain lacquer of formation after 1 hour.
5, the preparation of fully water based granite multicolor paint
By colour table requirement or requirement of client look grain lacquer not of the same race and ratio is mixed, and stirring at low speed is even.
The Performance Detection of fully water based granite multicolor paint of the present invention is as follows:
| Interventions Requested | Technical requirements | Measured data |
| Condition in container | No lump stirs the back uniform state | Meet |
| Cryostatic stabilization matter | Never degenerate | Meet |
| Time of drying | ≤2h | 1.5h |
| Water tolerance (96h) | No abnormal | No abnormal |
| Alkali resistance (48h) | No abnormal | No abnormal |
| Contamination resistance | ≤15 | 10 |
| Artificial ageing resistance | 800h is non-foaming, does not come off efflorescence≤1 grade, variable color≤1 grade | 1000h is non-foaming, does not come off 1 grade of efflorescence, 1 grade of variable color |
| Tension set (normal temperature) | ≥200 | 300 |
The colorful elastic exterior coating material of fully water based granite is full aqueous product, Voc is low, environmental protection, solvent-free, be ideal substitutes such as marble, grouan, its product performance can be according to GB/T9755-2001, synthetic resins exterior coating standard, and good elasticity is arranged, can cover the slight crack of body of wall.
Embodiment 2
Present embodiment primary process is with embodiment 1, and different is, fully water based granite multicolor paint comprises base paint, colloid and pure-acrylic emulsion, between weight ratio be: 40: 30: 20.
The component and the weight part of base paint are as follows: 50 parts of anionic emulsions (pure-acrylic emulsion AD-2); 1 part in hydrophilic protection glue (ethyl cellulose); 0.5 part of wetting agent (block polyoxyethylene polyoxypropylene ether X-405), 0.3 part of nonionic polyurethane dispersion agent TCP-8030N, 0.5 part of defoamer RF-202; 0.1 part of sterilant BIT; 10 parts of pigment R-902 titanium dioxides, 10 parts of fillers (600 order coarse whiting and talcum powder), 25 parts in water; 1 part of film coalescence aid HY-1800,0.5 part of thickening material TT-615.
Colloidal component and weight proportion: 10 parts of cationic synthetic resins (polyacrylamide), 2 parts in retardant magnesiumcarbonate, 2 parts of film coalescence aid 2-Butoxyethyl acetates, 80 parts in water.
Embodiment
Present embodiment primary process is with embodiment 1, and different is, fully water based granite multicolor paint comprises base paint, colloid and fluorine modified emulsion, between weight ratio be: 35: 40: 40.
The component and the weight part of base paint are as follows: 45 parts of anionic emulsions (modification organosilicon crylic acid latex BD-309); 2 parts in hydrophilic protection glue (polyvinyl alcohol); 0.1 part of wetting agent (block polyoxyethylene polyoxypropylene ether X-405), 0.5 part of nonionic polyurethane dispersion agent TCP-8030N, 0.1 part of defoamer RF-202; 0.2 part of sterilant BIT; 15 parts of pigment R-902 titanium dioxides, 10 parts of fillers (600 order coarse whiting), 20 parts in water; film coalescence aid HY-18002 part, 0.3 part of thickening material TT-615.
Colloidal component and weight proportion: 20 parts of cationic synthetic resins (fluorine modified copolymer emulsion PF919), 2 parts in retardant ammonium sulfate, 1 part of film coalescence aid propylene glycol, 86 parts in water.
The above is preferred embodiment of the present invention only, is not to be used for limiting scope of the invention process.So all doing according to the described shape of the present patent application scope, structure, feature and spirit all is equivalent variations or modification, all should be included within the claim of the present invention.
Claims (9)
1. a fully water based granite multicolor paint is characterized in that, comprises base paint, colloid and synthetic emulsion, between weight ratio be: 30～40: 30～40: 20～40; The component and the weight part of described base paint are as follows:
40～50 parts of anionic emulsions,
1～3 part in hydrophilic protection glue,
0.1～0.5 part of wetting agent,
0.1～0.5 part of dispersion agent,
0.1～0.5 part of defoamer,
0.1～0.5 part in sterilant,
10～15 parts of color stuffings,
20～30 parts in water,
1～2 part of film coalescence aid,
0.1～0.5 part of thickening material.
2. fully water based granite multicolor paint according to claim 1 is characterized in that, described anionic emulsion is selected one or more mixtures of phenylpropyl alcohol, pure third, elasticity or modification organosilicon crylic acid latex for use.
3. according to claim 1 or 2 described fully water based granite multicolor paints, it is characterized in that described wetting ability protection glue is selected from a kind of of polyvinyl alcohol, methyl or ethyl cellulose or its mixture.
4. according to any described fully water based granite multicolor paint of claim 1-3, it is characterized in that described colloid comprises following component and weight proportion:
10～20 parts of cationic synthetic resins,
2～4 parts of retardant,
1～2 part of film coalescence aid,
80～90 parts in water.
5. according to the described fully water based granite multicolor paint of claim 4, it is characterized in that described cationic synthetic resin solution is selected one or more mixtures of cationic polyacrylamide and fluorine modified copolymer emulsion for use.
6. according to claim 4 or 5 described fully water based granite multicolor paints, it is characterized in that described retardant is selected the salt of calcium, magnesium, aluminium or ammonium for use.
7. according to any described fully water based granite multicolor paint of claim 4-6, it is characterized in that described film coalescence aid is selected a kind of or its mixture of butyl glycol ether, propylene glycol, 2-Butoxyethyl acetate for use.
8. according to any described fully water based granite multicolor paint of claim 1-7, it is characterized in that described synthetic emulsion is selected one or more mixtures in phenylpropyl alcohol, pure third, elasticity or the fluorine modified emulsion for use.
9. prepare the method for any described fully water based granite multicolor paint of claim 1-8, it is characterized in that, comprise the steps:
1) elder generation mixes each composition of base paint, and viscosity controller is at 100-105ku;
2) will protect each composition of glue to mix then;
3) at last base paint is joined in the protection glue, stir, gelatinization reaction 1-2 hour, add synthetic emulsion again, and the continuation reaction formed in 1-2 hour.
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| CN2008100380594A CN101591491B (en) | 2008-05-26 | 2008-05-26 | Full water-borne granite multicolor paint and preparation method thereof |
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| CN2008100380594A CN101591491B (en) | 2008-05-26 | 2008-05-26 | Full water-borne granite multicolor paint and preparation method thereof |
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| CN101591491B CN101591491B (en) | 2012-06-13 |
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| CN104263047A (en) * | 2014-09-27 | 2015-01-07 | 安徽铁创新材料科技有限公司 | Preparation method of colorful finishing coat |
| CN104250482A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Method for preparing multicolor paint for imitating litchi surface granite |
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| CN106566345A (en) * | 2016-10-31 | 2017-04-19 | 四川泓川美居新材料科技有限公司 | Preparation method for granite imitation paint |
| CN106634340A (en) * | 2016-12-08 | 2017-05-10 | 安徽省阜阳闽安建材有限公司 | Water-based multicolor rock slice paint added with lanthanum-zinc antibacterial silicon dioxide |
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