CN104725944A - Aqueous rock color paint and preparation method thereof - Google Patents

Aqueous rock color paint and preparation method thereof Download PDF

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Publication number
CN104725944A
CN104725944A CN201310696595.4A CN201310696595A CN104725944A CN 104725944 A CN104725944 A CN 104725944A CN 201310696595 A CN201310696595 A CN 201310696595A CN 104725944 A CN104725944 A CN 104725944A
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Prior art keywords
parts
water
emulsion
rock color
color coating
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CN201310696595.4A
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Chinese (zh)
Inventor
曹兴龙
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ZHEJIANG MANDELI PAINT Co Ltd
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ZHEJIANG MANDELI PAINT Co Ltd
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Priority to CN201310696595.4A priority Critical patent/CN104725944A/en
Publication of CN104725944A publication Critical patent/CN104725944A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to an aqueous rock color paint, and belongs to the technical field of paint. The aqueous rock color paint comprises the following raw materials: 40-50 parts of a basic paint, 20-30 parts of a protective glue and 20-30 parts of a synthetic emulsion. The invention also provides a preparation method of the aqueous rock color paint. The preparation process includes the following steps: evenly mixing the components of the basic paint, controlling the viscosity at 100-105 ku, evenly mixing the components of the protective glue, evenly mixing the components of the emulsion, adding the basis paint to the protective glue, stirring evenly, carrying out gelling reaction for 1-2 h, adding the prepared synthetic emulsion, and continuing the reaction for 1-2 h to obtain the aqueous rock color paint. The aqueous rock color paint of the invention realizes the industrial production, and has the advanategs of short production cycle, high color stability of color granule, long time storage, environment-friendliness and strong decorative performance.

Description

A kind of water-based rock color coating material and preparation method thereof
Technical field
The present invention relates to a kind of coating, especially a kind of water-based rock color coating material and preparation method thereof, belongs to technical field of coatings.
Background technology
Coating is a kind of finishing material, comprise inner-outer wall building coating, floor coatings material, anticorrosion of steel structure material etc., building coating traditional is at present mainly based on aqueous latex paint, solvent-borne type synthetic resin coating, product sensory effect is single, color is based on single real look, and the decorative effect of product is not good.Along with the raising that people require decorative effect, market today adopt a large amount of granite building materials or glass curtain wall as finishing material, add the dependence to natural resources and consumption greatly, this material own wt is heavier simultaneously, and External Wall safety also exists larger hidden danger.Also the granite multicolor paint being applied to inner-outer wall is had in the market, but its product is all solvent-borne type or oil-in-water-type, containing a large amount of organic solvent in product, have greater environmental impacts in using, the weather resistance of the poor stability of product look grain, product is also poor simultaneously.Now water-based rock color coating material production process is commercially complicated, and technology difficulty controls very large, and the production cycle is longer, and product look grain is stable not.
Application number be 200810162869.0 patent of invention provide a kind of water-borne coatings and preparation method thereof, this water-borne coatings can be used as the decorative paint of external and internal wall, but employ non-serviceable gylcol ether material in " environmental labelling product technical requirements water-borne coatings " standard regulation in the patent, not environmentally, and this invention can not control effectively to product look grain, look grain less stable.
Summary of the invention
Technical problem to be solved by this invention is to provide that a kind of production cycle is shorter and look grain stability is high, can the water-based rock color coating material of standing storage.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is:
A kind of water-based rock color coating material, is characterized in that:
Described water-based rock color coating material comprises the raw material of following weight parts: base paint 40 ~ 50 parts, protecting glue 20 ~ 30 parts, synthetic emulsion 20 ~ 30 parts;
Described base paint comprises the raw material of following weight parts: emulsion 20 ~ 30 parts, ionized water 20 ~ 30 parts, dispersion agent 3 ~ 5 parts, wetting agent 1 ~ 3 part, gel 10 ~ 15 parts, pigment 10 ~ 15 parts, filler 5 ~ 10 parts, 0.1 ~ 0.2 part, sterilant, defoamer 0.2 ~ 0.3 part, thickening material 0.3 ~ 0.6 part;
Described protecting glue is wetting ability protecting glue, and described wetting ability protecting glue comprises at least one in polyvinyl alcohol, methylcellulose gum and ethyl cellulose;
Described synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 10 ~ 20 parts, retardant 2 ~ 4 parts, film coalescence aid 1 ~ 2 part, 80 ~ 90 parts, water.
Further, the emulsion in described base paint comprises at least one in water-base fluorocarbon emulsion and pure acrylic latex.
Further, described dispersion agent is nonionic surface active agent class, and described wetting agent is aniorfic surfactant, and described thickening material is the swelling associative thickener of alkali.
Further, described negatively charged ion synthetic resin solution comprises acrylamide and fluorine and changes at least one in surname copolymer emulsion.
Further, described retardant is the wherein one in calcium salt, magnesium salts, aluminium salt and ammonium salt.
Further, described film coalescence aid comprises at least one in propylene glycol and alcohol ester 12.
The present invention also provides a kind of preparation method of described water-based rock color coating material, and the preparation method of described water-based rock color coating material comprises the following steps:
(1) mixed by each composition of described base paint, viscosity controller is at 100 ~ 105ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 1 ~ 2 hour, then add synthetic emulsion obtained in step (3), and continue reaction 1 ~ 2 hour.
The present invention compared with prior art; the beneficial effect brought is: look grain stability of the present invention is high and can standing storage; base paint mainly provides the particle producing color; this particle is changeable; quite stable; and be insoluble in protecting glue; base paint tightly wraps up by protecting glue; base paint acts on mutually with the polar material in protecting glue, forms a reticulated structure, base paint is firmly wrapped; form look grain stable one by one; look grain size is controlled and look grain stability is high, and water-based rock color coating material of the present invention preparation is simple, with short production cycle.
Water-based rock color coating material of the present invention also has the following advantages:
(1) Water-borne modification completely: unique technique for packing makes its complete Water-borne modification, environment-protecting asepsis, substitutes day by day rare natural granite, meets the energy-conserving and environment-protective advances calls of country;
(2) good decorating effect: seam meter by different lattice, the combination of modern theory and the natural style of tradition, brings up the decorative effect built with lower cost;
(3) splitting resistance: have good ductility, can hide the fine cracks of metope;
(4) high-durability: washability, high temperature resistant, cold resistant, acid rain resistant, waterproof, gas defence, self-cleaning is good;
(5) construction is fast: use professional spray gun, once shaped, the construction time is short;
(6) cost performance is high: compared with natural granite, cheap;
(7) light material: lighter than natural granite, lightens the burden to body of wall greatly.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment, and described embodiment can be done further to supplement and illustrate to the present invention, but the present invention is not limited to these embodiments.
Embodiment 1
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 40 parts, protecting glue 20 parts, synthetic emulsion 20 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: water-base fluorocarbon emulsion 20 parts, ionized water 20 parts, nonionic polyurethane dispersion agent 3 parts, wetting agent (X-405) 1 part, gel 10 parts, pigment (R-902) 10 parts, filler (600 order coarse whiting) 5 parts, 0.1 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.3 part.
Protecting glue: polyvinyl alcohol 20 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 10 parts, calcium salt 2 parts, propylene glycol 1 part, 80 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 100ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint that step (1) is obtained is joined in protecting glue obtained in step (2), stir, gelatinization reaction 1 hour, then add synthetic emulsion obtained in step (3), and continue reaction 1 hour.
Embodiment 2
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 50 parts, protecting glue 30 parts, synthetic emulsion 30 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: water-base fluorocarbon emulsion 30 parts, ionized water 30 parts, nonionic polyurethane dispersion agent 5 parts, wetting agent (X-405) 3 parts, gel 15 parts, pigment (R-902) 15 parts, filler (600 order coarse whiting) 10 parts, 0.2 part, sterilant, defoamer (NX202) 0.3 part, thickening material (TT-615) 0.6 part.
Protecting glue: polyvinyl alcohol 30 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 20 parts, calcium salt 4 parts, propylene glycol 2 parts, 90 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 105ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 2 hours, then add synthetic emulsion obtained in step (3), and continue reaction 2 hours.
Embodiment 3
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 45 parts, protecting glue 25 parts, synthetic emulsion 25 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: water-base fluorocarbon emulsion 25 parts, ionized water 25 parts, nonionic polyurethane dispersion agent 4 parts, wetting agent (X-405) 2 parts, gel 12 parts, pigment (R-902) 12 parts, filler (600 order coarse whiting) 7 parts, 0.1 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.4 part.
Protecting glue: polyvinyl alcohol 25 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 15 parts, calcium salt 3 parts, propylene glycol 1 part, 85 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 102ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 1 hour, then add synthetic emulsion obtained in step (3), and continue reaction 2 hours.
Embodiment 4
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 42 parts, protecting glue 23 parts, synthetic emulsion 23 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: water-base fluorocarbon emulsion 23 parts, ionized water 23 parts, nonionic polyurethane dispersion agent 3 parts, wetting agent (X-405) 1 part, gel 13 parts, pigment (R-902) 11 parts, filler (600 order coarse whiting) 6 parts, 0.2 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.5 part.
Protecting glue: polyvinyl alcohol 23 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 13 parts, magnesium salts 4 parts, propylene glycol 2 parts, 83 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 103ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 2 hours, then add synthetic emulsion obtained in step (3), and continue reaction 1 hour.
Embodiment 5
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 48 parts, protecting glue 28 parts, synthetic emulsion 28 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: water-base fluorocarbon emulsion 28 parts, ionized water 28 parts, nonionic polyurethane dispersion agent 4 parts, wetting agent (X-405) 2 parts, gel 14 parts, pigment (R-902) 14 parts, filler (600 order coarse whiting) 9 parts, 0.2 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.5 part.
Protecting glue: polyvinyl alcohol 28 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 18 parts, magnesium salts 3 parts, propylene glycol 2 parts, 85 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 105ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 2 hours, then add synthetic emulsion obtained in step (3), and continue reaction 2 hours.
Embodiment 6
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 40 parts, protecting glue 20 parts, synthetic emulsion 20 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: pure acrylic latex 20 parts, ionized water 20 parts, nonionic polyurethane dispersion agent 3 parts, wetting agent (X-405) 1 part, gel 10 parts, pigment (R-902) 10 parts, filler (600 order coarse whiting) 5 parts, 0.1 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.3 part.
Protecting glue: methylcellulose gum 20 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 10 parts, magnesium salts 2 parts, alcohol ester 12 parts, 80 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 100ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 1 hour, then add synthetic emulsion obtained in step (3), and continue reaction 1 hour.
Embodiment 7
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 50 parts, protecting glue 30 parts, synthetic emulsion 30 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: pure acrylic latex 30 parts, ionized water 30 parts, nonionic polyurethane dispersion agent 5 parts, wetting agent (X-405) 3 parts, gel 15 parts, pigment (R-902) 15 parts, filler (600 order coarse whiting) 10 parts, 0.2 part, sterilant, defoamer (NX202) 0.3 part, thickening material (TT-615) 0.6 part.
Protecting glue: methylcellulose gum 30 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 20 parts, aluminium salt 4 parts, alcohol ester 12 parts, 90 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 105ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 2 hours, then add synthetic emulsion obtained in step (3), and continue reaction 2 hours.
Embodiment 8
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 45 parts, protecting glue 25 parts, synthetic emulsion 25 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: pure acrylic latex 25 parts, ionized water 25 parts, nonionic polyurethane dispersion agent 4 parts, wetting agent (X-405) 2 parts, gel 12 parts, pigment (R-902) 12 parts, filler (600 order coarse whiting) 7 parts, 0.1 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.4 part.
Protecting glue: methylcellulose gum 25 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 15 parts, aluminium salt 3 parts, alcohol ester 12 parts, 85 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 102ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 1 hour, then add synthetic emulsion obtained in step (3), and continue reaction 2 hours.
Embodiment 9
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 42 parts, protecting glue 23 parts, synthetic emulsion 23 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: pure acrylic latex 23 parts, ionized water 23 parts, nonionic polyurethane dispersion agent 3 parts, wetting agent (X-405) 1 part, gel 13 parts, pigment (R-902) 11 parts, filler (600 order coarse whiting) 6 parts, 0.2 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.5 part.
Protecting glue: methylcellulose gum 23 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 13 parts, aluminium salt 4 parts, alcohol ester 12 parts, 83 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 103ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 2 hours, then add synthetic emulsion obtained in step (3), and continue reaction 1 hour.
Embodiment 10
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 48 parts, protecting glue 28 parts, synthetic emulsion 28 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: pure acrylic latex 28 parts, ionized water 28 parts, nonionic polyurethane dispersion agent 4 parts, wetting agent (X-405) 2 parts, gel 14 parts, pigment (R-902) 14 parts, filler (600 order coarse whiting) 9 parts, 0.2 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.5 part.
Protecting glue: methylcellulose gum 28 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 18 parts, ammonium salt 3 parts, alcohol ester 12 parts, 85 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 105ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 2 hours, then add synthetic emulsion obtained in step (3), and continue reaction 2 hours.
Embodiment 11
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 40 parts, protecting glue 20 parts, synthetic emulsion 20 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: water-base fluorocarbon emulsion 10 parts, pure acrylic latex 10 parts, ionized water 20 parts, nonionic polyurethane dispersion agent 3 parts, wetting agent (X-405) 1 part, gel 10 parts, pigment (R-902) 10 parts, filler (600 order coarse whiting) 5 parts, 0.1 part, sterilant, defoamer (NX202) 0.2 part, thickening material (TT-615) 0.3 part.
Protecting glue: polyvinyl alcohol 10 parts, methylcellulose gum 10 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 10 parts, ammonium salt 2 parts, propylene glycol 1 part, 80 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 100ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 1 hour, then add synthetic emulsion obtained in step (3), and continue reaction 1 hour.
Embodiment 12
This kind of water-based rock color coating material comprises the raw material of following weight parts: base paint 50 parts, protecting glue 30 parts, synthetic emulsion 30 parts.Following raw material is all on sale on the market.
Base paint comprises the raw material of following weight parts: water-base fluorocarbon emulsion 15 parts, pure acrylic latex 15 parts, ionized water 30 parts, nonionic polyurethane dispersion agent 5 parts, wetting agent (X-405) 3 parts, gel 15 parts, pigment (R-902) 15 parts, filler (600 order coarse whiting) 10 parts, 0.2 part, sterilant, defoamer (NX202) 0.3 part, thickening material (TT-615) 0.6 part.
Protecting glue: polyvinyl alcohol 15 parts, methylcellulose gum 15 parts.
Synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 20 parts, ammonium salt 4 parts, propylene glycol 1 part, alcohol ester 12 parts, 90 parts, water.
The preparation of this kind of water-based rock color coating material:
(1) mixed by each composition of described base paint, viscosity controller is at 105ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 2 hours, then add synthetic emulsion obtained in step (3), and continue reaction 2 hours.
Although the present invention with embodiment openly as above; but it is also not used to limit protection scope of the present invention; any technician being familiar with this technology, not departing from the change and retouching done in the spirit and scope of the present invention, all should belong to protection scope of the present invention.

Claims (7)

1. a water-based rock color coating material, is characterized in that: described water-based rock color coating material comprises the raw material of following weight parts: base paint 40 ~ 50 parts, protecting glue 20 ~ 30 parts, synthetic emulsion 20 ~ 30 parts; Described base paint comprises the raw material of following weight parts: emulsion 20 ~ 30 parts, ionized water 20 ~ 30 parts, dispersion agent 3 ~ 5 parts, wetting agent 1 ~ 3 part, gel 10 ~ 15 parts, pigment 10 ~ 15 parts, filler 5 ~ 10 parts, 0.1 ~ 0.2 part, sterilant, defoamer 0.2 ~ 0.3 part, thickening material 0.3 ~ 0.6 part; Described protecting glue is wetting ability protecting glue, and described wetting ability protecting glue comprises at least one in polyvinyl alcohol, methylcellulose gum and ethyl cellulose; Described synthetic emulsion comprises the raw material of following weight parts: negatively charged ion synthetic resin solution 10 ~ 20 parts, retardant 2 ~ 4 parts, film coalescence aid 1 ~ 2 part, 80 ~ 90 parts, water.
2. a kind of water-based rock color coating material according to claim 1, is characterized in that: the emulsion in described base paint comprises at least one in water-base fluorocarbon emulsion and pure acrylic latex.
3. a kind of water-based rock color coating material according to claim 1, it is characterized in that: described dispersion agent is nonionic surface active agent class, described wetting agent is aniorfic surfactant, and described thickening material is the swelling associative thickener of alkali.
4. a kind of water-based rock color coating material according to claim 1, is characterized in that: described negatively charged ion synthetic resin solution comprises at least one in acrylamide and fluorine richness copolymer emulsion.
5. a kind of water-based rock color coating material according to claim 1, is characterized in that: described retardant is the wherein one in calcium salt, magnesium salts, aluminium salt and ammonium salt.
6. a kind of water-based rock color coating material according to claim 1, is characterized in that: described film coalescence aid comprises at least one in propylene glycol and alcohol ester 12.
7. a preparation method for water-based rock color coating material as claimed in claim 1, is characterized in that, comprise the following steps:
(1) mixed by each composition of described base paint, viscosity controller is at 100 ~ 105ku;
(2) each composition of described protecting glue is mixed;
(3) each composition of described synthetic emulsion is mixed;
(4) base paint obtained in step (1) is joined in protecting glue obtained in step (2), stir, gelatinization reaction 1 ~ 2 hour, then add synthetic emulsion obtained in step (3), and continue reaction 1 ~ 2 hour.
CN201310696595.4A 2013-12-18 2013-12-18 Aqueous rock color paint and preparation method thereof Pending CN104725944A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310696595.4A CN104725944A (en) 2013-12-18 2013-12-18 Aqueous rock color paint and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201310696595.4A CN104725944A (en) 2013-12-18 2013-12-18 Aqueous rock color paint and preparation method thereof

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CN104725944A true CN104725944A (en) 2015-06-24

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07247450A (en) * 1994-03-11 1995-09-26 Internatl Paint Kk Aqueous multi-color coating composition
CN101343436A (en) * 2008-08-06 2009-01-14 窦俊英 Novel water-covering water gorgeous paint and preparation thereof
CN101591491A (en) * 2008-05-26 2009-12-02 亚士漆(上海)有限公司 A kind of fully water based granite multicolor paint and preparation method thereof
CN103254710A (en) * 2013-04-11 2013-08-21 三棵树涂料股份有限公司 Scraping water-in-water multi-color paint and preparation method thereof
CN103333564A (en) * 2013-05-10 2013-10-02 南安市东宝新型建材有限公司 Granite imitating coating material and preparation method thereof
CN102876169B (en) * 2012-10-29 2014-10-08 重庆固安捷防腐保温工程有限公司 Suspension bleeding-proof water-based multicolor basic paint and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07247450A (en) * 1994-03-11 1995-09-26 Internatl Paint Kk Aqueous multi-color coating composition
CN101591491A (en) * 2008-05-26 2009-12-02 亚士漆(上海)有限公司 A kind of fully water based granite multicolor paint and preparation method thereof
CN101343436A (en) * 2008-08-06 2009-01-14 窦俊英 Novel water-covering water gorgeous paint and preparation thereof
CN102876169B (en) * 2012-10-29 2014-10-08 重庆固安捷防腐保温工程有限公司 Suspension bleeding-proof water-based multicolor basic paint and preparation method thereof
CN103254710A (en) * 2013-04-11 2013-08-21 三棵树涂料股份有限公司 Scraping water-in-water multi-color paint and preparation method thereof
CN103333564A (en) * 2013-05-10 2013-10-02 南安市东宝新型建材有限公司 Granite imitating coating material and preparation method thereof

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