CN104312341A - Reflective heat-insulation type really stone paint and preparation method thereof - Google Patents
Reflective heat-insulation type really stone paint and preparation method thereof Download PDFInfo
- Publication number
- CN104312341A CN104312341A CN201410492357.6A CN201410492357A CN104312341A CN 104312341 A CN104312341 A CN 104312341A CN 201410492357 A CN201410492357 A CN 201410492357A CN 104312341 A CN104312341 A CN 104312341A
- Authority
- CN
- China
- Prior art keywords
- parts
- reflection
- mineral varnish
- true mineral
- color sand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003973 paint Substances 0.000 title claims abstract description 7
- 238000009413 insulation Methods 0.000 title abstract description 10
- 239000004575 stone Substances 0.000 title abstract description 5
- 239000004576 sand Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 13
- 239000001913 cellulose Substances 0.000 claims abstract description 11
- 229920002678 cellulose Polymers 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003086 colorant Substances 0.000 claims abstract description 5
- 239000003899 bactericide agent Substances 0.000 claims abstract description 3
- 239000000839 emulsion Substances 0.000 claims abstract description 3
- 239000002562 thickening agent Substances 0.000 claims abstract description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 23
- 239000011707 mineral Substances 0.000 claims description 23
- 239000002966 varnish Substances 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 14
- 238000004581 coalescence Methods 0.000 claims description 12
- 230000008719 thickening Effects 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 10
- 239000013530 defoamer Substances 0.000 claims description 10
- 239000004816 latex Substances 0.000 claims description 10
- 229920000126 latex Polymers 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical group CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- -1 alcohol ester Chemical class 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 125000005375 organosiloxane group Chemical group 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 238000010276 construction Methods 0.000 description 5
- 239000007921 spray Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a reflective heat-insulation type really stone paint and a preparation method thereof, wherein the reflective heat-insulation type really stone paint is prepared from the following components in parts by weight: 100-110 parts of water, 2-3 parts of cellulose, 1-2 parts of a neutralizing agent, 0.5-2 parts of a defoaming agent, 10-20 parts of an anti-freezing agent, 1-2 parts of a bactericide, 100-140 parts of a silicone acrylic emulsion, 10-15 parts of a film-forming auxiliary agent, 2-5 parts of a thickening agent, and 700-750 parts of a reflective type color sand. The prepared reflective heat-insulation type really stone paint not only has the characteristics of rich colors, stable performance, safety, no toxicity and the like, but also has the efficacies of reflective heat insulation, environmental protection, energy saving and the like.
Description
Technical field
The present invention relates to true mineral varnish of a kind of reflection heat-insulating type and preparation method thereof, belong to technical field of chemical paint.
Background technology
Along with the development of society, improving constantly of living standards of the people, material of construction and decoration technology are also at development.True mineral varnish is in recent years at building trade development building coating comparatively rapidly, its similar natural real stone, rich color, the advantages such as have intensity good, hardness is high, corrosion-resistant, widely applicable.Present building advocates energy-conserving and environment-protective, but existing thicker insulating layer of external wall of building has increased the weight of the load-bearing of buildings, there is potential safety hazard.
Summary of the invention
For the problems referred to above, the object of this invention is to provide true mineral varnish of a kind of reflection heat-insulating type and preparation method thereof.Applying this true mineral varnish can effective save energy as skin coating, reduces the construction thickness of skin thermal insulation layer, reduces the load-bearing of buildings.
For achieving the above object, the present invention adopts following technical scheme:
The true mineral varnish of a kind of reflection heat-insulating type, formulated by its parts by weight by following component:
Water 100-110 part; Mierocrystalline cellulose 2-3 part;
Neutralizing agent 1-2 part; Defoamer 0.5-2 part;
Frostproofer 10-20 part; Sterilant 1-2 part;
Organosilicon crylic acid latex 100-140 part; Film coalescence aid 10-15 part;
Thickening material 2-5 part; Reflection-type color sand 700-750 part.
Described thickening material is hydrophobic base thickening material or associative thickener, wherein one or both; Described organosilicon crylic acid latex is fluorine-silicon modified acrylic resin emulsion; The film coalescence aid of described film coalescence aid to be alcohol ester 12 be main component; Described frostproofer is one or both of propylene glycol or ethylene glycol; Described sterilant is Kathon CG series bactericidal agent; Described defoamer is one or both of silicon ether Copolymer or organo-siloxane; Described neutralizing agent is ammoniacal liquor class or ammonium salt class neutralizing agent; Described Mierocrystalline cellulose is Natvosol.
On the color sand of described reflection-type is that Hensel steps infrared reflecting paint and general inorganic mill base oiliness is coated or sintering processing the dyes color sand of white, dye the artificially colored color sand had for infrared reflection function.
The preparation method of the true mineral varnish of a kind of reflection heat-insulating type, there is following step: first in Scattered Kettle, inject water, then drop into Mierocrystalline cellulose, neutralizing agent, frostproofer, sterilant, thickening material successively, dispersing speed is adjusted to 500-800rpm and stirs, disperse 30 minutes to uniform state; Drop into organosilicon crylic acid latex subsequently, dispersing speed is adjusted to 300-500rpm, disperse 10 minutes; Then drop into film coalescence aid and defoamer, continue dispersion 5 minutes; Finally the color sand of reflection-type adding different colours is needed to stir according to color, the obtained true mineral varnish of reflection heat-insulating type.
The constructional method of the true mineral varnish of a kind of reflection heat-insulating type of the present invention is: true mineral varnish uses spray gun spraying, easy construction, and the nozzle diameter of spray gun requires to select according to difference.
The true mineral varnish tool of a kind of reflection heat-insulating type adopting above-mentioned composition and engineering to prepare has the following advantages:
The true mineral varnish of reflection heat-insulating type of the present invention effectively can improve the reflection to sunlight, has obvious effect of heat insulation, save energy; Not containing volatile harmful material, protection of the environment; There is the good characteristic of reflective insulation, the thickness of skin adiabator layer can be reduced, improve construction speed, thus alleviate buildings deadweight, reduce potential safety hazard; Spray gun spraying can be adopted to construct, easy construction, save human cost.
Embodiment
After now specific embodiments of the invention being described in.
embodiment 1
The true mineral varnish of a kind of reflection heat-insulating type, formulated by its parts by weight by following component:
110 parts, water; Mierocrystalline cellulose 3 parts;
Neutralizing agent 2 parts; Defoamer 1.5 parts;
Frostproofer 20 parts; 1.5 parts, sterilant;
Organosilicon crylic acid latex 135 parts; Film coalescence aid 15 parts;
Thickening material 4.5 parts; Color 750 parts, the sand of reflection-type;
The preparation method of the true mineral varnish of a kind of reflection heat-insulating type, there is following step: in Scattered Kettle, first inject 110 parts, water, then Mierocrystalline cellulose 3 parts, neutralizing agent 2 parts, frostproofer 20 parts, 1.5 parts, sterilant, thickening material 4.5 parts is dropped into successively, dispersing speed is adjusted to 500-800rpm stir, disperses 30 minutes to uniform state; Drop into organosilicon crylic acid latex 135 parts subsequently, dispersing speed is adjusted to 300-500rpm, disperses 10 minutes; Then drop into film coalescence aid 15 parts and defoamer 1.5 parts, continue dispersion 5 minutes; Finally the color sand of reflection-type adding different colours is needed to stir according to color.
Reflection heat-insulating type true mineral varnish main performance index prepared by the present embodiment is as follows:
| Project | Performance index |
| Near-infrared reflection ratio, >= | L* value/100(L* value is brightness value) |
| Hemispherical emissivity | 0.86 |
| The heat insulation temperature difference, DEG C | 12 |
embodiment 2
The true mineral varnish of a kind of reflection heat-insulating type, formulated by its parts by weight by following component:
100 parts, water; Mierocrystalline cellulose 2 parts;
Neutralizing agent 1 part; Defoamer 1 part;
Frostproofer 10 parts; 1 part, sterilant;
Organosilicon crylic acid latex 110 parts; Film coalescence aid 10 parts;
Thickening material 2 parts; Color 700 parts, the sand of reflection-type;
The preparation method of the true mineral varnish of a kind of reflection heat-insulating type, there is following step: in Scattered Kettle, first inject 100 parts, water, then Mierocrystalline cellulose 2 parts, neutralizing agent 1 part, frostproofer 10 parts, 1 part, sterilant, thickening material 2 parts is dropped into successively, dispersing speed is adjusted to 500-800rpm stir, disperses 30 minutes to uniform state; Drop into organosilicon crylic acid latex 110 parts subsequently, dispersing speed is adjusted to 300-500rpm, disperses 10 minutes; Then drop into film coalescence aid 10 parts and defoamer 1 part, continue dispersion 5 minutes; Finally the color sand of reflection-type adding different colours is needed to stir according to color.
Reflection heat-insulating type true mineral varnish main performance index prepared by the present embodiment is as follows:
| Project | Performance index |
| Near-infrared reflection ratio, >= | L* value/100(L* value is brightness value) |
| Hemispherical emissivity | 0.85 |
| The heat insulation temperature difference, DEG C | 11 |
Claims (4)
1. the true mineral varnish of reflection heat-insulating type, is characterized in that: formulated by its parts by weight by following component:
Water 100-110 part; Mierocrystalline cellulose 2-3 part;
Neutralizing agent 1-2 part; Defoamer 0.5-2 part;
Frostproofer 10-20 part; Sterilant 1-2 part;
Organosilicon crylic acid latex 100-140 part; Film coalescence aid 10-15 part;
Thickening material 2-5 part; Reflection-type color sand 700-750 part.
2. the true mineral varnish of reflection heat-insulating type according to claim 1, is characterized in that: described thickening material is hydrophobic base thickening material or associative thickener, wherein one or both; Described organosilicon crylic acid latex is fluorine-silicon modified acrylic resin emulsion; The film coalescence aid of described film coalescence aid to be alcohol ester 12 be main component; Described frostproofer is one or both of propylene glycol or ethylene glycol; Described sterilant is Kathon CG series bactericidal agent; Described defoamer is one or both of silicon ether Copolymer or organo-siloxane; Described neutralizing agent is ammoniacal liquor class or ammonium salt class neutralizing agent; Described Mierocrystalline cellulose is Natvosol.
3. the true mineral varnish of reflection heat-insulating type according to claim 1, it is characterized in that: on the color sand of described reflection-type is that Hensel steps infrared reflecting paint and general inorganic mill base oiliness is coated or sintering processing the dyes color sand of white, dye the artificially colored color sand had for infrared reflection function.
4. the preparation method of the true mineral varnish of reflection heat-insulating type, it is characterized in that, there is following step: first in Scattered Kettle, inject water, then Mierocrystalline cellulose, neutralizing agent, frostproofer, sterilant, thickening material is dropped into successively, dispersing speed is adjusted to 500-800rpm stir, disperses 30 minutes to uniform state; Drop into organosilicon crylic acid latex subsequently, dispersing speed is adjusted to 300-500rpm, disperse 10 minutes; Then drop into film coalescence aid and defoamer, continue dispersion 5 minutes; Finally the color sand of reflection-type adding different colours is needed to stir according to color, the obtained true mineral varnish of reflection heat-insulating type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410492357.6A CN104312341B (en) | 2014-09-24 | 2014-09-24 | Reflective heat-insulation type really stone paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410492357.6A CN104312341B (en) | 2014-09-24 | 2014-09-24 | Reflective heat-insulation type really stone paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104312341A true CN104312341A (en) | 2015-01-28 |
| CN104312341B CN104312341B (en) | 2017-04-26 |
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Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104671709A (en) * | 2015-03-09 | 2015-06-03 | 乌鲁木齐市建筑建材科学研究院有限责任公司 | External wall stone-like paint prepared from industrial waste liquid slag |
| CN104692707A (en) * | 2015-01-29 | 2015-06-10 | 三棵树涂料股份有限公司 | Functional real stone paint building exterior wall coating material and preparation method thereof |
| CN104876469A (en) * | 2015-05-08 | 2015-09-02 | 上海贝塔建筑科技有限公司 | Imitation stone paint for preparing imitation sandstone and construction technology of imitation stone paint |
| CN104927541A (en) * | 2015-06-23 | 2015-09-23 | 陈良伢 | Reflecting heat-insulation type real stone paint and preparation technology thereof |
| CN105331231A (en) * | 2015-11-06 | 2016-02-17 | 南通市乐佳涂料有限公司 | Energy-saving and environment-friendly real stone type composite coating and preparation method and construction method thereof |
| CN105601177A (en) * | 2015-12-18 | 2016-05-25 | 三棵树涂料股份有限公司 | Thermal insulation reflective stone-like coating and preparation method thereof |
| CN105621959A (en) * | 2015-12-18 | 2016-06-01 | 三棵树涂料股份有限公司 | Flexible true stone paint and preparation method thereof |
| CN105860706A (en) * | 2016-04-28 | 2016-08-17 | 安徽开林新材料股份有限公司 | Lacquer for building outer wall marble-imitated decoration |
| CN106243869A (en) * | 2016-08-24 | 2016-12-21 | 上海贝塔建筑科技有限公司 | A kind of sand wall-like fluorescent aqueous paint and preparation method |
| CN106280650A (en) * | 2016-08-11 | 2017-01-04 | 无锡市虎皇漆业有限公司 | Reflective insulation ancient painted pottery rock coating and preparation method thereof |
| CN107739532A (en) * | 2017-09-14 | 2018-02-27 | 成都博美实润科技有限公司 | A kind of exterior wall true stone paint and preparation method thereof |
| CN108018955A (en) * | 2017-10-31 | 2018-05-11 | 上海宇培特种建材有限公司 | Composite thermal insulation system inside and outside wall |
| CN108793835A (en) * | 2018-06-25 | 2018-11-13 | 滁州麦斯特新型建材有限公司 | A kind of new type natural lacquer and preparation method thereof |
| CN109233471A (en) * | 2018-08-28 | 2019-01-18 | 广东神洲化学工业股份有限公司 | The outer wall building coating and preparation method thereof for having effects that reflective insulation Yu insulation |
| CN109593417A (en) * | 2018-12-12 | 2019-04-09 | 亚士漆(上海)有限公司 | A kind of coating aggregate, coating and its preparation method and application |
| CN109592933A (en) * | 2018-11-24 | 2019-04-09 | 浙江时进节能环保涂料有限公司 | Low-carbon microlite insulating moulding coating of nonuniformity and preparation method thereof |
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| CN112175469A (en) * | 2020-10-28 | 2021-01-05 | 湖州绿色新材股份有限公司 | Low-cost reflective heat-insulation type real stone paint |
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Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104692707A (en) * | 2015-01-29 | 2015-06-10 | 三棵树涂料股份有限公司 | Functional real stone paint building exterior wall coating material and preparation method thereof |
| CN104671709B (en) * | 2015-03-09 | 2016-10-12 | 乌鲁木齐市建筑建材科学研究院有限责任公司 | A kind of exterior wall true stone paint utilizing industrial waste liquid slag to prepare |
| CN104671709A (en) * | 2015-03-09 | 2015-06-03 | 乌鲁木齐市建筑建材科学研究院有限责任公司 | External wall stone-like paint prepared from industrial waste liquid slag |
| CN104876469A (en) * | 2015-05-08 | 2015-09-02 | 上海贝塔建筑科技有限公司 | Imitation stone paint for preparing imitation sandstone and construction technology of imitation stone paint |
| CN104876469B (en) * | 2015-05-08 | 2017-04-05 | 上海贝塔建筑科技有限公司 | A kind of true mineral varnish material and its construction technology for preparing imitative sandstone |
| CN104927541A (en) * | 2015-06-23 | 2015-09-23 | 陈良伢 | Reflecting heat-insulation type real stone paint and preparation technology thereof |
| CN105331231A (en) * | 2015-11-06 | 2016-02-17 | 南通市乐佳涂料有限公司 | Energy-saving and environment-friendly real stone type composite coating and preparation method and construction method thereof |
| CN105331231B (en) * | 2015-11-06 | 2018-09-11 | 南通市乐佳涂料有限公司 | A kind of energy-saving ring fidelity stone-type composite dope and preparation method thereof and construction method |
| CN105621959A (en) * | 2015-12-18 | 2016-06-01 | 三棵树涂料股份有限公司 | Flexible true stone paint and preparation method thereof |
| CN105601177A (en) * | 2015-12-18 | 2016-05-25 | 三棵树涂料股份有限公司 | Thermal insulation reflective stone-like coating and preparation method thereof |
| CN105860706A (en) * | 2016-04-28 | 2016-08-17 | 安徽开林新材料股份有限公司 | Lacquer for building outer wall marble-imitated decoration |
| CN106280650A (en) * | 2016-08-11 | 2017-01-04 | 无锡市虎皇漆业有限公司 | Reflective insulation ancient painted pottery rock coating and preparation method thereof |
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