CN105860706A - Lacquer for building outer wall marble-imitated decoration - Google Patents

Lacquer for building outer wall marble-imitated decoration Download PDF

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Publication number
CN105860706A
CN105860706A CN201610285027.9A CN201610285027A CN105860706A CN 105860706 A CN105860706 A CN 105860706A CN 201610285027 A CN201610285027 A CN 201610285027A CN 105860706 A CN105860706 A CN 105860706A
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China
Prior art keywords
parts
lacquer
add
sufficiently mixed
nano
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Pending
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CN201610285027.9A
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Chinese (zh)
Inventor
王和山
王和东
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Anhui Kailin New Material Co Ltd
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Anhui Kailin New Material Co Ltd
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Priority to CN201610285027.9A priority Critical patent/CN105860706A/en
Publication of CN105860706A publication Critical patent/CN105860706A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/32—Modified amine-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses lacquer for building outer wall marble-imitated decoration and relates to the technical field of building coating. The lacquer is prepared from, by weight, 30-40 parts of acrylic acid resin, 20-30 parts of methylated amino resin, 12-17 parts of natural colorful sand, 10-15 parts of fly ash, 8-12 parts of petroleum coke, 6-10 parts of chlorosulfonated polyethylene, 5-8 parts of Carbomer resin, 5-8 parts of soybean albumin glue, 4-6 parts of flexibilizer, 4-6 parts of nano titanium dioxide, 3-5 parts of nano aluminum oxide, 3-5 parts of castor oil, 2-3 parts of polyoxyethylene lauryl ether, 2-3 parts of sodium hexametaphosphate and 100-150 parts of water. The lacquer can be firmly attached to a building outer wall, is free of toxin and smell, and does not release harmful matter, appearance of a formed lacquer film is similar to that of marble, and the lacquer has natural and real gloss, has excellent fire prevention performance, water prevention performance, acid and alkali resistance and stain resistance, can effectively relieve erosion of the outside environment to the building outer wall and prolongs the service life of a building.

Description

True mineral varnish used by a kind of external wall parian decoration
Technical field:
The present invention relates to building coating technical field, be specifically related to a kind of external wall parian decoration and use True mineral varnish.
Background technology:
True mineral varnish is the coating that a kind of decorative effect exactly likes marble, granite.Mainly use shades of colour Natural stone-powder formulated, be applied to the imitative stone effect of external wall, therefore also known as liquid stone.Very Building after mineral varnish finishing, has natural real natural colour, gives elegance, harmony, serious Aesthetic feeling, be suitable for the indoor and outdoor decoration of all kinds of building.Particularly decorate on curved-surface building thing, raw Dynamic true to nature, there is the effect of a kind of back to nature.But the resistance to water of presently commercially available true mineral varnish and resistance to soiling are poor, Have a strong impact on the true mineral varnish decorative effect as exterior coating.
Summary of the invention:
The technical problem to be solved is to provide one to have excellent fire prevention, waterproof, acid and alkali-resistance Decorate with the external wall parian of resistance to soiling and good decorating effect and use true mineral varnish.
The technical problem to be solved uses following technical scheme to realize:
True mineral varnish used by a kind of external wall parian decoration, is made up of the raw material of following parts by weight:
Acrylic resin 30-40 part, methyl-etherified amino resins 20-30 part, natural color stone sand 12-17 part, Flyash 10-15 part, petroleum coke 8-12 part, chlorosulfonated polyethylene 6-10 part, carbomer 5-8 part, Soybean protein glue 5-8 part, toughener 4-6 part, nanometer titanium dioxide 4-6 part, nano aluminium oxide 3-5 part, Castor oil 3-5 part, ethoxylated dodecyl alcohol 2-3 part, calgon 2-3 part, water 100-150 part.
Its preparation method comprises the steps:
(1) acrylic resin, methyl-etherified amino resins and nano aluminium oxide are sufficiently mixed, grinding at room temperature 15 Min, microwave treatment 10min under microwave frequency 2450MHz, power 700W, it is subsequently adding oil Jiao, chlorosulfonated polyethylene and soybean protein glue, continue microwave treatment 5min, obtain material I；
(2) in water, add flyash and nanometer titanium dioxide, be sufficiently mixed the gentle and quiet 30min that puts of rear chamber, then add Enter castor oil and ethoxylated dodecyl alcohol, at 0-5 DEG C, stand 1h after mixing, obtain material II；
(3) in material I, material II, natural color stone sand, carbomer, toughener and calgon are added, Add in ball mill after being sufficiently mixed, be milled to fineness less than 50 μm.
Described toughener is made up of the raw material of following parts by weight: low density polyethylene (LDPE) 15-20 part, ardealite Powder 10-15 part, microwax 8-11 part, glutinous rice flour 6-9 part, microcrystalline cellulose 4-7 part, PEG400 4-7 part, polyvinylpyrrolidone 3-6 part, nano-calcium carbonate 3-6 part, urea 2-4 part, spaonin powder 2-4 Part, bone black 1-2 part, melamine 1-2 part, coal tar 10-15 part, rosin 20-25 part, its system Preparation Method is: first add in rosin by low density polyethylene (LDPE) and microwax, in supersonic frequency 40kHz, Ultrasonically treated 15min under power 50W, under microwave frequency 2450MHz, power 700W at microwave Reason 10min, is subsequently adding PEG400, nano-calcium carbonate and bone black, continues microwave treatment 5min, After naturally cool to adding phosphogypsum powder, urea, melamine and coal tar when 60-70 DEG C, insulation mixing 10min, adds glutinous rice flour, microcrystalline cellulose, polyvinylpyrrolidone after continuing to naturally cool to room temperature And spaonin powder, it is sufficiently mixed uniformly.
The addition of this toughener can not only improve paint vehicle mobility and paint film flexibility, moreover it is possible to improves paint film Insulating properties, wearability and heat-resisting quantity.
The invention has the beneficial effects as follows: the present invention true mineral varnish energy strong bond on external wall, nontoxic nothing Taste, will not discharge harmful substance, and the paint film appearance formed is similar to marble, have natural truly Natural gloss, and have excellence fire prevention, waterproof, acid and alkali-resistance and resistance to soiling, outside effectively slowing down The erosion to external wall of boundary's environment, extends the life-span of building.
Detailed description of the invention:
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
(1) 30 parts of acrylic resins, 30 parts of methyl-etherified amino resins and 3 parts of nano aluminium oxides are sufficiently mixed, Grinding at room temperature 15min, microwave treatment 10min under microwave frequency 2450MHz, power 700W, so 8 parts of petroleum cokes of rear addition, 8 parts of chlorosulfonated polyethylenes and 5 parts of soybean protein glue, continue microwave treatment 5min, Obtain material I；
(2) in 150 parts of water, add 10 parts of flyash and 6 parts of nanometer titanium dioxides, be sufficiently mixed that rear chamber is gentle and quiet puts 30min, adds 3 parts of castor oil and 2 parts of ethoxylated dodecyl alcohols, quiet at 0-5 DEG C after mixing Put 1h, obtain material II；
(3) in material I add material II, 12 parts of natural color stone sands, 6 parts of carbomers, 4 parts of toughener and 2 parts of calgons, add in ball mill after being sufficiently mixed, and are milled to fineness less than 50 μm.
The preparation of toughener: first 20 parts of low density polyethylene (LDPE)s and 10 parts of microwaxes are added in 25 parts of rosin, Ultrasonically treated 15min under supersonic frequency 40kHz, power 50W, then at microwave frequency 2450MHz, Microwave treatment 10min under power 700W, is subsequently adding 4 parts of PEG400s, 5 parts of nano-calcium carbonates and 1 Part bone black, continues microwave treatment 5min, after naturally cool to add when 60-70 DEG C 10 parts of phosphogypsum powders, 2 Part urea, 1 part of melamine and 15 parts of coal tar, insulation mixing 10min, continues to naturally cool to room temperature After add 8 parts of glutinous rice flours, 4 parts of microcrystalline celluloses, 4 parts of polyvinylpyrrolidones and 2 parts of spaonin powders, fill Divide and mix.
Embodiment 2
(1) 40 parts of acrylic resins, 25 parts of methyl-etherified amino resins and 4 parts of nano aluminium oxides are sufficiently mixed, Grinding at room temperature 15min, microwave treatment 10min under microwave frequency 2450MHz, power 700W, so 8 parts of petroleum cokes of rear addition, 6 parts of chlorosulfonated polyethylenes and 5 parts of soybean protein glue, continue microwave treatment 5min, Obtain material I；
(2) in 150 parts of water, add 15 parts of flyash and 4 parts of nanometer titanium dioxides, be sufficiently mixed that rear chamber is gentle and quiet puts 30min, adds 4 parts of castor oil and 2 parts of ethoxylated dodecyl alcohols, quiet at 0-5 DEG C after mixing Put 1h, obtain material II；
(3) in material I add material II, 15 parts of natural color stone sands, 5 parts of carbomers, 5 parts of toughener and 2 parts of calgons, add in ball mill after being sufficiently mixed, and are milled to fineness less than 50 μm.
The preparation of toughener: first 15 parts of low density polyethylene (LDPE)s and 8 parts of microwaxes are added in 20 parts of rosin, Ultrasonically treated 15min under supersonic frequency 40kHz, power 50W, then at microwave frequency 2450MHz, Microwave treatment 10min under power 700W, is subsequently adding 6 parts of PEG400s, 3 parts of nano-calcium carbonates and 1 Part bone black, continues microwave treatment 5min, after naturally cool to add when 60-70 DEG C 15 parts of phosphogypsum powders, 2 Part urea, 2 parts of melamines and 10 parts of coal tar, insulation mixing 10min, continues to naturally cool to room temperature After add 6 parts of glutinous rice flours, 5 parts of microcrystalline celluloses, 3 parts of polyvinylpyrrolidones and 2 parts of spaonin powders, fill Divide and mix.
The general principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (3)

1. true mineral varnish used by an external wall parian decoration, it is characterised in that by following parts by weight Raw material make:
Acrylic resin 30-40 part, methyl-etherified amino resins 20-30 part, natural color stone sand 12-17 part, Flyash 10-15 part, petroleum coke 8-12 part, chlorosulfonated polyethylene 6-10 part, carbomer 5-8 part, Soybean protein glue 5-8 part, toughener 4-6 part, nanometer titanium dioxide 4-6 part, nano aluminium oxide 3-5 part, Castor oil 3-5 part, ethoxylated dodecyl alcohol 2-3 part, calgon 2-3 part, water 100-150 part.
True mineral varnish used by external wall parian the most according to claim 1 decoration, it is characterised in that Described toughener is made up of the raw material of following parts by weight: low density polyethylene (LDPE) 15-20 part, phosphogypsum powder 10-15 part, microwax 8-11 part, glutinous rice flour 6-9 part, microcrystalline cellulose 4-7 part, PEG400 4-7 Part, polyvinylpyrrolidone 3-6 part, nano-calcium carbonate 3-6 part, urea 2-4 part, spaonin powder 2-4 part, Bone black 1-2 part, melamine 1-2 part, coal tar 10-15 part, rosin 20-25 part, its preparation side Method is: first add in rosin by low density polyethylene (LDPE) and microwax, in supersonic frequency 40kHz, power Ultrasonically treated 15min under 50W, microwave treatment 10 under microwave frequency 2450MHz, power 700W Min, is subsequently adding PEG400, nano-calcium carbonate and bone black, continues microwave treatment 5min, treats certainly So being cooled to when 60-70 DEG C add phosphogypsum powder, urea, melamine and coal tar, insulation mixes 10min, Glutinous rice flour, microcrystalline cellulose, polyvinylpyrrolidone and Chinese honey locust is added after continuing to naturally cool to room temperature Powder, is sufficiently mixed uniformly.
True mineral varnish used by external wall parian the most according to claim 1 decoration, it is characterised in that Its preparation method comprises the steps:
(1) acrylic resin, methyl-etherified amino resins and nano aluminium oxide are sufficiently mixed, grinding at room temperature 15 Min, microwave treatment 10min under microwave frequency 2450MHz, power 700W, it is subsequently adding oil Jiao, chlorosulfonated polyethylene and soybean protein glue, continue microwave treatment 5min, obtain material I；
(2) in water, add flyash and nanometer titanium dioxide, be sufficiently mixed the gentle and quiet 30min that puts of rear chamber, then add Enter castor oil and ethoxylated dodecyl alcohol, at 0-5 DEG C, stand 1h after mixing, obtain material II；
(3) in material I, material II, natural color stone sand, carbomer, toughener and calgon are added, Add in ball mill after being sufficiently mixed, be milled to fineness less than 50 μm.
CN201610285027.9A 2016-04-28 2016-04-28 Lacquer for building outer wall marble-imitated decoration Pending CN105860706A (en)

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CN201610285027.9A CN105860706A (en) 2016-04-28 2016-04-28 Lacquer for building outer wall marble-imitated decoration

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610285027.9A CN105860706A (en) 2016-04-28 2016-04-28 Lacquer for building outer wall marble-imitated decoration

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106633653A (en) * 2016-12-16 2017-05-10 东至天孚化工有限公司 Processing material for stirring paddle of chemical reaction kettle and preparation method of processing material
CN107033741A (en) * 2017-05-27 2017-08-11 安徽誉林汽车部件有限公司 A kind of auto parts machinery anticorrosion antirust paint coating and preparation method thereof
CN108531025A (en) * 2018-03-01 2018-09-14 珠海市美筑新材料有限公司 High temperature resistant antimildew and antibacterial type nanometer water baking vanish and preparation method thereof
CN117363122A (en) * 2023-11-09 2024-01-09 安徽开林新材料股份有限公司 Real stone paint and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104312341A (en) * 2014-09-24 2015-01-28 上海宇培特种建材有限公司 Reflective heat-insulation type really stone paint and preparation method thereof
CN104513038A (en) * 2013-09-30 2015-04-15 青岛兴国涂料有限公司 Real stone paint
CN104513556A (en) * 2013-09-30 2015-04-15 青岛兴国涂料有限公司 Really stone paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104513038A (en) * 2013-09-30 2015-04-15 青岛兴国涂料有限公司 Real stone paint
CN104513556A (en) * 2013-09-30 2015-04-15 青岛兴国涂料有限公司 Really stone paint
CN104312341A (en) * 2014-09-24 2015-01-28 上海宇培特种建材有限公司 Reflective heat-insulation type really stone paint and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106633653A (en) * 2016-12-16 2017-05-10 东至天孚化工有限公司 Processing material for stirring paddle of chemical reaction kettle and preparation method of processing material
CN107033741A (en) * 2017-05-27 2017-08-11 安徽誉林汽车部件有限公司 A kind of auto parts machinery anticorrosion antirust paint coating and preparation method thereof
CN108531025A (en) * 2018-03-01 2018-09-14 珠海市美筑新材料有限公司 High temperature resistant antimildew and antibacterial type nanometer water baking vanish and preparation method thereof
CN108531025B (en) * 2018-03-01 2020-04-24 珠海市美筑新材料有限公司 High-temperature-resistant mildew-proof antibacterial nano water-based baking paint and preparation method thereof
CN117363122A (en) * 2023-11-09 2024-01-09 安徽开林新材料股份有限公司 Real stone paint and preparation method and application thereof

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