CN105602383B - A kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting - Google Patents
A kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting Download PDFInfo
- Publication number
- CN105602383B CN105602383B CN201610209420.XA CN201610209420A CN105602383B CN 105602383 B CN105602383 B CN 105602383B CN 201610209420 A CN201610209420 A CN 201610209420A CN 105602383 B CN105602383 B CN 105602383B
- Authority
- CN
- China
- Prior art keywords
- parts
- oyster shell
- shell whiting
- exterior wall
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title claims abstract description 99
- 241000276489 Merlangius merlangus Species 0.000 title claims abstract description 74
- 239000003973 paint Substances 0.000 title claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 56
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 46
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims abstract description 46
- 239000000839 emulsion Substances 0.000 claims abstract description 45
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000843 powder Substances 0.000 claims abstract description 42
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 38
- 239000010457 zeolite Substances 0.000 claims abstract description 38
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000292 calcium oxide Substances 0.000 claims abstract description 25
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002270 dispersing agent Substances 0.000 claims abstract description 25
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000391 magnesium silicate Substances 0.000 claims abstract description 24
- 229910052919 magnesium silicate Inorganic materials 0.000 claims abstract description 24
- 235000019792 magnesium silicate Nutrition 0.000 claims abstract description 24
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 23
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 23
- 239000008367 deionised water Substances 0.000 claims abstract description 23
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 23
- 239000011775 sodium fluoride Substances 0.000 claims abstract description 23
- 235000013024 sodium fluoride Nutrition 0.000 claims abstract description 23
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 23
- 239000001293 FEMA 3089 Substances 0.000 claims abstract description 22
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 22
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 22
- 239000013530 defoamer Substances 0.000 claims abstract description 22
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 22
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 22
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract description 21
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920002545 silicone oil Polymers 0.000 claims abstract description 20
- 229960001124 trientine Drugs 0.000 claims abstract description 20
- 229920001661 Chitosan Polymers 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 16
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 16
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 16
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- 238000001354 calcination Methods 0.000 claims description 44
- 238000002360 preparation method Methods 0.000 claims description 26
- 239000003595 mist Substances 0.000 claims description 15
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000009413 insulation Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 238000010792 warming Methods 0.000 claims description 9
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical group CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 230000001007 puffing effect Effects 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 241000193879 Corbicula fluminea Species 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 241000237536 Mytilus edulis Species 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 241000237509 Patinopecten sp. Species 0.000 claims description 2
- 235000020638 mussel Nutrition 0.000 claims description 2
- 235000020637 scallop Nutrition 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 239000006210 lotion Substances 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- 229920000137 polyphosphoric acid Polymers 0.000 claims 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims 1
- 229940048086 sodium pyrophosphate Drugs 0.000 claims 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 33
- 238000000576 coating method Methods 0.000 abstract description 25
- 239000011248 coating agent Substances 0.000 abstract description 24
- 239000002253 acid Substances 0.000 abstract description 3
- 230000001458 anti-acid effect Effects 0.000 abstract description 3
- 230000003712 anti-aging effect Effects 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 15
- 230000003213 activating effect Effects 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- -1 mosaic Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 150000002085 enols Chemical class 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- 239000011257 shell material Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011468 face brick Substances 0.000 description 3
- 238000001802 infusion Methods 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002078 nanoshell Substances 0.000 description 3
- 235000015170 shellfish Nutrition 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000004887 air purification Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, it is made from the following raw materials in parts by weight：60 80 parts of oyster shell whiting, 40 60 parts of pure-acrylic emulsion, 30 50 parts of styrene-acrylic emulsion, 5 10 parts of surfactant, 5 10 parts of hydroxypropyl methyl cellulose, 5 10 parts of aluminium hydroxide, 10 20 parts of calcium oxide, 35 parts of magnesium silicate, 5 10 parts of zeolite powder, 5 10 parts of polyvinyl alcohol, 15 parts of nano-calcium carbonate, 12 parts of titanium dioxide, 13 parts of polyethylene glycol, 13 parts of turpentine oil, 13 parts of chitosan, 13 parts of trien, 0.1 1 parts of sodium fluoride, water-based 0.1 0.5 parts of silicone oil, 13 parts of defoamer, 13 parts of dispersant, 35 parts of propane diols, 30 50 parts of deionized water.Environment-friendlyexterior exterior wall paint of the present invention contains a variety of specific components, synergistic function has been played between each component, so that gained coating wearability is good, strong adhesive force, anti-aging, acid and alkali-resistance, there is formaldehyde at the same time, it is environmentally protective, wide market nontoxic to human body.
Description
Technical field
The present invention relates to household chemicals field of coating, is related to a kind of exterior coating, contains shellfish in particular to one kind
The Environment-friendlyexterior exterior wall paint of shell powder.
Background technology
Currently, skin decoration in China's is most also using tradition such as granite, mosaic, face brick, aluminium alloy glass
Building materials, not only cost is high for these materials, and has the hidden danger fallen and hurted sb.'s feelings, and is also not easy to safeguard renovation.It is reported that each big city in West Europe
The external wall in city is almost decorated with coating.The ratio for the external wall that Japan and other countries are decorated with coating be up to 70%~
90%, define skyscraper in the national building law such as Singapore, Malaysia and disapprove and decorated using materials such as face bricks.
From now on, China's decorating outer wall of building certainly will walk the road with paint replacement face brick and mosaic material.At present, China's exterior wall latex
Having for having developed and come into operation in paint is following several：1st, pure acrylic acid emulsion paint；2nd, the third emulsion paint of silicon, its weatherability is better than pure
Acrylic latex coating；3rd, aqueous fluorocarbon coating, its weatherability is fine, but price is high；4th, solvent type exterior wall coating, weatherability
It is good, but it is most of not environmentally.
Oyster shell whiting will be propagated artificially with natural shell by being made after high-temperature calcination, crushing.Its constituent is carbon
The calcified materials such as sour calcium, calcium oxide, calcium hydroxide, this has absorption, decomposes as cellular（Formaldehyde, benzene, TVOC, ammonia）'s
Effect and adjusting air humidity, odor eliminating function.Natural roasting oyster shell whiting, ancient times are known as " clam ash ", before cement appearance, quilt
It is widely used in civil engineering, such as clam ash is mixed with sticky rice syrup, bonding material is made, for viscous between city wall and house wall stone
Knot.Exposed to the weather through 1,100, that is, be used in stone weathering, cured clam ash bonding material, still highlights between stone, no
Weather.Patent document (publication number：CN 101774785A) a kind of interior wall coating as the main component with oyster shell whiting is disclosed,
It is using shell calcium carbonate and calcium oxide as main material, using dispersed latex powder as binding agent, with the addition of nano-titanium dioxide and
Anion powder, has the effect of certain purification air.But the technology that oyster shell whiting is used for exterior coating has no report.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, wearability is good, attached
Put forth effort strong, anti-aging, acid and alkali-resistance, while there is formaldehyde, environmentally protective, wide market nontoxic to human body.
Specifically, one aspect of the present invention provides a kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, by the original of following parts by weight
Material is made：60-80 parts of oyster shell whiting, 40-60 parts of pure-acrylic emulsion, 30-50 parts of styrene-acrylic emulsion, 5-10 parts of surfactant, hydroxypropyl
5-10 parts of methylcellulose, 5-10 parts of aluminium hydroxide, 10-20 parts of calcium oxide, 3-5 parts of magnesium silicate, 5-10 parts of zeolite powder, polyethylene
5-10 parts of alcohol, 1-5 parts of nano-calcium carbonate, 1-2 parts of titanium dioxide, 1-3 parts of polyethylene glycol, 1-3 parts of turpentine oil, 1-3 parts of chitosan, three
1-3 parts of ethylene tetra, 0.1-1 parts of sodium fluoride, water-based silicone oil 0.1-0.5 parts, 1-3 parts of defoamer, 1-3 parts of dispersant, the third two
3-5 parts of alcohol, 30-50 parts of deionized water.
In the embodiment of the present invention, the oyster shell whiting can be prepared using mode well known in the prior art,
Can also be commercially.Preferably, the oyster shell whiting is modified Nano oyster shell whiting, and its preparation method includes following step
Suddenly：
（1）Shell is spare with clear water cleaning, drying；It is crushed to 0.1-1mm's using high speed disintegrator or ball mill
The thick micro mist of shell；
（2）The thick micro mist of shell is placed in high temperature resistance furnace and carries out calcining expanding treatment, calcining is forged using three-stage gradient
Burn, specific calcination operation is：（a）Calcining 30-60min is carried out at 400 DEG C；（b）Heated up with the heating rate of 8-12 DEG C/min
To 800 DEG C, and insulation calcining 30-60min at such a temperature；（c）1200 DEG C are warming up to the heating rate of 5-8 DEG C/min, and
Insulation calcining 30-60min at such a temperature, after calcination, cooled to room temperature；
（3）Puffing rear thick micro mist will be calcined and carry out nanometer pulverization processing using nano grinder, obtain modified Nano shell
Powder.
In the embodiment of the present invention, the shell is mussel shell, scallop shell, oyster shell, cycle of sixty years shell, Corbicula fluminea
Shell.
In the embodiment of the present invention, the surfactant is ethoxylated dodecyl alcohol and coconut oleoyl amine
Propyl betaine, the proportioning of the two are 4:3.
In the embodiment of the present invention, the granularity of the magnesium silicate is below 0.5 micron.
In the embodiment of the present invention, the preferred modified zeolite powder of the zeolite powder, the system of the modified zeolite powder
Standby process includes：With natural zeolite, magnesia, zinc oxide, silica according to 3-6:1:1：1 mass ratio is uniformly mixed, so
After be heated to 800 DEG C -1000 DEG C progress calcining at constant temperature, calcination time for 2-6 it is small when, natural cooling to obtain the final product.
In the embodiment of the present invention, the zeolite powder can also use commercial zeolite powder.
In the embodiment of the present invention, the defoamer is dimethyl silicone polymer or tributyl phosphate.
In the embodiment of the present invention, the dispersant is sodium polyphosphate, calgon, pyrophosphoric acid
One or more in sodium, lauryl sodium sulfate.
In the embodiment of the present invention, there is provided a kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, by following weight
The raw material of part is made：80 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, 6 parts of surfactant, hydroxypropyl methyl are fine
8 parts of dimension element, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, 8 parts of polyvinyl alcohol, 3 parts of nano-calcium carbonate,
1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, 2 parts of trien, 0.5 part of sodium fluoride, water-based silicon
0.3 part of oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water.
In the embodiment of the present invention, there is provided a kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, by following weight
The raw material of part is made：70 parts of oyster shell whiting, 45 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, 5 parts of surfactant, hydroxypropyl methyl are fine
5 parts of dimension element, 6 parts of aluminium hydroxide, 20 parts of calcium oxide, 3 parts of magnesium silicate, 7 parts of zeolite powder, 6 parts of polyvinyl alcohol, 2 parts of nano-calcium carbonate,
1 part of titanium dioxide, 2 parts of polyethylene glycol, 1 part of turpentine oil, 2 parts of chitosan, 1 part of trien, 0.2 part of sodium fluoride, water-based silicon
0.2 part of oil, 2 parts of defoamer, 1 part of dispersant, 4 parts of propane diols, 50 parts of deionized water.
In the embodiment of the present invention, there is provided a kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, by following weight
The raw material of part is made：65 parts of oyster shell whiting, 55 parts of pure-acrylic emulsion, 45 parts of styrene-acrylic emulsion, 10 parts of surfactant, hydroxypropyl methyl are fine
8 parts of dimension element, 10 parts of aluminium hydroxide, 20 parts of calcium oxide, 5 parts of magnesium silicate, 8 parts of zeolite powder, 9 parts of polyvinyl alcohol, nano-calcium carbonate 4
Part, 1.5 parts of titanium dioxide, 2.5 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, 2 parts of trien, 0.8 part of sodium fluoride,
Water-based 0.4 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 4 parts of propane diols, 50 parts of deionized water.
In the embodiment of the present invention, there is provided a kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, by following weight
The raw material of part is made：70 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, 6 parts of surfactant, hydroxypropyl methyl are fine
8 parts of dimension element, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, 8 parts of polyvinyl alcohol, 3 parts of nano-calcium carbonate,
1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, 2 parts of trien, 0.5 part of sodium fluoride, water-based silicon
0.3 part of oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；The surfactant is laruyl alcohol polyoxy
Vinethene and Cocoamidopropyl betaine, the proportioning of the two are 4:3.
Another aspect of the present invention is related to a kind of preparation method of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting, including following step
Suddenly：
（1）It is spare that each component is weighed respectively；
（2）Deionized water is heated to 40-60 DEG C, adds hydroxypropyl methyl cellulose, polyethylene glycol, polyvinyl alcohol, shell
Glycan, in the fully dispersed dissolvings of 300~500 turns/min, forms uniform solution, is cooled to room temperature；
（2）Oyster shell whiting, magnesium silicate, zeolite powder, aluminium hydroxide, titanium dioxide, calcium oxide are added into the homogeneous of step 1) formation
In solution, in the case where there is water cooling using 1000~2000 turns/min high speed dispersions 10~30 minutes, after being uniformly dispersed
It is sanded at a high speed under 2000~3000 turns/min, fineness is less than 50 μm；
（3）Then surfactant, sodium fluoride, water-based silicone oil, turpentine are added under 500~1000 turns/min moderate rotations
Oil, defoamer, propane diols, add pure-acrylic emulsion and styrene-acrylic emulsion, stir evenly；
（4）It is eventually adding nano-calcium carbonate, trien, dispersant and adjusts viscosity to 85~100KU, is sufficiently stirred
After uniformly, finished product is obtained.
3rd aspect, the invention further relates to the environmentally friendly oyster shell whiting functional coating in exterior wall finishing, field of coating
Purposes.
Environment-friendlyexterior exterior wall paint wearability of the present invention containing oyster shell whiting is good, strong adhesive force, anti-aging, acid and alkali-resistance, together
When there is formaldehyde, environmentally protective, wide market nontoxic to human body.It can be used conventional method as sprayed, brush
The coating of the present invention is administered on exterior wall to be protected by the methods of painting, is acted on so as to fulfill functional protection.
It is and existing as described above, the present invention provides the Environment-friendlyexterior exterior wall paint containing oyster shell whiting, preparation method and its usage
Technology is compared, and the oyster shell whiting Environment-friendlyexterior exterior wall paint is used by a variety of certain material combinations, effectively improves the property of coating
Can, the effect of synergy is also unexpectedly shown between each component, there is quite varied actual application value.
Embodiment
Embodiment 1：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, surface
6 parts of activating agent, 8 parts of hydroxypropyl methyl cellulose, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, poly- second
8 parts of enol, 3 parts of nano-calcium carbonate, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, trien 2
Part, 0.5 part of sodium fluoride, water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surface
Activating agent is ethoxylated dodecyl alcohol and Cocoamidopropyl betaine, and the proportioning of the two is 4:3；
The preparation method of the wherein described oyster shell whiting includes the following steps：
（1）Shell is spare with clear water cleaning, drying；The shellfish of 0.5mm is crushed to using high speed disintegrator or ball mill
The thick micro mist of shell；
（2）The thick micro mist of shell is placed in high temperature resistance furnace and carries out calcining expanding treatment, calcining is forged using three-stage gradient
Burn, specific calcination operation is：（a）Calcining 30min is carried out at 400 DEG C；（b）800 are warming up to the heating rate of 10 DEG C/min
DEG C, and insulation calcining 30min at such a temperature；（c）1200 DEG C are warming up to the heating rate of 5 DEG C/min, and at such a temperature
Insulation calcining 60min, after calcination, cooled to room temperature；
（3）Puffing rear thick micro mist will be calcined and carry out nanometer pulverization processing using nano grinder, to obtain the final product；
Wherein, the preparation process of the zeolite powder is：With natural zeolite, magnesia, zinc oxide, silica according to 4:
1:1：1 mass ratio is uniformly mixed, and is then heated to 900 DEG C of progress calcining at constant temperature, naturally cold when calcination time is 3 small
But to obtain the final product；
The preparation method of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting, includes the following steps：
（1）It is spare that each component is weighed respectively；
（2）Deionized water is heated to 50 DEG C, hydroxypropyl methyl cellulose, polyethylene glycol, polyvinyl alcohol, shell is added and gathers
Sugar, in the fully dispersed dissolvings of 500 turns/min, forms uniform solution, is cooled to room temperature；
（2）Oyster shell whiting, magnesium silicate, zeolite powder, aluminium hydroxide, titanium dioxide, calcium oxide are added into the homogeneous of step 1) formation
In solution, 2000 turns/min high speed dispersions are used in the case where there is water cooling 20 minutes, after being uniformly dispersed under 3000 turns/min
It is sanded at a high speed, fineness is less than 50 μm；
（3）Then surfactant, sodium fluoride are added under 1000 turns/min moderate rotations, water-based silicone oil, turpentine oil, is disappeared
Infusion, propane diols, add pure-acrylic emulsion and styrene-acrylic emulsion, stir evenly；
（4）It is eventually adding nano-calcium carbonate, trien, dispersant and adjusts viscosity to 100KU, stirs
Afterwards, finished product is obtained.
Embodiment 2：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：It is made from the following raw materials in parts by weight：70 parts of oyster shell whiting, pure-acrylic emulsion
45 parts, 35 parts of styrene-acrylic emulsion, 5 parts of surfactant, 5 parts of hydroxypropyl methyl cellulose, 6 parts of aluminium hydroxide, 20 parts of calcium oxide, silicon
Sour 3 parts of magnesium, 7 parts of zeolite powder, 6 parts of polyvinyl alcohol, 2 parts of nano-calcium carbonate, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 1 part of turpentine oil,
2 parts of chitosan, 1 part of trien, 0.2 part of sodium fluoride, water-based 0.2 part of silicone oil, 2 parts of defoamer, 1 part of dispersant, the third two
4 parts of alcohol, 50 parts of deionized water；Surfactant is ethoxylated dodecyl alcohol and Cocoamidopropyl betaine, the two is matched somebody with somebody
Than for 4:3；
The preparation method of the oyster shell whiting includes the following steps：
（1）Shell is spare with clear water cleaning, drying；The shell of 1mm is crushed to using high speed disintegrator or ball mill
Thick micro mist；
（2）The thick micro mist of shell is placed in high temperature resistance furnace and carries out calcining expanding treatment, calcining is forged using three-stage gradient
Burn, specific calcination operation is：（a）Calcining 50min is carried out at 400 DEG C；（b）800 are warming up to the heating rate of 12 DEG C/min
DEG C, and insulation calcining 50min at such a temperature；（c）1200 DEG C are warming up to the heating rate of 5 DEG C/min, and at such a temperature
Insulation calcining 50min, after calcination, cooled to room temperature；
（3）Puffing rear thick micro mist will be calcined and carry out nanometer pulverization processing using nano grinder, obtain modified Nano shell
Powder；
The preparation process of zeolite powder includes：With natural zeolite, magnesia, zinc oxide, silica according to 5:1:1:1 matter
Then amount is heated to 800 DEG C of progress calcining at constant temperature, when calcination time is 5 small, natural cooling than being uniformly mixed to obtain the final product；
The preparation method of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, includes the following steps：
（1）It is spare that each component is weighed respectively；
（2）Deionized water is heated to 60 DEG C, hydroxypropyl methyl cellulose, polyethylene glycol, polyvinyl alcohol, shell is added and gathers
Sugar, in the fully dispersed dissolvings of 400 turns/min, forms uniform solution, is cooled to room temperature；
（2）Oyster shell whiting, magnesium silicate, zeolite powder, aluminium hydroxide, titanium dioxide, calcium oxide are added into the homogeneous of step 1) formation
In solution, 1500 turns/min high speed dispersions are used in the case where there is water cooling 20 minutes, after being uniformly dispersed under 2500 turns/min
It is sanded at a high speed, fineness is less than 50 μm；
（3）Then surfactant, sodium fluoride are added under 600 turns/min moderate rotations, water-based silicone oil, turpentine oil, is disappeared
Infusion, propane diols, add pure-acrylic emulsion and styrene-acrylic emulsion, stir evenly；
（4）It is eventually adding nano-calcium carbonate, trien, dispersant and adjusts viscosity to 90KU, stirs
Afterwards, finished product is obtained.
A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting of embodiment 3：
Formula is made from the following raw materials in parts by weight：65 parts of oyster shell whiting, 55 parts of pure-acrylic emulsion, 45 parts of styrene-acrylic emulsion, surface
10 parts of activating agent, 8 parts of hydroxypropyl methyl cellulose, 10 parts of aluminium hydroxide, 20 parts of calcium oxide, 5 parts of magnesium silicate, 8 parts of zeolite powder, gathers
9 parts of vinyl alcohol, 4 parts of nano-calcium carbonate, 1.5 parts of titanium dioxide, 2.5 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, Sanya second
2 parts of urotropine, 0.8 part of sodium fluoride, water-based 0.4 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 4 parts of propane diols, deionized water 50
Part；Surfactant is ethoxylated dodecyl alcohol and Cocoamidopropyl betaine, and the proportioning of the two is 4:3；
The preparation method of the oyster shell whiting includes the following steps：
（1）Shell is spare with clear water cleaning, drying；The shellfish of 0.5mm is crushed to using high speed disintegrator or ball mill
The thick micro mist of shell；
（2）The thick micro mist of shell is placed in high temperature resistance furnace and carries out calcining expanding treatment, calcining is forged using three-stage gradient
Burn, specific calcination operation is：（a）Calcining 30min is carried out at 400 DEG C；（b）800 are warming up to the heating rate of 8 DEG C/min
DEG C, and insulation calcining 30min at such a temperature；（c）1200 DEG C are warming up to the heating rate of 5 DEG C/min, and at such a temperature
Insulation calcining 30min, after calcination, cooled to room temperature；
（3）Puffing rear thick micro mist will be calcined and carry out nanometer pulverization processing using nano grinder, obtain modified Nano shell
Powder；
The preparation process of the zeolite includes：With natural zeolite, magnesia, zinc oxide, silica according to 6:1:1:1
Mass ratio be uniformly mixed, be then heated to 1000 DEG C progress calcining at constant temperature, calcination time for 5 it is small when, natural cooling is
；
A kind of preparation method of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting, includes the following steps：
（1）It is spare that each component is weighed respectively；
（2）Deionized water is heated to 40 DEG C, hydroxypropyl methyl cellulose, polyethylene glycol, polyvinyl alcohol, shell is added and gathers
Sugar, in the fully dispersed dissolvings of 300 turns/min, forms uniform solution, is cooled to room temperature；
（2）Oyster shell whiting, magnesium silicate, zeolite powder, aluminium hydroxide, titanium dioxide, calcium oxide are added into the homogeneous of step 1) formation
In solution, 1000 turns/min high speed dispersions are used in the case where there is water cooling 30 minutes, after being uniformly dispersed under 3000 turns/min
It is sanded at a high speed, fineness is less than 50 μm；
（3）Then surfactant, sodium fluoride are added under 1000 turns/min moderate rotations, water-based silicone oil, turpentine oil, is disappeared
Infusion, propane diols, add pure-acrylic emulsion and styrene-acrylic emulsion, stir evenly；
（4）It is eventually adding nano-calcium carbonate, trien, dispersant and adjusts viscosity to 100KU, stirs
Afterwards, finished product is obtained.
Embodiment 4：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, surface
6 parts of activating agent, 8 parts of hydroxypropyl methyl cellulose, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, poly- second
8 parts of enol, 3 parts of nano-calcium carbonate, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, trien 2
Part, 0.5 part of sodium fluoride, water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surface
Activating agent is Tween 80 and Cocoamidopropyl betaine, and the proportioning of the two is 4:3；
Other are the same as embodiment 1.
Embodiment 5：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, surface
6 parts of activating agent, 8 parts of hydroxypropyl methyl cellulose, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, poly- second
8 parts of enol, 3 parts of nano-calcium carbonate, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, trien 2
Part, 0.5 part of sodium fluoride, water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surface
Activating agent is ethoxylated dodecyl alcohol and Cocoamidopropyl betaine, and the proportioning of the two is 2:3；
Other are the same as embodiment 1.
Embodiment 6：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, surface
6 parts of activating agent, 8 parts of hydroxypropyl methyl cellulose, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, poly- second
8 parts of enol, 3 parts of nano-calcium carbonate, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, trien 2
Part, 0.5 part of sodium fluoride, water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surface
Activating agent is ethoxylated dodecyl alcohol and Cocoamidopropyl betaine, and the proportioning of the two is 4:3；
Oyster shell whiting and zeolite powder use commercial product, other are the same as embodiment 1.
Comparative example 1：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 85 parts of styrene-acrylic emulsion, 6 parts of surfactant, hydroxypropyl
8 parts of ylmethyl cellulose, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, 8 parts of polyvinyl alcohol, nano-sized carbon
Sour 3 parts of calcium, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, 2 parts of trien, sodium fluoride 0.5
Part, water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surfactant is bay
Alcohol polyoxyethylene ether and Cocoamidopropyl betaine, the proportioning of the two are 4:3；
Other are the same as embodiment 1.
Comparative example 2；A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 85 parts of pure-acrylic emulsion, 6 parts of surfactant, hydroxypropyl
8 parts of ylmethyl cellulose, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, 8 parts of polyvinyl alcohol, nano-sized carbon
Sour 3 parts of calcium, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, 2 parts of trien, sodium fluoride 0.5
Part, water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surfactant is bay
Alcohol polyoxyethylene ether and Cocoamidopropyl betaine, the proportioning of the two are 4:3；
Other are the same as embodiment 1.
Comparative example 3：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, surface
6 parts of activating agent, 8 parts of hydroxypropyl methyl cellulose, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, poly- second
8 parts of enol, 3 parts of nano-calcium carbonate, 1 part of titanium dioxide, 3 parts of turpentine oil, 2 parts of chitosan, 2 parts of trien, sodium fluoride 0.5
Part, water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surfactant is bay
Alcohol polyoxyethylene ether and Cocoamidopropyl betaine, the proportioning of the two are 4:3；
Other are the same as embodiment 1.
Comparative example 4：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, surface
6 parts of activating agent, 8 parts of hydroxypropyl methyl cellulose, 6 parts of aluminium hydroxide, 15 parts of calcium oxide, 4 parts of magnesium silicate, 8 parts of zeolite powder, poly- second
8 parts of enol, 3 parts of nano-calcium carbonate, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of trien, sodium fluoride
0.5 part, water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surfactant is the moon
Cinnamic alcohol polyoxyethylene ether and Cocoamidopropyl betaine, the proportioning of the two are 4:3；Other are the same as embodiment 1.
Comparative example 5：A kind of preparation of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting：
Formula is made from the following raw materials in parts by weight：80 parts of oyster shell whiting, 50 parts of pure-acrylic emulsion, 35 parts of styrene-acrylic emulsion, surface
6 parts of activating agent, 8 parts of hydroxypropyl methyl cellulose, 6 parts of aluminium hydroxide, 4 parts of magnesium silicate, 15 parts of calcium oxide, 8 parts of zeolite powder, poly- second
8 parts of enol, 3 parts of nano-calcium carbonate, 1 part of titanium dioxide, 2 parts of polyethylene glycol, 3 parts of turpentine oil, 2 parts of chitosan, 0.5 part of sodium fluoride,
Water-based 0.3 part of silicone oil, 2 parts of defoamer, 2 parts of dispersant, 5 parts of propane diols, 50 parts of deionized water；Surfactant gathers for laruyl alcohol
Ethylene oxide ether and Cocoamidopropyl betaine, the proportioning of the two are 4:3；Other are the same as embodiment 1.
1 wear-resisting property of test example is tested
Exterior coating is respectively coated in steel substrate, spray gun pressure during coating is 0.3MPa, and coating thickness is about
0.3mm, after the completion of coating, steel substrate is dried 35 minutes at 60 DEG C, is then placed in 88 DEG C of baking oven and is done again
Dry, curing, after curing completion and fully drying, cooled to room temperature, obtains the paint coatings in steel substrate.
The wearability of each coating is measured according to the measuring method in standard GB/T 1768-79, concrete operations are such as
Under：The steel substrate for being attached with each coating is fixed on the working rotary table of wear resistant instrument, applies having for 500g in pressing arm
Load is imitated, with identical 500 circle of rotating speed polishing, is weighed, so as to calculate waste.Test result is as shown in table 1 below.
Table 1
| Group | Wear weight loss（g） |
| Embodiment 1 | 0.0007 |
| Embodiment 2 | 0.0006 |
| Embodiment 3 | 0.0008 |
| Embodiment 4 | 0.0025 |
| Embodiment 5 | 0.0016 |
| Embodiment 6 | 0.0031 |
| Comparative example 1 | 0.0286 |
| Comparative example 2 | 0.0205 |
| Comparative example 3 | 0.0178 |
| Comparative example 4 | 0.0183 |
| Comparative example 5 | 0.0238 |
It can be drawn from the data in table 1,1-6 of the embodiment of the present invention is respectively provided with stronger wearability, while uses this hair
The particular surface activity and its proportioning of bright selection, and use ad hoc approach prepare oyster shell whiting and zeolite powder and can also improve coating
Performance；Meanwhile data are also shown that each component of the present invention mutually cooperates with table 1, interaction plays a role jointly, omits wherein
One kind can cause wearability to decline.
2 purifying formaldehyde performance test of test example
According to JC/T1074-2008《Indoor air purification material function coating material purifying property》The standard side of defined
Formula tests the air purification effect of preparation-obtained exterior coating, by measuring under fluorescent lamp before confined space experiment
With 24 when small after concentration of formaldehyde and final formaldehyde removing rate is calculated, it is specific calculate it is as follows：Formaldehyde removing rate (%)=
(concentration of formaldehyde after when initial concentration of formaldehyde -24 is small)/initial concentration of formaldehyde × 100%.Final removing result such as table 2 below institute
Show.
Table 2
| Group | Formaldehyde removing rate（%） |
| Embodiment 1 | 99.76 |
| Embodiment 2 | 99.90 |
| Embodiment 3 | 99.82 |
| Embodiment 4 | 97.35 |
| Embodiment 5 | 97.86 |
| Embodiment 6 | 97.25 |
| Comparative example 1 | 83.68 |
| Comparative example 2 | 84.93 |
| Comparative example 3 | 86.95 |
| Comparative example 4 | 85.84 |
| Comparative example 5 | 86.93 |
It can be drawn from the data in table 2,1-6 of the embodiment of the present invention is respectively provided with stronger formaldehyde removing effect, adopts at the same time
With the particular surface activity of the invention selected and its match, and prepare oyster shell whiting and zeolite powder using ad hoc approach can also improve
The performance of coating；Meanwhile data are also shown that each component of the present invention mutually cooperates with table 2, interaction plays a role jointly, saves
Slightly one of which can cause formaldehyde removing rate to decline.
Claims (7)
1. a kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting, is made from the following raw materials in parts by weight：60-80 parts of oyster shell whiting, pure third
40-60 parts of lotion, 30-50 parts of styrene-acrylic emulsion, 5-10 parts of surfactant, 5-10 parts of hydroxypropyl methyl cellulose, aluminium hydroxide
5-10 parts, 10-20 parts of calcium oxide, 3-5 parts of magnesium silicate, 5-10 parts of zeolite powder, 5-10 parts of polyvinyl alcohol, 1-5 parts of nano-calcium carbonate,
1-2 parts of titanium dioxide, 1-3 parts of polyethylene glycol, 1-3 parts of turpentine oil, 1-3 parts of chitosan, 1-3 parts of trien, sodium fluoride
0.1-1 parts, water-based silicone oil 0.1-0.5 parts, 1-3 parts of defoamer, 1-3 parts of dispersant, 3-5 parts of propane diols, deionized water 30-50
Part；The surfactant is ethoxylated dodecyl alcohol and Cocoamidopropyl betaine, and the proportioning of the two is 4:3；Institute
The zeolite powder stated is modified zeolite powder, and the preparation process of the modified zeolite powder includes：With natural zeolite, magnesia, zinc oxide, two
Silica is according to 3-6:1:1：1 mass ratio is uniformly mixed, and is then heated to 800 DEG C of -1000 DEG C of progress calcining at constant temperature, is forged
When the burning time is 2-6 small, natural cooling to obtain the final product.
A kind of 2. Environment-friendlyexterior exterior wall paint containing oyster shell whiting described in claim 1, wherein the oyster shell whiting is modified Nano
Oyster shell whiting, its preparation method include the following steps：
（1）Shell is spare with clear water cleaning, drying；The shell of 0.1-1mm is crushed to using high speed disintegrator or ball mill
Thick micro mist；
（2）The thick micro mist of shell is placed in high temperature resistance furnace and carries out calcining expanding treatment, calcining is calcined using three-stage gradient, tool
Body calcination operation is：（a）Calcining 30-60min is carried out at 400 DEG C；（b）800 are warming up to the heating rate of 8-12 DEG C/min
DEG C, and insulation calcining 30-60min at such a temperature；（c）1200 DEG C are warming up to the heating rate of 5-8 DEG C/min, and in the temperature
The lower insulation calcining 30-60min of degree, after calcination, cooled to room temperature；
（3）Puffing rear thick micro mist will be calcined and carry out nanometer pulverization processing using nano grinder, obtain modified Nano oyster shell whiting.
A kind of 3. Environment-friendlyexterior exterior wall paint containing oyster shell whiting described in claim 2, wherein the shell is mussel shell, scallop
Shell, oyster shell, cycle of sixty years shell, Corbicula fluminea shell.
A kind of 4. Environment-friendlyexterior exterior wall paint containing oyster shell whiting described in claim 1, wherein the granularity of the magnesium silicate is 0.5
Micron is following.
A kind of 5. Environment-friendlyexterior exterior wall paint containing oyster shell whiting described in claim 1, wherein the defoamer is poly dimethyl
Siloxanes or tributyl phosphate.
A kind of 6. Environment-friendlyexterior exterior wall paint containing oyster shell whiting described in claim 1, wherein the dispersant is polyphosphoric acids
One or more in sodium, calgon, sodium pyrophosphate, lauryl sodium sulfate.
7. a kind of preparation method of the Environment-friendlyexterior exterior wall paint containing oyster shell whiting of claim 1-6 any one of them, including it is as follows
Step：
（1）It is spare that each component is weighed respectively；
（2）Deionized water is heated to 40-60 DEG C, adds hydroxypropyl methyl cellulose, polyethylene glycol, polyvinyl alcohol, chitosan,
In the fully dispersed dissolvings of 300~500 turns/min, uniform solution is formed, is cooled to room temperature；
（3）Oyster shell whiting, magnesium silicate, zeolite powder, aluminium hydroxide, titanium dioxide, calcium oxide are added into the uniform solution that step 1) is formed
In, in the case where there is water cooling using 1000~2000 turns/min high speed dispersions 10~30 minutes, after being uniformly dispersed 2000~
It is sanded at a high speed under 3000 turns/min, fineness is less than 50 μm；
（4）Then under 500~1000 turns/min moderate rotations add surfactant, sodium fluoride, water-based silicone oil, turpentine oil,
Defoamer, propane diols, add pure-acrylic emulsion and styrene-acrylic emulsion, stir evenly；
（5）It is eventually adding nano-calcium carbonate, trien, dispersant and adjusts viscosity to 85~100KU, stirs
Afterwards, finished product is obtained.
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| CN201810074608.7A CN108342138B (en) | 2016-04-06 | 2016-04-06 | Preparation method of modified shell powder |
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| CN108342138A (en) | 2018-07-31 |
| CN105602383A (en) | 2016-05-25 |
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